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Desktop 3D Printers Shown To Emit Hazardous Gases and Particles (acs.org)

An anonymous reader writes: A new study in the journal Environmental Science & Technology by researchers at Illinois Institute of Technology and The University of Texas at Austin sheds more light on potentially harmful emissions from desktop FDM 3D printers. The researchers measured emissions of both ultrafine particles (UFPs) and volatile organic compounds (VOCs) from 5 commercially available polymer-extrusion 3D printers using up to 9 different filaments. [The researchers] found that the individual VOCs emitted in the largest quantities included caprolactam from nylon-based and imitation wood and brick filaments (ranging from ~2 to ~180 g/min), styrene from acrylonitrile butadiene styrene (ABS) and high-impact polystyrene (HIPS) filaments (ranging from ~10 to ~110 g/min), and lactide from polylactic acid (PLA) filaments (ranging from ~4 to ~5 g/min). Styrene is classified as a "possible human carcinogen" by the International Agency for Research on Cancer (IARC classification group 2B). While caprolactam is classified as "probably not carcinogenic to humans," the California Office of Environmental Health Hazard Assessment (OEHHA) maintains low acute, 8-hour, and chronic reference exposure levels (RELs) of only 50, 7, and 2.2 g per cubic meters, respectively, all of which would likely be exceeded with just one of the higher emitting printers operating in a small office.

26 of 96 comments (clear)

  1. Duh? by BoberFett · · Score: 5, Insightful

    Ummmm, duh? You're melting plastics in order to reform them into another shape. It doesn't take a study to realize you shouldn't stick your face in and breathe deeply.

    1. Re:Duh? by vlad30 · · Score: 4, Insightful

      Additionally which models did they test one with or without a case the diagrams suggest a case however most models with cases have fans and filters did they open the case and measure was the filter defective or removed to allow the particles to be measured they talk about the sealed room not a sealed printer in the setup

      --
      Your'e all thinking it, I just said it for you
    2. Re:Duh? by arglebargle_xiv · · Score: 2

      The important thing is that someone is pointing this out. The 3D printers I've worked with (large commercial units) all have fully enclosed ventilated fume hoods. I've always wondered about cheapie open-air ones and the amount of VOCs they'd spread throughout the environment. At least people will now be a bit more aware of the issue.

    3. Re:Duh? by dsmatthews9379 · · Score: 2

      I warned my state's Minister for Health about this issue last year and the reply was dismissive of my concerns about how 3D printers could impact on the health of children in schools. "No more dangerous than cooking fumes yada yada yada....." yeah right! And people wonder why I decided to provide my kids with a STEM based education from home.

    4. Re:Duh? by thoromyr · · Score: 2

      where I work, yes, they'd just vent it into the office space. That's what they do with the stratasys printers. Actually, there's no "venting" per se. They just sit in the office and emit.

      Sure, these units are sub $100,000 ABS printing units so maybe the really high end stuff is vented. But the comments here about "cheapo bad, expensive good" come off more as astroturfing for/by stratasys and 3d systems than reality.

  2. Plastic is nothing but toxic garbage by Anonymous Coward · · Score: 2, Insightful

    And now we are suddenly surprised that manufacturing plastics from toxic chemicals actually released toxic chemicals into the air. Even when you do it in your own home. Who would've known.

  3. Lots of toxic chemicals are usd every day by Anonymous Coward · · Score: 2, Insightful

    It would seem that the best approach is simply to 3D print things in a well-ventilated area. Lots of things are toxic if exposed to sufficient concentrations. In the absence (for now) of alternatives to the toxic chemicals, the best advice is ventilation and avoid the areas as much as possible where printing is being done.

    1. Re:Lots of toxic chemicals are usd every day by Anonymous Coward · · Score: 4, Interesting

      How many people ACTUALLY print in a well-ventilated area though? If many people are using these printers, and most of them are doing so indoors(many are inside bedrooms) and most of those aren't opening doors or windows to ventilate the room: I think the headline is of significant public interest. I have a printer running in our guest bedroom right now with all doors and windows shut. I walk in the room to check on the print and get a good smell of ABS fumes every hour or so.

  4. Um, ventilate? by Sowelu · · Score: 4, Insightful

    Doesn't every single printer and every single guide say to use in a well ventilated area for obvious reasons? You don't want to solder in a small office with no ventilation either.

