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Locking CO2 Away For Good

HobbySpacer writes: "The BBC reports that waste CO2 from methane extraction in the North Sea has been succesfully pumped back into the pourous sandstone beneath the ocean for the past 6 years without any signs of leaking. Carbon sequestration techniques like this are looking increasingly practical. CO2 is being pumped back into depleted oil fields, where it also helps extract remaining oil deposits, and into coalseams. The ocean is the biggest natural bank of CO2 but tests of ocean sequestration in Hawaii and Norway have been blocked by environmentalists who hate this kind of quick fix approach to the CO2 problem. But with developing countries like India and China certain to rely on their large coal reserves, sequestration may be the only realistic approach to reducing their CO2 output. An Economist article discusses currently available steam reformation technology that could allow a coal plant to output power and neatly separated CO2 and hydrogen. The non-polluting hydrogen is then available for cars with fuel cells while the CO2 is stuffed away."

25 of 69 comments (clear)

  1. This is really cool and all but... by eggstasy · · Score: 2, Insightful

    What if something weird happens and the CO2 gets released in massive amounts? Like, a bomb, or a sinking ship, or an earthquake? Really though, the Earth's crust isn't a very stable place in its natural state and we don't have the resources and technology to put huge reinforced structures under the ocean to store the CO2 properly.
    The ocean floor in particular is a very unstable place. If you look at the pacific, all those tiny little islands were made by volcanos that appeared there all of a sudden, out of the blue, with no early warning. Apparently there are some "hotspots" in the magma layers below our surface, which puncture the Earth's crust forming temporary volcanos, that go extinct as the crust moves tectonically away from the hotspot below it. You never know what might hit an undersea CO2 deposit even if it was a solid, well engineered structure. The crust is very thin there! Cave-ins, earthquakes, volcanic activity in general, you wouldnt want to live at the bottom of the sea.
    It sounds like a quick hack that will solve the problem temporarily, but I can just see the CO2 getting released sooner or later.

    1. Re:This is really cool and all but... by 0x69 · · Score: 4, Insightful

      The CO2 would be in thousands or millions of old oil wells, coal seams, etc. and millions of square miles of deep ocean. Any one of those spots could have a problem & release some small fraction of 1% of the CO2.

      If anything big enough to release a large fraction of the CO2 comes along (giant asteroid, Iraq's "Planet Buster" nuclear doomsday device, etc.), then we'll have *far* greater worries than the CO2 release.

      --
      It's easy to make up & spread cool- and credible-sounding stuff. Finding & checking hard facts is hard work.
    2. Re:This is really cool and all but... by sofar · · Score: 5, Insightful

      Near surface natural CO2 deposits (dry ice) have been discovered and found to be a huge danger to anything that comes around. These deposits generally lie very shallow under the seafloor and can be meters in thickness. The biggest danger is not their sudden release and toxic effects of that, but lies in a totally different factor.

      In several ocean slopes (offshore norway, east coast US) these deposits suddenly gave way in history, allowing the cover of these deposits to start sliding down the oceanic ramps. The gasses maybe killed some fish, but the Norway slide triggerd a tidal wave that reached elevations of over 100m in height when it crashed into the north of Scotland (that's 500-1000km further), destructing everything in it's path.

      Another danger is to ships and constructions. The massive amount of gasses makes the sea like a giant bubblebath. Anyone that every played with a rubber duck that barely floats in a bubblebath knows what happens when you turn on the bubbles hard enough: it sinks. A massive gas pipe blowout just below an oil righ in the North Sea caused a complete oil/gas rig to sink like a rock a few decades ago.

      That said CO2 looks like a dangerous thing to toy with, but that's not the case in the oil fields we are talking about here.

      Most of these fields are at enormous depths, the typical North sea fields (in which these experiments have been done for quite a while) are at depths of over 500m. The rocks at that location are much more stable, and at 800m we're talking about serious tough rocks.

      Using CO2 to extract the oil better (by pressurizing depleted oil fields) and returning the CO2 they are hitting the jackpot twice: First they can revive old fields relatively cheap and extract more oil, and secondly they can do something back for the environment in a very safe way.

      The argument of cave-ins, earthquakes are however very serious ones. The typical example of a colorado experiment where fluids were injected into deep crustal fissures resulting in earthquakes occuring daily instead of yearly warn us against toying with the earth's structure.

