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Lithium Air Batteries Get Boost From IBM and DOE

coondoggie writes "The Department of Energy and IBM are serious about developing controversial lithium air batteries capable of powering a car for 500 miles on a single charge – a huge increase over current plug-in batteries that have a range of about 40 to 100 miles, the DOE said. The agency said 24 million hours of supercomputing time out of a total of 1.6 billion available hours at Argonne and Oak Ridge National Laboratories will be used by IBM and a team of researchers from those labs and Vanderbilt University to design new materials required for a lithium air battery."

21 of 240 comments (clear)

  1. Hopefully not vaporware. by samurphy21 · · Score: 4, Insightful

    Because this is a game changing technology, if it pans out.

    1. Re:Hopefully not vaporware. by maxume · · Score: 4, Insightful

      "Affordable" isn't going to be anytime soon, at least not for comparison shoppers. Even at $5 a gallon, a decent sedan will go 100,000 miles on $20,000 of fuel (and neither of those assumptions are particularly aggressive, that $20,000 might get you closer to 250,000 miles).

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    2. Re:Hopefully not vaporware. by Rei · · Score: 5, Interesting

      Lithium-air is, IMHO, one of the least promising upcoming battery techs. It's really more like a fuel cell, and to be blunt, fuel cells suck. By that, I mean:

        * Expensive per watt
        * Short lifespans
        * Inefficient

      There are many, many promising next-gen battery techs other than li-air. Here's just a couple of my favorites.

      Lithium-sulfur: This has long been worked on, but only just recently one of its big problems has been worked around. It offers great energy density, but some of the intermediary reaction products -- various lithium polysulfides -- are rather soluble. They'd migrate across the membrane and precipitate out on the other side, being rendered permanently useless to the reaction and thus aging the cells very quickly. Older solutions to try to prevent this caused dramatically lower energy density. The latest technique involves wicking the sulfur into the pores of mesoporous carbon and then functionalizing the outside of the carbon with polyethylene glycol to keep the hydrophobic polysulfides inside when they form. The longevity improvements were amazing, without sacrificing energy density. We're talking that when they deliberately chose a worst-case solvent, one that's really good at dissolving polysulfides, the traditional Li-S cell lost 96% of its sulfur in 30 cycles while theirs only lost 25%.

      Nickel-lithium: It is, quite literally, a hybrid NiMH/li-ion battery -- a traditional NiMH cathode that can hold a tremendous amount of lithium, and a lithium metal anode (almost obscene anode energy density). That's normally impossible, since you want to run a NiMH battery with an aqueous electrolyte and your various lithium-based cells with an organic electrolyte. They do both -- they use a new tech called a LISICON membrane to keep the two different electrolytes apart but allow lithium ions across. An additional problem with li metal anodes is that dendrites tend to form that rupture the membrane -- but LISICON membranes are a rigid ceramic that resists dendrite damage.

      Digital quantum battery: This is my favorite, because it comes straight out of left field. It's really a type of capacitor. Now, capacitors normally hold a lot less energy than batteries; if the voltage gets too high, you get dielectric breakdown, it arcs across, and your energy is lost. But at very tiny scales, current must move as quanta. So if instead of a single big capacitor, you lithographically print an array of nanoscale capacitors, all of the sudden you can make it so that you essentially can't get dielectric breakdown. In fact, you can store so much energy that the stresses become so great that it's best to use a carbon nanotube for one of the electrodes in each nano-capacitor. :)

      And even ignoring next-gen battery techs, there is still *huge* range for improvement in li-ion. In particular, for the cathodes, my favorites are layered manganese cathodes which alternate long-life forms and high energy density forms of magnanese oxides to get both properties; and fluorinated metal cathodes. For the anodes, there's many kinds of tin and particularly silicon anodes out there that store nearly an order of magnitude more lithium than conventional graphite anodes. Silicon anode li-ion cells are just this month starting to hit the market. The tech has finally matured to the point where their longevity is sufficient.

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    3. Re:Hopefully not vaporware. by Rei · · Score: 4, Informative

      Accord. Prius.

      The Prius depreciates a lot as soon as you drive it off the lot, but less than half as much each year after that -- despite being a more expensive vehicle.

      Efficiency = low depreciation for the long run.