  5. Coming Attractions by rmdingler · · Score: 2
    "Did you or a loved one ever suffer infirmities, disease, or even death after using a 3D printer while working in a shipyard?

    If so, call us now for a free consultation. You don't pay a dime unless we win the settlement."

    --
    Happiness in intelligent people is the rarest thing I know.

    Ernest Hemingway

  6. Yep, they're almost useful by russotto · · Score: 4, Insightful

    ....must be time to ban them.

  7. Here we go again ... by quenda · · Score: 2

    Whatever happened to all those claims of illness from photocopiers and laser printers?
    Was it ozone ... dust ... nanoparticles? Or those evil LASERs?

  8. That's MICROgrams, not grams... by jeffb+(2.718) · · Score: 4, Insightful

    This is getting ridiculous. A moment's thought would make it obvious that the emission rates quoted in the summary are wrong by orders of magnitude. Are there even home printers today that can extrude as much as 180 g/min of material, never mind vaporize or aerosolize that much?

    1. Re:That's MICROgrams, not grams... by edjs · · Score: 5, Informative

      All the measurements are in micrograms/min, if you look at the article.

      I'm guessing the submitter pasted-in the text from the article without realizing the symbols would be dropped by ./ - preview is your friend.

  9. Re:No surprise here. by MightyYar · · Score: 4, Funny

    We can only hope that 3-D printers are someday as safe as chemistry sets.

    --
    W..w..W - Willy Waterloo washes Warren Wiggins who is washing Waldo Woo.
  10. Don't Worry by Roger+W+Moore · · Score: 4, Interesting

    Apparently one of the gases is "probably not carcinogenic" and the other is only classed as a "possible human carcinogen" so really the title should read "Desktop 3D Printers Shown to Emit Gases some of which might be hazardous". Not to mention that if the safe exposure level is 50g/m^3 that's almost 5% by weight of air so either someone messed up the units or one of the gases emitted are safer than carbon dioxide and nobody suggests that we ban candles.

    1. Re:Don't Worry by Dutch+Gun · · Score: 4, Funny

      Besides, if you do happen to get cancer, you can just 3D print yourself a replacement organ.

      --
      Irony: Agile development has too much intertia to be abandoned now.
    2. Re:Don't Worry by jandersen · · Score: 3, Interesting

      Apparently one of the gases is "probably not carcinogenic" and the other is only classed as a "possible human carcinogen" so really the title should read "Desktop 3D Printers Shown to Emit Gases some of which might be hazardous". Not to mention that if the safe exposure level is 50g/m^3 that's almost 5% by weight of air so either someone messed up the units or one of the gases emitted are safer than carbon dioxide and nobody suggests that we ban candles.

      The good old "it won't happen to me"? Unfortunately, reality isn't as kind as that, as I'm sure you know. The purpose of this research is not to get 3D printing banned, or even to "discover" that it is hazardous; we already knew that there are hazards connected with working with hot, melted plastic. We just hadn't quantified the hazards well enough, yet. It makes sense to figure this out, so we can make informed decisions about how to mitigate the problem.

    3. Re:Don't Worry by Rei · · Score: 3, Interesting

      Because Slashdot doesn't support unicode.

      Really though how much of idiots do these system designers have to be to not have thought of this? For fun I've been working on a design for a material-flexible 3d printer (though I don't actually plan to put the money and time into building it any time soon) and it became clear very early on that atmospheric control would be critical if you want to have it in the house. There are only a very few raw materials that come to mind that I wouldn't have outgassing or dust concerns with.

      I can't imagine why they didn't think to at least put an activated carbon pad and/or paper air filter in the airflow path through the housing. It'd have almost no effect on the final cost.

      --
      What the hells goin on in the engine room? Were there monkeys? Some terrifying space monkeys maybe got loose?
    4. Re:Don't Worry by Rei · · Score: 2

      Caprolactam is probably not carcinogenic, but it is most definitely an irritant and somewhat toxic, neither of which are good qualities to have for a gas in your home. Styrene, in addition to being a possible carcinogen, is toxic and mutagenic. In particular, it's toxic to the central nervous system. According to the EPA:

      Acute Effects:

              Acute exposure to styrene in humans results in respiratory effects, such as mucous membrane irritation, eye irritation, and gastrointestinal effects. (1,2)
              Tests involving acute exposure of rats and mice have shown styrene to have low to moderate toxicity by inhalation and oral exposure. (3)

