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Carbon Dioxide From the Air Converted Into Methanol (gizmag.com)

Zothecula writes: The danger posed by rising levels of atmospheric carbon dioxide has seen many schemes proposed to remove a proportion it from the air. Rather than simply capture this greenhouse gas and bury it in the ground, though, many experiments have managed to transform CO2 into useful things like carbon nanofibers or even fuels, such as diesel. Unfortunately, the over-arching problem with many of these conversions is the particularly high operating temperatures that require counterproductive amounts of energy to produce relatively low yields of fuel. Now researchers at the University of Southern California (USC) claim to have devised a way to take CO2 directly from the air and convert it into methanol using much lower temperatures and in a correspondingly simpler way.

37 of 158 comments (clear)

  1. Energy in? by Mr+D+from+63 · · Score: 4, Insightful

    I see no mention of the energy put into the process vs the methanol output. Unless they are close, this would make no sense.

    1. Re:Energy in? by Opportunist · · Score: 3, Informative

      They have to obey the laws of thermodynamics and conservation of energy? You don't say.

      --
      We used to have a Bill of Rights. Now, with the rights gone, all we have left is the bill.
    2. Re:Energy in? by blue9steel · · Score: 4, Insightful

      Even if it wasn't net positive a low enough ratio might make it worth it to just pull the carbon out of the air and store the methanol in tanks. This might be a good use for surplus power at renewable generating sites, they could actually be carbon negative.

    3. Re:Energy in? by Hussman32 · · Score: 5, Informative

      From the article:

      "To produce methanol from CO2 in the air, the researchers at USC's Dornsife College of Letters, Arts and Sciences first bubbled captured air through an aqueous solution of pentaethylenehexamine (PEHA), an ammonia-derived organic compound with multiple amino groups that – at raised temperatures – helps form chemical derivatives from alcohols. They then added a catalyst made from ruthenium (a member of the platinum group) to promote hydrogen attachment to the CO2 when the mixture was subject to high pressure.

      The solution was then heated to around 125 to 165 C (257 to 359 F), and around 79 percent of the CO2 was converted into methanol. Though the resulting methanol was still mixed with water as it was produced, the researchers state that it can be easily separated using simple distillation processes. In addition, with the new method operating at such comparatively low temperatures, minimum decomposition of the catalyst meant that the researchers were able to repeat the process five times with minimal loss of the catalyst effectiveness. It also uses a homogeneous catalyst (that is, a soluble catalyst in solution with the chemicals it is reacting with) resulting in a simpler and faster "one-pot" process."

      So they have to procure an amine in the pure form, mix it with purified water, heat it to 125 to 165 oC (a lot of energy, also under pressure), bubble the air through it (requiring at least the same pressure as the solution so there wouldn't be backflow) then recover the product using distillation (energy intensive). It's good chemistry and interesting catalysis, but I don't see how it will be cost-effective.

      My guess is it would be cheaper to let a tree reduce the CO2, chop it down, and make the wood alcohol from that.

      --
      "Who are you?" "No one of consequence." "I must know." "Get used to disappointment."
    4. Re:Energy in? by bobbied · · Score: 2

      Again, no way this makes sense... At least not for carbon sequestration.

      Just dumping waste energy into methanol production doesn't seem to be a viable way to sequester carbon to me. Now if you want to make it into a means of making use of this waste energy, say as a motor fuel or something, and reduce the amount of carbon we release, that might work... Some... But it's going to be hugely expensive and very inefficient...

      --
      "File to fit, pound to insert, paint to match" - Aircraft Maintenance 101
    5. Re:Energy in? by Obfuscant · · Score: 4, Interesting

      Trust me, it makes no sense... I can guarantee you that it takes a lot more energy input than you can get out of the methanol.

      Every energy storage process takes more energy to store it than you get back out. I don't think getting energy back out of the methanol is the goal. Using it for other industrial processes that require methanol would be more useful.

      but if you wan to produce methanol, just produce it the normal ways.

      This method can be used on the output of current industrial processes that produce carbon dioxide and prevent it from being released in the first place. It's less efficient to loose the dragon and then hope a tree eats him than to just keep the dragon in the dungeon to start with.

