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Research Promises Drastically Increased LiOn Capacity

daem0n1x writes "Could this be the breakthrough we've all been expecting that will finally make the electric car a reality? Researchers of Northwestern University USA discovered a new way to build lithium-ion batteries that changes dramatically both the charge time and capacity [original paper, paywalled]. Guess what it involves? That's right, graphene."

51 of 378 comments (clear)

  1. The magical ingredient by JDG1980 · · Score: 5, Funny

    Graphene. Is there anything it can't do?

    1. Re:The magical ingredient by Crudely_Indecent · · Score: 5, Funny

      Yo mama!

      --


      "Lame" - Galaxar
    2. Re:The magical ingredient by Halo1 · · Score: 5, Informative

      Actually, if you read the university press release, you'll see the magical ingredient is silicon. Current lithium-ion batteries already contain graphene sheets. What they did was

      • sandwich silicon between the graphene sheets, because silicon can bind many more ions than carbon (the downside is that it fragments, and that's what they addressed with their sandwiching process) -> more capacity
      • make minuscule holes in the graphene sheets to offer shortcuts to ions traveling from one side of the sheet to the other side (-> faster charging)
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    3. Re:The magical ingredient by timmy.cl · · Score: 5, Informative

      "graphene" is single-atom-thick carbon.

    4. Re:The magical ingredient by queequeg1 · · Score: 3, Insightful

      Actually, bacon bits are the pixie dust of the universe. There isn't anything they can touch which isn't improved by a whole order of magnitude.

    5. Re:The magical ingredient by marcosdumay · · Score: 3, Insightful

      Guess what bacon is made of?

    6. Re:The magical ingredient by oakgrove · · Score: 5, Funny

      I just sprinkled bacon bits on a stack of hundred dollar bills. I am so excited!!

      --
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    7. Re:The magical ingredient by cellocgw · · Score: 5, Funny

      Yep, it can do anything. In fact Texas Instruments is using it in their next-gen calculators. You'll soon be able to buy a ....
      .
      .
      .
      wait....
      Graphene Calculator!

      --
      https://app.box.com/WitthoftResume Code: https://github.com/cellocgw
    8. Re:The magical ingredient by darksabre · · Score: 5, Insightful

      Graphite is the form of carbon used in pencils. Anyway, my pencil is a lot more than a single atom thick ;-)

    9. Re:The magical ingredient by Anonymous Coward · · Score: 5, Funny

      I'll bet you say that to all the girls...

    10. Re:The magical ingredient by v1 · · Score: 4, Insightful

      it doesn't surprise me at all that scientists are finding all sorts of neat uses for graphene. (curious, that's NOT in my dictionary here...) The main novelty here is they're dealing with a building material on an atomic scale. Since things behave very differently at those scales, it's only natural to find new uses for it. And this is only one element they're working with. Imagine what all awaits discovery at the nano scale?

      It's like all these years you've been somehow managing to fix fine swiss watches using a baseball bat and tire iron for tools, getting at best mediocre results and only modest improvements from time to time. Now someone hands you a tweezers. Hey, this works better! really? They need to explore other nano materials instead of concentrating all their time on this one new one.

      --
      I work for the Department of Redundancy Department.
    11. Re:The magical ingredient by icebike · · Score: 4, Insightful

      This reduced the time it takes the battery to recharge by up to 10 times.

      I just cringe when I read that kind of stuff coming from an article about scientific fields.

      Does that mean 1/10 the time?

      --
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    12. Re:The magical ingredient by jeffmeden · · Score: 4, Informative

      Actually, if you read the university press release, you'll see the magical ingredient is silicon. Current lithium-ion batteries already contain graphene sheets. What they did was

      • sandwich silicon between the graphene sheets, because silicon can bind many more ions than carbon (the downside is that it fragments, and that's what they addressed with their sandwiching process) -> more capacity
      • make minuscule holes in the graphene sheets to offer shortcuts to ions traveling from one side of the sheet to the other side (-> faster charging)

      That's not quite the whole story: current lithium-ion battery designs have *graphite* in them, which is a bit disingenuous to describe merely as "many layers of graphene". The fact that in this design, they are in discrete multiple layers (with silicon and, as a result of this research, perforations) is what makes the difference. To my knowledge (correct me if I am wrong) no commercial battery has discrete graphene layers in it (graphene is a relatively new area of research, circa 2004, and conventional li-ion battery design has been relatively unchanged for about 20 years.)

