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World's First Battery Fueled By Air
Hugh Pickens writes "The Telegraph reports on the revolutionary 'STAIR' (St Andrews Air) battery could now pave the way for a new generation of electric cars, laptops and mobile phones. The cells are charged in a traditional way but as power is used an open mesh section of battery draws in oxygen from the surrounding air that reacts with a porous carbon component inside the battery, which creates more energy and helps to continually 'charge' the cell as it is being discharged. The battery has a greater storage capacity than other similar-sized cells and can emit power up to 10 times longer. 'The key is to use oxygen in the air as a re-agent, rather than carry the necessary chemicals around inside the battery,' says Professor Peter Bruce of the Chemistry Department at the University of St Andrews. 'Our target is to get a five to ten fold increase in storage capacity, which is beyond the horizon of current lithium batteries.'"
Would there be any danger of using this in a confined space? Any clue on how much oxygen this thing is churning through?
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Or is just hot air?
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Sometimes things sound too good to be true. Risk-free money smuggling from Nigeria. Enormous genitals from a few pills. Whiter teeth using only household chemicals. Articulate and clean presidential candidate who seems like he can fix anything.
Extending the life of batteries using the air sounds like a great thing. But what is the hidden problem that we are overlooking here? Will the chemical reaction of the battery and oxygen deplete the batteries faster than standard LIon? Are the batteries heavier? Output less power? Require usage patterns that aren't typical for normal users?
It just sounds too good to be true.
Now we just need to create a battery that recharges using CO2. That would be the invention of the century.
/. gets this kind of miracle technology often, most of the stuff has also an "Achilles heel" that prevents real worlds deployment.
This might be an exception (hopefully), but until you can get one off NewEgg people stay cool and cautious.
There is next to no information in the first article... this one is much more informative:
http://www.theregister.co.uk/2009/05/19/lithium_oxygen_stair_battery/
The concept (taking one of the reagents from air) is not new. There were zinc-air batteries for decades, and they are widely used. They have one of the highest energy densities of all types of commercially available batteries.
http://en.wikipedia.org/wiki/Zinc-air_battery
Seems like four years ago somebody even figured out how to make them electrically rechargeable (before that, the usual method of recharge was to replace the zinc plates and remove oxide waste, which was facilitated by cell design).
http://www.eetimes.com/news/semi/showArticle.jhtml?articleID=164903727
However, if those new batteries use carbon instead of zinc, they might have a higher theoretical upper bound on energy density. It looks like they're using graphite-lithium intercalate for the negative electrode (a standard thing), and the positive electrode is essentially a combined catalyst/adsorbent for Li2O2 which forms during electricity generation.
CnLi ---> Li+ + Cn + e
2Li+ + 2e + O2 --cat.-> Li2O2
Note that the first article is rather bogus: O2 does not "recharge" the battery, it is only a reagent.
I'm not familiar with the cost breakdown for the components of Li-ion batteries, but lithium seems like a major contributor, so this might not be much cheaper than the traditional Li-ion.
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