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MIT Develops Fast Charging Liquid Flow Batteries

An anonymous reader sends this from the MIT News office: "A radically new approach to the design of batteries, developed by researchers at MIT, could provide a lightweight and inexpensive alternative to existing batteries for electric vehicles and the power grid. The technology could even make 'refueling' such batteries as quick and easy as pumping gas into a conventional car (abstract). The new battery relies on an innovative architecture called a semi-solid flow cell, in which solid particles are suspended in a carrier liquid and pumped through the system. In this design, the battery’s active components — the positive and negative electrodes, or cathodes and anodes — are composed of particles suspended in a liquid electrolyte. These two different suspensions are pumped through systems separated by a filter, such as a thin porous membrane."

101 of 135 comments (clear)

  1. Wesley Snipes Flashbacks by microcentillion · · Score: 1

    "That's pure capacitance gel..."

    --
    But clearly you have something better to say...
  2. Dang it... (Demolition Man) by IBitOBear · · Score: 2

    You beat me to it.

    The idea has been around a long time, but making it work is a wholly different kettle of electromotive potential.

    --
    Innocent people shouldn't be forced to pay for inferior software development.
    --"Code Complete" Microsoft Press
  3. Comment removed by account_deleted · · Score: 2

    Comment removed based on user account deletion

  4. could by enderjsv · · Score: 1

    I hate the word "could." It's so inconclusive. I always think of the Geico commercial. "15 minutes could save you 15 percent or more on your car insurance." Yeah, and if I buy a lottery ticket, I could win millions of dollars. I probably won't, but I could.

    I'm probably just being too cynical. This is an interesting development, and I should be more supportive. But I can't get excited when there's so much "could" in an article. Just not in my nature.

    1. Re:could by Vegeta99 · · Score: 1

      At least Geico's honest. Everyone else says that people who switch to them "save hundreds."

      Well fucking DUH. Why the hell ELSE would you switch?!

      (One cynic to another)

    2. Re:could by agrif · · Score: 1

      Though completely off-topic, another reason people often save money when switching car insurance is that their cars are re-valued in the process. Of course, the car's current value is less than it was when the first insurance was purchased.

  5. Dangerous in the wild by IBitOBear · · Score: 3, Interesting

    Don't spill that shit. Imagine the average "I always top off my tank" bone head at a "gas pump" spilling what is basically the first practical, room temprature binary explosive all over the outside of his Jetta. Granted it isn't a proper explosive, it would be more of a flash of heat and electrical potential as the two materials mixed without the interleaving membrane.

    As a sealed cell this is a fine idea. As a dispensed material it has "technical issues".

    --
    Innocent people shouldn't be forced to pay for inferior software development.
    --"Code Complete" Microsoft Press
    1. Re:Dangerous in the wild by enderjsv · · Score: 1

      Could mean the end of self-serve pumps.

    2. Re:Dangerous in the wild by Vegeta99 · · Score: 1

      I've seen the sign.... and heard the gurgle as the froth from pumping a liquid at 5GPM settles down into the oddly-shaped, baffled tank.

      WTF shitty gas station do you go to where topping up leads to gas on the ground? I've only done that ONCE in my life, and it was because the gas station didn't properly maintain their pumps.

    3. Re:Dangerous in the wild by danlip · · Score: 1

      Not sure full service helps. The only time I've seen someone spill gas all over the ground is the guy at a full service pump. I've never done it myself.

    4. Re:Dangerous in the wild by LoRdTAW · · Score: 1

      Or it just means that the pump nozzle will have to plug into the fill port creating a liquid tight seal. There would also be a better over flow sensor to shut off the pump when the tank is full.

      Though, that means there will have to be a standardized fill port plug and it would have to accommodate both cars and heavy trucks.

    5. Re:Dangerous in the wild by IBitOBear · · Score: 1

      Topping off leads to gas on the ground all the time. Look at the ground at your gas station, heck lick it (I cannot honestly recommend touching the ground with a light lighter but it _would_ be funny) and see if you can see or taste gas. That stuff comes from somewhere, and it isn't just the disk-shake-drop that most people leave when they pull out too soon.

      A wait ten seconds and then trickle-pump some more top-off can be done with predictable results. It's never necessary. Most people who top off make a mess. The mess can be compounded by successive fouling of the vapor recovery lines.

      People top off and gush all over the place all the time.

      Its unnecessary. You aren't saving yourself anything by getting that extra tenth of a gallon into your tank. There is a good chance that when you top off, fully half of that extra tenth is actually ending up in the vapor recovery system instead of your tank anyway, and the gas station just gets to sell it on to the next guy.

      Am I innocent of topping off myself? no. Do I know its dumb? yes. Am I old enough that sometimes I do it without thinking? yes. Is it _still_ dumb? yes. Should I do it? no. Do I try not to do it despite a lifetime of practice? yes, at least when I am paying attention. Do I always spill, or even usually spill? no. Is it _still_ dumb? yes.

      You should not top off your tank. It's never the right thing to do, even if you can do it well. About half the people who do it do it worse than average. 8-)

      --
      Innocent people shouldn't be forced to pay for inferior software development.
      --"Code Complete" Microsoft Press
    6. Re:Dangerous in the wild by timeOday · · Score: 1

      The reason to top off is because sometimes it clicks off for no apparent reason; you might only have filled half way up so far.

    7. Re:Dangerous in the wild by peragrin · · Score: 1

      all those spills on the ground are caused by lawncare/ ATV people topping off secondary tanks.

      Watch a truck pull into a gas station hauling three lawn mowers with 3 5 gallon spare tanks on the ground, and them climbing on the lawn mowers to top those off too.

      or people hauling their boats and topping off at the gas station as it is cheaper, if not easier.

      There is lots of reasons gas spills at gas stations.

      --
      i thought once I was found, but it was only a dream.
    8. Re:Dangerous in the wild by glodime · · Score: 1

      At this point, that extra gas goes out of a little overflow hole, and typically runs down and onto the ground

      I'm quite skeptical of your claim. How is it legal to make a car that intentionally leaks gas, especially in a non-obvious way? Also, how is it that I've seen gas spill out of the port (is that the right word?) used to insert the nozzle? Is the overflow hole an insufficient size for its intent?

    9. Re:Dangerous in the wild by IBitOBear · · Score: 1

      That would be _FOUR_ liquids passing through the nozzle, not just one. Anode Charged and Cathode Charged going in, Anode Discharged and Cathode Discharged coming out. Mixing of the two charged liquids is the part I think would be hugely dangerous. Small amounts would invariably leak out in traces, and it only takes a some kid going "what's that daddy" for someone to touch the residue of both ports and shock or burn themselves.

      Closed systems would be much safer.

      --
      Innocent people shouldn't be forced to pay for inferior software development.
      --"Code Complete" Microsoft Press
    10. Re:Dangerous in the wild by IICV · · Score: 1

      Imagine the average "I always top off my tank" bone head at a "gas pump" spilling what is basically the first practical, room temprature binary explosive all over the outside of his Jetta.

      Do you really think that will be possible? The nozzle is already going to have to be different (since it's a binary compound) so they're going to have to redesign refueling anyway; if this goes commercial, they would build in safeguards against that, along with safeguards against accidentally putting some in your gas tank (or putting gas in this tank).

