Slashdot Mirror


High-Temp Superconducting Tape

DrLudicrous writes "The NYTimes is running a little overview of the current state of mass produced superconducting materials. A company named Superpower (another blurb on them here) is making a layered superconducting tape out of ceramic materials- ceramics that are high-temperature superconductors (no resistance at liquid nitrogen temperatures, 77K). This is much cheaper to maintain than technologies based on superconducting metals, which tend to require liquid helium (~4 Kelvin) temperatures. A note of contention: the article mentions that superconductivity is not well understood -- high-temperature superconductors are not, but classical 'low-temperature' superconductors are well-described under the Bardeen-Cooper-Schrieffer (BCS) theory."

37 comments

  1. Still only liquid nitrogen temps? by dankjones · · Score: 4, Interesting

    Man! We had that when I was in high school (late `80's)

    Looks like room temperature superconductivity is impossible. Have we made any progress in new superconducting materials in the last 15 years?

    1. Re:Still only liquid nitrogen temps? by PaulBu · · Score: 4, Informative

      Search for MgB2 , though it is not much better (except possibly for digital apps where HTS sucked big time...)

      And I actually used to work in SCE...

      Paul B.

    2. Re:Still only liquid nitrogen temps? by deglr6328 · · Score: 3, Informative

      Pardon, but wtf are you talking about?

      Search for MgB2...

      Yes....and...? MgB2 is a standard low temp. superconductor with a Tc of only ~40 Kelvin. ...except possibly for digital apps where HTS sucked big time

      Whaaa? HTS (high temp. superconductors) are perfectly suited to "digital apps" in many situations. A company called STI makes HT superconducting filters for cell phone antennas in order to increase data bandwidth and and decrease service dropout by making their recievers more sensitive. And Josephson Junctions make up some of the fastest digital IC's in existance at many hundreds of gigahertz.

      And I actually used to work in SCE...

      Am I the only one who has no idea what this is?

      --
      - "Hear that?! The percolations are imminent! Cease your ingress!"
    3. Re:Still only liquid nitrogen temps? by Arngautr · · Score: 1

      Not sure what "SCE" is either but a google search might yield some clues... Sony Computer Entertainment...no SCE Gaskets, Inc....no Sydney College of English...no . . . hmmm.. just a guess but Super Conducting Electronics? Whatever it is it's also a very common accronym.

    4. Re:Still only liquid nitrogen temps? by deglr6328 · · Score: 3, Informative

      It's worth noting that there are no theories (so far as I've heard anyway) that expressly forbid superconductivity at room temperature. The BCS theory of conventional superconductors forbids Tc's beyond about ~50K if I recall correctly, but high temp. superconductors don't follow BCS and have much higher Tc's, who knows if there's another class of electron superconductors with even higher Tc's. In fact it is thought that certain parts of the insides of neutron stars have superconducting protons floating around in a sea of superfluid neutrons at many millions of Kelvin!!

      --
      - "Hear that?! The percolations are imminent! Cease your ingress!"
    5. Re:Still only liquid nitrogen temps? by pfdietz · · Score: 2, Informative

      Actually, magnesium diboride is much easier to work with than the HTSCs. It doesn't have the grain boundary problems that bedevil the latter. Even better, its normal state conductivity at low temperature is close to that of copper (and something like 20 times that of niobium-tin), making the material much more resistant to damage during quenches.

    6. Re:Still only liquid nitrogen temps? by Anonymous Coward · · Score: 0

      As an ex-physicist (and an ex-physicist in that
      particular field actually), I can tell you the actual temperature is all sensationalist
      reporting; what is important commercially is
      the cost of coolant. Liquid nitrogen is
      cheap (made from air). Liquid oxygen is
      also cheap, but it is another 10 degrees
      lower, so it doesn't
      count. The next one up from liquid nitrogen
      which is cheap to produce is actually dry-ice (i.e. solid carbon dioxide, also made from air - therefore it is cheap).

