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Researchers Create Sodium Battery In Industry Standard "18650" Format (gizmag.com)

Zothecula sends word that a French team has developed a battery using sodium ions in the usual "18650" format. Gizmag reports: "A team of researchers in France has taken a major step towards powering our devices with rechargeable batteries based on an element that is far more abundant and cheaper than lithium. For the first time ever, a battery has been developed using sodium ions in the industry standard "18650" format used in laptop batteries, LED flashlights and the Tesla Model S, among other products."

39 of 209 comments (clear)

  1. Sakura Battery by Anonymous Coward · · Score: 4, Insightful

    It seems like we're getting announcements about revolutionary world changing never seen before astounding new battery designs every day, but nothing ever comes to market.

    Maybe it's time to question what the fuck is wrong with the shitty "journalism" that tries and make huge stories out of nothing.

    1. Re:Sakura Battery by ganjadude · · Score: 2

      I dont think its fair to say nothing has come to market, there have been many advances in just the past 10 years

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    2. Re:Sakura Battery by shaitand · · Score: 3, Insightful

      Have you considered it might be time to ask what the fuck is wrong with the fossil fuel giants who buy up any breakthrough energy related technology and vanish it.

    3. Re:Sakura Battery by Coren22 · · Score: 4, Funny

      I Googled 18650, does that count?

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    4. Re: Sakura Battery by Anonymous Coward · · Score: 2, Interesting

      I weep a little extra for the world when even a presumably technically literate audience like Slashdot don't understand and appreciate basic science and scientific progress but immediately starts the consumer chant 'I want to buy it now or it has no value'.

    5. Re:Sakura Battery by Orphis · · Score: 3, Insightful

      The first link in the article is pointing to the CNRS news website, which is part of the organization that made the research, that's a fair one.
      The second link paraphrasing the first one doesn't add value though...

    6. Re:Sakura Battery by Rei · · Score: 5, Funny

      My father has had various top executive roles in oil companies for the past two decades. We often crack jokes with each other about this sort of stuff. "Gee, dad, how was work - suppress any new revolutionary clean energy technologies today?" "Only two... and you know we've only managed to buy off twelve congressmen this month - total? *Sigh*, the business just isn't what it used to be..." "Oh, sorry to hear that dad... maybe you should start a new war, that always works." "Yeah, I'll bring it up at the next Illuminati meeting..." ;)

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    7. Re:Sakura Battery by Beck_Neard · · Score: 3, Insightful

      Battery factories are huge and expensive. We're talking billions of dollars. I wish I was kidding. An idea could have the potential to be way better and cheaper than Li-ion but still never make it to market because no one wants to be the first to take such a huge risk. That's why in the past several years plenty of incremental improvements to Li-ion have made it to market, but there haven't been any revolutionary new technologies.

      That said, if a technology proved clearly superior to Li-ion then people would seriously consider investing in it, but most 'battery breakthroughs' still fall short of Li-ion in some ways. For example, they may not have the same longevity, capacity, or safety factor.

      Actually, that's the case here. Sodium batteries have *less* energy capacity than Li-ion, and the expected lifetimes are similar. It's just that they have the potential to be cheaper. But they're never going to be cheaper if no one builds a big factory to make them.

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    8. Re:Sakura Battery by Dereck1701 · · Score: 3, Insightful

      While I have no doubt that some of the current heavyweights in the energy market like to buy up and sit on some companies with promising developments I highly doubt that they can keep major advances held down too long. The article notes that lithium-ion batteries were developed in Europe but never commercialized (patents? NIMBYs? Lack of production capacity?), then Asia got a hold of the technology and it exploded onto the market. You may be able to control minor advances in a few markets where corrupt government officials are willing to play ball with you but major advances are going to find a market somewhere no matter what, and those places are more likely to locations where governments haven't wrapped everything up in 12 layers of red tape (patents, copyright, OSHA, etc).