    13. Re:The magical ingredient by adonoman · · Score: 5, Funny

      No, in this case, "10 times" had nothing to do with multiplication. It's simply a statement of the number of instances on which they reduced the recharge time. "On last tuesday, we reduced the the recharge time by 1%. On wednesday, we got an extra 1%. We did that up to 8 more times (we lost count, but that's the upper bound)"

  2. Increased lion capacity! by biodata · · Score: 5, Funny

    Stay in the car!

    --
    Korma: Good
    1. Re:Increased lion capacity! by delinear · · Score: 5, Funny

      Not only are they increasing the capacity, they're increasing the charge speed. That's all we need, millions of super fast lions :(

    2. Re:Increased lion capacity! by ackthpt · · Score: 5, Funny

      Not only are they increasing the capacity, they're increasing the charge speed. That's all we need, millions of super fast lions :(

      If Marlin Perkins were here he'd have to rebadge the show EXTREME Wild Kingdom

      ... as Jim approaches the lions ... oh my, they are fast! Good thing his surviving family is covered by Mutual of Omaha.

      --

      A feeling of having made the same mistake before: Deja Foobar
  3. Increased Lion capacity by Xian97 · · Score: 4, Funny

    What if I am still running Snow Leopard?

  4. Coming to the market in 5 years time? by abigsmurf · · Score: 4, Funny

    Just in time for the cheap, ultra efficient solar panels that will be available then

    1. Re:Coming to the market in 5 years time? by karnal · · Score: 3, Funny

      Oh, I think we have the capability to build cars for a fly. Question is, would they sell?

      --
      Karnal
  5. Better Place by Enderandrew · · Score: 5, Interesting

    This is a must read article on the subject. Electric cars fail because batteries are too expensive, and because they required infrastructure of charging stations. This company however solves both these problems. You make an electric car without the battery, which is cheaper than a standard car and more reliable to boot. Then this company leases you a battery, which costs less per month than gas. And they handle the infrastructure, which includes stations that swap your battery out for a fully charged one. You never wait to charge your battery, and they can swap it out since you don't own it.

    http://www.wired.com/cars/futuretransport/magazine/16-09/ff_agassi?currentPage=all

    Part of this model is the assumption that battery technology still moves along rapidly. So the company can phase in newer, better batteries and you aren't tied to a battery you purchased when you bought your car.

    --
    http://blindscribblings.com - Tasty pop-culture in conceptual fashion.
    1. Re:Better Place by scamper_22 · · Score: 5, Interesting

      Managing that battery inventory is going to be a huge problem. How are you going to make sure each 'gas station' has enough batteries on hand. Since they're not cheap, it's a huge cost. This might not be a huge problem in the city, but that's not where people have a fear of running out of battery. Heck, a simple EV you charge at home would suffice if you simply traveled in the city.

      It's the spaces in the cities or commuters.
      The roll out and management of this is a huge problem.

      But even assuming you could manage that well enough, there is another minor problem.

      Maybe I'm just paranoid coming from Africa where people will steal anything making infrastructure hard to build out... but you're talking about an expensive batter than can be 'easily swapped out'. Something tells me that makes it 'easy to steal'.

    2. Re:Better Place by Enderandrew · · Score: 3, Interesting

      Last time I checked, this company was rolling out in select places like Denmark, Israel and Hawaii. It is easier to roll out initially in places with dense populations, and harder to roll out when the population is spread out. Once the model is proven to work, I expect it to spread.

      --
      http://blindscribblings.com - Tasty pop-culture in conceptual fashion.
    3. Re:Better Place by GameboyRMH · · Score: 4, Insightful

      Battery swapping is going to look like a hilariously silly idea 5-10 years from now when an electric car can drive plenty far enough on a single charge. Heck even now you can buy quick-charging electric cars off the showroom floor that can reach an 80% charge in 30 minutes.

      And to the guy about to post "Electric cars are a joke! I drive 900 miles every day you know!" well stick to your Ford Ranger with jerry cans in the back, but don't pretend that most people have any use for such range.

      --
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    4. Re:Better Place by necro81 · · Score: 4, Insightful

      I like the idea but it makes you dependent on them plus you need to live/work at driving distance of one of their station

      A similar argument could be made against internal-combustion automobiles: you are dependent on oil companies and you need to live/work at driving distance to a filling station. I know these are facile comparisons, but I hardly think that these limitations make Better Place an impossible or useless proposition. There are lots of people that live/work in an urban area that could have a sprinkling of such stations. You can recharge the battery at home or work like a typical EV. Being able to swap it out is a way to reduce capital cost/risk in owning a battery outright, and allows you to get a full charge in a few minutes when you need.