    11. Re:Dangerous in the wild by TheTurtlesMoves · · Score: 1

      You know what else is not safe. Gasoline in a atmosphere containing oxygen.

      Honestly you would never get people to switch to gasoline today because of "safety concerns".

      --
      The Grey Goo disaster happened 3 billion years ago. This rock is covered in self replicating machines!
    12. Re:Dangerous in the wild by vegiVamp · · Score: 2

      Oh come on. Do you think LPG is tanked the same way petrol is? There already are working, foolproof, airtight connectors. You just need another one, that has four tubes - 2 in, 2 out. Add some sensors and you're off.

      --
      What a depressingly stupid machine.
    13. Re:Dangerous in the wild by sjames · · Score: 1

      They'll have to make damned sure you can't accidentally add cathode to the anode tank or vice versa or it'll be like the Dell laptop scaled up to OMG RUN size.

    14. Re:Dangerous in the wild by tlhIngan · · Score: 1

      The reason to top off is because sometimes it clicks off for no apparent reason; you might only have filled half way up so far.

      In which case you leave it off for a few seconds to let it settle and try again. And yes, you should know roughly how much gas you need. The capacity of the gas tank is in the manual for a reason and assuming it's roughly linear, ought to be able to figure out how much gas you need from both the gauge and the distance travelled.

      The skill is particularly important these days as it's oftne pay-before-you-pump and if you wish to pay by cash, you need to guesstimate how much money you need to prepay. And some stations don't give change back if the change is under some limit ($2/5/10 - yes, $10. Over 3 gallons worth!)

      Anyhow, another reason to not top off is because you need space at the top for the expansion and contraction of the gas. Leave too little and on a hot day liquid gas can back up into the gas vapor recovery system and destroy it.

    15. Re:Dangerous in the wild by KozmoStevnNaut · · Score: 1

      I always let the pump run at full speed until it clicks off, then wait about 10 seconds and run it at full speed until it clicks off again.

      Due to the design of my car's tank etc., this means I can usually get another 1-1.5 litres in there. I haven't had a spill, yet.

      --
      Eat the rich.
  6. Nothing new by Jimbookis · · Score: 1

    I was told about this sort of battery research 2nd hand about 8 years ago. Go to the 'petrol' station, attach a nozzle to the car, have the battery fluids replaced in a matter of a minute or two and off you go.

  7. Re:I've seen this by blueg3 · · Score: 1

    Nope. The anode and cathode in a car battery are lead/lead oxide/lead sulfate plates. There's an aqueous electrolyte, like in any wet cell battery.

  8. Re:Hopefully... by rmstar · · Score: 2

    Well, we are talking scales and scales here. The energy density of gasoline is still about a 100 times higher than that of the best batteries available. And it's not like there hasn't been any research on batteries.

    Nitpic: the market for electric model airplanes took off before, with the NiMH cells. Of course, LiPo batteries are a lot nicer still.

  9. Re:"As quick an easy as pumping gas"? by Anonymous Coward · · Score: 1

    Really? All of the challenges that a technology like this faces and you think the engineering involved in designing a connector that pumps in new fluid, pumps out old fluid, and doesn't allow bubbles into the system while being as easy to use as a gas pump nozzle is the kicker? Any mechanical engineering graduate who couldn't design that connector should be stripped of their degree. Making it reliable over thousands of uses and cheap?Tthat may take a little more work, but I would hardly rank the idea as the most outlandish concept in the article.

  10. Radically new approach? by tragedy · · Score: 1

    It's hardly a "radically new approach". The idea has been around for a long time and is easy to come up with off the the top of your head. I did in
    this slashdot post. I'm not going to try to claim to have come up with a radically new approach there either since the idea has, in all likelihood, been around for about as long as batteries have (which is millenia, incidentally). Making it work is another matter altogether. If they have, it may be of some interest. Of course, in the post I linked to above, I speculated that such an approach was almost guaranteed to end up as an environmental disaster in one way or another. My view on that may have softened a little since that post, but it would take some extraordinary proof for me to believe that it wouldn't end up resulting in thousands of plumes of heavy metal laden electrolyte under filling stations everywhere.

    1. Re:Radically new approach? by shaitand · · Score: 1

      You have a high opinion of major metropolitan areas...

    2. Re:Radically new approach? by tragedy · · Score: 2

      Hard to tell which is more important: groundwater or air. I was actually arguing for sealed batteries as opposed to liquid flow battery juice. Concentrating the job of filling batteries with highly reactive heavy metal containing liquid compounds seems like a job best done in a small number of well-regulated facilities with serious containment and trained, careful personnel rather than at tens of thousands of little stations maybe inspected once every few years with the filling done by commuters in a rush or other careless people. I don't see why you can't have strings of batteries on serpentine chain belts that you can feed into cars while replacing the old ones.

      If someone could develop an actual 100% efficient quick-charging battery that could compete with a tank of gas, that would also be great, as well as a complete miracle. The problem without such a battery, and the reason something else is needed, is that the energy transfer rate from a typical gas pump is on the order of 10 MW, which is possible because it's a simple transfer of an inert substance. Charging a chemical battery requires energy conversion. If the conversion is 99% efficient, then that means that, to keep up with a gas pump, around 100 KW of heat is produced, which is a lot of heat to handle without the car melting and the person filling it bursting into flame, not to mention that the 99% efficiency is probably a pipe dream. Aside from that, it means that the electric equivalent of even a small four pump gas station has to be wired for 40 MW (buffering power somehow with ultracapacitors or a flywheel or something sounds doable until you look at what's actually available and do the math and realize they just wouldn't cut it for the usage patterns of a typical gas station) and so does the one right across the street.

    3. Re:Radically new approach? by AlienIntelligence · · Score: 1

      I speculated that such an approach was almost guaranteed to end up as an environmental disaster in one way or another. My view on that may have softened a little since that post, but it would take some extraordinary proof for me to believe that it wouldn't end up resulting in thousands of plumes of heavy metal laden electrolyte under filling stations everywhere.

      Most older gas stations are superfund qualifying sites anyway...
      so, do you have a point?

      http://www.google.com/search?sourceid=chrome&ie=UTF-8&q=what+is+a+superfund+site

      -AI

      --
      For me, it is far better to grasp the Universe as it really is than to persist in delusion
    4. Re:Radically new approach? by tragedy · · Score: 1

      Yes, the point is that the heavy metal loaded run off from these will be even worse than what ends up under the gas stations now. And yes, I have a point. I've already stated it too. The point is that sealed batteries would probably be a much more environmentally sound idea than filling up with liquid battery juice.

  11. How about... by errandum · · Score: 1

    Instead of refueling a battery, you change the whole battery every time you stop at a "gas" station. The system has been used for gas cans for decades now and it works.

    I always wondered why do they assume that a car battery needs to be the same every time.

    1. Re:How about... by ThosLives · · Score: 2

      I'm not sure comparing 30lbm propane gas cylinder swaps to swapping batteries is a fair comparison. (Assuming that's what you meant; I'm not aware of anywhere that swaps gasoline cans.)

