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'Detergent' Hydroxl Molecules May Affect Methane Levels In The Atmosphere (caltech.edu)

An anonymous reader quotes Caltech's announcement about the results of a study funded by NASA and the Department of Energy: During the early 2000s, environmental scientists studying methane emissions noticed something unexpected: the global concentrations of atmospheric methane -- which had increased for decades, driven by methane emissions from fossil fuels and agriculture -- inexplicably leveled off. The methane levels remained stable for a few years, then started rising again in 2007... New modeling by researchers at Caltech and Harvard University suggests that methane emissions might not have increased dramatically in 2007 after all. Instead, the most likely explanation has less to do with methane emissions and more to do with changes in the availability of the hydroxyl radical, which breaks down methane in the atmosphere... If global levels of hydroxyl decrease, global methane concentrations will increase -- even if methane emissions remain constant, the researchers say...

Tracking decadal trends in both methane and hydroxyl, Christian Frankenberg and his colleagues noted that fluctuations in hydroxyl concentrations correlated strongly with fluctuations in methane... "Think of the atmosphere like a kitchen sink with the faucet running," Frankenberg explains. "When the water level inside the sink rises, that can mean that you've opened up the faucet more. Or it can mean that the drain is blocking up. You have to look at both."

So what's changing the level of hydroxl in the atmosphere? The researchers say they have no idea.

68 comments

  1. Hydroxl? by Hognoxious · · Score: 1

    Perhaps they're being eaten by an Aloxotyl?

    --
    Confucius say, "Find worm in apple - bad. Find half a worm - worse."
    1. Re:Hydroxl? by Anonymous Coward · · Score: 0

      "Hydroxl" is just the American version of "hydro".

    2. Re:Hydroxl? by FatdogHaiku · · Score: 1

      "Hydroxl" is just the American version of "hydro".

      I thought it was an Oreo knockoff...

      --
      You have the right to remain sentient. If you give up the right to remain sentient, you will be elected to public office
    3. Re:Hydroxl? by piojo · · Score: 2

      No, that's backwards. Oreo was a Hydrox knockoff.

      Note that Hydrox has been reproduced using taste tests, science, and our wonderful legal system. It's available here: https://www.amazon.com/Leaf-Hy...

      --
      A cat can't teach a dog to bark.
    4. Re:Hydroxl? by FatdogHaiku · · Score: 1

      Someone needs to tell Google these things...
      https://www.google.com/search?q=Oreo+knockoff
      You are right, Oreo is the late comer to the party. I have still always liked the Oreo flavor better...
      http://www.cracked.com/article_20025_5-world-famous-products-that-are-shameless-rip-offs.html
      Thanks for the heads up.
      Now, do we need to get the cookies into the stratosphere or just leave open packages laying near methane sources?

      --
      You have the right to remain sentient. If you give up the right to remain sentient, you will be elected to public office
    5. Re:Hydroxl? by Plumpaquatsch · · Score: 1

      "Hydroxl" is just the American version of "hydro".

      Actually, it's the typo version of "hydroxyl. Or rather EditorDavid's version of hydroxyl (as it is spelled throughout the actual summary text as submitted, but neither in the headline nor his mini-lede).

      --
      Of course news about a fake are Fake News.
  2. Hmm by Anonymous Coward · · Score: 1

    Armchair comment, but you know what happened shortly after 2007? The housing crisis.

    What probably really happened is that a bunch of industries curbed their production for a few years before coming back up to full power.

    1. Re:Hmm by MightyMartian · · Score: 1

      Unless you have some actual statistics to back that up, this looks like a false correlation to me.

      --
      The world's burning. Moped Jesus spotted on I50. Details at 11.
    2. Re:Hmm by Anonymous Coward · · Score: 0

      Also, that was right after Nancy Pelosi became Speaker of the House. So it was probably her doing.

    3. Re:Hmm by quonset · · Score: 3

      Would these suffice?

      Sharpest drop in 27 years

      Year over year drop of 32%

      September 2008: housing starts lowest since 1991

      Third quarter drop of 20.5% in housing starts.

