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New Solar Cell Harvests Hydrogen From Water

Engadgets is reporting that researchers at Penn State have built a new kind of solar cell that can harvest hydrogen directly from water. "The folks at Penn State have now developed a process that more closely mimics the photosynthesis process in plants, and while we won't pretend to understand all the nitty gritty of dye usage and other such nonsense, we do know that such a system could eventually attain 15% or so efficiency, providing a nice and clean way to gather power for that fuel cell car of the future."

15 of 222 comments (clear)

  1. 15% efficiency by paulej72 · · Score: 2, Interesting

    I thought that current solar cells have efficiencies of up to 40%. So how is this better?

    1. Re:15% efficiency by cyfer2000 · · Score: 2, Interesting

      Solar cells with 40% efficiency are for aerospace applications and prohibitive pricey. BTW, the grass in your backyard has an efficiency about 1%.

      --
      There is a spark in every single flame bait point.
    2. Re:15% efficiency by orclevegam · · Score: 5, Interesting

      The real interesting point about this though is that it skips the extra electrical load to free the hydrogen from the water. Assuming there are no gotchas with the production of the dyes and such that make up this system, it could be the most ecologically sustainable system yet. The big problem with most of our fuel sources is that they either A) are non-renewable (oil), B) create greenhouse gases (oil, coal, ethanol), C) are non-portable (solar, wind, geothermal, nuclear [for anything but heating]), D) create radioactive (or hazardous in general) waste (nuclear), or E) Have higher energy input than output (hydrogen, and some say ethanol). Assuming this system works using just the dyes, water, and sunlight, that eliminates the high energy need to produce the hydrogen, thereby giving us a ultimately solar based energy system that's also portable. Of course we also need to get engines that run on hydrogen that are also safe and efficient, but this is a step at any rate.

      Now, what concerns me about this system is that usually the dyes used in these things are rather short lived and tend to break down after hardly any time at all. Maybe this should be one of the first real uses of biotech, we should engineer some microbes that produce this dye and live off O2 and water (and various proteins naturally), then we just harvest the excess hydrogen.

      --
      Curiosity was framed, Ignorance killed the cat.
    3. Re:15% efficiency by aardvarkjoe · · Score: 2, Interesting

      According to http://en.wikipedia.org/wiki/Electrolysis#Electrolysis_of_water, electrolysis of water to produce hydrogen has an efficiency of more than fifty percent, at least theoretically. If that's true, then you might be better off using the 40% efficient cell to generate hydrogen at 20% efficiency, rather than using this new cell to generate hydrogen directly at 15% efficiency.

      Of course, there are lots of other factors which might make using the new one more attractive. In particular, it certainly seems possible (based on nothing but the information in the summary) that these cells might be cheaper, more reliable, or better suited for small-scale use than the combination of solar cells + electrolysis equipment. If so, then they might be a better choice for installation in remote locations or in people's homes.

      --

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    4. Re:15% efficiency by ACMENEWSLLC · · Score: 4, Interesting

      I'm not sure I understand why my car needs to have a power plant in it. Why can't it just have a large capacitor or bank of batteries, which I can swap out at the filling station? Obviously I am not going to wait for charging at filling time, but why not just swap out the uncharged capacity for charged capacity much as we change out propane tanks?

      Then the power can be generated on the grid. If that is nuclear, coal, hydro, solar, or wind power - it can be whatever makes sense for the region. What ever is used, the filling station grabs the electricity from the grid and charges up batteries or capacitors. I swap mine out for a charged one and pay for the service.

      Seems to me that this is something we could do now. Seems to me this way we could adopt newer, cleaner sources of power much quicker than waiting the life span of the auto.

    5. Re:15% efficiency by HexaByte · · Score: 3, Interesting
      The practicality of your idea fails on several fronts.

      For one, there is no standard battery pack, nor could there be without making all the systems similar enough. How would you like to own an electric sports can that has the same battery pack as a single seat local commuter vehicle? There's also the need to invest in sufficient numbers of battery packs by the stations to meet consumer need. Many gas stations server over 1k customers a day! Even counting that the batteries are being charged and then re-used, you'd have to have 250 packs to service a station open for 16 hours/day with a 4 hr. mean charge time.

      There's also the issue of battery life. Since every battery eventually needs to be replaced, you have to have a way to track and credit or debit the customers for bringing in new or almost defunct batteries. That means every battery would have to have a battery life indicator on it, and a complex formula worked out for pricing. You: "I need recharged batt-paks." Service station attendant: "I only have once-recharged, and your's are at end-of-life, that'll be $1285.60, plus tax." You: "But I only need to go 50 more miles, I have brand new ones at home!"