      That said, there are many groups working on swappable battery packs. Part of the problem, though, is that you have structural issues, alignment issues, storage issues (it's a lot easier to store and move liquids than it is 100+ lbm battery packs), matching the correct battery pack to the correct vehicle, and issues like making sure that the terminals don't short to anything during the swap. Liquids also lend themselves much easier to continuous processes where swappable batteries are inherently batch. Managing an inventory of batteries is a lot more difficult than managing a giant tank.

      There are pros and cons to both approaches, but in general liquid-based approaches are much more flexible.

      --
      "There are a dozen opinions on a matter until you know the truth. Then there is only one." - CS Lewis (paraprhase)
    2. Re:How about... by errandum · · Score: 1

      That is the basic idea, but it's really simple:

      I've seen working prototypes with working swappable batteries, so that shouldn't be an issue.

      Same way every car either takes leaded gasoline, unleaded gasoline or diesel, just make 3 types of batteries (different power for different requirements).

      The management part should be possible to overcome, especially because the adoption would be slow. The infrastructure would have to be built, but that doesn't meant it isn't doable. The up side is that you wouldn't require a gas post - every store could trade your depleted pack for a new one.

      The only reason I see this not working is because of patents/money. Patents would be in the way of a standard, big oil would be in the way of widespread use of this idea.

    3. Re:How about... by CrimsonAvenger · · Score: 2

      Instead of refueling a battery, you change the whole battery every time you stop at a "gas" station. The system has been used for gas cans for decades now and it works.

      Trick is, a natural gas tank is just a can full of natural gas. and 30 pounds of natural gas is pretty much like any 30 pounds of natural gas.

      Batteries, on the other hand, age. As they get older, they hold less energy. So, you take your brand new battery (which you paid a pretty penny for when you bought your new electric car, and which will take your car 200+ miles), and swap it for a five-year-old battery which only holds enough energy for 150 miles. Or 100 miles, if it's a cheap knockoff. Or less, perhaps.

      As long as not all batteries are identical in performance, hot-swapping them will only be popular with people who currently have crappy batteries...

      --

      "I do not agree with what you say, but I will defend to the death your right to say it"
    4. Re:How about... by adolf · · Score: 1

      I think of it like a propane tank for a gas-fired barbeque grill:

      It's (usually) cheaper to refill the same tank over and over, but that takes more time, and can only be done at a limited selection of locations. Plus you've got to keep the thing free of rust, have it inspected periodically, and sometimes apply a new coat of paint. Eventually, the tank will fail inspection anyway, and needs replaced.

      And while some folks do all that, others just toss their empty tank into the car, and exchange it for a full tank when they do their shopping. It's easy, it's fast, it (usually) costs more, and it's done.

      The propane distributor handles details like inspection and painting. They are paid for this with the premium that they charge for the service. I'm sure they make more money on some exchanges than on others, but on average they must do reasonably well or there wouldn't be a propane exchange at every single corner gas station, convenience store, grocery store, and home center in my town. (Of course, large batteries are too costly to handle to make things up in a game of averages, but I'll get to that.)

      Back to the topic: It's also easy to analyze batteries The battery in my Dell laptop currently 7 years old, and it has a pretty good idea of the actual power availability that it has (which is not very much). At work, we use dedicated a battery analyzer to rate used battery packs for customers.

      It's also possible to design a battery so that it can be repaired. I once saw a gentleman replacing a single failed lead-acid cell in a Pandur. Each cell was containerized, and they were connected together in series with short jumper straps. (I forget it it had 6 or 12 individual 2.1V lead acid cells, but it doesn't matter...)

      Combine these three concepts, and you wind up with a battery exchange program which works as follows:

      1. The customer pulls in, and wants to exchange the battery in his electric MoonGoblin.

      2. The service attendant looks (visually, and electronically) at the condition of the battery and its current state of charge.

      3. While this is happening, the driver can select from a range of different batteries, priced differently (and predictably) based on their condition -- which should include new, or nearly new batteries as well as anything else.

      4. The battery gets swapped. Money changes hands (more money changes hands when getting a better battery than you came in with). Driver leaves in his MoonGoblin with his new (or at least newly-charged) battery.

      5. If warranted, the exchange station will repair a battery that is in poor condition, or send it out to be fixed (depending on their skill and the extent of the repair), but if it is a reasonably good battery it will just be placed back onto the charging rack, re-rated, and exchanged with the next guy.

      Here are the problems with my plan that I anticipate folks will be willing to point and laugh at:

      First, changing batteries. How the hell is this supposed to be done, exactly? A forklift? A gantry crane? Magic robots? I don't know either, sorry. Argue about something else please. :)

      Second, lies and deceit. There is a financial incentive, on all sides, to make batteries appear to be in better condition than they actually are. But the market will sort that out quite well enough, I think: The stations can keep track of individual cars and their exchange habits, so if the ol' MoonGoblin gets hacked by its owner to lie about the condition of the battery, stations will stop doing business with him (databases are cool). This provides a disincentive to counter the incentive for the costumer to lie.

      On the other hand, if a station has a tendency to be misrepresenting the batteries they offer, their reputation will keep people away. (On the other hand, the local Department of Weights and Measures will audit them periodically anyway, just like they do with gas pumps and deli scales

    5. Re:How about... by cnettel · · Score: 2
      What is also against is the current state of battery technology, i.e. we don't expect a stable fleet-wide solution to be based on current technology. Investing in standard form factors, designing drivetrains for their respective power delivery characteristics will just seem stupid.

      It's a bit like where we would be if we had at this moment just discovered petroleum as a viable engine fuel, but for some reason what we actually have in production is tar. Tar has terrible viscosity and it doesn't make a very good fuel, so now the options are to create a full infrastructure creating future fuel lock-in, or handle this a special case while volumes are low and standardize on something sensible later on.

    6. Re:How about... by GameboyRMH · · Score: 1

      There was a little Italian electric sports car that did exactly this. The trailer even had active steering so that it would always be directly behind the car.

      --
      "When information is power, privacy is freedom" - Jah-Wren Ryel
  12. hurray by xmousex · · Score: 1

    another amazing, wonderful, world changing, society fixing, all or our problems are solved, idea i heard about this week that ill be wondering what the hell ever happened to.... ten years from now when gas is $50/gallon to power a car that still doesnt fly and my cell phone charge still wont last more then an hour and all my friends are still obese and dying from cancer, lack of health care, with an upside down mortgage and no jobs and a microwave dinner that still fucking frozen in the middle.

    someday you should print an article when one of these brilliant mit/scientists/researchers/whoever people does something that actually makes it to market and changes the world.

    1. Re:hurray by Shrike82 · · Score: 1

      You think your cell phone was made from magic, unicorn farts and wishes? Research into materials, software, hardware and EM radiation. While I understand your sentiment to some degree I think perhaps you should go and find, for yourself, examples of how research translates into technologies you can use. I'm sure MIT's website will quickly get you into a publicity section that'll be happy to educate you about their knowledge transfer activities.

      --
      You can advertise in this sig from as little as £99.99 a month!
    2. Re:hurray by xmousex · · Score: 1

      yeah i came off critical of mit or something, i was really bugging more about tech journalism and OMG THE FUTURE!!! eeehhh .

  13. It's got what cars crave... by Anonymous Coward · · Score: 2, Funny

    It's got electrolytes!