      It should be self-evident if new housing construction plummets as it did in 2007-2009, all the industries who rely on housing construction would also cut back their production of products. It's the only time trickle down works.

    4. Re:Hmm by Anonymous Coward · · Score: 0

      It's a start. So which construction products involve a lot of hydroxyl? Insulation boards? Celotex?

    5. Re: Hmm by Anonymous Coward · · Score: 0

      I think he meant testing the relation between housing activity and atmospheric hydroxl...as well as supplying why such a relation might exist.

    6. Re:Hmm by MightyMartian · · Score: 1, Interesting

      I'm not asking you to prove a crash in housing starts, I'm asking to provide evidence of a link between that and methane levels.

      --
      The world's burning. Moped Jesus spotted on I50. Details at 11.
    7. Re: Hmm by Anonymous Coward · · Score: 0

      Notice to all Americans. You may think your country is shit hot. But it's not. Just because something happened in your politics means fuck all to the rest of us. Especially under Obama he was a douchebag, as is Trump and so was Busy.

    8. Re: Hmm by Anonymous Coward · · Score: 0

      Your sarcasm detector needs new batteries

  3. clouds by LesserWeevil · · Score: 5, Informative

    Some recent research points to the air-water interface in clouds as an unexpected Hydroxyl source: https://www.chemistryworld.com...

    1. Re:clouds by Gadget_Guy · · Score: 2, Insightful

      Don't you think that it is more arrogant to claim that all the climate models are wrong in their entirety simply because there was one thing that they hadn't factored? What will happen is that once some more research is done, the models will be updated and the outcomes will be affected in an insignificant way. But the graphs will continue to go in the same direction and none of this will suddenly disprove the theories. And above all, the temperatures will keep on rising.

      The habit of the deniers to find hope in even the tiniest of adjustments to the theories and models show how unscientific their viewpoint is. It is the same as how they all claimed that the world was actually cooling and pointed to how in 1998 it dropped back to same level as 1997 because it was an unusually hot year. They ignored all the decades of warming that we have had up until that point and desperately clung to the smallest of blips on the graph (which has been shown since then to be entirely insignificant). And yet they are still so sure of their beliefs (without any evidence) that they call the people who do have theories, equations, facts, and figures arrogant!

    2. Re:clouds by Anonymous Coward · · Score: 0

      Is it wrong to claim phrenology is wrong because there was one thing they hadn't factored. Hint. It's not one thing. It's one thing after another after another - an endless stream of excuses to account for the fact that the models fail to predict accurately. Funny but KE=1/2mv^2 is 100% accurate, every time, day or night, in any newtonian frame of reference.

    3. Re:clouds by Gadget_Guy · · Score: 3, Interesting

      Is it wrong to claim phrenology is wrong because there was one thing they hadn't factored. Hint. It's not one thing. It's one thing after another after another - an endless stream of excuses to account for the fact that the models fail to predict accurately. Funny but KE=1/2mv^2 is 100% accurate, every time, day or night, in any newtonian frame of reference.

      There have been errors found in the models due to previously unknown factors (like the one being discussed now). It should be noted that these errors were found by scientists; the ones the deniers keep saying are in collusion to only back the existing theories and hide the mistakes. (Oops! Yet another denialist theory that is not borne out by the evidence. Why is it that these errors are not treated with the same passion by the ignorant masses?)

      So for all the mistakes found, which ones have ever made enough difference to totally disprove the science behind the climate change theories? Answer: none at all. Some of the updates that have been incorporated into the models have shown that the older models actually underestimated the amount of warming going on. Still, it's far better just to say that there were mistakes in the models, and that therefore is must all be wrong, rather than have to admit that the models keep getting more accurate at showing that AGW is real.

      It is the same as bringing up phrenology to show that scientists can get it wrong, and therefore they must be wrong now. That is simply the same fuzzy-headed logic that brought about phrenology in the first place. There have been many more times that science in general got it right, even against opposition by the laypeople; the link between smoking and cancer, that asbestos is dangerous, that electricity doesn't leak from the wall sockets, that seat belts and helmets save lives, that plants and animals evolve to become new species. Congratulations. You have become just another one in the long list of people who think they know better than the trained scientists who spend every day analyzing the facts and figures.