    6. Re:Energy in? by sconeu · · Score: 2
      --
      General Relativity: Space-time tells matter where to go; Matter tells space-time what shape to be.
    7. Re:Energy in? by Anonymous Coward · · Score: 4, Insightful

      The first thing is that power plants like nuclear are extremely inflexible. Basically they have to keep producing energy no matter what. This means that sometimes energy costs become negative. The producers of electricity from nuclear will actually pay you to use their power.

      The next thing you need to know is that renewable, whilst mostly very flexible, has a relatively high capital, but very low marginal cost. This means that if there is a time when energy prices are low (e.g. due to nuclear power plants having to run during a low usage period) the renewable sources will be willing to sell you energy for almost any positive price.

      This means that there is quite a bit of time when energy loss really doesn't matter nearly as much as you think. If you can just store some of the energy and use it at a later peak usage time, when it's many times more valuable, then you can make a profit even with huge energy losses.

      Methane would be better than methanol. If you can produce methane you can power highly flexible gas power plants. Stiill, methanol is definitely better than nothing.

    8. Re:Energy in? by blue9steel · · Score: 2

      Just dumping waste energy into methanol production doesn't seem to be a viable way to sequester carbon to me.

      Well I'd prefer a non-toxic solid so we could just re-bury it. Calcium Carbonate or something along those lines.

    9. Re:Energy in? by currently_awake · · Score: 3, Insightful

      Using energy from windmills to power the process in a remote location (arctic etc) is cheaper than flying in gas. Using energy from the nuclear reactor of an aircraft carrier to produce jet fuel while at sea would save a lot of money/risk on transporting fuel. Using this tech to make fuel at a military base in a dangerous place (Afghanistan etc) would reduce the need for supply convoys, and save lives.

    10. Re:Energy in? by PolygamousRanchKid+ · · Score: 2

      5-10 years away means it's quite far from making economic sense.

      5-10 years away means that in 5-10 years, it will still be 5-10 years away.

      --
      Schroedinger's Brexit: The UK is both in and out of the EU at the same time!
    11. Re:Energy in? by Anaerin · · Score: 2

      So they have to procure an amine in the pure form,

      Correct.

      mix it with purified water,

      Right again

      heat it to 125 to 165 oC (a lot of energy, also under pressure),

      Partially Correct - there was no mention of it being under pressure.

      bubble the air through it (requiring at least the same pressure as the solution so there wouldn't be backflow)

      1.001 Atmosphere of pressure, yes.

      then recover the product using distillation (energy intensive).

      Correct. Though as the solution was originally at 125-165C, the methanol would most likely be in vapour form, so condensation would be a relatively simple matter.

      It's good chemistry and interesting catalysis, but I don't see how it will be cost-effective.

      My guess is it would be cheaper to let a tree reduce the CO2, chop it down, and make the wood alcohol from that.

      Oh, of course. Though that is a process that requires considerably more time than this one, it seems.

    12. Re:Energy in? by sumdumass · · Score: 4, Interesting

      Actually, it sounds like a perfect process for clean coal or other already existing energy production. The cooling towers alread carry enough heat to raise the temperature. As for pumping, well the generating already runs a bit under capacity so turning it up a little more shouldn't be too costly.

      With a little tweaking, it could relatively easily reduce the carbon footprint of existing power plants.

    13. Re:Energy in? by Hussman32 · · Score: 2, Informative

      There are 44.6 moles per cubic meter of air. At 300 ppm, or 0.03% CO2, that would be 0.013 moles of CO2, at a 70% conversion rate you'd get 0.01 moles of methanol from 1 cubic meter of air. 1 kilogram of methanol (which isn't jet fuel, but never mind) is 31 moles of methanol. A 737 burns 3 kilograms of jet fuel per mile, let's say you want 6000 kilograms per trip. That means you'd need 3100 m^3 of air for one kilogram, or 18,600,000 m^3 of air. Assuming a residence time of a day for a facility to produce enough jet fuel for one flight, you'd need a facility with a total volume of 18,600,000 m^3. I'm not really sure it's cost effective to fly out a facility that as a minimum would be about 264 meters long, wide, and high. If the residence time were an hour, it would be about 100 meters on a side.

