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Degraded Electrodes Observed In Aging Batteries

schliz writes "Scientists have identified nanoscale changes in aging lithium-ion batteries that could be responsible for their degradation over time. By dissecting and examining dead batteries, they found that some lithium was irreversibly lost from the positive to negative electrode of dead batteries, and no longer participated in charging and discharging. They discovered that finely-structured nanomaterials on dead batteries' electrodes had coarsened in size, and theorise that the coarsening of the cathode may be responsible for the loss of lithium."

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  1. Re:Keyword slapping strategy. by jeffb+(2.718) · · Score: 4, Informative

    Really? You're complaining about using the term "nano" to refer to structures bigger than molecules but smaller than the wavelength of light?

    By the same token, everything that goes on in your body is based on bio-chemistry, and therefore "nanoscale by definition". But it's still useful to distinguish (for example) biochemical changes in bone digestion due to biphosphonates from microscopic changes in bone structure associated with osteoporosis from large-scale changes associated with being run over by a truck.

    The nanoscale structure of battery electrodes, larger than individual molecules but smaller than the wavelength of visible light, is absolutely critical to optimizing battery performance. It's distinct from the battery's basic chemistry, it's distinct from gross electrode shape and size, and it's certainly distinct from the macroscopic and chemical changes "studied for ages" in association with corrosion.