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Carbon Nanotube Batteries Pack More Punch

cremeglace writes "Researchers at MIT have come up with a new way of making batteries from carbon nanotubes. Carbon nanotubes are attractive materials for battery-making because of their high surface area, which can accept more positive ions and potentially last longer than conventional batteries. Instead of this design, the MIT researchers introduced something new — using chemically modified carbon nanotubes as the positive ion source themselves. For now, the new batteries can power only small devices, but if the method can be scaled up, the batteries may provide the power needed for applications like electric cars."

40 of 163 comments (clear)

  1. Battery research by Walterk · · Score: 2, Interesting

    In the last year or so there's been a new battery research story every month promising longer lasting batteries that are smaller and usually cheaper. Yet the most advanced you can buy are still just play Lithium Polymer batteries which seem to power my Android phone for about 15 minutes.

    Call me when this research turns into a produced battery.

    1. Re:Battery research by Hognoxious · · Score: 3, Funny

      Obviously it's [Aliens|Battery manufacturers|the Taliban] who keep [buying up the patents|assassinating inventors|abducting scientists and anally probing them] in order to [build a new caliphate|prevent humans developing interstellar travel|protect their profits].

      --
      Confucius say, "Find worm in apple - bad. Find half a worm - worse."
    2. Re:Battery research by Nadaka · · Score: 3, Informative

      Yes, there are. High end golf clubs, tennis rackets and bicycles are starting to use carbon fiber enhanced with nano-tubes. It isn't 100%, but it is lighter and stronger than more traditional carbon fiber.

    3. Re:Battery research by jeffmeden · · Score: 4, Insightful

      In the last year or so there's been a new battery research story every month promising longer lasting batteries that are smaller and usually cheaper. Yet the most advanced you can buy are still just play Lithium Polymer batteries which seem to power my Android phone for about 15 minutes.

      How weird. The tiny lithium battery I put in my smartphone a year ago still powers it for at least a day's worth of use on a full charge, if not more depending on how little browsing and video watching I do. I won't spoil the ending and tell you what kind of phone I have; I will leave that as an exercise for the reader.

      And for what it's worth, it may feel like an eternity but no less than 10 years ago we had no such fancy-fangled inexpensive lithium batteries for our phones/laptops. If you wanted one, it was gonna cost you, it wasn't going to hold much energy, and it would be dead with about 6 months of regular use. Today's very cheap, highly durable, very energetic lithium polymer batteries are the result of continuous un-sexy research that made headlines in the 80s and 90s, but is still undergoing a lot of change and improvement. The next revolution in battery storage will probably also happen without much fanfare; I hope your phone holds out until then!

  2. Have they figured out the safety aspect? by jeffmeden · · Score: 4, Interesting

    Will they be able to prevent thermal runaway in these better than in, say Lithium based batteries? As density goes up this needs to be more of a concern. Laptops melting down are one thing, but imagine the havoc of a car exploding due to battery failure. That's the last thing the electric car movement needs to have happen.

    1. Re:Have they figured out the safety aspect? by Tekfactory · · Score: 2, Funny

      At least with the Pontiac Fiero, engine fires were truth in advertising!

    2. Re:Have they figured out the safety aspect? by IflyRC · · Score: 4, Interesting

      I fly a lot of R/C models ranging from turbines to electric powered helicopters. The chemistry in the batteries has changed over the years but the highest output batteries right now are lithium polymer. Now, there are some A123 type batteries that are better and getting better but most of the extremely high powered aircraft right now use Li-Po. Battery failures can be caused by several things but what alarms me about putting something like this in a vehicle is the hazard of fire in the even of an automobile accident. When you have a high impact with some of these batteries and a cell is ruptured - the packs begin to puff - then vent. When they vent, the heat is thousands of degrees which will set off other cells in the pack. Think of the old stories about exploding gas tanks in the event of a car crash. Now think of all of these batteries packed into tight places under trunks and back seats and getting rear-ended or even just a cell going bad...or the balancer in the charger going out and overcharging a cell causing failure in that cell. A failed charger can cost you your entire car...or better yet, your house. Think of this thing going up in the garage...and you having a gas water heater installed out there. This stuff is dangerous enough as it is right now.