      That said one must conclude that CO2 injection must be evaluated before it is even tried. As a geologist from the Netherlands I can honestly say this news is not new. CO2 injection has been discussed for over a decade now and thes tests were done in several other fields in small scale before this larger experiment by statoil.

      When you say "in general, you wouldnt want to live at the bottom of the sea" I can vough for that too, if you think the bottom of the sea is a safe place then you are wrong! But pumping some CO2 to fill up a hole you created again might be better than leaving the hole there. At least we should put a cover on the hole after we finished using it.

    3. Re:This is really cool and all but... by mmontour · · Score: 2

      Near surface natural CO2 deposits (dry ice) have been discovered and found to be a huge danger to anything that comes around

      Are you sure that those were CO2 deposits, and not methane hydrates?

      I've never heard of undersea dry ice, although there are a few lakes like Lake Nyos that contain very large amounts of dissolved CO2, and have occasionally released large clouds of the gas (killing hundreds of people in the valley below).

    4. Re:This is really cool and all but... by sofar · · Score: 2

      ahh yes, you are correct, I confused something there!

      As for the dissolved CO2, I once saw a video from one of my U. teachers trying to bounce a little submarine into a subsea pond of CO2 at 1100m depth, incredibly fascinating to see that the density was so dense that the sub (being neutrally buoyant to water) was too light and skidded right off, only to leave ripples on the surface!

      Many large lakes in Africa contain huge amounts of CO2 dissolved and sinking to the bottom. But there are quite some locations in oceans as well where smaller 'ponds' of CO2 exists. The mediteranean sea is a well known example.

    5. Re:This is really cool and all but... by geoswan · · Score: 2
      Is dry ice possible at the extreme pressure of the deep sea floor? I know, sofar acknowledged he/she really meant Methane hyrdrate ice, not dry ice. Still, I was curious. I found this page, which has an account of experimenting with liquid CO2 at depth. At that pressure CO2 is liquid, and denser than water.

      The clathrate the article mentions is a kind of slush of water ice with something else dissolved in it. So the methane hydrate we discussed is a clathrate too.

    6. Re:This is really cool and all but... by g4dget · · Score: 2
      The biggest danger is not their sudden release and toxic effects of that, but lies in a totally different factor.

      When CO2 suddenly bubbles up from a lake near a population center (as it has in some cases), it can lead to a sudden and massive disaster. But I agree that that's probably not much of a danger if it's pumped into an off-shore oil-field.

  2. CO2 future fuel... by wiretrip · · Score: 2, Interesting

    Cool, maybe in about 2000000 years CO2 will become the next major fuel and everyone will be fighting over land 'rich in ancient CO2 deposits'!

    1. Re:CO2 future fuel... by geoswan · · Score: 2
      what if he pumped h2 down with the co2? Will the pressure cause oil to be made in the distant future?

      I am not sure if you are joking.

      Pure hydrogen is, I believe, much more costly than crude oil. So this does not seem to be a win to me.

  3. Re:Why do I pay $12 for a CO2 tank by sofar · · Score: 2

    Actually, the CO2 they pump back comes from the degassing stage of the oil on the rig itself. This CO2 will never see an onshore installation, making it quite hard to make bubbles for beer form it.

    Now I've heard rumors about beans for breakfast in the UK, I wonder if that is where they get their CO2 from...

  4. Re:Disposal? by sofar · · Score: 3, Funny

    We might be better off getting rid of all the case-modders using dry ice to cool their mobos! Liquid Nitrogen is sooooo much more environmental conscious!

  5. Mineral carbonation is more permanent by pfdietz · · Score: 4, Informative

    This approach is useful, but it always leaves the possibility of leaks, and has limited capacity.

    The process of mineral carbonation exothermically reacts CO2 with certain silicate minerals (or materials derived from these minerals) to yield carbonates that are stable on a geological time scale. There are more than enough of the desirable silicates (serpentine, olivine) to react with all the CO2 that will ever be produced by fossil fuel combustion.

  6. Re:Kyoto by Tsar · · Score: 3, Funny

    I wonder why countries like USA worry about CO2 emission and do not sign the related treaty, i.e. Kyoto protocol...