  14. Better than public transportation by cryfreedomlove · · Score: 3, Insightful

    I'm a big believer in the personal freedom offered by owner-driven vehicles, even if the driver is often the only person in the vehicle. Therefore, I am in favor of advanced battery technology that will allow a gradual transition of the world's fleet of personal vehicles to all electric drive rather than gasoline and diesel. Gasoline and diesel require a state of constant war in the Middle East to sustain.

    1. Re:Better than public transportation by ShooterNeo · · Score: 1

      Right, but cars do work very well for the majority of this country's 300 million population. Only a small fraction have to live in the overcrowded metroxplexes that do not have adequate road systems for their populations.

      Ever tried driving a car in say, Lubbock, Texas? It works AMAZINGLY well. You can get anywhere in the city you want in 15 minutes, and delays are minimal.

    2. Re:Better than public transportation by schlameel · · Score: 1

      And where will the electricity come from? Oil is energy; transportable and relatively dense, but it still accounts for more than 35% of US energy use. A "transition... to all electric" does not mean energy independence anymore than a "hydrogen economy" does.

    3. Re:Better than public transportation by Black+Gold+Alchemist · · Score: 1

      Not oil, that's for sure. Right now, most electricity comes from gas and coal, nuclear and hydro. Oil makes up less than %1 of electricity generation. Even on a coal grid, there are less CO2 emissions from electric cars than gas cars. By the time all cars are electric, all electricity will come from solar and wind and hydro.

      --
      Responsibility is an addiction
      Virtue is a temptation
      Community is a cartel
    4. Re:Better than public transportation by Black+Gold+Alchemist · · Score: 1

      I'm in a town of 60,000 and we do not have traffic problems here. We have basically no public transportation, and our roads are poorly designed and confusing, and yet we rarely have traffic problems. You can get around any where you want with a car in about 20 minutes at maximum. Most driving trips are actually quite relaxing - I like it because it gives me an excuse to be uncontactable.

      --
      Responsibility is an addiction
      Virtue is a temptation
      Community is a cartel
    5. Re:Better than public transportation by fnj · · Score: 1

      2009 figures for U.S.: more than 2/3 from fossil fuels:
      coal 44.9%
      natural gas 23.4%
      nuclear 20.3%
      hydroelectric 6.9%
      other renewables 3.6%
      petroleum 1.0%

    6. Re:Better than public transportation by DerekLyons · · Score: 1

      Gasoline and diesel require a state of constant war in the Middle East to sustain.

      Not for the US. The vast majority of our oil comes from Canada, Mexico, Venezuala, and other locations in the Americas.

    7. Re:Better than public transportation by cryfreedomlove · · Score: 1

      And where will the electricity come from? Oil is energy; transportable and relatively dense, but it still accounts for more than 35% of US energy use. A "transition... to all electric" does not mean energy independence anymore than a "hydrogen economy" does.

      I expect electricity generation to get cleaner, greener, and cheaper over the next 100 years as we finally figure out safe nuclear that can run without lies and coverups.

    8. Re:Better than public transportation by Black+Gold+Alchemist · · Score: 1

      You clearly understand the issues. Some people don't understand the ridership issue. I suggest you get a slashdot account so people can see your posts.

      --
      Responsibility is an addiction
      Virtue is a temptation
      Community is a cartel
    9. Re:Better than public transportation by rjstanford · · Score: 1

      Its worth noting that approximately 60% of the US population lives in cities of 200,000 people and above. Lubbock, at 60,000 people in spacious (and relatively recently developed) West Texas, is actually quite different.

      Source: http://www.fhwa.dot.gov/planning/census_issues/metropolitan_planning/cps2k.cfm

      --
      You're special forces then? That's great! I just love your olympics!
  15. Am I the only one who saw this? by Jane+Q.+Public · · Score: 3, Insightful

    I have a very big issue with what appears to be publicly-funded research being siphoned straight off into some corporate treasuries.

    This BS needs to stop. Repeal the Bayh-Dole Act. It has done nothing but harm the public and our economy.

    1. Re:Am I the only one who saw this? by MyFirstNameIsPaul · · Score: 3, Interesting

      I once called MIT to inquire about getting license to a patent developed under a DOE grant. I was immediately transferred to their public affairs office where someone newly hired was rattling off the benefits of this act. I asked specifically about the process of bidding on the patents and was informed that for all intents and purposes it is by invitation only. The company getting all of the patents from the publicly funded research was owned by the head research scientist. Go figure.

      --

      I once took an excursion to Reddit, and later HN. Unlimited up/down voting sucks when dealing with a hive-mind.

    2. Re:Am I the only one who saw this? by Gibbs-Duhem · · Score: 2

      You can either have academic labs researching things which are commercially interesting, and then give the professors working on it the perk of having the opportunity to commercialize it first (or at least royalties), or you can have academic labs researching things which the professor is academically interested in, and hope that it is commercially interesting. It is difficult to get both.

      Either you get people complaining that publicly funded research isn't free to the public to use, or you get people complaining that stuff invented in academia has no practical application. And since there aren't any industrial research labs left, that means either no commercially interesting research, or encumbered research.

      Not to mention that it would be *damn* hard to get professors to work for peanuts (seriously, I've seen what these people make for their qualifications) while training basically all high-skill future scientists, and under a contract where all work they do they can't even commercialize because some big company will snap it up underneath them.

      No, I'm afraid that I have to disagree with your position. Yes, I have a bias because I am working very hard to commercialize technology that my lab invented, but I also think that is is more than fair to give the actual inventors first dibs on trying to commercialize something. I would have left academia in a hurry and just did all my work as a trade secret pretty quickly otherwise.

      National labs of course are a totally different story. Usually their inventions are licensed under reasonable terms in only non-exclusive licenses. But those inventors are *working* for the government as opposed to just having a small fraction of their costs paid for by a government grant.

    3. Re:Am I the only one who saw this? by MyFirstNameIsPaul · · Score: 1

      I don't care what the dude does, I don't want my money funding private enterprise outside of my own direct investments. As for there getting 'first dibs', where did they get the resources and right for 'first dibs'? What right do they have to take my money by force and then create a company that is in direct competition with me? This is just in your mind?

      --

      I once took an excursion to Reddit, and later HN. Unlimited up/down voting sucks when dealing with a hive-mind.

    4. Re:Am I the only one who saw this? by WindBourne · · Score: 1

      Personally, I have a lot more issues with it when the companies are fronts for Chinese gov. And yes, many of these VC companies that front the money are simply meant to hide what is going on.

      --
      I prefer the "u" in honour as it seems to be missing these days.
    5. Re:Am I the only one who saw this? by jackbird · · Score: 2

      Like how private trucks drive on public roads, and the government hires contractors to build infrastructure with tax money? You're a moron.

    6. Re:Am I the only one who saw this? by MyFirstNameIsPaul · · Score: 1

      Um, I can use the roads and the infrastructure. They are 'public'. I can't use the publicly funded research that is exclusively licensed to private entities. Who's the moron?

      --

      I once took an excursion to Reddit, and later HN. Unlimited up/down voting sucks when dealing with a hive-mind.

    7. Re:Am I the only one who saw this? by Jane+Q.+Public · · Score: 1

      "As for there getting 'first dibs', where did they get the resources and right for 'first dibs'?"

