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Ethanol From Waste Straw

phcrack writes "The CBC is reporting that 'Iogen Corporation of Ottawa has developed enzymes to break down waste straw and wood chips into ethanol on a commercial scale.' Apparently traditional ethanol from food crops like corn used at least as much energy to create as they released when burned. It's nice to see that big oil companies are helping fund a project like this too. It's very rare today to hear of a major company throwing money at a research project since the '80s."

13 of 449 comments (clear)

  1. Re:Corn is a very poor crop to use. by Anonymous Coward · · Score: 5, Informative

    You are conveniently ignoring the fact that most of the US is unsuitable for growing sugarcane.

    Corn on the other hand, can be grown all over the place.

  2. Re:so could you use thestalks of corn and other ag by the_2nd_coming · · Score: 5, Informative

    all cars built after 1995 are flexible fuel cars. and since then, cars have been certified to run on E85 which is 85% ethanol 15% gas.

    add to that the ethanol fuel cell, and screw hydrogen. if we can produce enough ethanol from ag waste and yard clippings, we can just use ethanol as it is easier to make, easier to transport, and is closed with regards to the carbon cycle (i.e. no negative impact on the environment from the CO2 used since the plants used have to use the same amount to grow.)

    --



    I am the Alpha and the Omega-3
  3. Actual press release by neonfrog · · Score: 5, Informative
    Contains a little more detail. Avalable here.


    Brings up an interesting question: Do all Canadian petroleum companies get use of this tech since Canadian taxes helped pay for it? Or does just the consortium get to profit from it for a while since they did the actual research?


    Either way seems fair from certain perspectives, but if Shell and Petro-Canada are the only ones to profit then what percentage of Canadian cars will actually run the stuff? How many petro companies are there in Canada? How many Canadians will really benefit from their taxes?

    --

    I'm thinking about it, therefore I might be.

  4. Re:How expensive? by belrick · · Score: 5, Informative

    No, no, in Canada the gallons are Imperial, which is 160 Imperial oz (28.41 mL/Imp oz) or 4.546 L, compared with a US gallon being 128 US oz (29.57 mL/US oz) or 3.785 L.

    More importantly, we drink beer in Imperial pints (1/8 Imp gal, or 20 Imp oz) which is 568 mL verses a US pint (1/8 US gal, or 16 US oz) which is 473 mL.

  5. Re:Rare != Not There by dAzED1 · · Score: 5, Informative
    that's funny, I work at a large Lockheed plant, and I have a decent clearance level...I don't know of any bombs being built here...

    Helicopters, mail sorters for the US postal service, advanced targetting systems, a few other things...but bombs? Not really. At some plants, sure, but its definately not even a large portion of the company portfolio.

  6. Re:so could you use thestalks of corn and other ag by FlashBIOS · · Score: 4, Informative
    Not true! Far from all cars built after 1995 are flexible fuel cars. There are only a small handful of cars from each manufacturer on the road right now, and using flexfuel in you car if it isn't rated for it can severely damage your engine. Check out these sites before you fill up. If you want to check if your car is compatable, e85fuel.com has an easy VIN guide.

    http://www.cleanairchoice.org/outdoor/e85.asp
    http://www.e85fuel.com/

  7. Ethanol Purification is Expensive by StateOfTheUnion · · Score: 4, Informative
    Anyone know if there is a cheap way to purify ethanol? Ethanol from biomass is essentially fermentation and the alcoholics ;-) in the crowd will know that typically it is hard to get fermentation to produce concentrations of alcohol above ~12%. This is because the fermenting bugs don't live well in liquid with high concentrations of sugar or alcohol.

    One must separate the water from the Ethanol to make it useful, this is typically done by distillation which uses nearly as much energy as the ethanol produced. What is worse is that Ethanol/Water is aziotropic. This means that when distilling ethanol from water, eventually the separation hits a stopping point at about 95% ethanol because the boiling points of water and ethanol in a mixture of 95%/10% ethanol/water are about the same. This is why the highest proof alcoholic drinks are typically 180-190 proof (as opposed to 200 proof which would be 100% Ethanol). Mass separating agents (nasty additives) have to be added to the ethanol/water mixture to elicit a near 100% separation. This makes purification even more expensive.

    Ethanol in gasoline is almost all chemical and refinery byproducts. Almost none is from bio sources because the chemical byproduct is so much cheaper than bio-fuel ethanol. In fact some alcohol produced at chemical plants is purified and sold for human consumption (it is added to some cheap gins). It's kinda weird to see a bonded and taxed tank of ethanol on a chemical plant site.