      Deniers like to jump on any news they think will embarrass the scientific community and try to pretend that it is a game-changer. They love to say "I told you so" even though they didn't tell us so. No denier has ever said that the methane levels are lower in the atmosphere than predicted because of the effect of hydroxl molecules. They simply don't have the scientific knowledge to understand why they say that AGW is wrong.

      On another note, it's a good thing that the Trump administration will gut the funding and ability of NASA and the Department of Energy from being able to help find discoveries that show us where the models are wrong (or even potentially bring about techniques to reduce the greenhouse gases that are already in the atmosphere).

    4. Re:clouds by Anonymous Coward · · Score: 0

      I'm not a denier, and yet I know that it is extremely arrogant to assert that we *know* what is going on with the climate. We don't. We have a hypothesis. Most good scientists will say the same thing. Only arrogant fools assert brazenly that either (a) humans are definitely heating up the planet; or (b) humans are definitely not heating up the planet. We don't have conclusive proof of either.

      We're pretty certain the temperature is increasing (over a stupidly insignificant 200 year timescale on a 4.5 billion year old planet). We believe CO2 and moreso Methane are involved. Now we also suspect Hydroxl is mediating the Methane. That's a cool thing to learn. It's a pretty far cry from conclusive proof of anything.

      Remember that our planet had ice ages all on it's own without us.

    5. Re:clouds by Gadget_Guy · · Score: 3, Informative

      I'm not a denier, and yet I know that it is extremely arrogant to assert that we *know* what is going on with the climate. We don't. We have a hypothesis. Most good scientists will say the same thing. Only arrogant fools assert brazenly that either (a) humans are definitely heating up the planet; or (b) humans are definitely not heating up the planet. We don't have conclusive proof of either.

      The IPCC states that the evidence is unequivocal that global warming is occurring and that the odds are at least 95% that humans are the principal cause of it. It seems that the scientists of the world disagree with your assessment. Maybe they are being arrogant as you say, or maybe they just know more about this than you do.

      For example, you think that the 200 year timescale is insignificant on a scale of 4.5 billion years, and yet it is the very short time that makes it significant. The temperature rise over such a short period is way above any naturally occurring climate change. You say that we only believe that CO2 and methane are involved, and yet the effect of those gases on the transfer of various forms of energy have been known by scientists for centuries. In fact, the idea that man's increase of greenhouse gases could result in the warming of the planet was postulated long before we had the measurements to back it up. Your notion of what scientists have established is over 200 years out of date.

      Finally, another claim that you make that I suspect is wrong is that you are not a denier. It is a favorite tactic of climate change deniers to make it appear that we are less sure of what is going on by suggesting that there is still debate within the scientific community about the causes. This has gone on ever since that leaked Republican party memo that warned "should the public come to believe that the scientific issues are settled, their views about global warming will change accordingly".

    6. Re:clouds by slashrio · · Score: 1

      ...climate models are wrong in their entirety...

      Yes, but not for the reason you suggested. Climate models, all models for that matter, can not 'predict' anything that lays outside the part of the parameter space for which they have been tested and calibrated.
      That is fundamental. They haven't been tested in that region in which we aren't living yet and nobody knows what they are going to 'predict' and whether it will be correct or not.
      One can simulate electronic circuits, yes, but the climate, and then such that it accurately will predict 'the first occurrence of AGW and its amount. We've never been there, so how will we even ever know whether they are correct or not?

      --
      "Trump!!", the new Godwin.
    7. Re:clouds by Gadget_Guy · · Score: 1

      You are completely wrong. Despite what the naysayers claim, the climate models are doing just fine. What you suggest is just a rehashing of the old denier argument that the climate is too complicated for anyone to understand and therefore global warming is false. And yet, as we keep spewing greenhouse gases into the environment the temperature keeps increasing just as was postulated it would way back in the 1890s. So even with their rudimentary understanding, the scientists back in the 19th century had more of an understanding of the mechanics of the climate than you want to credit those from today.

      Yes, there is still more to learn about the climate, and so models will get more accurate. But there is nothing to suggest that anything we find anything that will alter the outcome to any significant degree such that we can just ignore the problem.