      It's called the Bayh-Dole Act, and it's an abomination. It was well-intended, I think, but it had unintended consequences.

    8. Re:Am I the only one who saw this? by MyFirstNameIsPaul · · Score: 1

      Of the very few things I agree with FDR on, "In politics, nothing happens by accident. If it happens, you can bet it was planned that way" is certainly one of them. When I stated right, I think what I really meant was just laws. What just laws allow them to do this. The Constitution certainly does not grant Congress the power to fund private research. The Bayh-Dole Act is an example of the rule of man.

      --

      I once took an excursion to Reddit, and later HN. Unlimited up/down voting sucks when dealing with a hive-mind.

  16. Re:Hopefully... by rmstar · · Score: 1

    - NiMH planes were hardly a joke. There was a lot of airracing done with them. Worked well.

    - Many model planes get a lot of time out of their LiPo batteries, making the pilot want to have a break before the battery is empty. Gas, of course, runs much longer and you can sustain power for longer, but often the drawbacks (the mess) dominate.

    Still, flying most distances of interest with a useful load is off limits for batteries.

  17. Topping Off, An Aphrophal Correction by IBitOBear · · Score: 5, Interesting

    There is a reason it's called "topping off" if my father's long-ago explanation is to be believed...

    First: there is no "drain hole" in the fuel system (at least in the US etc) since the fuel system is supposed to be vapor tight. There _is_ a small drain hole behind the typical fuel filler door which mostly exists to prevent water from getting caught inside the compartment and rusting things out. That said...

    We pump gas _far_ too fast to be environmentally sound. It _froths_ out of the hose in a turbulent flow and a lot of vapor escapes because of the frothing, which is why we now have those vapor recovery hoods etc on a lot of pumps.

    When the tank is nearly full, e.g. "as full as it ought to be", the froth boils up the fill-pipe and triggers the back-pressure sensor causing the nozzle to click closed. I few seconds latter the frothing settles and there is now a space in the tank. "Topping off" is the attempt to fill that space.

    Back in the before time, that is, before gas was expensive and mileage was important, getting that quarter of a gallon into the car meant getting another three or four miles before needing to fill up. Nobody cared that the net effect was 3 cents of gas gushing out of the pipe and onto the ground because everybody thought "what the heck" because nobody knew that dispersing hydrocarbons did anything but smell nice and industrial. Plus gas fill points were low and typically at the bumper so it didn't even ruin the paint job.

    Now days, "topping off" is as bad as it ever was, and worse too boot. The attempt to fill that last little bit not only causes gas to gush out onto your paint job, and pollute the environment, not it also can put liquid gasoline into the vapor recovery system. This can cause the back-pressure valve in the pump to "miss" the fact that froth is rising in the fill tube. You can end up pumping gas right back out of your car and into the gas station tanks ( this costs you money) and then when you separate the nozzle from the car a _lot_ of gas can have collected in that rubber hood thing which then goes everywhere.

    Better yet, then next guy will get the same treatment if there is still liquid gas in the vapor recovery system. I filled up my Prius in a bad part of town the other day, and when I pulled the nozzle out, a good 3 cups of gas went everywhere. Some person before me must have "topped off" and that turned the vapor recovery system into a siphon. Who knows how many people that effected before me, and after as now _my_ gas was in the hose for the next guy.

    Your gas tank is never supposed to be _full_ by absolute measure. Just like every other container of liquid you have ever dealt with, there is a little space at the top.

    Topping off _any_ container is the act of trying to fill that last little bit between "properly full" and "absolutely full" and it _always_ results in waste and spillage due to over-filling.

    In my grandfather's age, the tank wasn't full until some spilled out. Topping off was the norm. People still do it because that's how they learned to do it "no matter what the sign says, my daddy showed me good"; this is the law of the dumb.

    --
    Innocent people shouldn't be forced to pay for inferior software development.
    --"Code Complete" Microsoft Press
  18. Another "upside" of this technology... by ferongr · · Score: 2

    Various governments around the world can impose a tax on the liquid, effectively being able to keep that huge income stream intact. When the price at the pump is 75% tax (in my glorious socialist EU country), at 1,70€/liter...

    Electric cars can use 20Amp 3-phase chargers to charge the batteries (albeit slowly) without requiring any changes in the electrical systems of a house. This makes government budget centers iffy, since they cannot easily tax you (despite the fact that in many EU countries you already pay for a yearly tax in excess of 150€).

    Cars with liquid-rechargeable batteries would allow them to control distribution of the liquid and keep taxing it.

    1. Re:Another "upside" of this technology... by White+Flame · · Score: 2

      At-home charging doesn't help when you're driving a distance larger than a single fill-up range. Nor does any charging scheme where the wait time is significant.

      There is a legitimate market for fuel substitutes that are easily flowed in & out of a vehicle.

  19. The Keywords Are "Lightweight and Inexpensive" by Weaselgrease · · Score: 1

    As soon as some corporate battery behemoth hears this, they'll buy up the patent and lock it away so it can't be manufactured until the current battery designs stop making so much money.

  20. Actually, no... but not a "stopper". by IBitOBear · · Score: 1

    I would expect a standardized interlocking cartridge thing, or in-place charging.

    In the case of replacing the fluids:
    (1) The quantity of the two liquids would need to be kept in balance, which would be very hard to do using a "pumping" paradigm.
    (2) The liquid isn't "consumed" (e.g. burnt) so much as "exhausted" (reduced to a non-charged state) so the spent liquid would need to be returned at the same time as the new liquid is supplied, which would get you up to four connections in the system instead of two.
    (3) Punctures to containment would be hugely problematic, unlike gas, so the storage mechanism would need to have internal isolations to keep "the whole charge" from going off at once. (gas is amazingly stable in an accident since the liquid itself does not burn, not so much for the charged binary liquid in question.)

    The in-place charging is much more likely. The charge process could be _very_ fast if the fluids are pumped quickly through a charging manifold. This would be the orthogonal structure to (or indeed the same exact structure as) the discharging manifold. Since the fluid is in motion it can be charged and _cooled_ immediately. That is the fluid would be pumped pass the charge point and into a heat sink or heat exchanger. In a full charging loop it might be chilled to an optimal pre-charge temperature, charged, and then cooled in series. Each individual annode/cathode element in the suspension would not have to take a full charge in one pass as you could keep circulating the fluid until the feedback voltage, charging current, and temperature told you the fluid was a charged as it was going to get. (and indeed the "worn-out-ness" of the fluid could probably be measured in the same way, telling you when you need to have your fluid changed by a proper professional etc.)

    The system could work in a gas-pump like time and user modality (e.g. I put this thing in my car, watch it go "ding" for a while, then take it out and drive away) but the chance that the four fluids being exchanged by an average-joe in an air-gap setting is quite low.

    No fluid exchange coupling known to date is absolutely residue free. It would only take one kid "checking out" the interlock and getting both liquids on his fingers and then touching them together to call in the liability lawyers big-time.

    --
    Innocent people shouldn't be forced to pay for inferior software development.
    --"Code Complete" Microsoft Press
  21. Not "Flaimbait", just flames... by IBitOBear · · Score: 1

    I love this moderation... it shoudl be +1 Flaimbait as any arrangement where four fluids (two charged fluids going in, and two discharged fluids coming out) of varying electrical potentials are being exchanged by someone of the same technical competence as, say, my mother, is _bound_ to end in flames, or at least tears... So having my mom pump this stuff, were she still alive, would be baiting flames indeed.