    3. Re:Have they figured out the safety aspect? by CAIMLAS · · Score: 3, Insightful

      IIRC, thermal runaway, as you call it, is a problem specific to Lithium based batteries due to the chemical properties of lithium. It's somewhat volatile, you could say: impact and temperature extremes tend to do bad things to it (whether we're talking explody-boom or cell lifetime). Carbon, on the other hand, is innately stable.

      Lithium powered hybrids are just a Bad Idea. I have no idea how they got that shit off the ground.

      --
      ~/ssh slashdot.org ssh: connect to host slashdot.org port 22: too many beers
    4. Re:Have they figured out the safety aspect? by jeffmeden · · Score: 4, Interesting

      But, "uh oh", these batteries still use Lithium! They simply have a new way of producing the electrode: "The result was a highly porous carbon nanotube electrode with lots of oxygens exposed on the surface, ready to bind with lithium."

      Also, there is nothing inherently tragic about Lithium; any technology that stores and releases energy can fall prey to thermal runaway. In the highly-available-power world in which I work, we have seen lead acid batteries go into thermal runaway after particular amounts of abuse (or defective manufacturing/installation).

      As someone who has used/abused lithium polymer batteries in the RC world (similar to the other respondent) I have seen what can easily happen to high-energy batteries when they are improperly maintained. The question is, what happens when there are hundreds of millions of these packs in cars all across the US, being put through various amounts of abuse? They will fail, and we need a safety mechanism that is highly reliable (like a re-enforced steel shell that can vent hot gases away).

      The comparison to a gas tank is somewhat inadequate as these batteries are far heavier than gasoline; if you have a serious accident that compromises the frame of the car you really can't guarantee that the battery container is going to be unperturbed. There needs to be two or more dedicated safety measures to contain or divert the energy from the batteries away from the occupants in the event of damage.

    5. Re:Have they figured out the safety aspect? by wisdom_brewing · · Score: 2, Interesting

      When it comes down to it, it's simply energy density... The more you have stored in a finite space, the more potential for release there is and the greater that release could be...

      I'm not saying its impossible to create something stable, all im saying is that certain conditions can have dramatic effects...

      The amount of energy easily released by a tank of petrol (gas, whatever) is massive, but safety precautions that are taken now are fantastic compared to earlier days...

      I'm sure there's a way to keep that energy trapped in a fairly safe way, but what I'm saying is there will be things going wrong once in a while and when they do, the greater the energy density, the greater the damage...

    6. Re:Have they figured out the safety aspect? by BlueParrot · · Score: 2, Insightful

      any technology that stores and releases energy can fall prey to thermal runaway.

      I'm so sick of this. Lithium-based battery technologies have a high energy/weight ratio because lithium is a very light metal. It has little to do with the fact that the spinel used for one of the electrodes is easily ignited. NiMH batteries are far safer and won't burn or explode the way lithium does, but because the metals used in them have higher atomic masses, they are also heavier for the same amount of energy.

      People keep talking about burning batteries as if the problem with li-ion is that we're trying to pack too much energy in a small space, but a plutonium based RTG packs WAY more energy, yet will never undergo thermal runaway ( it obviously has other problems though ).

      Chemistry is hard
      Physics is hard

      You can't pretend thermal runaway is due to energy density alone. The chemistry of the substances a battery is made of, the thermal conductivity of the electrodes, the physical size of the battery, the activation energy of the components... it all plays a part, and it's quite possible to store orders of magnitude more energy/volume or energy/weight than in a Li-ion battery without it being prone to thermal runaway. It's just not very practical for electric cars at the moment.

  3. I'll believe it when I see it by AdmiralXyz · · Score: 2, Insightful

    Of all the technologies that are supposedly "just around the corner": fusion power, flexible displays, etc., dramatically improved batteries are probably the most wearyingly repetitive. Literally every 3 months since 2005 I've seen an article on Engadget, or wherever, about some university that claims 500% longer-lasting batteries in the lab, to be available to consumers "in 18 months". Ain't happened yet. Let's all claim success about boosting battery capacity when we can actually buy them, until then this is just so much hot air.