      Another application is needed, this one won't cut it.

      --
      "Who are you?" "No one of consequence." "I must know." "Get used to disappointment."
    14. Re:Energy in? by Hussman32 · · Score: 4, Informative

      Pure amines are expensive, and purifying water isn't cheap at the volumes this would need (see my other notes).

      Note the process says it's aqueous, and therefore liquid. The temperature is 125-165 degrees, above the normal boiling point of water. Steam tables say 6 bars/atmospheres of pressure at 165 oC for pure water. 6 atmospheres isn't too bad for a pressure vessel, but you will need some engineering behind it.

      Condensation requires energy, especially if you need a vacuum.

       

      --
      "Who are you?" "No one of consequence." "I must know." "Get used to disappointment."
    15. Re:Energy in? by Mr+D+from+63 · · Score: 2

      Using energy from windmills to power the process in a remote location (arctic etc) is cheaper than flying in gas. Using energy from the nuclear reactor of an aircraft carrier to produce jet fuel while at sea would save a lot of money/risk on transporting fuel. Using this tech to make fuel at a military base in a dangerous place (Afghanistan etc) would reduce the need for supply convoys, and save lives.

      You couldn't fit enough windmills on a base to make all the fuel that base uses.

    16. Re:Energy in? by Obfuscant · · Score: 2

      you'd need a facility with a total volume of 18,600,000 m^3

      No, you'd need to process that much air. The facility could be much smaller, but you'd need to move so much air through it you'd be expending much more energy moving the air than you'd get back from the methanol.

      Even if you contain all the air in the one facility, you won't be using 18 million cubic meters of water and catalyst, so you still have to move the air.

      But it is a beautiful thought experiment to think about such a CO2 to methanol recovery device on the output of the burner of a hot air balloon. Maybe you could make enough methanol from it that you could replace the tank of propane and burn only methanol. And with thermal electric generation, you could install wireless networking in the balloon and have permanent access points in the sky...

    17. Re:Energy in? by dbIII · · Score: 2

      Again, no way this makes sense... At least not for carbon sequestration.

      It may make sense if waste heat can drive the reaction, or solar thermal or whatever. I heard something along those lines when it hit the press a few months back
      Also the possible military, agricultural and mining exploration implications are interesting if it can be done on a small scale anywhere with a heat source. Shipping fuel into remote areas has diminishing returns - hence bizzare stuff like using solar at Dome A in the Antarctic where the panels are mounted vertically on poles to catch the summer sun - just about the least sunshine on the planet but it saves shipping in a bit of fuel.

  2. Taking CO2 from the atmosphere?? by NotInHere · · Score: 4, Insightful

    What about not putting it there in the first place? It takes far more energy to extract the CO2 from the atmosphere than to build an energy chain that doesn't burn fossil sources. And if you really are keen on removing CO2, then just stop deforestation in south america.

  3. Pray for Timothy by sexconker · · Score: 4, Funny

    timothy are you okay? Post if you are okay.

  4. how about growing lots of trees & plants? by sittingnut · · Score: 3, Interesting

    how about growing and developing trees & plants that capture co2 more efficiently and can grow in places where there weren't any? why is there not much attention to this method? too easy? less news worthy? less grants?

  5. Re:Let's see if I've got this right... by bobbied · · Score: 5, Insightful

    1: Install intake funnels over party caucuses, presidential debates etc etc. 2: Intake hot air > lower temperature > less global warming 3: Intake CO2 > methanol > less fossil fuel burning 4: PROFIT!

    Just take their campaign cash from them, it will be easier, more efficient and might actually help the political process....

    --
    "File to fit, pound to insert, paint to match" - Aircraft Maintenance 101
  6. fischer tropsch process by Verdatum · · Score: 2

    The process to convert CO2 into long-chain hydrocarbons has been in use since the 1930s. It's not inefficient because it requires high heat. On the contrary, it produces excess heat, and must be actively cooled with water flowing through an internal heat-exchanger. The inefficiency lies in the need to create-and supply hydrogen, which requires some process such as electrolysis of water. Oh, and it does require high pressure, which costs energy. Oh and it does take energy to raise the concentration of CO2 to sufficient levels from the atmosphere while filtering out the nitrogen and oxygen. So it mostly makes more sense to start with a product like wood-gas, coal-gas or natural-gas, and then turn that into diesel. Not as interesting as pulling it from the air, but it does give you a carbon-neutral source of portable fuel, when you use plant material. It also ends up being similar to that whole "anything into oil" idea that Scientific American used to be crazy about, but turned out not to be price-competetive, and the smell of rotting turkey guys upset the neighbors.