    --
    Innocent people shouldn't be forced to pay for inferior software development.
    --"Code Complete" Microsoft Press
  22. Am I the only one who thought... by PJ6 · · Score: 1

    that these positively and negatively-charged gels would make fine additions to Portal 2?

  23. Pre-peer puffery by wonkavader · · Score: 2

    "The new semi-solid flow batteries pioneered by Chiang and colleagues overcome this limitation, providing a 10-fold improvement in energy density over present liquid flow-batteries, and lower-cost manufacturing than conventional lithium-ion batteries."

    It's statements like this that make me cringe when I look at the puffery which comes out of academia. 10 * better than A, and cheaper than B. Is it 10 * better than B? Or as good as B? Or (more likely) 1/10th as good as B.

  24. Charge time isn't the problem by Charliemopps · · Score: 1

    Charge time isn't the problem. We have capacitors that can take millions of volts in milliseconds after all. The problem is Getting enough power to the refilling station to top off 20 cars at once. We're talking kilowatts here. And the cable going from the station to the vehicle would be the size of a tree trunk unless we get super conductors involved.

    1. Re:Charge time isn't the problem by glorybe · · Score: 1

      There are several problems but charge time is still one of them. We have crowded gas stations with lines at times already. Suppose that we had a twelve minute charge time as opposed to the three minute fill time for gasoline. It would be enough to clog cities with cars that could not move from lack of charge. Then there are the numerous power generating stations that would be needed to supply electricity to the charging stations. It gets worse. Even if each car must gather solar energy on its roof to propel the car spinning electric motors still heats the environment. Really population is at the root of all of our woes and population size can not be regulated without totalitarian systems of government. Maybe it is more important for universities to find ways to keep people from reproducing than designing better batteries.

    2. Re:Charge time isn't the problem by headpushslap · · Score: 1

      Congestion actually helps solve the core issue. As congestion increases drivers begin to find other ways to get around. One electric bus could take up to 40 times the passengers of a single occupant vehicle, and transit becomes the best alternative for many commuters. In the long run cities become smaller and more accessible simply to overcome the inconvenience.

    3. Re:Charge time isn't the problem by Anonymous Coward · · Score: 1

      I think many people would choose to charge at home while their car is in the garage. Filling stations would be most often used for longer trips which is the vast minority of vehicles on the road.

      Also, yes electric motors generate heat. If that electricity came from solar, you know where most of the energy would have gone were it not for the solar collection? Heat. A tiny bit of reflection might escape the planet, but it would mostly go to heat.

  25. Re:Hopefully... by peragrin · · Score: 2, Insightful

    With a useful load is the real trick to electric anything.

    Sure you can have an electric car today. Try loading up 2-3 of your friends, luggage for 4-5 days, to go anywhere?

    The few cars that might get 200 mile range are suddenly cut down to 75.

    Electric will come when two things happen. Better energy storage, and people get over nuclear power fears. With out nuclear power generation electric cars are worthless. Solar, wind hydro, geothermal, tidal, won't produce enough power to cover current needs, let alone tripling it by 30% of the population using electric cars.

    --
    i thought once I was found, but it was only a dream.
  26. That's not "topping off" by IBitOBear · · Score: 1

    If you know your tank isn't anywhere near full, then you are not "topping off" technically or morally, you are continuing to fill your tank.

    There are two primary reasons that the nozzle will trip "for no reason". (1) improperly inserted nozzles will self trip when their stream of gas hits the side of the pipe and causes back-pressure, and likewise for letting the nozzle back out of the pipe. (2) Someone before you topped off and got "just a little" liquid gas into the vapor recovery system, when those liquid drops hit the internal sensors the last-ditch anti-siphon system kicks in and trips the shutoff. Both conditions are the result of improper fueling technique by the current or previous operator. (A caveat here is that the equipment can, through continued mis-used get worn out but that's a compounded case of items 1 and 2.)

    I had a car for a while that would only fill properly if I put the nozzle in at a slight angle because of item 1 and crappy design of the fill pipe.

    If you put eight gallons of gas in a rated-ten-gallon tank that wasn't bone dry you have no reason to squeeze the handle again. And if you do and it trips _again_ and you squeeze the handle a third time you are wanking off.

    I've watched people re-squeeze the handle like eight times. This is topping off at its most primal level of idiocy.

    --
    Innocent people shouldn't be forced to pay for inferior software development.
    --"Code Complete" Microsoft Press
    1. Re:That's not "topping off" by Zebedeu · · Score: 1

      I don't think it's fair to call it idiocy, it's simple misinformation.

      They probably figure that the more fuel they put in now, the more they can drive before having to refill again.

      In my defense, I don't top off for two reasons: 1) those extra drops don't mean much in terms of extra distance traveled, and 2) some guy at a gas station one topped my tank so much that it blocked the fuel meter at half full until I used up the fuel in the tank until that level. On a related note, never buy Peugeot.

      But I'd never heard that topping off too much leads to fuel leaking to the ground. Live and learn I guess.

    2. Re:That's not "topping off" by IBitOBear · · Score: 1

      Oh you'll know it if it hits the ground. There is no secret hole it comes out of where you won't see it.

      The thing you are likely not to see is when the fule gets sucked into the vapor recovery system. If there is a big hood thing you will see it clearly when you separate the noces and tank. If its the kind where there are a bunch of holes around the outside of the tip of the nozzle then a slow-fill top-off may send a non-trivial amount of that gas you are pumping back into the pump.

      There is an ongoing design war to prevent topping-off from becoming an all-out spill. The vacuum in the recovery system getting stronger, the sensors getting more responsive. all sorts of little tweaks. blarg.

      --
      Innocent people shouldn't be forced to pay for inferior software development.
      --"Code Complete" Microsoft Press
  27. quick and easy, sure, but not the same at all. by IBitOBear · · Score: 1

    Two fluids, out and in, reduce the mixing so that the fresh fluid is not diluted unacceptably by the stale, ensure none of the anode fluid _ever_ mixes with the cathode fluid, ensure that no person (including a curious child) is exposed to both fluids at once even if they "poke at" the nozzle. This is not a "fill the tank with gas" analog operation at all.

    I think the material has great promise, and since it is fluid based, it is probably very able to be cooled quickly as it charges so a closed-loop fast charge in-place is probably _way_ more workable than replacing the fluid every time a charge is needed.

    The gas-pump experience I would expect would be a "hose" from the pumping station which carried an electrical cable and a cooling loop. The fluids inside the closed system in the car would be pumped "briskly" though the charging manifold, the "nozzle" would sandwich the charging manifold and both apply the electric potential and aggressive chilling. The charged fluid would return to primary containment somewhat cool to the touch.

    The cooling would alleviate the thermal degradation that limits current fast-charging of batteries. The closed system would eliminate the dangers inherent in letting untrained people move 100kwh of charged chemical danger out in the wild. It would be "as quick and easy as pumping gas" as far as the user experience. But it would not be "filling an empty tank with go-juice", and even the article doesn't say it would be.

