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The New Chemistry

danny writes: "The New Chemistry is a survey of the science behind many of Slashdot's technology stories - read on for my review. (An older title of related interest is Chemical Evolution: Origin of the Elements, Molecules, and Living Systems )." Read on for the rest of Danny's review. The New Chemistry author Nina Hall, ed. pages 500 publisher Cambridge University Press rating 8.5 reviewer Danny Yee ISBN 0-521-45224-4 summary an overview of modern chemistry and its applications.

The New Chemistry provides an overview of modern chemistry and its applications, with seventeen review articles by specialists. Though commissioned for this volume, these take different approaches and are pitched at different levels: some are quite broadly accessible, while others assume the reader has studied chemistry at university (I found my physics and biology background helped a lot). Apart from multiple explanations of semiconduction, there is little repetition and an immense range of material is covered. The result is a fascinating picture of the science underpinning much modern technology.

The first five articles involve a fair bit of physics. "The Search for New Elements" looks at the synthesis of elements beyond uranium. "Bonding and the Theory of Atoms and Molecules" touches on a mix of theory: chemical bonds, reaction dynamics, simulation of liquids, and mathematical chemistry. "Chemistry in a New Light" and "Novel Energy Sources for Reactions" look at new tools for controlling reactions: lasers, electrosynthesis, microwaves, and ultrasound. And "What, Why and When is a Metal?" explains how the well-known criteria for distinguishing metals and insulators don't always work; this is one of the more accessible chapters, with a good selection of colour illustrations and historical "boxes."

The more "pure chemistry" chapters were the ones I had the most trouble following. These include "The Clothing of Metal Ions: Coordination Chemistry at the Turn of the Millenium," "Surface Chemistry", and "New Roads to Molecular Complexity." Other chapters connect more with biology. "Medicines from Nature" illustrates the search for new medicines through a case study of Erythromycin biosynthesis. "From Pharms to Farms" has two parts, one surveying major drugs and fragrances and the other pesticides. And "The Inorganic Chemistry of Life" is an unusual abstract overview of life from the point of view of an inorganic chemist.

A range of chapters are oriented towards engineering applications; these will be of particular interest to those following new computing technologies. "Supramolecular Chemistry" is an accessible look at the building of structures, at the chemical approach to nanotechnology. "Advanced Materials" focuses on applications to electronics - alternatives to silicon, packaging materials, liquid crystals, plastic batteries, and more - while "Molecular Electronics" focuses on actual circuits, on conductors and switches and molecular computing. "Electrochemical and Photoelectrochemical Energy Conversion" looks in detail at a range of traditional and experimental battery and fuel cell systems, and more briefly at photoelectrochemical cells and photochemical waste disposal.

"Chemistry Far from Equilibrium: Thermodynamics, Order and Chaos" is the most mathematical chapter, presenting some dynamical theory with a few examples. And a final chapter "Chemistry in Society" outlines the contributions of chemistry back to the Industrial Revolution, and urges better research both to avoid environmental problems and to correct popular misconceptions.

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8 of 58 comments (clear)

  1. Good stuff by dciman · · Score: 5, Interesting

    I own this book and it is a wonderful overview of some astonishing things. As a microbiologist I would love to see a similar title come out covering the major developments of molecular biology over the past 40 years or so. Where chem. has had quite some time to develop over the years... there has been a literal explosion of scientific data being uncovered in the world of molecular microbiology. Just think.... it wasn't untill the 1950's that the structure of DNA was established. ALL of the knowledge we have now, has developed since then... to me... that is amazing.

  2. Hope its better than the "New Economy" by chinton · · Score: 3, Funny

    What do you mean my reactions have to balance? This is the New chemistry. I'm not bound by the principles of your out-dated models.

  3. So, um, is it good? by iiii · · Score: 3, Insightful

    This is supposed to be a review, right? He tells us some objective facts about the book, but there are no conclusions or recommendations here. Does Danny recommend the book or not? If all you have to do for a book review is give the table of contents, I need to get into that industry.

    --
    Light cup, beer drink, thin so chain, neck turtle fat, man I won't say it again
    1. Re:So, um, is it good? by danny · · Score: 3, Interesting
      I think the review makes it clear I think the volume is good: "fascinating", "accessible", ... It is, however, hard to generalise about 17 rather different articles - how "good" they are likely to be depends a lot on who the reader is and what their background is.

      But some of my reviews are definitely more substantial than others, 'tis true. You might like to check out what I think is the shortest. The average review length is only 400 words, though that's been climbing slowly.

      Danny.

      --
      I have written over 900 book reviews
  4. New Elements by ackthpt · · Score: 4, Funny

    Firstpostium: Always attempts to appear at the top of the Periodic Chart, usually for no fathomable reason, frequently target of moderatium reactions.

    Taconium: Bonds readily with Kathleenium.

    Kathleenium: Bonds approx. 15 minutes later with Taconium.

    Athlonium and Pentium: Elements which increase energy levels frequently, highly exothermic, although less so as they are refined, in constant competition for best performance.

    Trollium: Densest element known to man, will react even with itself but prefers to bond to any other element.

    Moderatium: Appears in cyberspace, sometimes where least needed or bonds inappropraitely, sometimes replaced by Metamoderatium.

    Katzium: Occasionally emits photons of insight in cyberspace, frequent target of trollium reactions.

    Slashdottium: Highly radioactive, half-life ~20 minutes, when bonded to a link often replaces it with blackhole.

