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It Came From Beyond ... In Buckyballs!

ooky writes: "Scientists at NASA have claimed to have found conclusive proof that gases from outside the solar system can arrive on Earth (and other planets, presumably) in neat little buckyball cages! They've found a type of helium 3 that does not exist (nor, presumably, has ever existed) in our solar system in these fullerene packages, deposited in a layer around the Earth dating from the 65 MYBP dino-killing asteroid collision. Some of our own atmosphere may have arrived this way during the Age of Bombardment! For more info on buckyballs and what they are, see here and here." The article is boundingly enthusiastic rather than the least bit skeptical, so take it with a few mols of (fullerinzed) sodium chloride. Still ...

28 of 112 comments (clear)

  1. Fullerines and Medicine by Frugal · · Score: 2

    Various people here and in the articles linked from the story have gone on about using Fullerines as a drug delivery system.

    However it has also been stated that fullerines are incredibly stable.

    So how do the drugs (or indeed anything else carried by the fullerine) get out of the bucky ball and actually delivered?

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  2. Re:Who named them buckyballs by drix · · Score: 2

    Named after Buckminster Fuller. The chemical formula is C60 and the actual name is "Buckminsterfullerene". Who said scientists don't have a sense of humor? ;)

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  3. Another possible explanation by unitron · · Score: 2
    Maybe it was a delivery of nano-soccerballs gone astray : )

    65 MYBP? Million years before petroleum?

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  4. Our friend He-3 by Graymalkin · · Score: 2

    The most likely source of the extraterrstrial He-3 isn't beyond our solar system, more to the center of it. The Sun produces lots of He-3 and He-4 which flies out of the chromosphere, we call this the solar wind. AFAIK buckyballs form naturally when you flash-boil carbon (something that would be happening in lots of places in the solar system due to the heat of formation of the early solar system). During this time of the buckyball formation He would get itself trapped in the middle of these molecules. I highly doubt few if any of our atmospheric gases arrived by asteroid. Some of it would have been collected from the acretion disk and some would have been formed in chemical reactions from high energy particles (alpha particles and high energy photons) whacking into the surface of the Earth. Probably in the next two centuries He-3 will end up causing a Helium Rush to the moon. He-3 is VERY nice for fusion reactions and is also very useful for cooling things to very low temperatures, things like superconductors.

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  5. Re:Helium 3? by quadong · · Score: 2

    Um, I can't find any plutonium that emits He-3, maybe you ought to check a table before making such claims.

    Also, there is no way that fusing He-3 gets you water and hyrogen. What it does get you (when you do He-3 + H-2) is a proton (i.e. a hyrdogen nucleus) which can be chemically burned to form water at the expense of your breathing oxygen. Not a good deal for long term space travel.

    I highly doubt that He-3 + He-3 fusions gets you oxygen. If you think that it does, please show me a source.

  6. Re:helium 3 by quadong · · Score: 2

    Read "unlikely" as "impossible" and yes. At least in any sense useful for this discussion.

  7. Re:New type of Helium 3, I think not. by quadong · · Score: 2

    I am not sure if you think that you can actually store antimatter inside buckyballs or not, so many pardons if I seem patronizing.

    If you had an atom of, say, anti-He-4 inside a molecule of C60, the positron cloud of the He would very quickly interact with the electron cloud of the carbon atoms (i.e. before you can blink 4 electrons will have annihilated with 4 positrons). Additionally, I would guess that not long after that the bare anti-He nucleus would either be forcefully ejected or annihilated by a carbon nucleus. Not a very practical storage arrangement.

  8. forget lighterfluid by ruppel · · Score: 2

    I wonder whether one can trap oxygen inside these buckyballs. If one can get enough stuffed inside and mass produce them, they'd be the perfect lighterfluid for BBQs, even better, one could mix them with normal charcoal to make "super"-charchoal - burns fast and is easy to light - no more lighterfluid aftertaste on them ribs...

