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New Electron Microscope Shows Atoms in Color

Cornell's Duffield Hall has acquired a new electron microscope that is enabling scientists to see individual atoms in color for the very first time. While old electron microscopes can be compared to black and white cameras, this new scanning transmission electron microscope uses a new aberration-correction technology that is both more intense and allows for faster imaging speed. "The method also can show how atoms are bonded to one another in a crystal, because the bonding creates small shifts in the energy signatures. In earlier STEMs, many electrons from the beam, including those with changed energies, were scattered at wide angles by simple collisions with atoms. The new STEM includes magnetic lenses that collect emerging electrons over a wider angle. Previously, Silcox said, about 8 percent of the emerging electrons were collected, but the new detector collects about 80 percent, allowing more accurate readings of the small changes in energy levels that reveal bonding between atoms."

25 of 110 comments (clear)

  1. Not color, false color. by oskay · · Score: 4, Informative

    These atoms are color coded, not *seen* in color by the microscope.

    1. Re:Not color, false color. by Spudtrooper · · Score: 3, Funny

      Ted Turner, eat your heart out.

    2. Re:Not color, false color. by kebes · · Score: 5, Informative

      I'm not sure what the actual innovation is here. Using false-color in an image is certainly not the innovation. What is innovative is their use of corrective optics to achieve much higher signal (100-fold increase compared to conventional techniques), and the integration of energy-loss spectroscopy. This means that for each pixel in the image, they can determine what kind of atom is being measured. So they can generate false-color maps of atomic identity. Most electron microscopes simply measure electron density: you can guess which element is which based on density, but there can be ambiguities. Some microscopes include detectors for determining what elements are present, but not with high spatial resolution. This new refinement allows precise maps where individual atoms can be both localized, and elementally identified.

      The image they show is impressive when you consider that each blob of color is actually an individual atom, and that they've identified exactly what kind of atom is at each position. In this case they were using it to analyze interdiffusion of atoms at an interface. As nanotechnology becomes more and more 'real' you can imagine how useful it will be to image nano-objects with atomic resolution and elemental discrimination.
    3. Re:Not color, false color. by koolguy442 · · Score: 5, Informative

      Not to get too technical here, but each blob is actually a column of atoms, as the specimen is wedge-shaped and certainly more than one atomic layer thick.

      Electron energy-loss spectroscopy (EELS) has been combined with STEM imaging for several years at least, allowing similar sorts of images to be synthesized. The major contribution of this work is that they've modified the optics so that, even at 0.5 angstrom beam widths (and hence pixel sizes), they still get enough signal to the EELS detector to allow for EELS mapping and spectra acquisition for each of those pixels, giving direct bonding information about the particular portions of atoms probed by the beam. That means that the researchers can tell the difference between titanium atomic columns at different locations within the crystal, depending on the other atoms surrounding them.

      Well, I suppose I did end up getting too technical.

      IAATEL (I am a transmission electron microscopist)

    4. Re:Not color, false color. by davros-too · · Score: 2, Interesting

      The scientists quoted are top notch. I used to work with David Muller, and you can trust this to be both scientifically sound and bleeding-edge technically.

      I was *almost* doing this in the 1990s. I could have showed you a coloured image at atomic resolution with colours based on EELS spectra, but IIRC the contrast was mainly from electron-channeling and therefore bullshit. I'm confident that these guys have eliminated such effects.

      The uses of this technology in materials science will be enormous.

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      In theory, there's no difference between theory and practice; in practice there is.
  2. Schrodinger's Fridge by sm62704 · · Score: 4, Insightful

    The summary didn't say, but the colors MUST be false color, since atoms are smaller than light wavelengths. But will it allow you to photograph atoms without destroying them? (yes the link is humorous, but the question I ask is serious)

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    1. Re:Schrodinger's Fridge by sconeu · · Score: 2, Funny

      But do we know if Schroedinger has milk in his Fridge without looking?

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    2. Re:Schrodinger's Fridge by Anonymous Coward · · Score: 2, Funny

      Let's hope he has milk. Otherwise his poor cat would starve to death.

    3. Re:Schrodinger's Fridge by esocid · · Score: 3, Informative

      I doubt that they still survive the process. Organic cells are destroyed due to the direct irradiation with electrons necessary to produce the "photograph" from the microscope. There are ways around this, such as only focusing the beam on a small part of a specimen or to use a deflection technique that minimally exposes the specimen and deflects the electron beam to the viewing stage. Others are preirradiating the specimens at low doses to stabilize them for increased irradiation. There are other complex techniques outside the realm of my understanding, but I think it still is really tough to preserve organic cells during electron microscopy.

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      Absolute power corrupts absolutely. indymedia
  3. Proof at last... by pushing-robot · · Score: 4, Funny

    So we'll finally know for certain that carbon is black, oxygen is red, nitrogen is blue, and hydrogen atoms really are white.

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    1. Re:Proof at last... by Actually,+I+do+RTFA · · Score: 2, Funny

      hydrogen atoms really are white.

      So that is why the Hindenburg didn't use Helium.

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  4. Atoms don't have color! by ramk13 · · Score: 5, Insightful

    At least not how they are implying. Color as most people think of it has to do with absorbed, reflected and transmitted light. The arrangement of the atoms as much as the atoms themselves affect color. But individual atoms in a crystal don't have color, at least as most people understand. The headline makes it seems like you could come away saying, "So iron atoms really are red..." or something equivalently silly.

    1. Re:Atoms don't have color! by Jesus_666 · · Score: 4, Funny

      They just use smaller light, duh!

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  5. Re:False Color by dido · · Score: 2, Insightful

    After all, an atom is smaller than a wavelength of visible light, so atoms are quite literally colorless.