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    4. Re:Hopefully not vaporware. by Rei · · Score: 4, Informative

      Oh, and also, to help you "extrapolate" properly in the future:

        * EV drivetrains are currently handmade in small volumes, so they're very expensive. Even a low-end AC drivetrain will cost you about $10k (say, a DMOC445, AC24LS, and a Manzanita Micro PFC charger). A good one like the AC-150 that the Roadster's drivetrain was originally based on will run you more like $25k.
        * The Tesla Roadster's pack is very, very different from the Volt's, so it's not a good idea to compare the two. The Roadster's is a high capacity based on cobalt cells with a massive cooling system and a high DoD. The Volt's is low capacity based on manganese cells with a smaller cooling system and a low DoD.
        * The Tesla Roadster is a luxury carbon fiber sports car that does 0-60 in under 4 seconds. You get what you pay for.

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    5. Re:Hopefully not vaporware. by Korin43 · · Score: 4, Insightful

      If you're looking to reduce your environment impact, I'd guess that living closer to work will have a much larger effect than buying a different car.

    6. Re:Hopefully not vaporware. by iamhassi · · Score: 4, Funny

      "I'd guess that living closer to work will have a much larger effect than buying a different car."

      with the current job market people would be moving twice a year to keep up. Might as well just get an RV and live your new employer's parking lot until they go bankrupt and you have to change jobs again.

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    7. Re:Hopefully not vaporware. by fractoid · · Score: 4, Informative
      NiMH batteries are terrible compared to LiPoly or nanophosphate lithium batteries. The only reason we're still stuck with them is manufacturers trying to gouge back the R&D costs that they sunk before lithium batteries appeared and sunk their NiMH market.

      Metal-air battery chemistries have been used before in EVs - specifically zinc-air batteries - but they are generally primary cells and need to be mechanically recharged. TFA mentions charging so possibly the lithium-air cells are proper secondary cells. Also, the specific power of air-based batteries is historically very low, and I note that the only mention of power in TFA is where they say:

      The most important [scientific challenges] are to realize a high percentage of the theoretical energy density, to improve electrical efficiency of recharging, to increase the number of times the battery can be cycled, to limit the negative effects of moisture in the air, and to improve the power density.

      Of course you could always do a hybrid battery pack using Li-Air for bulk storage and nanophosphate lithium or even ultracaps for load levelling.

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  2. absolutely by Anonymous Coward · · Score: 4, Funny

    Absolutely a game changer. In fact, I got a real charge out of reading about them. The current methods are terminal. I was much more depressed before reading about these things. I think the technology really has potential. Hopefully they will cell, but they might have to amp up the advertising.

  3. Overstated by Areyoukiddingme · · Score: 4, Interesting

    capable of powering a car for 500 miles on a single charge - a huge increase over current plug-in batteries that have a range of about 40 to 100 miles

    Current plug-in vehicles? Like, what a Chevy Volt or a hacked Prius? Nonsense. Try a Tesla Roadster, with a single charge range of 250 miles. Lithium-air might double the range then. But a factor of 5? No.

    I do have one question though. How are lithium-ion batteries affected by increasing cell size? The Tesla Roadster currently uses a ridiculous number of very small cells in its pack, in a move that looks dictated by ridiculous patent licensing terms limiting cell sizes to those suitable for laptops in an effort to prevent the existence of something like the Roadster. That's what it looks like. But is there a technical reason to limit cell size? There is surprisingly little information available about how the performance of lithium cells change as they get physically larger (or smaller).

    1. Re:Overstated by dragonsomnolent · · Score: 4, Informative

      I had read once that they were using the same technology as laptops so that they could let laptop battery manufacturers do the heavy lifting on battery R&D (a sensible approach I suppose) and after reading thier pdf about the batteries it seems to hint that they use them because they are cheap, standard (same ones used in laptop batteries), and should one fail, it doesn't affect the entire system as much overall (there is no mention of fire damage however). I'm sorry that I can't answer your question regarding increase or decrease of performance as size increases. But it doesn't seem Tesla is using small cells to avoid patent licensing issues (after all, Wikipedia indicates that they license their AC Motors in the Roadster)

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    2. Re:Overstated by Rei · · Score: 4, Informative

      The person who responded to you first is indeed correct. It's not about patents; you're mixing up this with the old EV1 debacle. The Roadster uses 18650-format cobalt/graphite li-ion cells, which are already in mass production. They did this for obvious reasons; when they started out, the phosphates and spinels that everyone else is now using weren't really available.

      As for fire, which the previous person commented on, each cell is contained within its own can that's designed to isolate failures to just that cell. It's a pretty complex pack indeed. Future EVs won't have such a complex pack. It's doubtful that even the Model S will, even though it's still going to be based on cobalt tech (that's what Tesla has experience with, after all -- and despite all its downsides, it is quite energy dense)

      If you're curious as to how the pack is structured, there are 11 "sheets", each one made of 9 "bricks", and each of those made of 69 cells. Each of the cells in a brick are wired in parallel. The failure of one, therefore, has relatively little impact on the performance of the brick. The bricks and sheets are wired in series. Each sheet monitors the performance of all of its bricks and does load balancing on them, as well as logging failures. It's a pretty impressive piece of engineering.

