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Microreactors Change Propane into Hydrogen

Roland Piquepaille writes "Microreactors have already been used for on-site reforming of fuels, such as methanol or propane, to produce hydrogen to be used in fuel cells. Now, researchers at the University of Illinois at Urbana-Champaign (UIUC) have designed very efficient ceramic microreactors to do this task. The scientists say that their microreactors are much better than other fuel reformer systems. They are now trying to reform gasoline and diesel, which are more widely distributed than propane. Does this mean that one day we'll be able to go to a gas station to refill the fuel cells powering our laptops? Probably not before a while, but read more for additional details, references and a picture of a prototype."

24 of 122 comments (clear)

  1. huh? by Dan+Guisinger · · Score: 4, Insightful

    I don't get it..... ......aren't there better things we should be trying to turn into hyrdogen?
    I mean.... propane, oil, gasoline, thats great......but half the problem is we are running out. And what happens to all the carbon when its converted to hydrogen? (I admit I didn't read). I would hope its not released as an emission of sorts, that wouldn't help what so ever....other than localizing a problem possibly making containment easier.

    1. Re:huh? by CoderDog · · Score: 5, Funny

      Suckered by a Roland Piquepaille submission, Again. Hate it when that happens.

      They mentioned that the reactor operates at high temps (800 C. to 1000 C.) to avoid carbon (as soot) fouling of the reactor. So, they've either got an ash bin somewhere downstream or they sprew CO and/or CO2. The other boast was that they'd reformed ammonia (at 1000 C.) to produce hydrogen. No word on whether the waste was gaseous nitrogen or nitrous oxides. Hope it's not nitrous oxides. Denver's "brown cloud" used to be mainly nitrous oxides from car exhaust.

      This looks like a really cool trick, but otherwise nearly worthless at this late date. I really don't want to run down to the gas station every couple of hours for a hydrogen recharge, and really, really dont't want a long warmup 800 C. appliance running in the house -- unless it also cooks 60 second pizzas. Additionally, the world's running out of their feedstock. If they had something that took plastic packaging, waste paper, saw dust, or the neighbors yapping little pets as an input and efficiently produced butane, propane, diesel or gasline, along with nicely segregated saleable piles of sulfur and laser printer toner, that'd be a newsworthy dazzling thing.

      If it also made nutritious little green biscuits (maybe call 'em Soylent Green?) that'd be extra special.

    2. Re:huh? by rolfwind · · Score: 2, Insightful

      Even petroleum is only "energy storage", it didn't get there by itself, but through millions of years, solar energy, and decaying plants/animals life cycle as far as we know.

      But agreed, current electrolysis is too costly, perhaps high temperature steam electrolysis too. Perhaps Fusion, when it comes, will solve these problems with sheer energy production, or high-efficiency solar panels or some other thing we can't currently imagine.

      But whatever the case, "never" predictions have a long time coming to be proven right or wrong - so I don't bank on them.

    3. Re:huh? by pipingguy · · Score: 2, Informative

      Maybe they're using pure oxygen to reach those temperatures and get a more complete burn.

      http://www.fossil.energy.gov/programs/powersystems /gasification/howgasificationworks.html

    4. Re:huh? by Shimmer · · Score: 2

      Where do you think the hydrogen on the shuttle comes from? Not from the Great Offshore Hydrogen Mine, I'll tell you that much. Hydrogen is like a battery - it's a good way to temporarily store energy that you've obtained from somewhere else. This is why the GP is correct in saying the hydrogen is not a fuel source. Most likely, the hydrogen on the shuttle comes from a source such as (gasp) fossil fuels.

      --
      The most rabid believers in American Exceptionalism are the exact same people whose policies are destroying it.
    5. Re:huh? by Jah-Wren+Ryel · · Score: 3, Interesting

      aren't there better things we should be trying to turn into hyrdogen?