      Unless you can reach dry-ice temperature
      (-30 celsius-ish), how much up from liquid
      nitrogen temperature (-200 celsius -ish)
      isn't really going to change much about how
      superconductivity is used in daily life.
      You can't use save money on electical
      energy and waste it on making coolant to keep
      it operating. Just not economically viable.

      Good heat insulation can only do so much. The
      rest you have to relie on the coolant evaporating
      and keeping your stuff cold (at the temperature
      of evoporation, until you exhaust all your coolant).

    7. Re:Still only liquid nitrogen temps? by PaulBu · · Score: 3, Informative

      MgB2 is a standard low temp. superconductor with a Tc of only ~40 Kelvin.

      As pfdietz pointed out below, MgB2 is so much easier to work with than HTS ceramics. Its discovery is considered the next big thing in the field since the discovery of high-temperature superconductivity, not because of increased Tc, but because it can be deposited using standard semiconductor tools and one does not have to worry about grain size/orientation/etc.


      Whaaa? HTS (high temp. superconductors) are perfectly suited to "digital apps" in many situations. A company called STI makes HT superconducting filters for cell phone antennas in order to increase data bandwidth and and decrease service dropout by making their recievers more sensitive.


      STI/Conductus filters are purely passive devices, there is not a single Josephson junction nor a single cold logic gate. As a matter of fact filters themselves are rather simple, their main achievement is development and mass-production of relatively low cost and reliable cryocoolers. And of course they are not used in "cell phone antennas", rather in "cell phone *base station* antennas", big difference! :-)

      But when I was talking about "digital" I meant exactly the stuff from your second link. Search for a guy named Paul Bunyk there , look at my user ID and then decided if I have something to say about those matters... ;-)

      Am I the only one who has no idea what this is? SuperConductor Electronics.

      Paul B.

    8. Re:Still only liquid nitrogen temps? by deglr6328 · · Score: 1

      OK then, that clears things up considerably. :)

      --
      - "Hear that?! The percolations are imminent! Cease your ingress!"
  2. Re:For what? by Anonymous Coward · · Score: 1, Funny

    You could convince the nuttier audiophiles to wire their speakers with it.

  3. Irritating article snippets by Daniel+Dvorkin · · Score: 4, Insightful

    Fascinating stuff, but some of what's in the article really makes me grit my teeth. I love this bit:

    Even now, they have yet to develop a comprehensive theory to explain its appearance in materials as diverse as metal and ceramics.

    Such scientific conundrums are of only passing interest at Superpower, a four-year-old subsidiary of Intermagnetics General, and at other companies like it. After years of false starts and setbacks, these companies say they are closing in on the goal of producing relatively inexpensive superconducting wire for power generators, transformers and transmission lines.

    Success requires making yard after yard of wire, and eventually mile after mile. The focus at the companies, at national laboratories and at many universities is on questions that call for a genius more like Edison than Einstein.


    Uh, bullshit. If they don't understand how it works, they're never going to move this stuff beyond the applications possible at liquid nitrogen temps. I'm not selling that short -- it's neat, and has a number of industrial applications -- but we're not going to be making power lines, or even wiring our houses, with that kind of cooling.

    --
    The correlation between ignorance of statistics and using "correlation is not causation" as an argument is close to 1.
    1. Re:Irritating article snippets by stvangel · · Score: 4, Insightful
      Success requires making yard after yard of wire, and eventually mile after mile. The focus at the companies, at national laboratories and at many universities is on questions that call for a genius more like Edison than Einstein.

      Uh, bullshit. If they don't understand how it works, they're never going to move this stuff beyond the applications possible at liquid nitrogen temps. I'm not selling that short -- it's neat, and has a number of industrial applications -- but we're not going to be making power lines, or even wiring our houses, with that kind of cooling.

