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Future Astronauts Must Deal With Toxic Chemicals In Martian Soil
Thorfinn.au sends this quote from Space.com:
"The pervading carpet of perchlorate chemicals found on Mars may boost the chances that microbial life exists on the Red Planet — but perchlorates are also perilous to the health of future crews destined to explore that way-off world. Perchlorates are reactive chemicals first detected in arctic Martian soil by NASA's Phoenix lander that plopped down on Mars over five years ago in May 2008. It is likely both of NASA's Viking Mars landers in 1976 measured signatures of perchlorates, in the form of chlorinated hydrocarbons. Other U.S. Mars robots — the Sojourner, Spirit and Opportunity — detected elemental chlorine. Moreover, orbital measurements taken by the Mars Odyssey spacecraft show that chlorine is globally distributed. [Phoenix principal investigator Peter Smith] said microbes on Earth use perchlorate for an energy source. They actually live off highly oxidized chlorine, and in reducing the chlorine down to chloride, they use the energy in that transaction to power themselves. In fact, when there's too much perchlorate in drinking water, microbes are used to clean it up, he said. Furthermore, seasonal flow features seen on Mars may be caused by high concentrations of the brines of perchlorate, which has a strong attraction to water and can drastically lower its freezing point, Smith told SPACE.com. The high levels of perchlorate found on Mars would be toxic to humans, Smith said."
AIUI, it's not quite that simple.
On Earth, the extremophiles are believed to arisen in more benign environments, and evolved to colonize the extreme environments. It's not clear that Mars ever had the necessary benign environment for long enough for life to arise in the first place, let alone for it to evolve and begin to colonize the extreme margins. (Which, at the time, would have been far less extreme than currently.)