      Right now, today, we only have one, maybe two, wide-scale energy distribution systems. Its gasoline. If we can easily and cheaply make a gas station do double-duty as a hydrogran station that solves the short term problem of how to fill-up hydrogren powered cars. The expectation is that over time, as hydrogren powered cards theoretically become widespread, we can slowly build up alternate distribution system(s) to support them as we wean off of gasoline.

      PS - the other "maybe" distribution system is electricity. I say "maybe" because we do a power grid, but we don't have metered charging stations nor do we have the capacity to support wide-scale automobile recharging. Yet. Start putting some nukes online and we might get there pretty quick.

      --
      When information is power, privacy is freedom.
    6. Re:huh? by Daemonik · · Score: 2, Insightful

      Hey guess what, nothing is a fuel 'source', as energy can not be created or destroyed, only stored and transferred. That lovely black gold we call oil didn't magically appear, it's just a storage medium. Nor does gas jump straight out of the ground and into my car either, energy must be expended to drill, pump, process, refine and distribute it. Still doesn't get around my point.

    7. Re:huh? by bloobloo · · Score: 2, Informative

      At 1000C it's likely to be nitrogen coming out. It's got to be hotter to form significant amounts of NOx.

  2. How much better is it? by dbIII · · Score: 4, Informative

    One thing I would like to hear is if you really get much better results with this and hydrogen-oxygen fuel cells than you would get with a propane-oxgen fuel cell. If it is a much larger difference than you get with reforming the propane then it is interesting - propane is easier to store and ship around.

    1. Re:How much better is it? by sydsavage · · Score: 2, Funny
      My family sold propane and propane equiment when I was a kid

      Bobby Hill, is that you?

  3. That's a cool thing, but what about by KalElOfJorEl · · Score: 3, Insightful

    Turning hydrogen into fossil fuels. Now THAT would be something to see.

    1. Re:That's a cool thing, but what about by kfg · · Score: 2, Funny

      Turning hydrogen into fossil fuels. Now THAT would be something to see.

      They're called "plants" and "fungi." Perhaps you've heard of them? The hydrocarbon compound they produce is often refered to colloquially as "vodka."

      KFG

  4. vaporware by macadamia_harold · · Score: 4, Funny

    Microreactors Change Propane into Hydrogen

    Finally, a good example of vaporware. And not in the Duke Nukem Forever sense of the word.

  5. Whatevs by Y-Crate · · Score: 4, Funny

    This shit is nothing. I'm putting the finishing touches on a process that will turn diamonds into multifunction printer paper.

  6. Benefits. by Jartan · · Score: 2, Insightful

    I think the point of turning gasoline into hydrogen would be that it would finally solve one of the biggest problems with fuel cell acceptance. The problem of where do you "fill up".

    If your car has a method of efficently turning gasoline into hydrogen then a huge distrubition problem is solved. Fuel cell cars could become accepted much more easily because you wouldn't have to worry about being out of fuel. Yet in a large majority of the cases you'd never actually need to fill up at the gas station assuming you recharged your fuel cells overnight.

    Of course that's assuming this is really efficent instead of just more efficent than an already unefficent process.

    1. Re:Benefits. by kfg · · Score: 2, Funny

      Yet in a large majority of the cases you'd never actually need to fill up at the gas station assuming you recharged your fuel cells overnight.

      Fuel cells are "recharged" with. . .hydrogen, not electricity. The electricity is stored in. . .the hydrogen. When the hyrdrogen is gone, so is the electricity. That's the way it works.

      If you want to recharge your electric car overnight without going to a filling station you'll need a battery. Perhaps you can use it to make it back to the filling station.

      http://www.howstuffworks.com/fuel-cell.htm

      KFG

  7. Yet again... by just_forget_it · · Score: 2, Insightful

    Making a fossil fuel "alternative" with fossil fuels.

    Hydrogen and fuel cell technology as it stands today is a white elephant of epic proportions. When you convert one form of energy to another, there is always a loss of efficiency. Instead of just converting the fossil fuel to energy in the vehicle, it's converted into another form of fuel, losing efficiency.
     