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  4. Re:looks like another pinto car by John+Hasler · · Score: 4, Insightful

    > They use highly flammable metals to do this so we will have another round of
    > explosive cars out on the highways...

    Anything that packs enough energy to run a car 300 miles into the volume of a gas tank is going to be potentially dangerous. There's no way around it.

    > ...and being metals they will require some thought into the use of water to
    > put the flames out at accidents.

    Whereas water works real well on gasoline fires.

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  5. Re:looks like another pinto car by Anonymous Coward · · Score: 4, Informative

    Rare earth elements consist of the f-block metals. The first column s-block metals Li, Na, K, Rb and Cs are all alkali metals. Lithium is actually the least reactive metal of the column. Potassium catches fire on exposure to water and Caesium essentially explodes on contact.

  6. Re:Recharge time? by Rei · · Score: 4, Informative

    8 hour charge for how many miles? I don't know about you, but my daily commute isn't 600 miles.

    It's level 1 or level 2 charging at home, and level 3 or higher for long trips. And that's what it's going to be for probably the next century. It doesn't make sense to do it any other way. You only need fast charges when you're taking long trips, so you need fast charging stations available on the road. Around home, you want slow charging, which is gentler on the batteries (and, not to mention, the grid), as well as being more efficient.

    By the way, for those who are curious:

    Level 1: ~110V, 20A or less. US standard: SAE J1772 or the ever-common NEMA 5-15 plug.
    Level 2: ~220V, 80A or less. US standard: SAE J1772. European standard: Mennekes, based on IEC 60309.
    Level 3: ~440V, up to "hundreds" of amps. No official standard, but the TESCO connector seems to be becoming dominant.

    The most powerful EV charger I'm aware of is an 800kW charger created by Aerovironment for TARDEC. That's ~800V and ~1000A, if I recall correctly. It's about the size of four vending machines pushed together.

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  7. 24 million hours? So that's.... 2,500+ yrs? by iamhassi · · Score: 4, Informative

    " And after the 1.6 billion hours, does the computer self destruct? Just curious."

    Same. 24 million hours? There's only 8,765 hours in a year, so what is that, about 2,500 years?

    So I googled it. Apparently supercomputer hours aren't people hours, they're processor-hours, so 1 processor working for 1 hour is 1 processor hour. 24 million hours means (# of processors) * (# of hours) = 24 million. For example, (24,000 processors) * (1,000 hours) = 24 million. So it could be done in 41 days, not 2,500 years, if they have 24,000 processors working on it.

    Not sure if I like this method of measuring processor usage since a project that took a million hours in 2001 wouldn't take a million hours in 2010 but that's what's in the article.

    Oh and to answer your question: no, it probably doesn't self-destruct but it'd probably be replaced since I'd imagine if 1.5% is anywhere near my hypothetical 41 days then that'd put 1.6 billion at about 7.4 yrs.

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  8. Re:DOE is serious? by iamhassi · · Score: 5, Informative

    "And after the 1.6 billion hours, does the computer self destruct? Just curious"

    Sorry I'm back and I have answers.

    The Oak Ridge "Jaguar" Supercomputer is the World's Fastest, with 37,376 six-core AMD processors. That puts it at 224,256 processors, so those 24 million hours should be done in 107 hours, or a little more than 4 days.

    The 1.6 billion hours comes from the here: "....computing facilities at Oak Ridge and Argonne national laboratories will employ a competitive peer review process to allocate researchers 1.6 billion processor hours in 2010." That works out to be about 297 days.

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  9. Re:Recharge time and price bigger issue by Rei · · Score: 4, Informative

    The annual energy usage of automobiles is more than the current electricity usage in the US.

    True but grossly misleading. :) The average car has a tank-to-wheel average efficiency in normal combined city/highway driving of about 20%. Your average li-ion electric vehicle has a plug-to-wheel average efficiency under the same conditions of about 85%.

    The reality is that almost no new generating capacity is needed.

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  10. Re:Gasoline's energy density is a fundamental limi by Rei · · Score: 4, Informative

    Gasoline at 50MJ/kg is pretty much the most dense energy storage possible in this universe excluding nuclear energy.

    Not even close. For example, beryllium blows it away in both volumetric and gravimetric energy density (and hydrogen blows beryllium out of the water in gravimetric comparisons, but sucks at volumetric). And comparing any of them to nuclear energy is laughable.