    9. Re:Sakura Battery by dbIII · · Score: 2

      In the late 1990s a famous artist brought his "revolutionary fuel saving" device to the university mechanical engineering department I worked at for independent testing. It turns out he was tuning for idling. So his car engine used very little fuel while sitting at the lights doing nothing and produced crap performance and crap fuel economy while actually moving the vehicle. There was a lot of that going on.
      However there have been a small number of real advances from non-experts, I think it was sometime in the 1950s that somebody thought of running a fuel pump in the opposite direction to the normal gravity fed tradition and it made a difference. Normally it's someone who improves one thing and doesn't understand that it doesn't help the entire system at all.

      A classic that wasn't actually from the layman was the all-ceramic engine. The idea was that you could run it really hot and get more out if the fuel. Fantastic performance on a testbed, but the extra mass of the more involved cooling meant that one you tried to move it around it performed worse than what it was supposed to replace. Whoops. They only thought of a part and not the implications to how it was actually going to be used, just like that artist who was paranoid about his "invention" being suppressed.

    10. Re:Sakura Battery by mwvdlee · · Score: 2

      What happened to the all-ceramic engine? Not all engines have to move themselves, some just move other things while staying in place. (though not many I can think of right now).

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    11. Re:Sakura Battery by dbIII · · Score: 2

      Mercedes built one - it worked, for a carefully crafted single prototype. One underlying problem is the cost of machining to tolerances tight enough to use as an engine was very high. Another is that although "tough" ceramics are used the size of acceptable flaws is very low or the components crack - so quality control and a large number of rejects becomes an issue. It looked like around a million dollars per engine would be the cost if mass produced.
      The commercial outcome was ceramic cylinder liners for some truck engines. The entire point, apart from a stupid boast of it being all ceramic, is to run at higher temperatures so the cylinder liners accomplished some of that without being a brittle all ceramic engine made out of a great big insulator. Little bits of insulator do the job just as well inside a nice big conductive metal block where it's easy to cast or forge water channels.

      I've put "tough" in quotes because it's relative to other ceramics and not to a typical alloy used in engine parts. With ceramics you can't get away with a dent.

    12. Re: Sakura Battery by Joce640k · · Score: 3, Informative

      Except...this time it's true. The Gasoline car manufacturers _really do_ own the patents for making large automotive batteries. That's why Tesla has to make do with using several thousand tiny 18650s instead of a few big cells.

      https://en.wikipedia.org/wiki/...

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  2. So, just out of curiosity - by Bookwyrm · · Score: 5, Funny

    Using sodium ions?

    So, they would be (re)charged with "a salt in battery"?

  3. Far more abundant than lithium? by Rei · · Score: 3, Insightful

    Yeay! Because you know that $7-8/kg for lithium carbonate was really breaking the bank.

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    1. Re:Far more abundant than lithium? by U2xhc2hkb3QgU3Vja3M · · Score: 2, Insightful

      Because if everyone on the planet starts using batteries to store energy in their cars and at home, there won't be enough lithium and the price will go way above $8/kg?

      I dunno.

    2. Re:Far more abundant than lithium? by mspohr · · Score: 4, Informative

      Lithium is about as abundant as chlorine. Concentrated deposits occur all over the world with proven reserves of about 14 million tonnes and annual production of 36,000 tonnes. It would be really hard to run out (or create scarcity) of lithium.

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    3. Re:Far more abundant than lithium? by U2xhc2hkb3QgU3Vja3M · · Score: 3, Insightful

      But if Sodium is less damaging for the environment, is easier to process to make batteries and is cheaper as a result, it means cheaper electric cars and cheaper energy storage at home.

      $5000 electric cars, maybe?

    4. Re:Far more abundant than lithium? by mspohr · · Score: 2

      Lithium is cheap ($7/kg). A 18650 cell has only 0.6 gm lithium... not a major cost.

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    5. Re:Far more abundant than lithium? by ShanghaiBill · · Score: 3, Insightful

      $5000 electric cars, maybe?

