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Cheap Metal-Insulator-Metal (MiM) Diode Created

An anonymous reader writes "Progress on metal-insulator-metal diode manufacturing was just reported online in the professional journal Advanced Materials (abstract). For the first time a high-performance 'metal-insulator-metal' diode was created with cheap materials. This is a fundamental discovery. It could change the way manufacturers produce electronic products at high speed, on a huge scale, and at a very low cost, even less than with conventional methods."

34 of 137 comments (clear)

  1. Ground breaking by Anonymous Coward · · Score: 4, Funny

    A complete gamechanger, just like memristors!

    1. Re:Ground breaking by Zerth · · Score: 2, Informative

      Whatever happened to memristors?

      HP just developed an implementation in the last year.

      It will take them a couple years to get a production line going, then a few more years before it starts showing up in products.

    2. Re:Ground breaking by TopSpin · · Score: 4, Informative

      Whatever happened to memristors?

      HP has partnered with Hynix to develop the manufacturing process and commercialize memristor products. Memristors used for storage will eventually appear as ReRAM (resistive RAM.) Meanwhile, other companies are working on memristor designs based on material other than TiO2 as is used by HP.

      Would someone with a good grounding in semiconductors please elaborate on why MIM diodes are significant? I have a good handle on basic electronics but not enough experience to deduce how MIM diodes would improve circuit design.

      --
      Lurking at the bottom of the gravity well, getting old
    3. Re:Ground breaking by i.of.the.storm · · Score: 2, Informative

      I think you're right, and I would guess that the startup costs are much cheaper with this technology. But I wonder how useful it is when we can already print thousands transistors for pennies after the initial cost of a fab. Maybe it will allow for easier tinkering for people sitting in their garage? Would be pretty cool to build your own diode.

      --
      All your base are belong to Wii.
    4. Re:Ground breaking by blackraven14250 · · Score: 3, Interesting

      even if it costs pennies now, the fact that it will cost a single penny later is definitely a step forward. That is especially true if the silicon supply is less abundant (not likely), or less easy to mine (possible), than the supply of the metals and insulators used here. That would mean a greater rise in the price of silicon over a given time frame than the price of the metal/insulator.

    5. Re:Ground breaking by kurokame · · Score: 5, Interesting

      Mainly, most immediately, it gives you an additional way to make a diode or diode-based structure when you're designing your fabrication sequence. Fabrication on the foundry / mass-production level occurs through processes which give you pretty much a set sequence of layers (deposited materials, treatments, patterning, etching, etc.). You can make anything you can design within that process...and most anything else usually stays in a research lab.

      The extraordinarily common CMOS process involves numerous metal layers "high" above the wafer (numerous layers intervene). These are separated by insulators. Normally, you make diodes at the wafer layer where you're doing your doping.

      MiM means you can put diodes in regions of your chip where they couldn't practically be fabricated before without a lot of time doing a one-off chip in a lab. With "a lot" often being several months to a year, assuming everything turns out perfectly, assuming your lab even HAS all the necessary equipment, and assuming you don't have something better to do - which is rare if you're not still a grad student.

    6. Re:Ground breaking by kurokame · · Score: 5, Insightful

      Silicon is not something we're going to run out of in the foreseeable future. If we do, it would probably be right after we ran out of nitrogen.

    7. Re:Ground breaking by kurokame · · Score: 4, Insightful

      The insulator is generally treated silicon, e.g. silicon nitride.

      Also, metals are something you find pockets of in the Earth's crust. The majority ended up in the core by virtue of its greater density. Silicon, on the other hand, is a key ingredient in the crust itself, and tends to be present in the minerals which you would have to find, extract, and process to get the metals involved in circuit-on-silicon fabrication.

      Also, the amount of material in the silicon wafer itself is far, far more than the entirety of all surface features comprising the integrated circuit.

      If anything, you would want to be comparing the relative scarcity or value of the metals involved versus the dopants involved, the relative ease of fabrication, and the particulars of what you can fabricate like minimum feature size, chip area per circuit element, and compatibility with other things you want to do on your wafer.

    8. Re:Ground breaking by davester666 · · Score: 2, Interesting

      And even though everything about the process will be cheaper, faster and better, the 'cheaper' part will magically disappear through the use of patent fee's.

      --
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    9. Re:Ground breaking by Pinky's+Brain · · Score: 2, Interesting

      This might be true, but looking at the thesis linked below the main target seems large area/feature size devices devices such as TFT display backplanes and drivers.

    10. Re:Ground breaking by DarkKnightRadick · · Score: 2, Insightful

      So much for the fast pace of new tech. ;)

      --
      "There is a way that seems right to a man, but its end is the way of death." Proverbs 16:25 (NKJV)
    11. Re:Ground breaking by John+Hasler · · Score: 5, Informative

      No. It's that MiMs are fast. The best junction diodes run out of steam at a few THz while MiMs work up into optical frequencies and so can be used to rectify sunlight. MiMs have been made before and are used in some exotic lab equipment but those point-contact devices are hard to make and touchy. These guys claim to have produced MiMs using more or less standard planar processes.