    Bio-produced ethanol often sounds good to politicians, but unless there is a new low energy water/ethanol separation process, it will never be economicall feasible on a large scale.

  8. Re:Why do oil companies fund this research? by Erich · · Score: 4, Informative
    Take solar energy. Oil companies own somewhere around 90% of the patents on solar energy. Why do you think they do this? Simple, better to fund the research themselves so they own the patents. This prevents anyone else from actually inventing something new and possibly marketing it.
    Let's see some links. Or did you just hear this from some guy?

    Oil companies do lots of research into natural gas and ethanol and the like because they know that one day, many many years from now, the oil production will not be able to meet demand. The company that can provide the fuel via another method will be the one making the profit. It just makes sense.

    Anyway, if you get a patent on something, it is made public knowledge, and it is available for public use by anyone after a few years. And, in the meantime, the knowledge is used to further the state of the art.

    So what you are saying is: Oil companies fund alternative fuel resource research and that knowledge is made public, furthering the state of the art and making us more independant from oil. They own the rights to the inventions for a while, but they make the invention public knowledge and the invention is released to the public after a period of time.

    Well, that sounds pretty reasonable! Maybe these companies aren't the evil entities the propaganda you listen to would leave you to believe? Maybe they are normal people, trying to make some money, and concerned about the future.

    On the flip side, when was the last time someone who went "off the grid" contributed to the state of the art in energy production?

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    -- Erich

    Slashdot reader since 1997

  9. Solar Cells, Solar Cars... by BigBlockMopar · · Score: 4, Informative

    Yeah, it's really smart to replace petrol with ethanol; a fuel that takes more energy to produce it than it yields...

    Isn't that the same as solar cells, given that they require massive amounts of energy to make, output feeble amounts of energy on a per-cell basis (and at most 0.707 of that is harnessable as alternating current), and have a finite lifespan (primarily to cracking caused by heating/cooling cycles)?

    Actually, ethanol/methanol is a great step toward solar-powered cars; capture the solar energy with plants, store it as chemical energy, release it as heat energy within an internal combustion engine. Of course, one could argue that this is already what happens when you start up your Hummer.

    Enthanol/methanol are a far better automotive fuel than electricity, so if this replaces the (misguided) efforts to produce electric cars, that would be excellent. It's still effectively zero emissions, since every CO2 molecule which comes out of the car's tailpipe was already scrubbed from the atmosphere when the plant was growing. There will still be NOx and unburnt HC, as there are with conventional cars, but neither one of those species is chemically stable in our atmosphere and both are rendered back to N2, CO2 and H2O very quickly.

    I have two big worries with electric cars. The biggest being the batteries - by necessity, the greater the energy density of the battery, the nastier the chemicals inside it have to be. Weird things happen to cars - accidents, ditched in lakes, etc. - so it doesn't seem like a good idea to be carrying around hazmats which make gasoline look benign. The other great worry is that electric cars all must be recharged somewhere - how many new nuclear and coal power plants will have to be built to keep all these electric cars recharged?

    Transition would be easy, too - as soon as the fuel is economically feasible, gas stations can start dedicating a pump or two to it. Many modern vehicles are already built to run on methanol - Chrysler experimenting with "Flexifuel" Plymouth Acclaims and Dodge Spirits as far back as 1992. And with a little bit of work - swapping old rubber-diaphragm fuel pumps then doing standard tune-up stuff like adjusting the mixture and the timing - just about any antique vehicle will run happily on the stuff. The hardest converts will probably be 1980s EFI cars.... and diesels.

    Well, okay, diesels will already run happily on vegetable oil.

    --
    Fire and Meat. Yummy.
    1. Re:Solar Cells, Solar Cars... by Spamalamadingdong · · Score: 4, Informative

      Isn't that the same as solar cells, given that they require massive amounts of energy to make, output feeble amounts of energy on a per-cell basis (and at most 0.707 of that is harnessable as alternating current), and have a finite lifespan (primarily to cracking caused by heating/cooling cycles)?

      What solar cells are those? The ones I'm familiar with pay back their invested energy in 2-4 years, and last 15-25 years at a minimum. They don't crack unless they are abused, such as by overheating with concentrated light.

      Their output is also convertible to AC at 90+% efficiency, using modern inverters. Where'd you get this sqrt(.5) nonsense?

      Actually, ethanol/methanol is a great step toward solar-powered cars; capture the solar energy with plants, store it as chemical energy, release it as heat energy within an internal combustion engine.