      I tend to disagree. Edison, arguably one of the greatest and most prolific inventors, wasn't really an scientific man and didn't understand how many of the things he discovered really worked. He was very persistent and intuitive in the way he would develop things. He'd just keep plugging away at different experiments till he found something that worked. Many famous inventions were an accidental discovery that worked without really understanding the underlying physics. Vulcanized Rubber, Penicillin, and even high-temperature superconductors themselves come immediately to mind. The majority of medicines and drugs were all developed this way. The first of the high-temperature semiconductors was found this way and was against everything known about semiconductors at the time. Many initial breakthrough discoveries were initially called impossible or impractical by conventional knowledge.

      There is nothing to say there will even be superconductors at much higher temperatures anyway. What we really needed is an innovative thinker who can come up a unique way of using the existing superconductors we have. Perhaps an innovative refrigeration process to keep them cool in practical applications... Perhaps blending them with non-superconducting materials to make a semi-superconducting material with much higher strength and current carrying capacity? What about a way of encapsulating them in something like a nested Peltier Junction to keep the interior at superconducting temperatures? What about a way to incorporate the superconductors into the junction itself? There are many possibilities to experiment with. Even if you don't discover what you're looking for, there are lots of other things you might find.
    2. Re:Irritating article snippets by barawn · · Score: 2, Informative

      but we're not going to be making power lines

      Thankfully there are others who aren't as paranoid as you are about physics we don't quite understand theoretically, but do understand phenomenologically, as we already have power lines made out of this stuff.

      Here are several press releases about it: Copenhagen, Chicago, and Detroit already are laying high-Tc superconducting cable. They're already in use at Copenhagen. And that was in 2001.

      The mass and resistive loss savings by going to superconductors can easily pay for the excess cooling equipment and cost, if the scale is right. And when you're talking about kilo-amperes, that scale is right.

    3. Re:Irritating article snippets by pfdietz · · Score: 2, Interesting

      Another saving with SC cables is volume. In many cities there is a severe space crunch in underground cable runs. Digging new ones is very expensive. If the SC cables have a higher average current density than conventional cables (and they do, even counting the space occupied by thermal insulation and coolant channels), then they can pay for themselves.

  4. REAL TROLL!!! by PaulBu · · Score: 0, Offtopic

    (Thorugh got the FP... ;-( )

    Please mod accordingly...

    Paul B.

  5. Super Conduction by Arngautr · · Score: 3, Interesting

    That floating magnet experiment/demonstration they describe is one of the coolest physics phenomena I've witnessed, for those without subscriptions you chill the superconductor below its critical temperature and place a small magnet with high magnetic field strength to mass ratio above the superconductor and it floats or sits in mid air spining slightly, pretty cool to see.

    This article is low on actual content, it fails to even mention what the Tc is for this tape. The highest Tc I'm aware of is in the 130K while room temperature is on the order of 300K. If we can find materials with high enough Tc and without bad qualities it will revolutionize the world, imagine an electric motor with near zero resistance, unfortunately it could be used for evil too.

    1. Re:Super Conduction by krymsin01 · · Score: 2, Funny

      Yes, like making it easier for people to never have to walk again because the tech will exist for them to have floating body suits like that Baron guy.

      --
      stuff
  6. Re:For what? by Urkki · · Score: 1

    That's just a matter of cost.

    The article states that "Superpower's next generation tape has a pre-mass production cost of $50 kA/m". That's $50 for a meter of wiring able to carry 1000 amps.

    Hardly a neglible current, though cost is probably hundreds of times more than equal current carrying capacity with copper wire.

  7. bullshit by Anonymous Coward · · Score: 0

    Maybe he is wrong, but he isn't a troll. People like you, who moderate everything they don't like or disagree with as "troll", are the real problem on Slashdot.

    If you disagree with the guy, make an informed, well-reasoned response, instead of the bullshit you actually wrote.

  8. Re:For what? by Yarn · · Score: 2, Interesting

    Electrons are not bled out of materials as the temperature decreases. In semiconductors they do indeed become less mobile, increasing resistance, but in true conductors they become more mobile, as there are fewer lattice vibrations to get in the way (a simplistic metaphor, of course).