    Probably for the same reason that I support a number of good causes, but haven't signed a contract with United Way to do so. For that matter, it's probably for the same reason we declared independence in the first place.

    If that doesn't make sense to you, how about this: I'll send you my address, and you can mail me US$100 each month. I'll make sure that at least 70% of it goes toward environmental improvement. What, you won't do it? What are you, an anti-environmentalist? Oh, you're going to go it alone, eh? What are you, an anti-globalist?

    And why are we even worried about CO2 when Dihydrogen Monoxide is everywhere?

  7. Re:Kyoto by Scrameustache · · Score: 2

    Well you're way ahead of them in pollution. USA #1 Polluter! Yay! U-S-A! U-S-A!

    The reason why the US won't sign the kyoto treaty is because they have the Bomb, and they have a god given right to poison the rest of the world (and to bomb it).

    Most of india and china are rural, in the medieval ox-cart sense of the word. They need to catch up to the industrialised nation and get out of their rut. In case you haven't noticed, the US is the most industralised nation in the world and doesn't need to catch up.
    Personally I'm amazed to know that you still use coal as an energy source...what is this? The 18th century? The world needs treaties to force people to stop poisoning their neighbours for fun and profit.

    "If we do that, the environmentalist win!" - Homer Simpson

    --

    You can't take the sky from me...

  8. somewhat related article... by foolish · · Score: 2, Informative

    An interesting article at:

    http://www.spacedaily.com/news/energy-tech-02o.h tm l

    Seems like another interesting way to sequester CO2. More ideas, more ways of approaching the problem...especially since peanuts are a pretty good soil-poor crop and have all those other uses.

    I mean, you're going to have peanut shells anyways...

    --foolish

  9. LLNL simulation of CO2 ocean sequestration by minesweeper · · Score: 2, Informative
    Last month, Lawrence Livermore National Laboratory scientists released a study modeling the effectiveness of direct injection of carbon dioxide into different oceans at different depths. They've proposed injection into the ocean as a way to slow the accumulation of CO2 in the atmosphere.

    Injections were simulated at 800 meters, 1500 meters and 3000 meters for 100 hypothetical years near the Bay of Biscay, New York City, Rio de Janeiro, San Francisco, Tokyo, Jakarta and Bombay.

    The models showed that injection at 3000 meters is quite effective at sequestering carbon from the atmosphere for several centuries while injections at shallower depths are less effective. (Not too surprising.) In general, injections into the Pacific Ocean (San Francisco and Tokyo) were more effective than injection at the same depth in the Atlantic Ocean (New York City, Rio de Janeiro and the Bay of Biscay).

    The full press release is available here.

  10. Re:Kyoto by Scrameustache · · Score: 2

    The USA was the #1 polluter in 1970. Now it ranks #4. Get your numbers straight.

    I'm sorry, Tinky Winky didn't send me the memo!

    I mean, you get to make up phony statistics

    Just like you just did? yay!

    NO scientific debate! EVER!

    All hail lord John Worfin?
    Maybe, just MAYBE, you should get your facts straight and look at the science behind environmental concerns instead of declaring that there is no science.
    Really, you accuse others of doing what you're just doing right there and now, come on!

    It must be nice to be an environmentalist.
    Actually, its quite depressing...

    --

    You can't take the sky from me...

  11. Re:Disposal? by monkeydo · · Score: 2

    The only problem is that the trees we chop down are usually used for something. Sure we can recycle paper (which uses energy and releases polutants) but would yo want a house built out of recycled wood? Steel and Aluminum are becoming more popular building materials, but those have to come from somewhere. How do you feel about mining?
    No, we will chop down trees and we will replant. We will mine and we will polute. We will eventually make the Earth uninhabitable for humanity, and then humans will be extinct. "Take only photographs and leave only footprints," may work at Yosemite, but it doesn't scale very well.

    --
    Si vis pacem, para bellum
    The only thing more annoying than a Libertarian is an (un|mis)informed Libertarian
  12. Re:Disposal? by monkeydo · · Score: 2

    One thing I don't understand about this argument. An old tree has a lot of carbon in it. At some point the growth of this tree is going to slow, and so will it's CO2 consumption. If I cut down that tree I've made room for a younger faster growing tree that will in turn lock up a bunch more carbon. Assuming I don't burn the tree I've cut down the carbon is still traped. Granted the seedling won't process as much CO2 to start with as the old Oak, but since it's still growing it will probably consume more in total over the next n years. So why exactly are environmentlists so fascinated by leaving old trees in the ground? Old growth forests are also more likely to have out of control fires which leads to more carbon release.

