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Molybdenite As an Alternative To Silicon

An anonymous reader writes "Molybdenite (MoS2) can be used to make transistors that consume 100,000 times less energy in standby state. This mineral, which is abundant in nature, is often used as an element in steel alloys or as an additive in lubricants. Research carried out in Switzerland at the Ecole Polytechnique Fédérale de Lausanne's Laboratory of Nanoscale Electronics and Structures (LANES) has revealed that is a very effective semiconductor. Molybdenite's 1.8 electron-volt gap is ideal for transistors and gives it an advantage over graphene (which does not have a gap)."

29 of 169 comments (clear)

  1. Molykote? by cvtan · · Score: 4, Interesting

    Isn't this just Moly disulphide, the lubricant in Molykote? http://www.dowcorning.com/content/molykote/anniversary.aspx?bhcp=1

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    1. Re:Molykote? by macraig · · Score: 2

      Already asked and answered in TFS. What's your point, aside from giving Dow free advertising?

    2. Re:Molykote? by pwagland · · Score: 3, Informative

      Isn't this just Moly disulphide, the lubricant in Molykote? http://www.dowcorning.com/content/molykote/anniversary.aspx?bhcp=1

      Possibly, from the article:

      This mineral, which is abundant in nature, is often used as an element in steel alloys or as an additive in lubricants. But it had not yet been extensively studied for use in electronics.

      That is this material has been known about for quite some time, however it's applications to electronics are only now being investigated, and he initial results appear to be quite favourable.

    3. Re:Molykote? by arivanov · · Score: 5, Interesting

      Probably not pure enough.

      You need 99.995+% purity for most semiconductor stuff (99.999+ for CPUs and memory) which can be achieved only via zone smelting. In order to zone smelt the material needs to be able to re-crystalize after being heated locally in the first place. If it does not you can forget using it as a production semiconductor. There are in fact plenty of materials out there which have electron gaps are more "interesting" than silicon. We just have not figured out how to grow to purify them in quantity.

      As far as MoS2 is concerned it does not melt and does not recrystalize (it decomposes straight away) so zone smelting is not an option. It decomposes straight away. So frankly I do not see how you can achieve 99.99+ purity to do anything useful with it.

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  2. reduction in subthreshold leakage current by RichMan · · Score: 4, Interesting

    In the latest technologies a lot of current is wasted to subthreshold conduction . Current that flows then the transistors should be "off".

    A material with a higher bandgap 1.8ev to silicons 1.1ev will naturally have less leakage. As it is an exponential thing the leakage should not just be a reduction of 1.1 to 1.8 thing but much more significant.

    1. Re:reduction in subthreshold leakage current by MagusSlurpy · · Score: 3, Insightful

      That would be the band gap.

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    2. Re:reduction in subthreshold leakage current by GospelHead821 · · Score: 3, Informative

      In insulators, there are no energy states that involve conductive electrons. In conductors, all of the energy states involve conductive electrons. In semiconductors, electrons normally reside in a nonconductive state but you can inject some energy and the electrons will be raised to a conductive state. The amount of energy required to raise the electrons to a conductive state is that semiconductor's gap.

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  3. Re:Make better computers, kill more plants by Shihar · · Score: 4, Insightful

    I'll keep that in mind before I strip mine any farms for molybdenum. Otherwise, I am pretty sure the plants inside of the middle of a mountain are not going to mind.

  4. Re:Make better computers, kill more plants by Mr+Z · · Score: 5, Insightful

    Huh? Just like all the steel we produce somehow reduces the amount of iron plants and animals can make use of? Are you suggesting that a significant fraction of mined molybdenite goes to fertilizer manufacture?

    Molybdenum may not be as abundant as silicon, but it's still fairly abundant. (54th most abundant in the crust and 25th most abundant in sea water, says Wikipedia.) And given its fairly high cost, I imagine any increased demand will be offset by its cost. This would limit molybdenum to niche applications where controlling leakage is a must. I imagine MoS2 based semiconductors would only be cost effective if they can figure out how to use as little of it as possible, perhaps with MoS2 over some other substrate.