    At extremely low temperatures the electrons pair up, which leads to superconductivity in metals. The amount of power which can be transferred is very high. These pairs are very easily broken apart, which is why superconductors are not perfect reflectors, any light breaks the pairs. IIRC it also limits the power that can be transferred over a superconductor.

    --
    -Yarn - Rio Karma: Excellent
  9. Re:For what? by pfdietz · · Score: 2, Insightful

    Where did you get the weird (and completely incorrect) belief that 'electrons get bled out of materials as the temperature decreases'?

  10. Re:For what? by CodeMonkey4Hire · · Score: 2, Interesting

    I don't know what you mean by bloody electrons (is that a British thing?).

    As far as potential applications - they are numerous. Without thinking very hard a couple came immediately to mind.

    (1) Electro-magnets - there are a lot of applications in medical and theoretical physics that require strong magnetic fields. Assuming that high-temp superconductors can be found whose properties don't break down under higher magnetic fields, superconductors could be used to create magnets stronger than any that we currently have.

    (2) Particle detectors. If you have a superconducting loop and a charged particle passes through it, it will induce an EMF on the loop, causing a current to circulate. Since there is no resistance (i.e. no signal degradation), the current is much easier to detect and measure.

    (3) MagLev anyone? Not on tape I guess, but levitating trains would be really nice. Then again, the previous ideas probably don't work very well with tape, but anything that helps move the field forward is bound to help.

    I'm sure there are plenty of more interesting applications than these.

    --

    Let's go Hurricanes!!! 2006 Stanley Cup Champions!!!
  11. High Hemp Superconducting Tape by Anonymous Coward · · Score: 0

    That's what I read that as anyway.

  12. Re:For what? by Anonymous Coward · · Score: 0

    Hundreds of times more? Not even close.

  13. High Tc Superconductivity explained by Goldsmith · · Score: 3, Interesting

    High Tc superconductivity actaully has the begginings of a good theory to explain it.

    In BCS theory, electrons interact with phonons (lattice vibrations) to coordinate into pairs and form bosons.

    In much the same way, electrons in high Tc superconductors interact with spin waves in an antiferromagnetic material to coordinate into pairs and form bosons.

    An antiferromagnetic material is one where the magnetic moments of neighboring atoms are opposite

    up down up down up down up down up

    You could imagine trying to move the middle electron over one position (trade with the electron to its right):

    up down up down down up up down up

    Now our magnetic order is screwed up, and this defect can propogate:

    up down down up down up down up up

    Each pair of "up up" or "down down" next to eachother is a spin wave, which is a boson, with a spin of 1.

    Of course, really proving this theoretically is much harder, I don't think it's been done in 3D.

    1. Re:High Tc Superconductivity explained by Anonymous Coward · · Score: 0

      You mean the sub ionic polarization of the material is not in phase with the energy wave function due to environmental interference resonance (generic EM radiation like heat which excitates material ion fields) - this could be isolated using high density magnetic fields, 3d is not in question, try 5 or 6th dimensions ordering to accomodate a denser field in 3 dims mapping in a straight line wire. Dont you ever watch star trek? Did that make sense? As far as your up down hick ups ;) try some quantum cellular automata to see how patterns can develop. What kind of latices are we talking about? How many light years off am I from reality?

  14. Re:For what? by Anonymous Coward · · Score: 0
    Hundreds of times more? Not even close.

    Not sure what you mean. I agree the grandparent post was wrong. Starting from 12-guage 3-wire romex I get $20 kA/m for copper, but I'm not sure I did the math right.

  15. Re:For what? by Urkki · · Score: 1
    • I agree the grandparent post was wrong. Starting from 12-guage 3-wire romex I get $20 kA/m for copper, but I'm not sure I did the math right.

    Interesting. Is copper really that expensive?

    Or was that retail price for a small quantity, and you'd get it for some fraction of that if you ordered a few km of it?