    --
    Dislike the Electoral College? Lobby your state to join the National Popular Vote Interstate Compact.
    1. Re:I'll believe it when I see it by John+Hasler · · Score: 4, Insightful

      > Currently nothing to see here.

      Yes, because none of us have any interest at all in developing technology. We just want to see the results on the market. Ongoing research? How boring. Wake me up when you can make my 'Pod run longer. Don't waste my time with this stupid "science" crap. That's for nerds.

      --
      Warning: this article may contain humor, sarcasm, parody, and perhaps even irony. Read at your own risk.
    2. Re:I'll believe it when I see it by Cyberax · · Score: 3, Insightful

      It's working. Battery capacity is increasing, albeit slowly.

      It doubles every 5-7 years.

    3. Re:I'll believe it when I see it by radtea · · Score: 3, Insightful

      dramatically improved batteries are probably the most wearyingly repetitive

      My vote is solar cells, which have had so many breakthroughs that will double their efficiency in the past few years that they must be converting 500% of the light that strikes them by now...

      --
      Blasphemy is a human right. Blasphemophobia kills.
    4. Re:I'll believe it when I see it by Hurricane78 · · Score: 2, Interesting

      iPod? Sorry, we only work on curing baldness, and making erections work longer.

      (As there is no way to link to it, I’m including the quote here. Just imagine I would have linked to it ;)
      “The years passed, mankind became stupider at a frightening rate. Some had high hopes the genetic engineering would correct this trend in evolution, but sadly the greatest minds and resources were focused on conquering hair loss and prolonging erections.”
      — Narrator
      Idiocracy (2006)

      --
      Any sufficiently advanced intelligence is indistinguishable from stupidity.
    5. Re:I'll believe it when I see it by Rei · · Score: 2, Interesting

      What articles were you reading that said a battery tech would go from "in the lab" to "on the market" in 18 months? 5 years or so is more typical. And 500% battery improvement tech announcements are rare. There are a couple out there, like li-air, but not many. And many people confuse significant improvements on one part of a battery (say, the anode or cathode) with improvements on the cell as a whole.

      Li-ion batteries have advanced about 40% since 2005.

      There's a serious problem with the announcements making the news but the commercialization coming in under the radar. Remember back in 2007 when Slashdot covered that silicon nanowires had been determined to be an excellent anode for li-ion batteries? The reporting was crap, mind you -- they confused an anode density improvement "up to 10x" with being a whole battery improvement (even a 10x anode improvement would be an under 2x battery improvement if not paired with an equivalent cathode improvement, mind you). The researcher was looking to be "forming a company", but first they would have to deal with "cycle life" problems. The first batteries of this type were to hit the market as early as 5 years.

      It's only 3 years later and it's already started. Mind you, these first versions are much more limited -- they start out. But as the tech is refined, they will continue to advance, just like the old graphite anodes did. Early li-ion cells really sucked compared to what we have today. Silicon will go through the same process.

      You see the same thing with cathodes. And other anode materials. And separators, and electrolytes, and casings. And all in all, the tech marches on. But consumers don't even notice it because their devices just keep shrinking the batteries and consuming more power. The battery improvement isn't Moore's impressive doubling-every-1.5-years. But it's just as relentless.

      --
      Yes, I've read a poem. Try not to faint.
  4. Always a Catch.... by BJ_Covert_Action · · Score: 4, Insightful

    ...but if the method can be scaled up, the batteries may provide the power needed for applications like electric cars.

    And it's that one big damn, 'if,' that actually prevents most technologies like this from seeing commercial production/practical application.

  5. I call BS by Tekfactory · · Score: 4, Funny

    Extra power packed into batteries by a Scientist named Shoe Horn!

  6. Re:YEAH! by Yvan256 · · Score: 3, Interesting

    How about potatoes?