    8. Re:clouds by slashrio · · Score: 1

      A model is a simulation of an existing system in existing situations.
      During the development of a model, a lot of time is put into tweaking and adjusting all kinds of parameters in order to get realistic results.
      How do we know they are realistic? Because we can track the past, feed it into the model, and check the outcome with what we know happened.
      Now how are we going to be sure that those models will also be able to predict the future, while their parameters have been adjusted in order to 'predict' the past?
      If the expected outcomes lay outside the parts of the parameter space that have occurred in the past, then it can't accurately predict the future.
      It's quite basic, and I don't know why people don't see it.
      ("Because it's wrong", you will say, and there we'll go again...)

      --
      "Trump!!", the new Godwin.
    9. Re:clouds by Anonymous Coward · · Score: 0

      Of course this claim is also technically true *within* the sampled region of parameter space in coordinates you haven't actually sampled, but it doesn't seem to bother you. There's a reason for this; most models are based on reality and have fairly well behaved parameter and phase spaces. Some do not, and distance in parameter space does not necessarily relate to response difference.

      I spent close to a decade of my life working with neuronal models successfully predicting behavior outside of the region of parameter space used to train the model, and that was with a fairly pathological fitness landscape. I haven't worked in climate models, but I'm willing to bet that maybe they've thought this through more than an armchair slashdotter has, and considered the nature of their models and their dynamics.

      However, if you'd like to come up with a model that matches the current set of observations and predicts that the earth will turn into a giant icebox and the moon will be replaced by a big ball of green cheese, be my guest. I'm sure Rex will throw you a funding bone. You might even learn something in the process.

  4. Paging President Trump by Anonymous Coward · · Score: 0, Troll

    Why are we wasting tax dollars on these fake news "studies"? These groups are not profitable and only seek to increase regulations that harm businesses and our national economy.

    It just makes good business sense to defund these, Mr. President! #MAGA

    1. Re: Paging President Trump by Anonymous Coward · · Score: 0

      The sarcasm fails to come through...at least I hope it was sarcasm.

  5. Re: "The science is settled" by Anonymous Coward · · Score: 0

    Ignorant.fuck.

  6. Re:Global warmists. by Mikkeles · · Score: 1

    'So what's changing the level of hydroxl in the atmosphere? The researchers say they have no idea.'

    I'm sure the AGW Denialists will continue to pull arbitrary, self-serving arguments, with no evidence, out of their arses.

    --
    Great minds think alike; fools seldom differ.
  7. Re: "The science is settled" by Anonymous Coward · · Score: 0

    Says the guy who doesn't even know how climate models work.

  8. Re:Global warmists. by Anonymous Coward · · Score: 0

    Says the guy who doesn't know how climate models work.

  9. Re:Global warmists. by religionofpeas · · Score: 0

    As well you warmists will be right there with same, spewing hatred of technology and pushing for more and bigger government and socialist programs.

    You're welcome to accept AGW, but propose a different policy. Denying basic science just because you don't like the results is dishonest.

  10. Hydrox be good by turkeydance · · Score: 1

    don't care for the L

  11. Re:Global warmists. by njhunter · · Score: 1

    Until a Red Team is created to actual debate the "issue," neither side is going to yield.

  12. Re: Finally: real science by Anonymous Coward · · Score: 0

    my theory is catalytic converters

  13. Re:Global warmists. by Orgasmatron · · Score: 0

    Oh good. Climate models that are unphysical, unskilled at prediction and understood by no one are now "basic" science. I dread to ask what "advanced" science looks like.

    --
    See that "Preview" button?
  14. Re:Global warmists. by Anonymous Coward · · Score: 0

    Except that this proves, ONCE AGAIN, that this is NOT basic science. It's very complicated! And worse, these are very complicated predictive models, which are almost never right. Get one variable slightly wrong and the butterfly effect takes hold and you come up with an answer that is completely wrong. If we don't know what is, or even what CAN effect hydroxyl radical concentration in the atmosphere, how many other things do we not know?