      The problem is efficiency. There are many more losses with the conversion to plant matter and back, so you need a lot more capture area. As long as you're effectively getting it for free (as a byproduct of something you're growing anyway) you're fine, but if you have to pay for the acreage with the fuel production alone your costs just went through the roof. Speaking of roofs, the average house's roof can capture more than enough sunlight to power the average household's daily driving even if you're only using solar cells. If you assume 340 WH/mile and 20 miles/vehicle/day, you need 6.8 KWH/vehicle/day. If you get good sunlight for 6 hours/day, you need a bit over 1 KW(peak) of solar panels to supply this. At 10% efficiency this is only about 10-14 square meters of roof. Your typical ranch house has upwards of 100 square meters of roof.

      Enthanol/methanol are a far better automotive fuel than electricity, so if this replaces the (misguided) efforts to produce electric cars, that would be excellent.

      You're half right.

      1. Ethanol and methanol have far higher energy density than the batteries required to use externally-supplied electricity in a vehicle; you can get many more miles of range into a liter of space with alcohol than batteries.
      2. Batteries require no heat engine to convert their stored energy to a useful form (electricity can be converted to motion with efficiency well above 80%), and most useful batteries have a pretty high power density (W/kg) as well. Many electric cars are extremely quick.

      The optimal solution for current (cheap) batteries is the plug-in hybrid; the batteries store power for short trips and surge acceleration, and the sustainer engine burns fuel for longer trips. The efficiency of such a vehicle can easily be twice that of a non-hybrid. I recall seeing a figure of 17% which works with other calculations I've done, but Chevron has published a figure claiming that the average is closer to 12%. That's probably where your Ram is hovering around.

      If either lithium-ion cells or the recent NEC resin-based battery hit an inflection point in their production cost curve and start heading down, it won't be long before we see all-electric cars with 300+ mile ranges and sub-5-second 0-60 performance. This can already be done with laptop Li-ion cells, but the cost is about ten times too high for bulk production. I don't see anything which forces this to remain so.

      I have two big worries with electric cars. The biggest being the batteries - by necessity, the greater the energy density of the battery, the nastier the chemicals inside it have to be. Weird things happen to cars - accidents, ditched in lakes, etc. - so it doesn't seem like a good idea to be carrying around hazmats which make gasoline look benign.

      Lithium is not exactly a toxic substance; for some people, it's medicine. The electrolyte of NEC's proton polymer bat

  10. Re:How expensive? by Mildew+Man · · Score: 4, Informative

    Cellulose ethanol is a terrific idea, and saves food crops for food purposes...

    Actually, it's a myth that the ethanol process uses corn that goes for food. Most corn doesn't get processed into food. It is used as animal feed and the by-product of corn ethanol production is a distiller's mash that is actually better for animal feed since it is high in protein and rich in water-soluble vitamins and minerals. Because the fermentation process removes only starch, all the remaining digestible nutrients are left in the distiller's grain.

    Additionally, the net energy output of corn ethanol is 34% (PDF). It does not take as much or more energy to produce a gallon of ethanol. Plus, this is using traditional distillation methods. If we really wanted cheap energy we could use solar stills and run a 160-170 proof ethanol in our slightly modified E-85 cars and trucks.

    I do think ethanol from waste straw is a good idea but getting it from corn is also a good idea that could be even better.

  11. This is a positive step but it won't change much by KnightStalker · · Score: 4, Informative

    You have to dig around a bit on Iogen's site, but they do come up with *some* numbers. On their FAQ page they claim 300 liters per tonne of feedstock. Corn-based ethanol has a similar yield, though, and it yields more per acre than barley or wheat. (If my superficial googling is reliable, corn can yield 10 or more tons per acre compared to about 3 or 4 tons of straw.)

    This is fantastic if it reduces the cost of ethanol production, and allows it to be produced from straw that is currently just burned. But it won't make the gas industry obsolete.

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    * And remember, it's spelled N-e-t-s-c-a-p-e, but it's pronounced "Mozilla."
  12. Re:Ethanol by confused+one · · Score: 4, Informative
    E85 fuel can be placed in the EXACT same fueling infrastructure that we have here in the US

    Not true. Apparently you can't run the mix through long pipelines. Much of our fueling ifrastructure relies on these pipelines from the refineries to fueling depots where it is further distributed by truck.

    When sent through the pipelines, E85 tends to separate back out... It's only available near locations where the alcohol is produced and can be mixed directly.