    (Not expecting a reply from an AC poster, but perhaps someone who happens to read this knows about the stuff too.)
  16. Re:For what? by barawn · · Score: 3, Interesting

    Interesting. Is copper really that expensive?

    Yes, actually. It's about $20-25/kAm right now.

    But it's the recurring cost that's a big deal: at kiloampere levels, the power burned off by copper resistance starts to become more expensive than the cost of cooling. Since superconductors have strictly zero resistance, the cooling cost is fixed as the current scales, whereas it's linear in copper. At some point it becomes more economical.

    The problem with high-Tc superconductors is that they have a current limit as well, and it's quite moderate, so the scale isn't quite there yet, when you work out all of the factors involved.

    There are other reasons to switch, though: simply physical size: in Detroit, where they're replacing copper with superconducting cable in a few areas, they're replacing 18,000 pounds of copper with 250 pounds of superconductor - they replaced 9 cables with 3, and left 6 empty cable lines. This gives them 3 times the energy capacity without having to dig new cable lines at all.

    The capacity issue is really what's been driving cities to replace them, though - digging new power lines, especially in cities, is simply ludicrously expensive, and so any option to replace with higher capacity lines without digging is a win.

    So yes, really, they will replace copper with superconductors ... and they have, actually. Copenhagen was the first, if memory serves. All of them quoted the capacity increase without digging as being the main reason. Per kA, it's probably more expensive, but the costs savings from not digging will probably make it cheaper over the lifetime of the cable.

  17. Which leads to a new law by Tau+Zero · · Score: 1

    Tau's Law: Any sufficiently clueless claim is indistinguishable from a troll.

    --
    Time is Nature's way of keeping everything from happening at once... the bitch.
  18. Re:For what? by calidoscope · · Score: 2
    >Interesting. Is copper really that expensive?

    Yes, actually. It's about $20-25/kAm right now.

    I just looked up the copper wire tables in my copy of Standard Handbook for Electrical Engineers - 1kA requires a 700mcm (mcm = 1,000 circular mils (cmils), 1 cmil is the area of a circle 0.001 inch diameter). That cable weighs about 2.2 pounds per foot, so a 1 meter long cable would be about 7.5 pounds. The latest price for copper was a bit less than $1.20/lb - so we're looking at $9/kAm.

    The resistance loss with copper can be an issue, but you need to balance it against the refrigeration requirements for supercon's.

    Probably the biggest commercial success for superconducting wire has been for NMR magnets - especially for MRI use.

    --
    A Shadeless room is a brighter room.
  19. Wrapping lines by some+guy+I+know · · Score: 1

    Say, did you know that you don't have to hit the return key when you reach the right-hand side of the text entry box?
    Your text will automatically wrap around to the next line!!
    Yes, it's true; it really, really will!
    Isn't technology wonderful?

    --
    Those who sacrifice security to condemn liberty deserve to repeat history or something. - Benjamin Santayana
  20. Re:For what? by barawn · · Score: 2, Interesting

    Do a search for "copper kAm" and you'll find the $20 /kAm figure. You're neglecting a ton of the production cost, and considering the *raw* copper cost is just $9/kAm, an additional $10/kAm for the rest of the cable is entirely reasonable. They don't just lay bare copper in the ground, after all. Most of the HTS figures they give show the rest of the cable costing about $10/kAm as well.

    The $50/kAm figure for HTS cable is the final cost for the full cable, ready to lay in the ground.

    As for the resistance loss vs refrigeration requirements, it's important to remember exactly how cheap liquid nitrogen is. *Very* cheap. In fact, going much higher in temperature really isn't economically important! I haven't seen any figures on "maintenance cost", but considering the resistive losses for copper can be large (at 1000A with the resistance of copper for a 0.8" diameter cable being ~0.02 ohms/1000', you're talking roughly 60W lost per meter) the refrigeration costs are going to be quite manageable.

  21. The secret to High Tc Superconductivity... by dankjones · · Score: 1

    Up up, down down, left right, left right, B, A, Start