Chemists Synthesize "Impossible" Molecule

neilest writes "Organic chemistry textbooks will need to be revised to recognize a chemical species that chemists have discovered at Northwestern University. The species -- pentamethylcyclopentadienyl cation -- was thought not to exist for long because theory said it was unstable. The full story can be found at this suntimes article"

Comments

Re:What is it?

[MarkusQ]

The artical was short, and missing one major detail...What is it?

The said it was "a pentamethylcyclopentadienyl cation" which tells you exactly what they made if you have the right secret decoder ring.

penta- means five -methyl- refers to a methane group; a methane group is a carbon with all it's free bonds capped with hydrogen.

pentamethyl- means it has five methyl- groups dangling off of it; they don't tell us where, but we'll shortly see why they didn't bother.

-cyclo- means the base structure is a ring. -penta- is five again -dienyl- means alternating single and double bonds like so ...--C==C--C==C--C==...

-cyclopentadienyl- means that it's a ring of five carbons with every other other bond double. But wait, you say, what does "every other mean" in a five element ring? Thus we get to...

-cation means it's got a positive charge, so the whole bonding picture may be off, with the double bonds playing resonance leap-frog around the ring.

So (in English) it's a positively charged ring of five carbon atoms, with a CH3 hanging off each carbon, and an average of 1.4 bonds between each pair of carbons in the ring.

As for what it's good for, that depends. It could be good for a thesis, or for tenure, or for funding, or...it all depends on where you are in the food chain.

-- MarkusQ

Explains the how a little better...

[jsimon12]

Here is an article that explains the how and why, which the article on Slashdot doesn't explai:

http://www.sciencedaily.com/releases/2002/04/02041 2074739.htm

Link to Lamberts Group

[jsimon12]

http://www.chem.northwestern.edu/~lambert/index.ht ml