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  6. Re:This thread is useless without pics! by pushing-robot · · Score: 5, Funny
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    How can I believe you when you tell me what I don't want to hear?
  7. Yow! by $RANDOMLUSER · · Score: 2, Interesting

    A STEM shoots an electron beam through a thin-film sample and scans the beam across the sample in subatomic steps.
    Holy crap! And we think 45nm is small!
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    No folly is more costly than the folly of intolerant idealism. - Winston Churchill
  8. What do the electrons "reflect" off of? by JoeGee · · Score: 2, Insightful

    Most of the space occupied by the atom is exactly that, space, nothing more. The electron cloud is a fuzzy region of probability, not a solid thing. The "side" of an atom must be defined by a force, not a particle?

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    1. Re:What do the electrons "reflect" off of? by esocid · · Score: 2, Interesting

      It isn't so much a question of reflection, but more of capturing the excitation of electrons in the atoms that make up the sample by absorbing the irradiated energy. The electrons are excited into higher orbits, which gives off light that the "camera" on this microscope captures and resolves into a cleaner image. That is why organic samples are pretty much goners in EMs. They can't survive that much radiation.

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      Absolute power corrupts absolutely. indymedia
    2. Re:What do the electrons "reflect" off of? by kebes · · Score: 4, Informative

      Most of the space occupied by the atom is exactly that, space, nothing more. The electron cloud is a fuzzy region of probability, not a solid thing. The "side" of an atom must be defined by a force, not a particle? You're right that an atom is mostly empty space, but that doesn't matter. An electron microscope works by shooting a beam of electrons at the sample, and measuring how many of those electrons are transmitted (this is called a TEM; an SEM works differently). The electrons that didn't go straight through the sample were scattered by the atoms of the material. Remember that electrons are charged: as the incident electrons travel through the atoms there will be very strong Coulomb forces. The incident electrons will be repelled by the electrons in the material. This interaction is 'long-range' by subatomic standards: even though the electrons themselves are vanishingly small, the Coulomb interaction distance is quite large.

      To a first approximation, 'heavier' atoms (higher atomic number) will scatter electrons more strongly, since they have more electrons. On an electron micrograph, heavy atoms show up as dark (absorbed/scattered alot of electrons), whereas lighter atoms show up as being bright (most electrons were transmitted).

      I'm glossing over many details, of course. The important thing to remember is that the incident charged electrons are interacting with the charged electron density surrounding the atoms in the material.
    3. Re:What do the electrons "reflect" off of? by Quadraginta · · Score: 2, Informative

      The electron cloud is a fuzzy region of probability, not a solid thing.

      Ah, the evil remnants of a flawed basic chemistry and/or atomic physics class.

      Just FYI -- not that it relates to this article -- this is wrong. So far as we know, an electron is a point particle, and the electrons in an atom aren't any different from a free electron. They are a collection of little points located at various definite positions. There's no "fuzziness" and they aren't "smeared out" in any sense at all. The "fuzzy cloud" you see drawn around atoms is just the probability distribution of where the electrons are. It's only fuzzy for the same reason a photo of a bridge at night shows the car headlights all smeared out: the image you've chosen to construct averages over some very fast motion in which you're not interested.

      It's amazing to me how often people end up so often misunderstanding [x,p] = ih, and how often teachers misstate its implications. It's not that you can't pinpoint the position of an electron exactly. It's that if you do, it then has a very indeterminate momentum, and you now have no clue where it will be in a few moments.

  9. Real Harmonic Color by Doc+Ruby · · Score: 3, Interesting

    I'd like to see these atoms rendered in necessarily false color (they're smaller than visible light wavelengths) that is at least the color corresponding to their size. They're smaller than visible wavelengths, but their actual size is a specific fraction of a visible wavelength. Let's see the atoms colored with the color that's a harmonic multiple.

    Or maybe the color should be derived from the "texture" of the atom, just like the actual color of macroscopic materials. If a carbon atom has 12 electrons evenly distributed around a sphere in shells (2, 8 and another 2 in valence), let's see it get colored accordingly. Maybe the inner shell's diameter harmonic color in the visible range, divided by 2 and scaled back into the visible, overlapped with the same algorithm for the outer 8 in the second shell, then again for the 2 in the outermost shell.

    The point is that these colors can mean something. And since the number and combination of electrons is so important to the characteristics of the electron, as well as offering the femtoscopic equivalent to macroscopic colored surfaces, I'd like to finally see what I've been imagining since high school chemistry class.

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  10. Screenshot by peterpi · · Score: 5, Funny

    Screenshot:

                    .

  11. Actually, it *is* real color. by CustomDesigned · · Score: 2, Interesting

    The color is based on the energy of the electrons, just like photon "color" is based on the energy of individual photons. The microscope is "color" because it can record the energy of the electrons as well as their density. Thus it is "color" just as much as your eyes - which measure photon energy (cone cells of 2 to 3 or in some cases 4 types) as well as photon density (rod cells). Note that your cone cells require more light to get a color signal. In dim light, you see black and white via your rod cells only - the situation with earlier electron microscopes. By increasing the electron capture 10 fold, true electron color vision is enabled.

    1. Re:Actually, it *is* real color. by davros-too · · Score: 2, Interesting

      Sorry, no. The colours are atom types as inferred from the energy loss spectra - for example in one image lanthanum is coloured green.

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      In theory, there's no difference between theory and practice; in practice there is.
    2. Re:Actually, it *is* real color. by CustomDesigned · · Score: 2, Interesting

      Yes, energy loss spectra - as in electron energy. As in "color". Electron energy is "color". Just like photon energy.