    The fluids would clearly have a replacement schedule, much like engine oil, and you would take your car in for that maintenance when the pump told you that the charging rate during your "fill up" was sub-optimal.

    Much better than a true pump and nozzle arrangement.

    --
    Innocent people shouldn't be forced to pay for inferior software development.
    --"Code Complete" Microsoft Press
    1. Re:quick and easy, sure, but not the same at all. by GameboyRMH · · Score: 1

      You remember Atari cartridges and cartridge slots that had flaps that protected the connectors and made them difficult to accidentally touch? Use something like that. Inside have a connector that only fits on one way.

      For replacing the fluid, you can have a switch or data interface for the pump to tell the car to go into "charging mode" that opens any valves and opens a small bypass around any pumps so that the station pump can force new electrolyte through the system. That is if it needs to be air-free at all.

      If it's possible to test voltage on the "waste" side (I don't see why not), consider the system flushed when the voltage jumps.

      The only downside vs. gas is that you can't do partial fill-ups. When you go for a fill you're dumping the old electrolyte, regardless of what charge it had, for the new.

      --
      "When information is power, privacy is freedom" - Jah-Wren Ryel
  28. Re:It's called a fuel cell by cheater512 · · Score: 1

    It is, because the 'recharging' occurs at the 'petrol' station long after you've left.

    Its then pumped in to someone else's car.

  29. Re:Hopefully... by haruchai · · Score: 2

    If my math is right, you're off by nearly a factor of 10.
    To replace every ICE passenger vehicle in America with an EV with double the battery capacity of the Nissan Leaf would increase annual US electric consumption by 40% not a 300% increase by replacing only a third.

    Passenger vehicles in US incl SUVs = approx 250,000,000 (2006)
    Nissan Leaf battery capacity is 24 kWH so double = 48kWh
    Assume full charge every 3 days so annual # of fillups = 120

    (The vehicle number is somewhat low but the charging and capacity numbers are high)
    Total electricity usage for EVs = 250000000 x 48 kW-hrs x 120 / yr = 1 440 000 000 000 kWh/yr or 1,440,000,000 MWh/yr
    Annual US electricity usage for 2009 = 3,750,000,000 MWh/yr
    Divide total projected EV usage / Annual current usage = .384 or 38.4%

    Not that's current USAGE not current capacity; having only a fraction of those EVs enabled with Vehicle-to-Grid in large population centers would give the grid enormous benefits for distributed storage. Businesses and manufacturing may not be so happy as the cheap or free nighttime power they've enjoyed would become a thing of the past.

    --
    Pain is merely failure leaving the body
  30. Fuel cell? by Thomas+Shaddack · · Score: 1

    Isn't this a kind of a fuel cell?

    1. Re:Fuel cell? by sjames · · Score: 1

      Not quite. The fuel cell consumes fuel and an oxidizer in an electrochemical reaction. This is more a rechargable battery where anode and cathode are thick liquids. Unlike a fuel cell, if you exchange the liquids out, the spent ones can then be recharged in another battery. You can also just recharge it if you have the time.

  31. About spilling gas, you wanna read this... by LongearedBat · · Score: 1

    After borrowing my father's 4WD (not some big city pretender, but a proper off roader, diesel, 2 tanks, etc.) I went to fill it up as thanks. So, I filled up the 1st tank with 75 litres. Then I started fillling up the 2nd tank, and at about 20 litres, this passer by points out some liquid on the ground. I looked around and found that I'd stuck the bowser into a hole in the wall of the car for connecting water. Literally just a hole in the side of the car. So I had filled the car floor with 20 litres of diesel. Oh, crap! My poor father. (Turns out that both tanks were supposed to be filled using the same hole.)

    Insurance paid for the car to be disassembled, the parts cleaned and then reassembled. They had no problem accepting that as an accident, 'cos seriously, who on Earth would do something so stupid on purpose?

    I really hope I'm not on track for a Darwin Award. But hey, I'm in software, and cars are hardware.

  32. Nope, not a fuel cell. Nothing is consumed. by IBitOBear · · Score: 5, Informative

    A fuel cell basically "burns" (uses up) its reagent to make electricity directly.

    This (according to the article) is a reversible reaction between two liquids, one acting as an anode and one acting as a cathode, where the reaction is bounded by a membrane. It is really more of the "capacitance gel" idea, only with two carries (which makes sense).

    Think of it as two halves of a standard battery that can only interact when brought into proximity. While electrons (or maybe ions or something beyond my simple ability translate, not having seen the research or studied in the field) pass through the membrane by definition, the idea is that the charged medium is not part of the fixed assembly, so the fixed assembly (the reactor and membrane) is permanent while the charged part moves.

    In a standard battery the anode and cathode are permanent parts of the battery. When the battery is discharged the whole battery is trashed. For instance, and alkaline battery is assembled in a charged state, the dissolving of the metals in the alkaline solution is what makes the voltage. Lead-acid batteries wear out because the lead is changed by the charging process (applying voltage in the presence of acid solution) and changed back by the discharge. This cycling slowly causes the lead to flake and degrade until there is either so much lead flakes in the battery that a cell shorts out because of the lead connecting the two parts, or the odd chemical impurities and available oxygen slowly make the lead into a chemical that will not react with the acid correctly any more.

    In this arrangement the parts that would degrade are in the fluids, draining and replacing the fluids "assembles a new, fully charged battery". In this model the ideal of pulling into a service station and replacing your discharged battery pack with a new, charged one, becomes practical.

    In the alternate, as a rechargeable battery the non-solid nature of the battery itself lets the battery be charged and cooled all at once. The anode and cathode material won't "flake" because it isn't sold to begin with. Plus nearly all of the anode and cathode material is used by weight, there is no "inner core" area acting as a superstructure. This should improve the energy density (how many kilowatt hours you can store per pound etc).

    In the rechargeable battery usage the battery would probably need to be changed regularly, like an oil change, but _then_ one could probably use charged plates to separate/filter the degraded particles from the good ones, so the "battery" could be recycled in place instead of having to take it back to a factory.

    There is a lot potential wins here, but it is _very_ unlike a fuel cell.

    --
    Innocent people shouldn't be forced to pay for inferior software development.
    --"Code Complete" Microsoft Press
    1. Re:Nope, not a fuel cell. Nothing is consumed. by ThatsNotPudding · · Score: 2

      This is why oneshould avoid buying batteries with a dramatically higher CCA (cold cranking amperage) than the factory spec. To get that larger potential in the same size case, the number of lead plates is higher while also being much thinnner. The thinner plates break down faster and the individual cells in the battery short out more quickly.

  33. Re:Topping Off, An Apocryphal Correction by IBitOBear · · Score: 1

    And one way or another, when you fill that canteen you either leave/trap a little air or waste some water due to overspill. In fact I bet you often do both.

    And the word I meant to put in the subject was "Apocryphal"...

    Not to be pedantic. Twice. 8-)

    --
    Innocent people shouldn't be forced to pay for inferior software development.
    --"Code Complete" Microsoft Press
  34. Re:Hopefully... by indeterminator · · Score: 1

    Yes, for now, real travel requires a "real" car. However, most car trips are short commute and shopping mall trips with 1 person in the car. Where electric would be more efficient than gas.

    Electric will come when it's the most attractive alternative financially, i.e. when gas prices go high enough.