      Unlikely. Lithium is only a small fraction of the cost of lithium batteries, so switching to sodium won't save much, and sodium is much heavier and has lower power density (by mass or volume). A sodium battery may make sense for static applications where neither weight nor power density matter, but electric car batteries will continue to be based on lithium.

    6. Re:Far more abundant than lithium? by Rei · · Score: 2

      Actually, it's just the other way around. The reserves of in-demand materials - especially those for which there was relatively little demand for previously - tend to grow, by orders of magnitude, over time. And the maximum production cost of lithium is essentially capped, because the oceans have an essentially inexhaustable supply, and it costs an estimated $20-35 per kilogram (last I checked, the figure may have gone down since then) to produce lithium salts from it. But nobody is going to be touching that in the foreseeable future because there are such vast reserves onshore - salars, hectorite clays, pegmatites, geothermal lithium, etc. Actually $7-ish/kg is rather expensive for lithium salts, the long-running price has been more like $4-5/kg. Which has led to a new rush of lithium exploration, as it was so underexplored previously. And companies are finding huge lithium deposits bloody everywhere. A lot in the US, actually.

      It's simply not a rare element.

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  4. Our house is powered by these by Anonymous Coward · · Score: 2, Interesting

    But not in 18650 format. We have 25kwh of aqueous sodium ion batteries (5000 full cycles and still counting) giving us solar energy at night. Because of the lower voltage per cell, they use a safe sodium salt water electrolyte. G**gle aquion pittsburgh..

    1. Re:Our house is powered by these by rch7 · · Score: 2

      If you google for aquion price, 2.6kWh costs $1200, which means $461/kWh. Or 30.6 kWh for $15,000. As usually, if price is not disclosed, it means it is for people who don't care about price :(

  5. Battery Advancements by Anonymous Coward · · Score: 2, Insightful

    I keep old rechargeable batteries around to disprove the notion that there have been no advancements.

    #1 Radio Shack NiCad D size battery from the late 1980's. 1.2V 1200 Mah
    #2 Energizer NiMh AA size battery from the late 2000's 1.2V 2600 Mah (up to 1.4v when fully charged)
    #2 R/C heli Lipo, volume equivalent to C size from post 2010 3.7V 5000 Mah

    You do the math.

    1. Re:Battery Advancements by x0ra · · Score: 2

      #1 Radio Shack NiCad D size battery from the late 1980's. 1.2V 1200 Mah
      #2 Energizer NiMh AA size battery from the late 2000's 1.2V 2600 Mah (up to 1.4v when fully charged)

      1) battery voltage without load is meaningless, 2) a 2x capacity increase over nearly 30 years is pretty laughable and 3) I think you meant mAh, not Mahhttp://hardware.slashdot.org/story/15/11/30/2018211/researchers-create-sodium-battery-in-industry-standard-18650-format#

    2. Re:Battery Advancements by nightfire-unique · · Score: 4, Insightful

      Assuming a linear-ish discharge curve over a 70% discharge, 1.44Wh D cell to 18.5Wh (equivalent) C cell is not a 2x capacity increase.

      I want battery technology to increase an order of magnitude every year too, ... but come on. We've made enormous strides.

      You, yourself, can buy low-resistance, low-self-discharge lithium ion batteries at 250Wh/kg. And they're cheap. Compare that to 30Wh/kg NiCD batteries of 30 years ago.

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    3. Re:Battery Advancements by Anonymous Coward · · Score: 2, Informative

      Consumer secondary batteries have 10x higher energy density by weight and volume today as compared to 30 years ago.

      Your smartphone battery would weigh 1lb, and be 5 times the thickness of your phone, if made using 1980s nicd.

  6. "Advanced battery technology" is a flashlight batt by raymorris · · Score: 3, Interesting

    I knew that power tools and laptops used 18650 cells, which are slightly larger than AA batteries. Given the hype about "Tesla's advanced battery technology", I'm pretty surprised to learn the Tesla battery is also simply 7,000 flashlight batteries.