    Redmondium: Pervasive, claims to be more stable than linuxium, but is frequently reduced by hax0rium, replaces atomic structure every ~2 years, but still looks almost exactly the same.

    Hax0rium: Great affinity for almost any of the Techthanide or Codeinide series of elements, will often reduce or produce warzeides.

    CowboyNealium: Only exists in the margins of cyberspace, always appears last in Periodic Chart, regardless of the number of elements represented.

    --

    A feeling of having made the same mistake before: Deja Foobar
  5. Re:bitterness... by Graff · · Score: 4, Informative
    It may be just my opinion (as a former chemist turned physicist), but I think that chemists are rather limited. They're (in general) not very well versed in technological issues and the hard science -- I've found that they're usually an "end-user" of other disciplines' accomplishments.
    Well, as a former physicist turned chemist I can say that I think you're a bit off here. All professions have these sort of people and these statements you have made are true with physicists as well.

    One of the main difference between chemists and physicists is that more chemists tend to be experimentalists and more physicists tend to be theorists. That is, a good deal of chemistry is focused on physical experiments with the end goal of being able to produce physical substances. A much larger percentage of physics is focused on mathematical theory and mathematical constructs. For many more branches of physics than of chemistry the focus is on producing models rather than physical objects.

    This doesn't mean that chemists are not versed in physics or math. It's just that for many branches of chemistry the focus on higher-order physics and math is not as necessary. This is just like for physicists the focus is not on higher-order chemistry and biochemistry. Most chemists do have a good understanding of fast fourier transforms and quantum mechanics because these things are integral to the field of chemistry. I wouldn't expect, however, for a chemist to instantly know all there is to know about general or special relativity, or string theory - this are topics not vital to a chemist's job.

    Chemists do get a good share of the grant money out there, but don't discount the amounts that physicists get. There are quite a few physics centers out there that pull in the big bucks, such as Kamioka Observatory, CERN, and Fermilab, among others. Sure the total amount of money that all physics projects receive is not as much as the total that all chemistry projects receive, but people are more focused on the quicker fruits that chemistry tends to produce rather than the future fruits that physics tends to produce. This does not diminish the importance of the work of physicists and physicists should not blame chemists for getting the grant money, it's not a horse race for who can get the most cash.
  6. Re:bitterness... by Masem · · Score: 5, Insightful
    Coming from a chemical engineering background, I would argue that chemists ARE well-versed in hard sciences, more than you expect.

    You use the NMR as an example. The NMR was developed by chemists (and I believe the inventors got the Nobel a few years ago for it). Some of the technology is end-use developed from other fields (for example, spinning magnets I would expect from friends in physics), but the fundamental science that NMR uses (looking at spin coorelations between neighboring atoms in a molecule) is pure chemistry, and putting together those end-use systems as well as unique elements together in such a way to be able to capture that is what makes the NMR invention unique. This is typically the way with most chemical instrumentation.

    Now, just because NMR or other equipment that a chemist uses has a FFT in it, does it mean they need to know it? Typically not: they should be aware that the time-based signal they are collecting is being converted to frequency, which is the data of most interest, but they don't need to know all the mathematical computations that go into the FFT. That's not to say that chemists don't know it; there is a large body of chemists that overlap with mathematicians and comp scis to develop new and improve existing algorithms common in analysis. Even typical organic chemists that work mostly in a lab will know what the FFT transform is, though not necessarily being able to fully describe it.

    And I would argue heavily with chemists not knowing quantum mechanics. There's typically 4 (recently 5) unofficial divisions of chemistry: organic, inorganic, analytical, theorhetical, and of late, bio-organic; the division is heavily weighted with organcis and bio, but the other 3 divisions are about equal in terms of distribution. I'd estimate that between 5 and 10% of chemists are in theorhetical, based on my experiences at grad schools and paper outputs. And theorhetical chemists spend most of their time working with molecular simulations, quantum mechanics, and other computer tools to develop models and predictions for how matter interacts. These models certainly aren't perfect, but they do know quantum theory quite well since most of these simulations account for quantum-type effects. As for other chemists, there is a need to know what quantum theory is, but in the typical lab reaction that most chemists do, it doesn't make a big difference. So therefore, they know the quantum theory, but they never need to apply it at large.

    So I completely disagree that chemists hand-wave. A poor chemist will, but those that are trained at good graduate schools know that they can't get through doing that. But there is a point that you need to assume that the instrument or reading is correct and you don't need to understand the underlying principle in order to proceed forward; a good chemist knows how to test and calibrate an instrument to the point of being satisfied that the reading is as what should be predicted, and then will 'question' everything else beyond that.

    (And the reason for macs is that much of the best chemical structure drawing and professional graphing (!Excel) software was developed on Macs first, and while PC versions have come out to equate those versions, its hard to get academics to spend the money to switch over when what they have *works* for their needs. Also, a lot of older equipment only has software that works on specific versions of an OS, and so they are limited by that as well.)

    --
    "Pinky, you've left the lens cap of your mind on again." - P&TB
    "I can see my house from here!" - ST:
  7. Re:bitterness... by loydcc · · Score: 3, Insightful
    The original poster complains that chemists don't understand physics and then uses a math trick to illustrate his point. All the sciences stem from some mathematical model or another. I do agree with you that not all the mathematical models are needed for good chemistry.

    It comes down to Physics gets diddly, Chemistry gets some but don't forget that hands down Biology is where the grant money is. As for money it seems the further away from math you get the more the grant money.