  15. Ultimate hippy dream by Anonymous Coward · · Score: 0

    Ban soap.

    1. Re: Ultimate hippy dream by Anonymous Coward · · Score: 0

      I no Wright? I Kant believe thees lozerz think climate change is reel. It gets colder every September, shows wat those lozerz no.

  16. The authors clearly have some ideas: The tropics by laughingskeptic · · Score: 5, Informative

    Sources of volatile hydroxils include fermentation and plant respiration. The authors did not say "they have no idea", they said they do yet have a mechanistic explanation. They clearly have some ideas and those ideas are related to the differences between the tropics and the rest of the planet and they are all calling for more studies on specifically this.

    "However, the authors do not yet have a mechanistic explanation for the last decade's global changes in hydroxyl concentrations. Future studies are needed to investigate this further, Frankenberg says. The researchers also would like to see the trends they detected verified with a more detailed study of both methane sources and sinks."

  17. Re:Global warmists. by slashrio · · Score: 1

    No no, you got it all wrong, this was the last flaw!

    --
    "Trump!!", the new Godwin.
  18. Re:Finally: real science by Gadget_Guy · · Score: 1

    Finally some scientists that have the guts to say that they don't know why something is happening! Rejoice!

    What a stupid thing to say. Perhaps you would like to cite an example of any scientist who claims that they know everything. You won't be able to, because you just lied.

    Think about it, if you can. If scientists went around saying that they knew it all then they would put themselves out of business because there would be no need to do any more research. Scientific papers usually provide margins of error to show the parts where they still don't know all the factors. They also will conclude with where they still think that more research is needed, either because there questions that their research could not answer (or was out of the scope of the paper) or there were new questions raised by the results. That is hardly the thing that would need to be said if the scientists thought that they had all the answers.

  19. Re:"The science is settled" by Gadget_Guy · · Score: 2

    You are misrepresenting what was said. The science was settled that an increase in greenhouse gas emissions by humans leads to a warming of the atmosphere. Nobody ever said that all climate research had been finished and that every aspect of global warming was known.

    So yes, the science that was being discussed at the time remains settled because this new research does not disprove AGW. It is merely quibbling about the rates of change.

  20. Re:Global warmists. by gtall · · Score: 3, Insightful

    You needn't believe in anthropomorphic global warming. However, the increase in CO2 in the atmosphere is raising the PH of the oceans. You do recall the oceans, yes? Base of the food chain?

    BTW, check in with the fishermen along the East Coast of the U.S. Their fish have been moving north as their water has gotten warmer. Damn those fish, they are more intellligent than you.

  21. It's "hydroxyl radical" not hydroxl. by BitterOak · · Score: 5, Informative

    The spelling mistake in the headline may have had readers scratching their heads wondering what "hydroxl" is and trying to look it up on Wikipedia. (It isn't there.) The correct spelling is "hydroxyl" and the molecule is called the "hydroxyl radical". The Wikipedia article is actually very good and informative.

    --
    If I can be modded down for being a troll, can I be modded up for being an orc, or a balrog?
    1. Re:It's "hydroxyl radical" not hydroxl. by Anonymous Coward · · Score: 0

      Thank God for Captain Obvious!

  22. Re:"The science is settled" by Anonymous Coward · · Score: 0

    Do you ever read the stuff you write?

  23. Re:Global warmists. by Anonymous Coward · · Score: 0

    Go back to high school and read a book. They wont be "unphysical, unskilled at prediction and understood by no one" anymore.

  24. TFW when the globalists triangulate you by Anonymous Coward · · Score: 0

    We'll be back to river water in no time.

  25. Re:When will scientist show humility by KeensMustard · · Score: 1
    Don't like science?

    Feel free to live free from science - in a cave and die at 23 from some easily preventable disease.

  26. Re:When will scientist show humility by Anonymous Coward · · Score: 0

    I seriously doubt there are any climatologists (or scientists from other fields) who claim they know everything about how climate works. There are many who know a great deal about specific parts. For the most part science is an iterative affair of improving accuracy by improving precision in models.