    5. Re:Better Place by peragrin · · Score: 4, Insightful

      What is easier to store? Gasoline for 1000 cars or battery packs for 1000 cars? Your typical gas station has a couple thousand gallons of gas below it. A battery pack for elevtric cars occupies 16 cubic feet(figure 4'x4' area). To store enough batteries for 1000 cars will require 16'000 feet of storage or roughly the area occupied by a 5 bay mechanics garage.

      It will also by using more power than a hospital. And you need one on every street corner. Even with home charging we will need to double the electtical capacity and output of the USA in order to move a significant populations to electric cars.

      Take a look at the whole problem. It is really scary when you put hard numbers into play.

      --
      i thought once I was found, but it was only a dream.
    6. Re:Better Place by nedlohs · · Score: 3, Insightful

      There's this new fangled idea called the rental car.

      Such rare requirements aren't worth meeting when choosing your vehicle. Just rent the long range car or the moving van for those times you need such things.

    7. Re:Better Place by milimetric · · Score: 3, Insightful

      Sure, if you look at it that way. But...

      You don't need to store 1000 batteries, you only need to store enough for X hours worth of demand. So you take data on your gas station and find the busiest X hours in history, where X is the number of hours it takes to charge a battery. From that you find that you had N cars in your busiest X hours. So then you set up N charging stations with N spare batteries. You can multiply N by some fudge factor to give you the ability to handle failures, unprecedented spikes in demand, etc.

      Hard numbers are indeed scary, and we humans are scaredy cats so we evolved this lovely brain to help us out.

    8. Re:Better Place by Enderandrew · · Score: 3, Interesting

      Gas is relatively cheaper in the United States than England. The last time I traveled to England, gas was something like $3/gallon in the United States and the equivalent (pounds and litre conversion) to $7/gallon in England.

      Filling up a sedan with a 14 gallon tank for $50 isn't unreasonable in the United States. That being said, it isn't fair to say that a fill up costs $5000.

      The battery on hand might cost that, but the fueling station isn't paying $5000 each time they swap a battery. And keeping several of these batteries on hand is a one-time fixed cost. A gas/petrol station pays daily to have their fuel tanks filled. I actually managed a gas/petrol station while in between IT jobs. Giant tanker trunks have to drive the fuel to each station, which is horribly inefficient and costly.

      I haven't seen the Better Place design, but they could use underground conveyors. The batteries aren't just sitting around where they can be stolen. The conveyor moves the battery underground to the robotic arm that swaps it at your car. It wouldn't be vastly different from how gas/petrol stations store all their gas underground.

      --
      http://blindscribblings.com - Tasty pop-culture in conceptual fashion.
    9. Re:Better Place by w_dragon · · Score: 3, Insightful

      Wow apples-to-orages much? a couple thousand gallons of gas will not fuel 1000 cars, so why compare the storage space to batteries for 1000 cars? Also every time you're swapping a battery, so each station only needs enough batteries that it has time to recharge before that battery is needed again. Unlike a gas station where you need to have massive trucks trying to get through tiny downtown streets to refuel all the stations.

      If everyone switched to electric tomorrow then yes, infrastructure would be an issue. Amount of energy would not be (what do you think we're going to do with all the gas if we aren't using it in the cars? Just stop buying oil because we like brown-outs?) You're being scared by numbers that we already have, just calculate the potential energy in the fuel in all the gas stations in the country. Then stop fear-mongering.

    10. Re:Better Place by scamper_22 · · Score: 3, Informative

      yes, $50/ fillup. I'm Canadian and drive a small 4 cylinder. That's what it costs me to fill up.

      Try running a business... any business.

      But if it helps. Let's work through this example.
      Let's suppose you run the gas station and want to keep enough reserves to service 1000 fill-ups.

      Using gasoline (assuming $50/fill up), you need inventory worth 1000*50 = $50,000. Need more gas, you just have it delivered on demand. It's easy to manage supply and demand here given the low cost per fillup.

      Using battery exchange, you would need 1000 battery packs. That's an inventory of 1000 * $5000/battery pack... that's $5,000,000. Not to mention the huge space this would take to store the batteries. Not to mention the complexity of the batteries (failure rates...).

      Again, I'm not saying it's impossible. But it is significantly more difficult and requires significantly higher capital costs to have a battery exchange style system.

      It's not something I'd put my money into. I'd put my money on new innovation on battery technology, hybrids, rapid charging...

    11. Re:Better Place by Big_Breaker · · Score: 3, Interesting

      Close... They are rolling out in areas that have closed traffic systems, so called traffic islands. In Hawaii they have a traffic island because Hawaii is physically a collection of islands. Israel is a traffic island because Israelis rarely drive out of Israel, relations with the neighbors being what they are. Density is certainly a part of it but the closed nature of the roadways is a bigger one.