    This is kind of a fundamental limit as to how much energy can be stored in *any* system using potential energy of the electric field of matter.

    No, it isn't. Nor is beryllium. Energy doesn't even have to be stored in chemical bonds (see, for example, digital quantum batteries).

    You may get 2x better efficiency in an electric motor,

    Try 4x in typical driving conditions.

    but I can not see how a battery can approach this value.

    It doesn't need to. A motor the size of a watermelon propels the Tesla Roadster from 0-60 in under 4 seconds. In gasoline cars, the fuel is light and the engine is heavy. In EVs, the motor is light and the "fuel" (the battery pack) is heavy. It's a reversed paradigm. You have to compare the mass and volume of the engine + fuel to the mass and volume of motor + fuel. And with current battery tech, you'll find that EVs are about 1/4 to 1/3 of the way to matching gasoline cars. But batteries have increased nearly 5-fold in energy density the past 21 years, and show no signs of stopping.

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  11. Re:Recharge time? by scdeimos · · Score: 4, Informative

    Didn't anyone ever tell you that the fuse is *meant* to be the weakest link? Now, with your 200 amp fuse/breaker in place you'll burn out the house wiring instead.

  12. Re:Gasoline's energy density is a fundamental limi by Rei · · Score: 4, Informative

    Not even close. For example, beryllium blows it away in both volumetric and gravimetric energy density (and hydrogen blows beryllium out of the water in gravimetric comparisons, but sucks at volumetric).

    Hydrogen was included in TFA comparison.

    Nice try at changing the subject away from the fact that you're quite simply wrong about gasoline being the most energy-dense or nearly most energy dense substance in the universe. It's not even close. If you really want to find the most energy dense chemicals, you need to look at metastable solids. Cubane and nitrogen rings, for example. And there are some theoretical ones that may be even higher, such as triplet helium. These things way, way outclass gasoline in terms of energy density.

    Energy is still stored in the electrical field in matter. A quantum battery needs a lot of infrastructure to handle the forces, so at least 50% of the weight will be wasted. (compare to the weight of a clamp holding a spring.)

    1) "Still"? Chemical batteries don't store energies in electrical fields.
    2) You're trying to bond energy released in a chemical reaction with tensile strength. Tensile strength != energy. And no, they're not related. A beryllium cord has a *lot* less tensile strength than a carbon nanotube cord (orders of magnitude), but releases significantly more energy when it burns.

    No, A small VW diesel has up to 40% efficiency.

    "Up to" != "Average usage". Duh. Diesel cars average about 25% efficiency in typical mixed usage. Engines only get their peak efficiency within a narrow power band.

    An elelctric car may have 90%, but you can only use 60% of the battery without damaging it in a few cycles, so overall, 2x is conservative.

    Wrong on so many different levels.

    1) Efficiency has nothing to do with pack capacity. You're equating the two. 90% *efficiency*. Versus 20% *efficiency*.
    2) The Tesla Roadster uses over 90% of its pack's capacity. Most li-ion BEVs are in the 75-90% DoD range. Not 60%. The Volt uses 50%, but only because A) they're taking an extremely conservative approach, and B) it's a small-pack PHEV.

    You are partially correct. A brushless electric motor can have very high intermittent power density. maybe 10x of a gas engine. It is only limited by cooling. For continous power its power density is the same as a gas engine.

    First off, you're confusing DC and AC motors. All AC motors are brushless. Brushless is a category of DC motors. Secondly, no. The Tesla Roadster can do anything but track duty without a liquid cooling system. With a liquid system it could easily due track duty. And even with just air cooling, it beats the hell out of non-sports cars in sustained power output, despite having an engine much smaller than even non-sports-cars that run on gasoline. And furthermore, how important is track duty to the average person?

    It is actually quite complicated to cool an electric motor.

    No. You can buy motors with the cooling already in place.

    Think 100kW power, and 10kW heat.

    First off, 100kW power is something you'll only ever get during very high acceleration or extremely high speeds. Cruising power is more like 10kW, meaning 1kW heat. Secondly, since gasoline cars average about 20% net efficiency, 100kW of gasoline power output equals *80* kW of heat that you need to get rid of. It's much, much easier for the EV.

    Find an electric motor that had higher energy density than a gas engine for continous output, and I will stand corrected, and learn something new.

    The very one we're talking about. The Roadster's motor can do 2/3rds of its peak output as sustained. And peak output does 0-60 in under 4 seconds.

    Note that the Roadster's motor is hardly the most power dense electric motor out there. Look at the PML Flightlink in-wheel motors used in the Lightning GT, for example. Each in-wheel motor is rated for 120kW peak and are.. well, the size of a wheel.

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