    Take a kitchen sink faucet, turn it on for 30 seconds. Measure the water. There's a fair amount one can say about flow rate and volume from that but there's even more one can't. To make statements about turbulent flow or increasingly complex fluid dynamics you need an iterative process of improved models, improved testing apparatus. And yet your initial statements about flow rate and volume of water are still just as valid. The subsequent tests don't invalidate the initial ones, they improve upon them.

    I guess it's possible if you asserted no water flowed out of the faucet somebody might accuse you of being a racist homophic(sic) faggot what hates babies but it's hard to see why and probably wouldn't happen.

  27. Re:Global warmists. by mspohr · · Score: 1

    The earth is going to eliminate this invasive species (homo sapiens sapiens) which is attempting to destroy it. Good self-regulation.
    A few tens of million years of a carboniferous period should return things to equilibrium... then it can start over with amphibians and the rest... maybe it will work out better next time.

    --
    I don't read your sig. Why are you reading mine?
  28. Re:"The science is settled" by hey! · · Score: 3, Insightful

    Some of the science is settled, certainly. Methane is a greenhouse gas; nobody expects that to change. Atmospheric methane decays primarily through a long, well-documented chain of reactions starting with oxidation by the hydroxyl radical; the carbon in the CH4 eventually ends up in a CO2 molecule. This is nothing new, and nobody expects it to change.

    The precise dynamics by which CH4 interacts with hydroxyl radicals in the atmosphere is far from settled science, and nobody should be particularly surprised that there are things about the process we don't know. Not knowing some things about a process doesn't mean we can't know other things about that process.

    But some people obviously do believe it means that. They do not distinguish between not knowing everything and knowing nothing. Implicitly requiring scientists to know everything before you consider science credible makes everything a matter of opinion, and all opinions more or less equally valid, at least as far is evidence is concerned. And it's easy to see the attraction: if everything is a matter of opinion you can believe whatever you find comforting. Why not believe Adam and Eve rode around on dinosaurs? After all scientists don't know everything, which means science is never "settled".

    But of course settling questions with evidence is what science is all about. True, there is no science so settled it cannot be attacked; but there *is* science sufficiently settled that claims to the contrary require extraordinary evidence.

    --
    Post may contain irony: discontinue use if experiencing mood swings, nausea or elevated blood pressure.
  29. It's the end of the world as we know it... by Anonymous Coward · · Score: 0

    ... and I feel fiiiiiinnnnneeee!

  30. Classified program by Anonymous Coward · · Score: 0

    The hydroxyl radical program was classified because the political stance was carbon taxes to solve the issue. Reality vs. politics.

    Politics: many, blood sucking insects.

  31. Re:Global warmists. by Anonymous Coward · · Score: 0

    Or is it lowering the pH?

  32. Re:"The science is settled" by cbeaudry · · Score: 1

    Quibbling? I think that is the most important part. Or do you think 0.1C over 100 years is the same as 10C over 100 years?

  33. Re:"The science is settled" by slashrio · · Score: 1

    Or they mod you down for 'flamebait'... Well, if slashdot allows this I don't give a crap anymore about there 'karma' points.

    --
    "Trump!!", the new Godwin.
  34. Re:"The science is settled" by Gadget_Guy · · Score: 1

    Quibbling? I think that is the most important part. Or do you think 0.1C over 100 years is the same as 10C over 100 years?

    Whenever there is some change that has to be made to the predictions it is never as large as you suggested. I defy you to name a single time that some error or new mechanism in climate science that has ever made such a difference to the projected outcomes.

    If scientists found that the warming levels would be limited to 0.1C over 100 years then it would be major news and would cause joyous celebrations everywhere. Hell, if this kept us below the 2C target of the Paris agreement then it would be plastered all over the news sites. But this isn't that news. Nobody has even suggested in any quietly optimistic way that this is that news. For a 0.1C increase to be the case, the temperature graph would have to suddenly turn to be almost completely flat. Even if CO2 and methane levels stayed constant at current levels, the temperature rise would be more than that.

    Also, no model shows a prediction anywhere near 10C, so your example was of a range that has nothing to do with the temperature rise over the next 100 years. Your estimates are widely inaccurate, as is your belief that this is anything more than a quibble.