Negative CTE material
florescent_beige writes "An article on Yahoo talks about zirconium tungstate (ZrW2O8), a material that has a negative coefficient of thermal expansion over a wide range of temperatures. Being non-toxic, it has applications in dentistry, as well as metallurgy and optics. Johns Hopkins physicyst Collin Broholm describes the physics behind the behaviour."
If all this should have a reason, we would be the last to know.