    1. Re:fischer tropsch process by thegarbz · · Score: 2

      The inefficiency lies in the need to create-and supply hydrogen, which requires some process such as electrolysis of water.

      The first part of your post was good, but no industrial plant produces hydrogen by electrolysis. Rather it is produced by Gassification + water-gas shift reactions (which produce pure CO2 as a byproduct) which is a modern way of doing it and the number one choice for new designs, or Steam Methane reforming which produces CO as a byproduct and is sometimes then combined with another water-gas shift reaction to again churn out hydrogen + CO2.

      Both processes are massively inefficient, burn hydrocarbons, and produce CO2, but neither is as bad as electrolysis.

  7. The blurb is plagiarised - this has to stop! by Dr.+Spork · · Score: 4, Informative

    Unless user Zothecula is actually Colin Jeffery, the author of the article, then it is disgracefully misleading to represent the content of the blurb as something that "Zothecula writes". Those words were instead lifted directly from the Jeffery's article, and no indication was made that this was done. Where I teach, anyone who shows this little regard for proper attribution gets a failing grade for plagiarism, and a second offense gets you expelled. It's depressing that a for-profit journalistic outlet could be so indifferent to plagiarism. If the article must be quoted in the blurb, then fucking quote it. You have a tag for that, and you also have the power to use quotation marks.

  8. CO2 to ETHANOL, not Methanol! by Irate+Engineer · · Score: 3, Insightful

    If some one could invent a cocktail machine, powered by wind and solar, that could take in atmospheric CO2 and spit out a daiquiri (no, wait, a Hurricane), how long would it take to get everyone behind the solution to global warming?

    Do I have to come up with all the great ideas around here? Come on, let's get some people on this, stat!

    --

    Left MS Windows for Linux Mint and never looked back!

    Vote for Bernie in 2016!

  9. Sabatier Reaction - Methane from CO2 and H2O by Irate+Engineer · · Score: 2

    The Sabatier reaction is being used to convert exhaled CO2 and hydrogen produced by electrolytic decomposition of water into methane and water on the ISS. It is a means to produce fuel on the surface of Mars (copious amounts of CO2 and water ice, and solar power to run the cycle).

    The fact that it is a net energy sink doesn't matter here - it saves having to haul a whole lot of fuel to Mars.

    --

    Left MS Windows for Linux Mint and never looked back!

    Vote for Bernie in 2016!

  10. that would be nice, but weather systems are big by raymorris · · Score: 2, Insightful

    First I want to be clear - wind is a great supplemental power source in some areas. Having said that ...

    > they are spread around national grids so the wind is always blowing on some somewhere.

    It would be nice if any of those three things were true. In fact, weather systems are generally larger than most countries. Here's the current weather map for a very large country, the United States:
    http://sirocco.accuweather.com...

    You'll notice there's very little weather in the US today. Next week, a storm system may cover most of the population of the US.

    Regarding "national electric grid" - you may recall a few years ago a blackout left the northeast without power for several days, while the nine other power regional grids including had plenty of power. The California grid had a chronic power shortage for decades, while the neighboring grid for Texas was fine. There are 10 regional power grids in the US. There's no such thing as "the national grid", and can't without save a complete redesign of the technology and replacing billions in infrastructure.

    Lastly, wind farms are NOT spread evenly around the country. They are located in specific areas where it makes sense to have them. You need steady, predictable wind (the cube power law means high winds destroy them), near population centers, but with cheap real estate. The last two requirements are of course contradictory, so a limited number of locations fit all of the criteria.

    In those places where it DOES make sense, wind power allows producers to reduce fuel usage on the natural gas generators whenever the wind happens to be right, and that's a good thing.

  11. Fuck it, let's convert CO2 to diamonds and oxygen by elrous0 · · Score: 2

    Everyone loves those.