      Here's a paper that explains MiM theory, though it isn't about this development.

      --
      Warning: this article may contain humor, sarcasm, parody, and perhaps even irony. Read at your own risk.
    12. Re:Ground breaking by camperslo · · Score: 2, Informative

      It's a bit surprising to find out that some relatively unknown experimenters may have actually stumbled on tunnel-diode-like technology in the early days of radio over 80 years ago. I think they were officially invented by Sony in 1957, although most that I've seen in the U.S. came from G.E.
      http://www.sony.co.jp/Products/SC-HP/outline/overview/history.html

      Perhaps some here have experimented with a homemade cat-whisker diode for a crystal radio.
      As it turns out, making a little oscillator with a homemade metal-metal tunnel diode is easy enough that many here could do it. (a couple of variations using other materials are linked from the page below)

      http://home.earthlink.net/~lenyr/ntype-nr.htm

      I wish the story had made it clear just what sort of diode properties besides "cheaper" they were going for. It doesn't seem like they'd merge into current I.C. designs being of a much different process. The energy conversion thing is interesting, but that's much different than fast efficient diodes for switching power supplies or tunnel diodes for oscillators and high-frequency or pulse/trigger circuits. And it's a little hard to tell exactly how it ties in with LCD technology as that's pretty low frequency. Most digital I.C.s don't need or contain many diodes. They don't say anything about this helping to make better transistors. Normal diodes, even fast and cheap ones, usually can't replace transistors. And more unusual diodes with the negative-resistance effects of tunnel-diodes would certainly would not be a simple transplant into logic circuits. They've been well suited to a small niche of applications in the past.

      I guess it is time to dig up the old Trek episode where Spock was on old Earth building electronics with a bunch of vacuum tubes...

  2. Re:Ugh... yet another paywall stopping innovation by WarJolt · · Score: 4, Insightful

    Everyone wants information to be free... Until they come up with an idea of their own and publish it.

  3. Re:Cheaper than silicon? by seanadams.com · · Score: 3, Informative

    er never mind, the point is _higher performance_ done more cheaply than before, not a cheaper diode in general.

  4. Re:Ugh... yet another paywall stopping innovation by Anonymous Coward · · Score: 2, Funny

    the article?

    There may be a building in your neighborhood that houses paywall penetrating tools. You can even go there and use them for free. I believe your community may call this building a "Library."

    Or, if you are talking about them patenting the "invention", then yeah.. that sucks.

  5. Re:Dooooood !! by mail2345 · · Score: 2, Informative

    A diode maintains a one way flow of current.

  6. Re:Dooooood !! by $RANDOMLUSER · · Score: 4, Funny

    What about Smoke Emitting Diodes? (or Light Emitting Resistors?)

    --
    No folly is more costly than the folly of intolerant idealism. - Winston Churchill
  7. Re:Ugh... yet another paywall stopping innovation by coldmist · · Score: 2, Insightful

    Information wants to be free. People want to control it and hide it and charge for it. But, if I told you a secret, you naturally want to share it. If I write a book, and people read it, that information is now theirs too, ie "free".

    Of course people want free information. But, some people keep it in chains and lock it up and prevent it from becoming "public" knowledge, for their own personal gain. It's a war that has been waged for ever and will continue to rage...

    --
    Don't steal. The government hates competition.
  8. How does this work? by Required+Snark · · Score: 4, Informative
    I went and asked Mr. Google how this worked, and I couldn't find any answers. The best clue I got was that these devices use quantum tunneling, but this still does not explain how they exhibit diode behavior. Even the font of all online knowledge, Wikipedia, doesn't seem to know. Someone please post about this.

    One thing I did see is that this kind of diode can operate at 100's of THz frequencies, and that this enables nantennas. http://en.wikipedia.org/wiki/Nantenna If these kind of MIM diodes can be made cheaply then a new cost effective class of solar power device may become feasible. So it could be a really big deal.

    --
    Why is Snark Required?
    1. Re:How does this work? by ikkonoishi · · Score: 3, Informative

      I found the patent for it. The background section has a pretty good looking writeup, and is not a PDF.

  9. Re:Cheaper than silicon? by Tailhook · · Score: 4, Informative

    the most abundant element in the universe?

    The most abundant element in the universe is Hydrogen. Silicon, while plentiful in raw form, must be purified, crystallized, doped, etc. for use in microelectronics. This is an expensive, energy intensive process with less than perfect yield. Copper and aluminum are vastly easier to deal with.

    --
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  10. Re:Dooooood !! by Ethanol-fueled · · Score: 2, Informative

    In other words, it's an electronic check valve.

  11. Re:Ugh... yet another paywall stopping innovation by martin-boundary · · Score: 5, Insightful
    What are you smoking? Sounds yummy.

    Just about every scientist who's employed in a university wants to give away their published articles for free to anyone with even a tiny interest. The only ones who like paywalls are publishers.