    You actually use MORE petroleum running a hydrogen car than an equivalent gasoline-powered vehicle.

  8. Re:Merely a slight improvement to existing technol by Lehk228 · · Score: 2, Informative

    ethanol is a waste, to fill up an SUV it takes enough ethanol to feed a family for a year with the grain instead of turning it to ethanol, and using corn ethanol you burn more petroleum making the corn than you get in ethanol out of it

    --
    Snowden and Manning are heroes.
  9. Information on fuel cell vehicles by loshwomp · · Score: 4, Interesting

    Here's a paper from AC Propulsion that explains why fuel cells are the technology that never will be. The smart money got out of fuel cells years ago.

    Perspectives on Fuel Cell and Battery Electric Vehicles

    1. Re:Information on fuel cell vehicles by Anonymous Coward · · Score: 2, Informative

      Nice article, untill it told me that 1 KG of Hydrogen weighed the same as 1 gallon of gas. 1 gallon of gas weighs 6.5 lbs, or 2.9 kg and at 45 or so miles per Kg, you could get approx. 130 miles by carrying the same weight as the equivilant amount of gas. It's just a personal bais of mine, but when i see an article lie to me i stop listening to it.

  10. Re:It's probably to deal with byproducts of biodie by Quadraginta · · Score: 2, Informative

    I think the point is to be able to generate electricity much more efficiently. This is not a replacement for a gasoline engine in your car. It's a replacement for a laptop battery for a traveling salesman or satellite-phone battery for a USMC lieutenant in the field.

    As such, it's a big win. Batteries are an environmental disaster, since they often need nasty heavy metals (e.g. lead or mercury), and they don't last very long. Furthermore, you waste a lot of transportation energy transporting around the mass of batteries in something that's supposed to be portable. Finally, the process of generating and distributing the electricity you need to use to recharge the batteries is itself not very efficient at all. Generation losses, transmission losses, the fact that you can't store the stuff easily and have to have it running all the time for the intermittent occasions you need to recharge your batteries, et cetera.

    This way, you generate your electricity on the spot, very efficiently (hence fewer emissions). And you don't need a heavy battery containing noxious metals.

  11. Fuel cells are not the answer! by bradbury · · Score: 3, Insightful
    People in developed countries have largely been duped by the so called "green" arguments that hydrogen (and indirectly fuel cells) are the solution to their energy problems. This is because you combine hydrogen with oxygen and get nonpolluting water (thus no CO2 and no CO). If done in a fuel cell the secondary reactions with N2 are avoided and thus no NO. This means no pollution. But existing automobiles through the proper management of the air fuel mixture (computer controlled fuel injection) and catalytic converters have minimized the NO problem.

    You have to separate the problem of the energy carrier from the energy source. All current existing methods to make hydrogen available start with upstream in-the-ground based energy sources (methane, propane, gasoline, etc.) and involve dumping the CO2 that results from extracting the hydrogen into the atmosphere. So long as the hydrocarbon (or carbon) source is coming out of the ground you have only solved the NO pollution problem -- you haven't solved the CO2 part of the global warming problem. I.e. you have not produced a sustainable solution.

    The only sustainable solutions involve producing hydrocarbon carriers using carbon extracted from the atmosphere -- that currently means biodiesel, bioethanol or biomethane. Propane, methane and gasoline in our current economy are energy carriers produced using solar energy harvested in ancient times. Until one switches to an economy based on energy harvested or created in real time one has an unsustainable reality. That means one has to be harvesting solar energy (incident visible or IR energy, wind or hydroelectric) or nuclear energy (in the long term using breeder reactors or fusion). The bio-carrier sources are inefficient (harvesting 1-2% of incident solar energy) but there is a large installed infrastructure designed to produce them. As whole genome engineering and/or mass production of inexpensive photovoltaic cells increase the solar energy harvesting efficiencies it will become completely feasible to migrate from a "steal from the past" to a "harvest the present" sustainable economic framework. It would help if people could keep this straight in their minds (and if people in leadership and press positions would not mislead or misdirect where the emphasis should be placed).