    I see that the Tesla battery pack weighs 1,200 pounds. Reducing weight greatly improves efficiency, handling, braking, and acceleration, meaning lighter weight is all around better. It seems a bit wasteful of weight and materials to have 7,000 metal casings around 7,000 tiny batteries, connected with thousands of connections, rather far fewer larger cells. I'm surprised they don't use perhaps 24 or 100 larger cells instead, thereby eliminating thousands of unnecessary casings and connections.

  7. Battery Specs by myrdos2 · · Score: 2

    The most important details: The energy density performance (90Wh/kg) are above the expectations especially considering the excellent cycle life (at least 2.000 charge/discharge cycles). It would also be nice to see voltage drop-off as the battery discharges and expected price, but now I'm getting greedy...

    1. Re:Battery Specs by JoeMerchant · · Score: 2

      Price will be at a disadvantage until production has scaled up. Personally, I like having a more linear voltage dropoff with discharge - you can always switch the voltage up to whatever you need, and if you are discharging near capability limits - unless this is a drag cycle, you are going to have disappointing time to full discharge.

  8. Re:"Advanced battery technology" is a flashlight b by TheGavster · · Score: 4, Informative

    The idea on many small battery cells is that the standard size makes them available from multiple suppliers, reducing risk, and the gaps between the cells due to the packing fraction provide a conduit for cooling.

    Telsa does have a lifecycle plan to refurbish packs from cars for use in the home; at least in the press photos, the home packs are a different form factor, so I wonder if they break up the packs to cull outright broken cells and then reconstitute the good ones into wall units. Since the breakdown is a function of electrode area, having the area in smaller pieces might help with reuse.

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  9. Re:"Advanced battery technology" is a flashlight b by Anonymous Coward · · Score: 4, Informative

    If you want an actual answer instead of just an excuse to bag on Tesla ... Smaller cells have more surface area to dump heat, which is crucial when recharging. In other words, the mass of the casing (which is not large) is actively being used for thermal management. Additionally, in the manufacturing process, smaller cells have a lower reject rate and allow both a much more repairable battery pack than custom cells and improve the performance as cells degrade. The packing density for these cells is pretty good, (85%) and smaller cells allows tailoring to custom shapes, though Tesla doesn't take advantage of that, having roughly rectangular packs.

  10. Yes, exactly. by Medievalist · · Score: 2

    The "many small batteries" approach is what makes it possible to get a decent charge in a Tesla in around 20 minutes... instead of 80+ hours.

    If you charge 7,000 small batteries in parallel you'll do it roughly 1000 times faster than charging seven huge batteries with the same total capacity.

    1. Re:Yes, exactly. by tlhIngan · · Score: 4, Informative

      The "many small batteries" approach is what makes it possible to get a decent charge in a Tesla in around 20 minutes... instead of 80+ hours.

      If you charge 7,000 small batteries in parallel you'll do it roughly 1000 times faster than charging seven huge batteries with the same total capacity.

      More importantly, the 7000 little batteries actually make the system more efficient than 7 large ones. Because of the massive amount of power the motors have (50+ kW), using more cells in series means higher voltages. And higher voltages means lowered currents which mean less wasted power in IIR losses. Double the voltage, halve the current, one-quarter the loss. It's why transmission lines are high voltage, why data centers usually get 208V or higher (besides three-phase) at the racks, etc.

      7 lithium batteries only gets you 28V. If we use 56kW, that's nearly 2000A you have to draw - you probably will have to use the chassis split down the middle to carry that kind of current. 7000 lithium batteries as 7x1000 (4000V) series packs means drawing 14A from each pack, or 98A total. Of course, no one runs that high a pack voltage - safety reasons - it's usually closer to 480V or so, which is a large current but still manageable.

  11. Battery Tech Has Impoved! by HannethCom · · Score: 3, Informative

    When I first started looking at standard AA batteries in about 1994 you had your normal Zink-carbon batteries that the good ones would be 1200mAh capacity. There were some premium Alkaline batteries that were 2000mAh. If you wanted rechargeable you were looking at NiCd at about 800mAh.