  6. Re:/. is an empty shell of what it once was. by elrous0 · · Score: 5, Funny

    I don't even comment on /. anymore.

    --
    SJW: Someone who has run out of real oppression, and has to fake it.
  7. Re:Reality by sgt+scrub · · Score: 5, Insightful

    Flying cars are already a reality. They are just expensive and inefficient.

    --
    Having to work for a living is the root of all evil.
  8. Re:Reality by Baloroth · · Score: 5, Insightful

    Interstellar travel is already a reality. It is just expensive and inefficient.

    --
    "None can love freedom heartily, but good men; the rest love not freedom, but license." --John Milton
  9. "Guess what it involves? by circletimessquare · · Score: 4, Funny

    That's right, bacon."

    More appealing answer.

    --
    intellectual property law is philosophically incoherent. it is your moral duty to ignore it or sabotage it
  10. New battery stories by P-niiice · · Score: 5, Funny

    If we could combine all the tech from all of the battery stories we've read in the past year, we could power an interstallar craft for a year with a single AAA battery and recharge it by rubbing it on a fluffy shirt for a few seconds.

  11. Don't confuse Duration with Capacity by DumbSwede · · Score: 5, Informative

    Having read the article (*gasp*) as well as a few others it seems these batteries do NOT hold 10x more power. They degrade 10x slower on on drain/recharge cycles and can be charged 10x faster. BUT this is not the same as having 10x more POWER per cycle. Gonna have to wait some more before you get an cheap electric car that can go 500 miles before charging (though charging 10x faster is nice).

    1. Re:Don't confuse Duration with Capacity by Dr_Barnowl · · Score: 5, Informative

      They do have more capacity - this isn't the traditional carbon electrode, this is a graphene-stabilised silicon anode, and silicon holds more charge.

      They also have more power, as well as more capacity. If the internal resistance is low enough to charge it in 15 minutes, it's low enough to discharge it that fast as well.

      Alas, the missing bit is similar innovations in cathode technology.

    2. Re:Don't confuse Duration with Capacity by kjhambrick · · Score: 3, Informative

      Not to mention that Gasoline or Diesel contains ooo 45 MJ/KG while a LIon Battery stores ooo 1 MJ/KG ... http://en.wikipedia.org/wiki/File:Energy_density.svg

      Seems we have a 'little' ways to go before LIon can replace good ole hydrocarbon fuels.

      -- kjh

  12. And when they finally hit the market... by Guspaz · · Score: 5, Insightful

    ... they'll fit right into the steady curve of slowly but steadily increasing battery capacity. People assume that all these battery advancements we keep hearing about never pan out. Well, some of them do, but once the researchers silly claims are brought down to be a bit more realistic, and after the years go by before they actually hit the market, they're just incremental improvements on what was available before they came out.

    There's nothing wrong with that.

  13. Re:Better battery life is always a year away by delinear · · Score: 4, Funny

    Yes, we've progressed from not having invented it to having solved some interesting research problems. Next stage is cancelation.

  14. Re:whatever by arkane1234 · · Score: 3, Funny

    or duke nukem forever...

    --
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  15. Re:Better battery life is always a year away by necro81 · · Score: 5, Informative

    Although it is subtle, battery technology has improve energy density steadily over the years. For lithium-ion, the trend has been about 5-10% / year for over a decade now. The battery pack from my ten-year old laptop (yeah, it's sittin' in a box somewhere) has just over half the nominal capacity of a battery of similar volume today. It's not Moore's Law, but it is there.

    On the other hand, with the exponential increase in transistor count / computing power has some a corollary effect of decreasing energy needed to do that computation: Koomey's Law. So if I take a look at the battery pack from my 5-y.o. flip phone and compare it to what's in an iPhone, they are roughly the same volume. But the newer battery has more capacity, and the newer phone does jumping jacks around my old feature phone, and has about the same amount of talk time / standby time, if not more.

    Call me an optimist, but I think that in this regard we're still coming out ahead.

  16. Re:Reality by GameboyRMH · · Score: 3, Insightful

    That's quite affordable for a car that runs on electricity which is far, far cheaper than gas, and requires much less maintenance.

    --
    "When information is power, privacy is freedom" - Jah-Wren Ryel
  17. Cars? Who cares about cars? by afabbro · · Score: 3, Interesting

    Will this improve the battery life on my cell phone, laptop, and tablet?