  7. Re:Sometimes it's more mundane by Avtuunaaja · · Score: 5, Interesting

    Everybody knows that if you can design an economically viable improvement on present-day batteries, you are going to be wildly, obscenely rich. There are plenty of applications where people would be perfectly willing to pay several times more for a battery than what they are paying now if there was a significant improvement in capacity/mass. This leads to a lot of research being concentrated even on very wild potential ideas. Many are viable in the lab, but are too expensive to produce (by a margin of several orders of magnitude), too dangerous, too short-lived, or any combination thereof.

    No matter how many misses there will be, this situation is more or less the ideal case for a free market to optimize for -- if it is possible to safely store more electrical energy in a smaller mass, it will be found eventually.

  8. Re:Sometimes it's more mundane by radtea · · Score: 4, Insightful

    We're already close to the limits and it can't really be improved.

    Yeah, I remember hearing a talk way back when pointing out that we're going to run out of shrink Real Soon Now because 100 nm is the absolute limit that simply can't be bettered. The guy introducing the talk said he'd given a similar one on the 60's or early 70's saying that 1 micron was the absolute limit that simply couldn't be bettered...

    This is not to say that there aren't limits, but that we are terrible at predicting them. Anyone who confidently pronounces a limit on something is just announcing their ignorance of technological history, which pretty much disqualifies them from pronouncing a limit on something. It's the only catch...

    --
    Blasphemy is a human right. Blasphemophobia kills.
  9. The issue is price anyway by BlueParrot · · Score: 4, Insightful

    There's plenty of battery technologies that perform well enough for cars already.
    Lithium Iron Phosphate is almost ideal as an example. It holds less charge than a
    Li-Ion pack, but in return it can recharge in a sensible amount of time ( 10-15min ).

    Now I know some people with no clue will come claim that amount of energy can't safely
    be transferred or something. You're wrong. Recharging a 25kWh battery pack (corresponding
    to ~150km of driving) in 15 minutes would require 100kW. This is a bit more power than
    most devices, but heck, my hairdryer does 2kw out of a standard socket, and I'm pointing
    that thing in my face every morning. 100kW might be a lot compared to a cellphone charger,
    and it will take a bit of engineering to design a connector, but it's hardly an unachievable
    amount of power.

    The problem is that these advanced batteries are expensive. Heck even Li-ion is prohibitive
    for a family car. Tesla gets away with it because they are selling a luxury model, but if
    batteries are going to power a significant fraction of cars then their cost has to come down.

    The question now is not so much if but when batteries will take over. Much will depend on what happens
    with the oil and electricity prices, but eventually petroleum will become sufficiently expensive that
    an electric car is simply a more economical choice.

    1. Re:The issue is price anyway by Anonymous Coward · · Score: 2, Interesting

      The problem is getting 100kW to your house, about 417 amps at 240V. The NEC standard for a single-family home is 100 amps, but most are only rated for about 60. The power pole transformers are usually well provisioned, which means that entire neighborhoods would need to be upgraded to increase everyone's capacity. It is a bigger problem than upgrading phone lines from copper to fiber.

    2. Re:The issue is price anyway by BlueParrot · · Score: 2, Interesting

      American power grid supporting oodles of people charging up their cars at 100kw a pop? That would be a hell of a series of spikes, probably bring the dilapidated grid down.

      Even if it was a problem in reality all that would be needed to mitigate it would be to mandate that chargers spend 1 minute at the start and end of a charging session to slowly ramp the power up/down. That would only add 1 minute to the total charge time, and since modern turbines in load leveling power plants can spin up and down on those timescales it solves the issue.

    3. Re:The issue is price anyway by Spy+Hunter · · Score: 3, Insightful

      You don't need a fast charger at your house; overnight charging will work great using cheaper non-peak power, and will probably extend your battery life vs. fast charging all the time. Fast charge stations can be spaced as sparsely as gas stations.