    So I agree with comments that better reformers are not particularly worthy of attention. A more efficient catalytic system for splitting water (compared with photosynthetic efficiencies) would be worth getting excited about.

    Of course I'm waiting for the day when our fusion reactors are powering the breeding of Gd-148 which in turn is used to power the nanorobots and/or replicators which will sustain our economy. But we are probably a several decades away from that at this time.

    1. Re:Fuel cells are not the answer! by evilviper · · Score: 2, Interesting
      All current existing methods to make hydrogen available start with upstream in-the-ground based energy sources (methane, propane, gasoline, etc.) and involve dumping the CO2 that results from extracting the hydrogen into the atmosphere.

      I think the issues that should be discussed is how terribly ineffecient such conversions are, plus the ineffeciencies in the fuel cells, etc. It would be far more effecient to burn the propane/gasoline in a power plant, and charge a battery-powered car from the grid, and batteries are improving more quickly than fuel cells...
      --
      Slashdot gets worse every day... Pipedot: News for nerds, without the corporate slant
  12. Re:Merely a slight improvement to existing technol by el_womble · · Score: 4, Insightful

    Now look at what you've written and tell me where the inefficiency is.

    I'll agree that using corn to make ethanol is brain dead, but thats got more to do with voters in Iowa than it does about saving the environment. Sugar cane and sugar beet do a much better job and with a net gain in energy - even when using diesl machinary. But if you do grow corn for transportation energy it is possible, and with zero fossile fuel consumption - its called manpower. The Greek and Roman Empires ran off it, most of South America, India, China and Africa still do. So where is the inefficiency. Is it in the use of corn, the use of ethanol or the use of diesel guzzling mechinary.

    I'm not going to tell you that working a corn field using ox/shire horse and man power is fun and good, honest work. Its not. But using fossil fuels to replace man power is a stop gap. It might mean that the US is able to compete with northern Africa or Asia for corn, but at some point, unless we figure out a way to replace the internal combustion engine, we will have to force the poor in to peasantry again - I guess we might get away with communism for a couple of years - that tends to take the edge off being a slave.

    Then there is the other statement: "to fill up an SUV it takes enough ethanol to feed a family for a year" I'm not sure if thats entirely true, but I suspect its not that far off. Now is it the ethanol that is inefficient or the SUV?

    The energy in gas, doesn't just appear, it had to be stored at some point so the surely the issue is that the SUV eats more in a week than your family eats in a year, be it fossil fuel or corn.

    Lets look at some other options. Smaller EU cars like the Smart or Japanese minis like the Yaris get twice as much bang per gallon. 125cc four stroke motorbikes make Smart cars look like SUVs (two strokes are as bad as diesels for pollution). A 500cc bike will eat up american highways, carry a passenger and enough luggage for communting. They're faster than 90% of cars and still get over 50 mpg. Oh, and they're fun. If you can swap to a bike for your commute and all the single passenger journeys you'll actually save money, time and the environment. Better yet, fuel cell motorbikes are starting to be produced in the UK albeit with a very young technology (they kind of remind me space age Indians... you can see that they have the potential for greatness).

    Then there is the use of horse. They sure eat a lot of grain, but is it anywhere near as much as an SUV? Sure you've got long highways to deal with, but America was forged with the horse. It can be so again, although I'd be suprised if it could stay a federation. Fedral government needs good communication to survive. Even was spilt into many kingdoms before the Romans came along and gave us roads (oh and Alfred the Great kicking some danish arse didn't hurt either).

    Or perhaps the real answer is bread power. One loaf of bread contains enough energy to propel a bicycle for over a hundred miles. If you want to do a direct comparison, you could even run the bike of ethanol (although most civilized nations have rules about drink driving).

    Like I said, I agree there are better options than ethanol from corn for powering an SUV. But you I think the real question is, is there a right way to power an SUV?

    --
    Scared of flying, pointy things snce 1979!