    --
    Advice: on VPS providers
  18. Re:Where was this reasearch done? by dokebi · · Score: 5, Informative

    The confusion is because the paper linked in the summary is incorrect.

    The Northwestern paper is titled "In-Plane Vacancy-Enabled High-Power Si–Graphene Composite Electrode for Lithium-Ion Batteries (pages 1079–1084)" and the summary linked paper is titled "In Situ Generation of Few-Layer Graphene Coatings on SnO2-SiC Core-Shell Nanoparticles for High-Performance Lithium-Ion Storage".

    Can people mod me up or have the summary corrected?

    --
    In Soviet Russia, articles before post read *you*!
  19. Wrong article linked in summary by dokebi · · Score: 5, Informative

    The Northwestern paper is titled "In-Plane Vacancy-Enabled High-Power Si–Graphene Composite Electrode for Lithium-Ion Batteries (pages 1079–1084)". The article linked in the summary is titled "In Situ Generation of Few-Layer Graphene Coatings on SnO2-SiC Core-Shell Nanoparticles for High-Performance Lithium-Ion Storage".

    Can people mod me up or have the summary corrected?

    --
    In Soviet Russia, articles before post read *you*!
  20. Re:The Singularity? by mangu · · Score: 3, Insightful

    If there's one event that tipped us into the Singularity that should be the invention of the integrated circuit in the late 1950s.

    Or maybe the invention of the scientific method, but that happened centuries before, too much could nave happened in between.

  21. Re:Better battery life is always a year away by DrgnDancer · · Score: 4, Informative

    Still, the main use case they are touting in the summary is cars. Faster charging, higher storage density batteries are a huge deal in that space. One of the big complaints with electric cars is that they take much longer to charge than a gas powered car takes to fill up, so faster charging is a big deal. More power density means either a) you can store the same amount of power in fewer batteries (thus theoretically reducing the weight and cost) or b) can get much farther on the same sized battery.

    Right now electric cars are right on the cusp of being really commercially viable. If they become a hair cheaper, a hair longer range, a hair quicker to charge... it could put them over the top. This has the potential to do all three, and if the research is accurate increase all of them by more than a hair.

    Plus, you know, I wouldn't complain if my iPhone went 3 days without a charge.

    --
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  22. Re:I though they were already a reality... by cartman · · Score: 3, Informative

    Compare a $10k used car to $10k electric car: The cost of a decent LiFePO4 battery pack is $6k

    That seems like a problem in your argument. There is no electric car+battery combination which costs $16k. The figure you cite is less than half the actual retail cost of an electric car+battery. Even the prius plug-in, due next year, costs over $30k, and the battery pack only provides a 10 mile range.

    The cost of electricity to recharge the pack is ~$0.10

    Retail electricity for residential consumers in states which don't burn coal is about $0.14/KwH, not $0.10. If we burn coal to generate electricity, then we've negated any environmental benefit of electric cars, so we should use the $0.14/KwH price for electricity. Electricity from renewables would be at least 50% more expensive than even that.

    Let's try a comparison with these figures. The Nissan Leaf costs $35,000, and an approximately equivalent Nissan Versa Hatchback costs $15,000. If we drive the versa for 150,000 miles with $4/gal fuel at 35 mpg, we pay $17,142 for fuel. If we drive the Leaf for 150,000 mi (which is the rated life of the battery pack), the fuel (electricity) would cost $8,400 (leaf has a 24 KwH battery pack which costs $3.36 to recharge at $0.14/KwH and takes us 60 mi on average, for a per-mile charge of $0.056, *100,000 = $8,400).

    We must also include the cost of financing. Interest at 3% above inflation for 5 years would cost $2250 for the Versa and $5250 for the Leaf. Even if you pay using cash upfront, you are foregoing interest you could have earned by investing the same money, so it's an opportunity cost.

    There will also be different insurance costs, for insuring a $15,000 car against theft vs. a $35,000 car. But let's ignore that now.

    Of course the government will give you a $7,500 tax break right now if you buy an electric car, but will only do so for a small number of buyers until the incentive expires, so let's ignore that now because it's not generalizable.

    The total cost of the Versa for 150k mi is $34,392, and the total cost of the Leaf for the same distance is $48,650. It costs about 41% more to drive a similar electric car at present, not counting insurance or limited-time government incentives. It is not cost-competitive.

    It's possible that an electric car will become competitive if gasoline costs far more in the future and batteries cost less. If the Leaf costs $30k in the future and gasoline costs $7/gal (in 2011 dollars), then the Leaf would be approximately cost-competitive with a gasoline-powered car. This circumstance is definitely possible within the next 15 years.