      --
      main(c,r){for(r=32;r;) printf(++c>31?c=!r--,"\n":c<r?" ":~c&r?" `":" #");}
  10. At least they don't promise "12 month" deployement by sirwired · · Score: 4, Interesting

    Unlike the fuel cell guys, which are constantly promising consumer products shipping in "just a few months", I'm glad these folks realize their work is still well away from widespread application where it's really needed.

  11. Re:YEAH! by jgagnon · · Score: 4, Funny

    It isn't a good idea to eat green potatoes. Unless you are eating them with green eggs and ham, that is.

    --
    Remember to maintain your supply of /facepalm oil to prevent chafing.
  12. Re:Failed Technologies by Monchanger · · Score: 4, Insightful

    No. We should instead find someone who is not only intelligent but also honest to listen to.

    The AEI who funds Green would love nothing more than to keep the world running on coal and oil until Armageddon. The pseudo-intellectuals they hire are no authority on science, technology, economics, politics, or even religion.

  13. Re:Some Day, Right by cacba · · Score: 3, Interesting

    You may try to apply moore's law to things other than cpus, but that doesnt make it happen. The frequency of the news articles shows only a huge demand by consumers and researches need for funding.

  14. Re:YEAH! by jbeaupre · · Score: 2, Funny

    and nothing to replace batteries?

    I hear that Nicolaus Otto has made great strides in the confined ignition of distillates. But work by Rudolf Diesel my lead to a even more efficient version.

    --
    The world is made by those who show up for the job.
  15. even Chuck Norris would agree, by Thud457 · · Score: 2, Funny

    Robert Conrad > Chuck Norris

    --

    the preceding comment is my own and in no way reflects the opinion of the Joint Chiefs of Staff

  16. Re:Epic article fail by drinkypoo · · Score: 2, Interesting

    In most designs regenerative braking has to throw away power because you can't charge the packs fast enough. A battery that CHARGES faster would be useful not only for quick-charging but also for regenerative braking. I didn't RTFA though so I have no idea if it carries more current in both directions.

    --
    "You're right," Fisheye says. "I should have set it on 'whip' or 'chop.'"
  17. Wow! by Rytr23 · · Score: 2, Funny

    Is there no end to the usefulness of these 'carbon nanotubes'? And, umm...how many decades before we actually see something commercially viable that uses them?

    --
    So many injustices..so little time..
  18. Combine these with solar panel breakthroughs... by GodfatherofSoul · · Score: 2, Funny

    ...you know, all the revolutionary achievements we read here every week...and our energy problems are solved!

    --
    I swear to God...I swear to God! That is NOT how you treat your human!
  19. Re:Sometimes it's more mundane by PitaBred · · Score: 2, Insightful

    Yeah, well... when we're arriving at wires being tens of atoms wide, I'm tending to believe we're at the limits of physics rather than process.

  20. Faster than gasoline, too. by Ungrounded+Lightning · · Score: 2, Interesting

    The comparison to a gas tank is somewhat inadequate as these batteries are far heavier than gasoline; if you have a serious accident that compromises the frame of the car you really can't guarantee that the battery container is going to be unperturbed. There needs to be two or more dedicated safety measures to contain or divert the energy from the batteries away from the occupants in the event of damage.

    Also: They can release their energy much more quickly (and thus more hotly) than gasoline. Gasoline requires oxygen from the air (or wherever) to burn and this limits its thermal power. Lithium cells are self-contained and have all the pieces of the reaction ready to go. (That's why they're heavier than an equivalent amount of gas.) They're only limited by the physics of the propagation of the catastrophic energy release mechanism.

    --
    Bantam Dominique roosters crow a four-note song. Once you've heard it as "Happy BIRTHday" you can't NOT hear it that way
  21. Re:Sometimes it's more mundane by phantomfive · · Score: 3, Informative

    The problem is your source of information. Press releases aren't a very good source. If it's something you care about, look deeper like in a journal or something.

    --
    Qxe4
  22. Re:YEAH! by An+ominous+Cow+art · · Score: 2, Funny

    I do not like green potatoes and ham.

  23. Re:Sometimes it's more mundane by Drakai · · Score: 2, Funny

    That's when we will say "There is no wire."