      --
      HexaByte - he's a square and a half!
  2. photosynthesis by wizardforce · · Score: 4, Interesting

    The water splitting requires 1.23 volts, and the current experimental configuration cannot quite achieve that level so the researchers add about 0.3 volts from an outside source. Their current system achieves an efficiency of about 0.3 percent.
    perhaps they should take a lesson from real photosynthesis and use an equivalent of a second photosystem. in photosynthesis,photosystem II is excited to a higher state followed by an electron transport system producing ATP then with a second photon to excite photosystem I which produces the reducing equivalent required for further reactions.
    --
    Sigs are too short to say anything truly profound so read the above post instead.
  3. Re:Energy from water... by Smidge204 · · Score: 2, Interesting

    Thermal Depolymerization can convert almost any organic substance into raw hydrocarbons. So yeah, converting humans into oil is entirely possible.

    That's actually how I'd prefer my body to be disposed of when the med students are done with it. Burying corpses is so wasteful in the grand scheme of things.
    =Smidge=

  4. Re:You don't need high efficiency though... by arizwebfoot · · Score: 3, Interesting

    Perhaps, the paint on the car can be treated in some way to act as the acceptor for the sun and thus be converting water into hydrogen "on the fly"?

    --
    Beer is proof that God loves us and wants us to be happy.
  5. Re:15% by wizardforce · · Score: 2, Interesting

    there's nothing saying we couldn't use energy from nuclear plants to electrolyze water but considering the sheer amount of energy in the form of sunlight that is available, ignoring it is not an option. as you said, storing hydrogen is the problem although we have catalysts to react carbon dioxide and hydrogen to form numerous compounds, hydrocarbons, misc carbohydrates, even plastics. imagine it, using sunlight or nuclear power to reduce and remove carbon dioxide from the air while simultaneously making more plastics, the more plastic produced, the more CO2 is removed from the air- harnessing consumerism to help the environment!

    --
    Sigs are too short to say anything truly profound so read the above post instead.
  6. ...about those hydrogen cars by Sandbags · · Score: 5, Interesting

    Well, personally I don't care how we get H2. It's all pointless anyways. H2 will never be a common fuel for motor vehicles.

    Here's why:
    In regards to using liquid H2 in vehicles:
    - It's too dangerous. You're driving a bomb. Every car using liquid H2 is a has-mat vehicle by legal definition. Imagine the terrorists glee where they don't have to rent a car and then build a bomb because the rental car IS a bomb.
    - it must be trucked in liquid form - can't be pipelined, and therefore we'll have to deal with massive supply issues, thouands more has-mat trucks on the roads, and reduculous logistics.
    - fuleing requires extensive safety measures and extremely specialized and expensive equipment
    - you either have MASSIVE pressurized tanks (taking a very large portion of your vehicle space and weight) or you have to have the H2 actively cooled to extremely cold termurateres, requiring the car to be powered 100% of the time.

    For metal infused H2 gas vehicles:
    - well, it's much safer... but:
    - maximum range uning even theoretical technologies is about 220 miles per fill up, assuming you leave enough seating room in a large SUV for 5 people and no luggage.
    - the tank is huge, and weighs hundreds of pounds, eating at vehicle efficiency and space (too big for those small commuter cars in Europe)
    - IT TAKES UP TO 8 HOURS TO FILL UP, and requires active cooling to prevent explosions while doing it.

    H2 in general:
    - it's dangerous to use a vapor gas as a fuel. Imagine auto shops all over the country having to worry about gas being spilled during repairs? Spill hydrocarbon, just avoid dropping a spark in the liquid until you soak it up with sawdust. Cause an H2 leak and you have to evacuate the building, no different than a natural gas or propane leak. Also, if liquid H2 leaks, you not only have to worry about combustion, but vapor expansion and extreme freeze issues.
    - It costs 3-5 times more energy to make it that it would to simply run the car on electricity
    - It's expensive. best estimates, you go the same distance on H2 for 2-4 times the cost of gasoline, and that's with all the current government funding lowering the costs.
    - Where do you plan to store all the H2? Large scale containers are very difficult to make assuming you're storing it in liuquid form. We simply don't have enough room to store it in gaseous form.
    - Fuel cells don't get repaired, they get replaced. The repair costs will be immense, collision insurance even worse (not to mention the danger issues insuring rolling bombs).
    - burning H2 directly in ICEs is barely more efficient than burning ethanol.
    - minimum car price. You can forget about those $7,000 cars. Minimum price for a fuel cell vehicle will be in the 20K range once the government subsidies stop becoming affodable.

    no, we can't power every vehicle on earth on ethanol
    yes, we will run out of oil, sooner than you like to admit
    yes, we havre to do something, but what?