  35. Interesting idea, with some flaws by Jack+Malmostoso · · Score: 2

    I just read the Advanced Energy Materials article (which you can easily find by googling the title and filtering for pdf).
    The idea itself is interesting, and could potentially remove some manufacturing problems (i.e. no need to dry, calender, cut electrodes and then assemble single cells and wire them in a pack) but I see a couple of big flaws in it:
    1) Let's get off the table the idea of "refueling". Li-ion batteries are assembled in their discharged state. The slurries containing LiCoO2 and Li4Ti5O12 (as per the article), when put in contact, produce exactly 0 energy. You have to either charge them using electricity, or prepare slurries of Li0.5CoO2 and Li7Ti5O12. Neither of the two materials is stable in air, thus I don't think it's possible to prepare a "refueling" system with current Li-ion battery materials.
    2) The beauty of Li-ion batteries is that they have 99.995% efficiency round-trip. This system seems to be based on very thick slurries which probably require strong pumps to circulate in a system, thus killing such efficiency.
    3) What's more, the slurries are prepared with highly flammable solvents (dioxolane). Not sure I'd like to carry around two tanks of the stuff, considering that a breach in the separator or in the "fuel" lines could ignite the whole thing.
    It is true that changing materials is a simpler problem than designing a completely new system, but as the authors themselves admit this is just a readaptation of an old system.
    I think it would be much more practical to redesign redox flow batteries to use non-aqueous electrolytes, thus allowing to work in a larger potential window (water only allows about 1.5V).
    I'm not sure things are looking up for A123, and I hope Prof. Chiang won't sink with this idea either. Good luck to all the researchers involved.

  36. Re:Hopefully... by vlm · · Score: 1

    I sure hope they can develop this concept into a design that can be used by consumers.

    Get prepared for plenty of toxic waste spills. I did some research on vanadium flow batteries a decade or so ago, and they're just too toxic for the average redneck or the average MBA to be placed in charge of. Like giving matches to a little kid.

    The bad news is the vanadium-based chemistries are probably the safest, least reactive, least corrosive of the flow batteries. The others are worse. Lithium chemistries that occasionally burst into flame, iron based chemistries that are basically controlled rust (yeah as if GM can control rust...) etc.

    http://en.wikipedia.org/wiki/Flow_battery

    http://en.wikipedia.org/wiki/Vanadium

    "The National Institute for Occupational Safety and Health (NIOSH) has recommended that 35 mg/m3 of vanadium be considered immediately dangerous to life and health."

    "Vanadium traces in diesel fuels present a corrosion hazard; it is the main fuel component influencing high temperature corrosion."

    --
    "Science flies us to the moon. Religion flies us into buildings." - Victor Stenger
  37. honey ... by georgesdev · · Score: 1

    the batteries leaked again!

  38. Re:Hopefully... by Shrike82 · · Score: 2

    Petrol (gasoline for the Americans), diesel and engine oil are all highly dangerous and extremely harmful to the environment if spilled. We still manage to use them in unimaginable quantities every day without unmanageable problems. I think the toxicity of liquid-based batteries would easily be mitigated by safe storage designs and fool-proof extraction and refilling procedures. Yeah, yeah, I know nothing is fool proof but you can imagine a pair of tubes you have to screw onto your car and an automated retrieval and refilling procedure at fuel stations.

    --
    You can advertise in this sig from as little as £99.99 a month!
  39. Re:Nope, not a fuel cell. Nothing is consumed by coffeegoat · · Score: 1

    "A fuel cell basically "burns" (uses up) its reagent to make electricity directly."

    Going to have to disagree with you here, a fuel cell is an electrochemical energy conversion device, which use a chemical reaction (in most cases a redox) to convert chemical bond energy to electrical energy. Generally this is run in one direction only, for instance hydrogen plus oxygen goes to water vapor and electricity. However, fuel cells by nature (not necessarily engineered for) are completely reversible. You can apply power and run electricity in and make hydrogen and oxygen (or whatever).

    However, due to the various engineering factors (flow resistance, phase transformations, electrical resistance etc....) they aren't often used in reversible mode. The perk of a flow battery is that if is designed to be used in reversible mode, and its engineered to avoid a bunch of these problems. Essentially on the continuum between batteries and fuel cells it's closer about right in the middle.

  40. Not really that new. by ResidentSourcerer · · Score: 1

    The only difference in this one is that the reacting material is a suspended, particular solid. There are commercial systems that use flow through batteries already.

    See:

    Flow batteries have historically had low energy densities, as the entire reacting mass was in solution. E.g. the article above cites 25-75 Wh/kg

    Which means a 50 kWh system would require roughly a cubic meter of tank, or about 5 standard drums. This is acceptable for a house, unworkable for a car. (50 kWh is about 2 days average power for a non-electrically heated house. This size unit would give impressive load level capability to the grid, and would be awesome for off grid use.

    Going to a slurry increases the energy density, but possibly with problems with charging. How do you keep the particles the same size during the charge cycle. In many conventional cell batteries, differential plating on charge is often the limiting factor on the number of cycles.

    In principle, the working solution could be filtered and the large chunks broken up. From the description of the press release, however the slurry has the consistency of light grease. Filtering would be problematic.

    This may require periodic extraction and reprocessing of the working material. Still, this should be easier than rebuilding a battery.

    --
    Third Career: Tree Farmer Second Career: Computer Geek First Career: Teacher, Outdoor Instructor, Photographer.
  41. Re:Hopefully... by CPerdue · · Score: 1

    Um, I think you missed the point. The important number is the amount of energy used for ICE transport. The number and capacity of brand x electric vehicle does not matter. I'm supposed to be working now so I won't go and look this up, but I suspect that 30% of the energy content of our transport fuel far outstripps all "alternative" generation capacity. IIRC, an article in the IEEE Spectrum way back in 1996 stated that replacing the average energy flux into gas tanks in the greater L.A. basin on a typical Friday afternoon would require about 100x the output of the Hoover Dam. Polywell fusion anyone? Sorry about the line breaks, don't know why they are not showing up correctly.

  42. Comment removed by account_deleted · · Score: 1

    Comment removed based on user account deletion

  43. Re:Hopefully... by rjstanford · · Score: 1

    Of course, one mitigating benefit is that electric motors weigh far less than gasoline-powered ones do, and are more efficient.

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  44. Re:Hopefully... by semi-extrinsic · · Score: 1

    Ignore this, modded wrong.

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  45. Re:Hopefully... by haruchai · · Score: 1

    Not at all - he made a clear mistatement or miscalculation. Yes, there is a hell of a lot of energy content in our liquid fuels but since a fairly small percentage actually moves the vehicle versus heating the engine, it's not a one-to-one replacement. A gallon of gasoline has more energy than a fully charged Nissan Leaf but I don't know any comparable street legal cars that'll get 100 mpg.

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  46. Re:Hopefully... by GameboyRMH · · Score: 1

    The batteries might bring the weight right back up and higher than an ICE vehicle however, for example the Lotus Elise vs Tesla Roadster. The Tesla weighs about 500lbs more.

    However that uses relatively heavy (compared to other modern technologies) Li-ion batteries, Li-pos are much lighter, and I don't know how much this new battery type will weigh.

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