    I can think of much stupider things that we could do (and in fact are doing already), such as bottling water, or hyperfocusing food production on corn and subsidizing large quantities of corn-based ethanol production.

  5. Oh dear by Tideflat · · Score: 2

    Oh dear. This means they might have to rename Silicon Valley to Molybdenite Valley, but that doesn't sound nearly as nice.

  6. finding a good material is not the problem by Goldsmith · · Score: 4, Interesting

    There are plenty of materials out there that make good semiconductors, the question is: can we make them?

    Moly disulfide is a material a couple of different graphene groups have been looking at (hey, we know there's an issue with graphene). What this paper really means is that the Ecole group has figured out how to *make* MoS2 better than other people, and that's really the hard part. Of course, they're still making devices using scotch tape exfoliation...

    It's really hard to mass produce 2D materials.

    1. Re:finding a good material is not the problem by evanspw · · Score: 2

      Sing it, brother! I work in compound semiconductor designing RF chips. I know a lot of silicon guys and very few of them have any clue what makes silicon a damn useful semiconductor (namely, it's oxide). I can't think of another semiconductor that has anything like as nice an oxide as silicon, easy to grow, very effective insulator with decent breakdown. If any of the compound semiconductors had anything like as good a native oxide, there would be no silicon industry (silicon otherwise mediocre electron mobility and band-gap, though ok thermals).

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    2. Re:finding a good material is not the problem by crgrace · · Score: 2

      If any of the compound semiconductors had anything like as good a native oxide, there would be no silicon industry (silicon otherwise mediocre electron mobility and band-gap, though ok thermals).

      I don't know about that... most compound semiconductors have really good electron mobility and so-so or worse hole mobility. One of silicon's great strengths is that the hole mobility is only 3X smaller than the mobility for electrons so p-channel devices are useful.

      Also, silicon repairs itself when annealed. That's why you can do simple ion implants and don't have to screw around with expensive compound semiconductor stuff like MBE.

      So, yeah, the Si native oxide is great, but there are other reasons why silicon is dominant.

  7. Re:Make better computers, kill more plants by Mr+Z · · Score: 2

    And actually, it appears that MoS2 over a silicon substrate is exactly what they're proposing. I knew I should have looked at the blowup first.

  8. Re:Let me just say by x0ra · · Score: 2

    in reality, you will just get more features out of the same die consuming the same amount of power than today. We did great with small CPU, the software we run on them just became full of bloat (not to speak about all the HD crap). That said, Intel's business is to sell you a new CPU every few years, not make it last 15 years.

  9. Abundant ... hello? by angel'o'sphere · · Score: 4, Informative

    This mineral, which is abundant in nature, is often used as an element in steel alloys or as an additive in lubricants. That is a joke, isn't it? Or is it just /.? From Wikipedia: Molybdenum is the 54th most abundant element in the Earth's crust and the 25th most abundant element in the oceans, with an average of 10 parts per billion; it is the 42nd most abundant element in the Universe. That is not abundant that is pretty rare. Considering 35% of the planet is silicon ... or is it more? Regards, Angel

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    1. Re:Abundant ... hello? by KiloByte · · Score: 2

      It is very abundant compared to what is needed for this task, as opposed to some other proposed replacements. It's not like you need tons of molybdenite.

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    2. Re:Abundant ... hello? by m85476585 · · Score: 4, Interesting

      How much of that silicon is ultra pure semiconductor grade? Probably none, so both materials need to go through a refining process. If there are areas with high moly concentrations, it doesn't matter how much the rest of the world has, as long as those mines are enough to meet demand (and can continue to do so for a while).

    3. Re:Abundant ... hello? by dakameleon · · Score: 4, Insightful

      It's pretty convenient that the US also happens to be the world's largest producer of the stuff too: http://en.wikipedia.org/wiki/File:2005molybdenum_(mined).PNG

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    4. Re:Abundant ... hello? by mcelrath · · Score: 4, Insightful

      You don't need 10kg of the stuff to make a semiconductor device. Compare it to gold: we produce about 30x more Mo, and you certainly have a few grams of gold somewhere in your house. Anyway my guess is that it might be laid down in layers on top of an insulating substrate (and the substrate doesn't have to be MoS2). So the quantities required are not out of line with production, despite the fact that it is relatively rare in the universe.