    --
    Si vis pacem, para bellum
    The only thing more annoying than a Libertarian is an (un|mis)informed Libertarian
  13. What CO2 does in oil fields by Spamalamadingdong · · Score: 3, Interesting
    Using CO2 to extract the oil better (by pressurizing depleted oil fields)
    If I understand correctly, the CO2 provides a lot more than just pressurization (otherwise, water would be just as good and a lot cheaper). Liquid CO2 is a solvent, and can dissolve and transport oil which would otherwise remain stuck in the pores of rocks. It offers a way to recover oil from "tapped out" fields (where water has infiltrated between the remaining spots of oil and keeps them from being pushed save by density differences), and of course - if the CO2 is there under the ground, it isn't in the atmosphere and might even form carbonate rocks to lock it into place permanently.
  14. I think that's the wrong problem scenario by Spamalamadingdong · · Score: 3, Interesting
    What if something weird happens and the CO2 gets released in massive amounts?
    That's rather unlikely, due to the depths we're talking about here, but... what if it doesn't get released?

    The pH of the ocean is moderated by a carbonate/bicarbonate buffer. If you add acid to the ocean (including carbonic acid, H2CO3), some of the carbonate (CO3--) ions soak up hydrogen ions and become bicarbonate (HCO3-) ions. This is okay, but a lot of ocean organisms require carbonate ion to build their skeletons, including corals, molluscs, and a host of smaller things. Cut the fraction of carbonate in the ocean (and add acid, which tends to eat the carbonate they've already laid down) and they have a tough time surviving. The last thing we need at the moment is to put extra pressures on the surviving coral reefs, clam and oyster beds, and everything else out there.

    Dumping CO2 where it changs the ocean chemistry may be a bad idea.

  15. Recycling? Think about where the tech is going. by Spamalamadingdong · · Score: 2
    Sure we can recycle paper (which uses energy and releases polutants) but would yo want a house built out of recycled wood?
    We're pretty much there already. Have you looked at structural beams and floor joists lately? They are no longer solid wood. The beams are laid up of layers of veneer, and the joists are I-beams with small cap-strips of solid wood (finger-jointed) joined by a web of waferboard. You can practically crank out floor joists out of debarked scrub timber and the chips and shavings you get from milling the cap strips.

    We already make insulation out of used newsprint. If the price of wood goes much higher, it may become economical to make joists and beams out of recycled paper.

    Steel and Aluminum are becoming more popular building materials, but those have to come from somewhere. How do you feel about mining?
    Looks to me like a steel building could be recycled fairly easily, and a huge fraction of the earth's crust is aluminum (in the form of aluminum silicates). Then there are the low-tech standbys of adobe and rammed earth. How do you feel about digging up your building materials wherever you happen to be? Regardless of how primitive our methods are now, they won't remain so any more than aluminum remained more precious than gold.
  16. Re:Disposal? by monkeydo · · Score: 2

    I agree with all of your points, and the answer certainly lies in some moderate middle ground. However, I have never seen an environmentalist (by that I mean professionals who dedicate a large portion of their time to being interviewied, lobbying, forming other's opinions, etc. wrt environmental issues) who was in favor of moderation in anything.

    --
    Si vis pacem, para bellum
    The only thing more annoying than a Libertarian is an (un|mis)informed Libertarian
  17. Dihydrogen Monoxide Warming by SEWilco · · Score: 2, Informative

    Well, yes, dihydrogen monoxide vapor does cause well over 90% of the Earth's greenhouse effect. But carbon dioxide has a better public relations staff so it gets more publicity.

  18. Re:Disposal? by p3d0 · · Score: 2
    At some point the growth of this tree is going to slow, and so will it's CO2 consumption.
    Your whole argument rests on this. Do you have any evidence for it?
    --
    Patrick Doyle
    I mod down every jackass who puts his moderation policy in his sig. Oh, wait a sec....