    We could also start a massive nuclear war, which would have the benefits of greatly reducing the population and offsetting global warming with nuclear winter. It's a win-win.

    --
    SJW: Someone who has run out of real oppression, and has to fake it.
  12. here's an idea: grow FOOD by ihtoit · · Score: 2

    Crops turn CO2 into things like grain and fruit. Some crops can be grazed, such as spring onions, chives, and other herbs, some only take three months or so to mature. They all do the same thing: lock carbon into a stable and USABLE and USEFUL form.

    And it costs fuck-all except a little time and patience.

    --
    Political debates have me rolling my eyes so much I think I got optical whiplash. I should sue. - Foamy The Squirrel
    1. Re:here's an idea: grow FOOD by Chas · · Score: 3, Insightful

      That's just it though. Everyone wants a solution "RIGHT NAO!!!!"

      Instead of planting more trees than we remove (as a species) and increasing our long-term carbon sink

      As for growing crops, while yes, it does bind SOME carbon, the short growth span of modern plants actually limits the amount of actual carbon that's sequestered in the process.

      But no, we continue to clear-cut areas, and then pave/build them over.

      --


      Chas - The one, the only.
      THANK GOD!!!
  13. Re:good for for remote locations by aliquis · · Score: 2

    But the low-temperature catalyst-driven system has a MUCH BETTER application: fuel generation in places where you can't grow trees, like, say, Mars.

    Would it also work within Uranus? I was going to ask whatever a liquid or gas source was preferred but it seems like whatever one prefer or use methanol or methane Uranus would contain them both in all forms from solids to gas. Hot gases seem to be leaking from Uranus.

  14. Not for me by nospam007 · · Score: 2

    I'll wait until they sell a machine that can turn air into ethanol, thanks.

  15. CO2-sugar by Phil+Karn · · Score: 2

    Well, I've recently developed a machine to convert atmospheric CO2 into various simple organic molecules known as "sugars", which have the significant advantage over methanol of being relatively nontoxic. My design has been successfully tested for some time and it only requires sunlight, water and a few miscellaneous other inexpensive materials. And best of all, my machine is self-replicating!

  16. the point about wind: power = speed CUBED by raymorris · · Score: 2

    You're missing the main point about wind power, the fundamental law of physics that controls everything with wind power. The power of wind is the speed CUBED. Not squared, but CUBED.

      If a 10 mph wind has 1,000 units of energy, a 20 mph wind has 8,000, and 40 mph has 64,000. That's right, 10 mph wind has less than 1.5% as much power as 40 mph. At 10 mph, it might, maybe have just enough power to overcome bearing friction, but there's no power left to harvest as electricity. You -might- see it turning, but it's freewheeling, there's no power generation occurring.

    Use lighter components that spin more easily, you say? If 10 mph is 1,000 units, the cube power law means 60 mph imparts 216,000 units of force to that lightweight structure, destroying it.

    The cube power law is a law of physics, it can't be repealed by your favorite politician, and it mercilessly ensures that wind power comes only when nature chooses, in the amount that nature chooses.

    1. Re:the point about wind: power = speed CUBED by jbengt · · Score: 2

      Use lighter components that spin more easily, you say? If 10 mph is 1,000 units, the cube power law means 60 mph imparts 216,000 units of force to that lightweight structure, destroying it.

      A cube power law is not a cube force law.
      Wind has a velocity pressure that is proportional to the square of the speed. This pressure over an area gives you force. Adjusting the angle of the blades can change the force vectors and apparent area enough to withstand the wind. (In high enough winds, at the expense of shutting down power production)
      Not that it's easy to make a big blade both strong enough for normal operation and light enough to start rotating at low wind speeds. I believe, however, that once you get one going, it can keep rotating in pretty low winds and produce at least some power.

  17. clean coal is a dead end. Re:Energy in? by 140Mandak262Jamuna · · Score: 2

    Dirty coal is more expensive than natural gas. Clean coal will be even more expensive and not at all competitive with natural gas. What is killing the coal industry is simple free market economics. Not EPA, not tree hugging enviro nazis, not government waging war on coal.

    --
    sed -e 's/Chuck Norris/Rajnikant/g' joke > fact