    What is the answer? Super conducting electrical grids (which we can make today with existing technology at reasonable costs), fed by renewable energy in target locations around the world (wind farms where it's windy, water where there's natural falls, solar in the deserts, etc). We use all that to recharge plug-in cars using batteries from Toshiba and others companies that have already been developed which have as quick as 90 second recharge times. For those of you who say we can't do it, that we can't run recharge units all around towns for people to plug into on the run, well look at how Alaska has done it, and many other countries in the fridgid north of Europe, where cars that don't have engines running need to be plugged so their heaters can prevent fuel lines from freezing. Every parking meeter in some coutries have power cables attached. We CAN do it. It's been done before. We'll still use ethanol as a backup to the battery using ethanol in ICEs until small turbines (like BMW uses in their motercycle) become more cost effective through mass production.

    --
    There is no contest in life for which the unprepared have the advantage.
    1. Re:...about those hydrogen cars by Anonymous Coward · · Score: 1, Interesting

      your reasoning is totally flawed. hydrogen can easily be converted into more convenient hydrocarbons, albeit with an energy efficiency loss. but it may be worth for the easier handling/reuse of current infrastructure. with respect to hazards, H2 is actually less dangerous than gasoline (flame burns upwards, and h2 quickly lifts away from the ground, where people tend to be)

      the one HUGE advantage of hydrogen over electricity production is storability. Try to store the reaction energy of 1 kg of H2 within a magnetic or electric field. I don't want to be near your test. Also, try to heat your house with a solar cell in winter...

      And for those doubting there's not enough sunlight energy: the sun irradiates the earth (~12000km wide disc) with roughly 100 Exawatt. That's about 10 Gigawatts per human being. Or, terms of imperial units, 50000 Hummers/American. This is literally more Energy than we will likely ever need.Given a 0.1% of landspace dedicated to h2 production, 1-3% efficiency (like plants) would be totally enough, 15% would be awsome!. but all boils down to the cost of the cell. Efficency is no problem when the the cell is really really cheap.

      You can quote me with "10^20 Watts ought to be enough for everyone" ;)

    2. Re:...about those hydrogen cars by evilviper · · Score: 2, Interesting

      It's too dangerous. You're driving a bomb.

      As opposed to current gasoline vehicles, which are non-flammable.

      Imagine auto shops all over the country having to worry about gas being spilled during repairs?

      Every auto shop I've been too has very high ceilings, and big, wide open doors that can easily vent TONS of vapor.

      Cause an H2 leak and you have to evacuate the building, no different than a natural gas or propane leak.

      When my idiot neighbor put a shovel through a natural gas line, the fire department didn't tell us to shut off our cars, avoid open flames, etc.

      I'd be happy to barbecue a few yards away from a hydrogen leak. Completely the opposite of a gasoline spill.

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  7. Re:You don't need high efficiency though... by afidel · · Score: 2, Interesting

    The way to deal with dents is to use lots of interconnections and make the transport system from a tube in a tube design. The outer tube contains a polymer that hardens when exposed to H2O, any dent significant enough to cause the tubing to burst seals itself and the interconnections route around the blocked tube. Think of it as a cross between internet routing and the bodies clotting system =)

    --
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  8. Re:Wrong. by overunderunderdone · · Score: 2, Interesting

    Electric heat pumps can actually get more heat in your home than they use to do it.

    Heat pumps as the name implies aren't generating heat, they're moving it from one place to another and heat pumps using chemical fuels (like natural gas) also get more heat into your home than they use to do it. I doubt converting electrical energy to heat via resistive heating is any more efficient than converting a chemical to heat via combustion. (Certainly not when you consider that most of that electricity is generated using the exact same chemical combustion to produce the same heat, to produce pressure, to spin a turbine, to generate electricity, carried with transmission losses to your electric heater.)

    The ONLY reason that chemical fuels seem valuable now is because we essentially get them for free. Or rather, all the work has already been done to store the energy. We just need to dig it up, refine it a bit, and get it where it is needed.

    Certainly that's PART of the appeal but I think it's also significant that you can easily store chemicals but it's hard to store electricity. This is particularly relevant when what you want to do with the energy is transportation where you have to store the energy in the vehicle itself. (There are of course modes of transportation like trains which have set routes and it can be arranged that they can be plugged into the grid on those routes, but there are obvious limitations to such vehicles which vehicles that store their own energy don't face)