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    5. Re:Abundant ... hello? by Namarrgon · · Score: 3, Informative

      That table you linked to says the annual production of molybdenum is 80 kilotonnes, which is not exactly rare.

      It also says that the annual production of electronics-grade silicon is only 5 kilotonnes, so our needs aren't going to be a problem.

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  10. Re:Let me just say by Gaygirlie · · Score: 3, Informative

    Plus, can you image a goddamn smart phone with a week long battery life?? Or a laptop that runs for days without needing to recharge? A server farm that could be powered by solar power and a few large battery power storage units?

    You have misunderstood the article. It clearly says molybdenite transistors consume 100.000 times less energy than silicon ones in STANDBY. Not when operational. Sure, it would increase efficiency of mobile devices where you turn unneeded transistors off to save energy, but it would do nothing for when the system is operational and in use. Thus your idea of a server farm being solar powered is completely without basis.

    Molybdenite's strength is in mobile applications: when the device is in standby mode it consumes a lot less energy than traditional silicon-based ones. But it has another strength here: silicon is a 3-layer material, whereas molybdenite is monolayer. This means that you can make smaller chips, or cram more stuff in a chip of the same size.

  11. Taking a page from Mac by Anonymous Coward · · Score: 2, Funny

    Google just announced their new browser update, "Chrome Moly".

  12. Re:Can't reduce anything by more than 1X by omglolbah · · Score: 2

    It is not a quirk of mathematics. It is a quirk of language.
    While it can be parsed the way you say, most would parse it to mean "1/100000 of previous consumption".
    It might not be the "right" way, but it is the way most people read it.

    So on one hand what you state is correct from a mathematical standpoint but on the other hand irrelevant.
    It is technically incorrect but the phrase "xxx times less" has become the way people express that something is 1/xxx of what it used to be.
    You can yell at people until you're blue in the face but it is pointless to try to change the language back to what it used to be :p

  13. Re:Make better computers, kill more plants by Shihar · · Score: 3, Insightful

    Um, okay. You can pass on my TED talks. Otherwise, the point stands.

    Molybdenum is generally gathered as a byproduct of other mining operations. The "free" molybdenum in soil that plants uses is utterly unaffected when you tear open a mountain to get at it. The original point of "OMG BUT PLANTS USE IT!" was dumb and reactionary. Hell, just re-read the original post if you are in doubt. This is like if someone declared that they found a novel use for nitrogen and someone else freaked out be cause OMFG nitrogen is critical for all life!!!11!!

    There are actual legitimate road blocks to using molybdenum in place of silicon. OMFG the plants!11!!! isn't one of them.

  14. Re:Let me just say by MadnessASAP · · Score: 3, Insightful

    You're doing some freaky ass computing if all the transistors in your CPU are active at the same time.

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  15. great, more advertising by press release by cats-paw · · Score: 3, Interesting

    let me know when you have I-V curves for a moly disulpide FET. Both p and n types please.

    I learned many moons ago, that one of the most important things about Si is the fact that it's so easy to grow an oxide. It's EXTREMELY useful when processing integrated circuits. Otherwise everything electronic would use III-V's.

    Any new material which aims to replace Si is going to need an equivalent process capability.

    Personally I'm hoping for a breakthrough in organic semiconductors. I want to be able to screen print transistors at home.

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    1. Re:great, more advertising by press release by Ranzear · · Score: 3, Insightful

      I don't see moly transistors replacing the entirety of silicon transistor applications in the same way that graphene will never replace silicon.

      I can, however, see moly transistors stepping in for the power regulation side of a chip and system where efficiency is demanded, and graphene-based 'burst processing' cores that are shut down completely when not in use on the performance side.

      Everything is about application, adaptation, and integration of technologies, not seeking out a replacement for every end of the spectrum at once. Silicon is the Jack in the middle, while the specialists should be looked upon as integrable to the whole of transistor arrangement.

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  16. Re:Let me just say by msauve · · Score: 2

    40 kW average? Home? That would be 83 amp service @480V, for a single computer. How many of these supercomputers do you have?

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