      Chronic Effects (Noncancer):

              Chronic exposure to styrene in humans results in effects on the CNS, with symptoms such as headache, fatigue, weakness, depression, CNS dysfunction (reaction time, memory, visuomotor speed and accuracy, intellectual function), and hearing loss, peripheral neuropathy, minor effects on some kidney enzyme functions and on the blood. (1-3)
              Animal studies have reported effects on the CNS, liver, kidney, and eye and nasal irritation from inhalation exposure to styrene. (1)
              Liver, blood, kidney, and stomach effects have been observed in animals following chronic oral exposure. (5)

      ---

      Reproductive/Developmental Effects:

              Human studies have not reported an increase in developmental effects in women who worked in the plastics industry, while an increased frequency of spontaneous abortions and a decreased frequency of births were reported in a study on the reproductive effects of styrene in humans. However, these studies are not conclusive, due to the lack of exposure data and confounding factors. (1,2)
              Animal studies have not reported developmental or reproductive effects from inhalation exposure to styrene. (1)
              Lung tumors have been observed in the offspring of orally exposed mice. (12)

      But hey, it's only probable that it'll also give you "leukemia, lymphoma, and other stem, blood, and bone marrow cancers", so let's totally play it down.

      --
      What the hells goin on in the engine room? Were there monkeys? Some terrifying space monkeys maybe got loose?
    5. Re:Don't Worry by dywolf · · Score: 2

      well, that part usually comes after someone says "hey there might be a problem here", not before.

      --
      The guy who said the election was rigged won the presidency with the second-most votes.
  11. First step... by Alypius · · Score: 2

    ...for the inevitable lawsuits by California bottom-feeders under Prop 65.

  12. I would like to know whats different with the olde by gl4ss · · Score: 3, Interesting

    whats different with the older study? the new nylon, wood filaments?

    the old study that was at some media quoted as OMG IT KILLS YA actually when covered correctly was titled about "3d printer as hazardous as cooking".

    and well if you cook your peek/teflon parts in the extruder then thats pretty hazardous..

    --
    world was created 5 seconds before this post as it is.
  13. When you panic and regulate based on... by Anonymous Coward · · Score: 5, Interesting

    what you can DETECT rather than what's actually significantly harmful, and without any tether to the reality of the relative risks, you will regulate everything and panic over everything eventually as technology gives you an ever-increasing ability to detect. This is one of the big problems with the EPA. When President Nixon created that agency, it merrily started regulating based on detection. A huge know-nothing portion of the population has now been raised in this anti-science omni-political activist environment falls for any shrieking by any group that points anything it chooses to, never knowing the truth about why a particular person or group decided to start whipping-up panic over a particular thing.

    Example of this modern madness: Mankind has used mercury thermometers for centuries; they've saved more lives and advanced human understanding of the world more than any person could possibly quantify. Several years ago at a public school in Southern California, a student in a science class accidentally broke one in the lab - and the school had an evacuation and a HazMat team was called-in wearing full protection suits to clean-up the "toxic spill". There were weeping mothers on the evening news worried about the permanent harm their children might have suffered...

    Odds that any person will be permanently harmed or killed by fumes from a 3D printer? Zero

    Odds that a user of a 3D printer will be permanently harmed or killed by drugs, or alcohol, or base jumping, or a vehicular accident?

    I leave it as an exercise for the reader to figure out what to worry about, and whether to panic over the next obnoxious moron trying to generate publicity and scare you into demanding the government control even more of your life.

  14. Re:No surprise here. by SharpFang · · Score: 4, Funny

    "Mostly"?

    My uncle died when working with a chemistry set and standing upwind. He was just reducing CuO with Mg, standing upwind, when a drunk truck driver drove an 18-wheeler into his house killing him instantly.

    Now if he only stood downwind, these 3 meters would have saved his life.

    --
    45 5F E1 04 22 CA 29 C4 93 3F 95 05 2B 79 2A B2
  15. Re:cheap activated carbon filter? anyone KNOW? by Gilgaron · · Score: 2

    Carbon is what you use in a respirator cartridge. For stuff like organic vapors, a hobbyist is better off wearing a respirator than trying to filter since the former is cheaper and easier to get right. The same sort of thing you'd wear to spray some lacquer in your garage would do well enough, I'd think.