    Fast forward to about 2004. Alkaline batteries at about 2000mAh was standard. Lithium batteries at 3000mAh were around and NiMH had almost completely replaced NiCd at about 2100mAh for good quality ones. Then there is also the proliferation of Li-Ion batteries for other applications. Charge times for rechargeable batteries had come way down.

    Today Alkaline batteries are at about 2600mAh, with Lithium still at 3000mAh. NiMH are still in use and the good ones are still at 2100mAh with some "Pro" batteries at 2550mAh. Li-Ion still in great use, but getting smaller while keeping the same amount of power. Charging times have continued to decrease, mostly with new charging technology that can be used on the older batteries as well.

    What does the future hold? Well, we have heard about tech for making Li-Ion batteries fully charge in minutes. There is the improvement in sodium batteries. Different chemical combinations of Li-Ion to hold more power.

    Why is it not here now? Most new technology takes at least 5 years from announcement of it working, to being able to mass produce it at a decent cost. That is for companies that have lots of money and experience in that specific field. More of an average is 10 years between proof of concept and mass production. 10 years may sound like a long time to people, but in the manufacturing world with new technology, it really isn't that long. Intel runs with a 10 year plan, and they can bring many of their advancements to market in 5 years. Intel is a company with a lot of money and a lot of knowledge about exactly what they do and yet, they still work on basically 10 year plans. Most companies are not as efficient.

    Yes many times products will be designed and brought to market in 1 to 2 years, but they usually use existing technology. They use chips, tech, batteries that exist when the product is announced. They already have the full design done, all they need to do is mass produce them, and it still takes 1-2 years. Even though exactly how to mass produce it and all the parts are known. New technology on the other hand is a different beast that there are often problems in figuring out how to mass produce it, or they find out that it can't be mass produced cheaply enough.

    The other thing is that you are getting the new technology all the time, you just don't notice it because it is done in an incremental process. The battery has a little more power, it is a little smaller, it charges a little faster. Where if you compare something today to 10 years ago you would notice that the battery stores a lot more power, it is a lot smaller and it charges a lot faster.

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  12. Re:except they don't. Voltage of 120 batteries by aXis100 · · Score: 2

    The charging comment is only true up to a point. As you get larger solid packs, the surface area doesn't increase as fast as the volume and the insides can get very hot. Thermal management is super critical for many battery types so this is a major limitation.

    With a small cylindrical battery, the empty packing space between the cells provides a perfect channel for cooling.

  13. Re:Sodium and explosions by clovis · · Score: 2

    Isn't sodium really toxic (not good when exposed to air) and explodes on contact with water (youtube.com has plenty of examples of this)? I wonder how long it would be before a lawyer sues the battery makers after someone opens a battery somewhere near water? Maybe they have taken this into account with the battery design?

    Does not matter because they aren't using sodium metal, they're using a sodium compound.

  14. It's dug out of salt lakes by dbIII · · Score: 2
    Take a look at the mining operation halfway down the page:
    https://en.wikipedia.org/wiki/Salar_de_Uyuni

    And also where the hell did you get your numbers for cost? I found $9.50/0.1kg or $95/kg if buying bulk, and in smaller amounts it's $270/kg

    Why are you shifting the goalposts to a price that a battery manufacturer buying by the tonne would never pay? Maybe you could just do a google search like this:
    http://www.google.com/search?q=lithium+price+per+tonne

    1. Re:It's dug out of salt lakes by Rei · · Score: 3, Informative

      Indeed, lithium mining from salars is actually one of the more benign mining processes that exists. You're out on an area that is virtually devoid of life, pumping up saltwater, letting it evaporate in ponds to concentrate it, selectively crystalizing the desired salts (such as lithium salts) out, and setting the remaining salts back on the salt flat. Every year the annual floods come and resurface the entire thing.

      You know, sometimes it feels like people just want to hate any new technology.

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