  12. Re:Dooooood !! by DiegoBravo · · Score: 2, Insightful

    No, it's a car without retro.

  13. Re:Fundamental discovery? by MichaelSmith · · Score: 3, Interesting

    But isn't a transistor just a diode with a way to control the junction? So maybe you could position a third wire and get some gain out of it.

  14. Re:Ugh... yet another paywall stopping innovation by mdmkolbe · · Score: 5, Informative

    As a published academic myself, I concur. I don't get a dime from my published articles so paywalls don't help me. I benefit from people hearing about, reading, being influenced by and eventually citing my work because those things lead to higher academic ratings which lead to better positions, grants, etc.

  15. Re:Whats the catch? by Guy+Harris · · Score: 2, Informative

    When I hear electron tunneling I can't help but see oxide or whatever the hell these things are made of slowly being eaten away.

    You need to look elsewhere.

  16. Horrible horrible public science by Bender_ · · Score: 5, Informative

    I am a semiconductor scientist, but I completely fail to understand what this news is about. The article does nowhere mention the materials used, the device behavior, the application, the purpose or anything else.
    A MIM device as is, is a capacitor. And that is exactly what the picture is showing. When this type of capacitor is scaled to the nanometer regime it starts to get leaky due to quantum mechanical tunneling through the dielectric. The abstract mentions 'controlled quantum mechanical tunneling'... Aha, this could be what it is about. But as long as metal electrodes are involved this will only create a nonlinear resistor. Still no idea what the exact purpose is.

    Are nanoscale MIM capacitors new? No, not at all. Right now you have billions of them doing their job in your computers main memory. Depending on the vintage of your computer, these capacitors employ nanolaminates of ZrO2 and Al2O3 at a total thickness of 5 to 10 nanometers. Quantum electrical tunneling is of high relevance in these devices, since it leads to loss of stored information. So, is cheap new? A quick calculation suggests that the manufacturing cost of a single MIM device in a DRAM is approximately 10^(-10) US$.

    1. Re:Horrible horrible public science by GrepNut · · Score: 5, Informative

      I agree that the article could be a lot more informative. However, one can actually figure out quite a lot. For instance, since they call it a diode, it means the leaky capacitor you mention is asymmetric, and leaks more easily in one direction than the other. This is born out by the picture, which seems to show two layers of insulator, of different thickness, between the metal layers. And once you have electrical asymmetry, you can start building all sorts of interesting logic. But I agree they do not explain why tunneling through two layers A and B in the order "A then B" should be different from "B then A". Is it because of the direction of applied voltage, or are the insulator materials asymmetric at the molecular level, or is there some deep fact about quantum tunneling that makes it work? I would certainly have liked to see that covered.

      Second, in terms of benefits, it seems this device would be far easier, simpler and cheaper to fabricate than a normal PN diode. In a PN diode, you essentially need to arrange a metal wire, a small P-doped semiconductor region, a small N-doped semiconductor region and another metal wire. In addition, the two semiconductor regions need to be insulated from their surroundings somehow. This all requires pretty careful alignment. It looks like the MiM diodes would be self-aligning, in the sense that you could just create a pattern of vertical metal wires on one layer, then overlay the two layers of insulator, followed by a layer of horizontal metal wires. The diodes would form at the points where the wires cross, without any precise alignment being needed. And the fact that the middle layers are insulators would mean no further insulation was necessary. One could probably fabricate giant sheets of these things very cheaply.

      Finally, the fact that they can use these for rectifying infrared radiation implies they can operate many orders of magnitude faster than normal CMOS diodes.

      Googling a little also hints that MiMs are better at extracting the full energy from incident photons in photovoltaic applications, which could be a useful side benefit, allowing one to efficiently convert optical or infrared radiation into DC current with a single type of device. But I'm just guessing, an expert would need to confirm that.

      In summary, I agree this article could be a lot better. However, I have seen a lot worse, and it does seem to be alerting us to something which could turn out to be important.

  17. Displays? Meh. by John+Hasler · · Score: 3, Interesting

    That may be where the money is but the interesting applications are elsewhere. For example, MiMs could be useful as mixers and detectors all the way up to the visible. If they can be fabricated with a negative-resistance region they could serve as oscillators over the same range.

    --
    Warning: this article may contain humor, sarcasm, parody, and perhaps even irony. Read at your own risk.
  18. Re:Dooooood !! by FriendlyPrimate · · Score: 2, Insightful

    ...or Light Emitting Resistors?

    You mean light bulbs?

  19. Metal on Metal diodes are not new... by metaforest · · Score: 2, Informative

    The appearance of them is as old as corroded copper wire.. What has changed is that some materials specialists have figured out how to characterize these so called "parasitic" diodes and fabricate them with predictable parameters. As others have pointed out they are quite useful as they can be fabricated in the metal layers above the doped silicon, thus removing this type of component from the die and placing it in the metallization layers where there is a lot more room.

    Now basically, as I understand it, diodes do not take up 1/2 a transistor foot print on the substrate. "Free as in beer" diodes.... from a floor-planner's perspective.