    1. Re:forget lighterfluid by Gurlia · · Score: 2

      Silicon buckyballs? Hmm, 'twill be interesting to have stable silicon buckyballs... however AFAIK, Si-Si bonds tend to be quite unstable -- there are things like silanes (similar to molecules in petroleum but with silicon instead of carbon) but silanes are very unstable and spontaneously combust or decompose in some way. A buckyball configuration of silicon *might* stabilize the bonds, but still... those Si-Si bonds tend to broken in favor of Si-O bonds.

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    2. Re:forget lighterfluid by mirreke · · Score: 2

      It might be possible to trap molecules into a buckyball, but (as far as I know) no one has succeeded at that yet.

      I think it is already possible to put atoms inside but i know of failed experiments to put CO (carbon monoxide) inside. Because of the stability of the buckyball you would need very high pressures of the molecules you want to push into the balls.

      The other possibility is to catch the molecule while the buckyball is being formed, but conditions under which these things are being made are so bad (high temperatures and stuff) that normal molecules do not survive this. Atoms can of course survive, so this is probably the way in which the atom-buckyballs are made.

      And for the ideas to put drugs inside to make effective drug-deliver-agents (mentioned in another reply), those big molecules will probably not fit inside the cage. Furthermore there has no research been done on the toxicity of fullerenes. They have six-rings which are very much like benzene (C6H6), which can cause cancer and other bad diseases. I don't know if i want to eat buckyballs, especially not when I'm sick already!

      So the theoretical possibilities of buckyballs might be very big, but in practise the use is still very limited.

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    3. Re:forget lighterfluid by ozbird · · Score: 2

      You can't turn buckyballs into lighter fluid, but you can turn lighter fluid into buckyballs - some of the soot deposited from the flame (e.g. onto a spoon) will contain some buckyballs. (Candles are a better source of soot, but the principle is the same for any carbon-based fuel source.) Could you build buckyballs from other elements e.g. silicon? It's been years since I did high school chemistry, so I'm a little rusty (to put it mildly!)

    4. Re:forget lighterfluid by Dienyddio · · Score: 3

      Sure you can trap just about anything inside a buckyball, current trends are focused on trying to trap large metal atoms inside them in the hope of producing superconductors.

      Traped Oxygen wouldn't cause bucky balls to burn all that well... Buckyballs are _very_ stable (Surviving ground zero of a planet killer impact) the amount of energy you would need to pump into one of these to burn would probably be more that you would get out... That said i can't confirm that this is the case as i do not have the data to hand.

  9. So what are we doing with them? by Greyfox · · Score: 2

    It looks like there's a lot of research and stuff, but what are we really doing with these things? What's the hold-up?

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  10. Helium 3? by Fruan · · Score: 2

    I'm fairly certain that there is only *one* type of Helium 3 :o)

    And while it may not occur on earth in any amount worth thinking about, it *does* occur with in our solar system. It is believed that many asteriods contain it, and that one of the most profitable space bussinesses would be mining it, and bringing it back to earth.

    Now correct me if I'm wrong, but Helium 3 makes a better fusion fuel that the classic Hydrogen 2 & 3 mix, and his fact combined with its complete scarcity make it currently the most valuable substance known to mankind.

    Man would I love to have a tank of Helium 3.

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    1. Re:Helium 3? by Christopher+Neufeld · · Score: 2
      Now correct me if I'm wrong, but Helium 3 makes a better fusion fuel that the classic Hydrogen 2 & 3 mix, and his fact combined with its complete scarcity make it currently the most valuable substance known to mankind.
      Well, first thing to point out is that there are, currently, no helium-3 fusion reactors, so its extreme value is somewhat speculative. It is valuable, in part because of its scarcity, its primary use is in physics apparatus, notably in helium dilution refrigeration equipment. A dilution refrigerator can cool something down to millikelvins. Helium-3 is the end-product of the beta decay of a tritium atom, the primary source of it at the moment is from "expired" fusion-boosted nuclear weapons, those which don't generate their tritium from lithium fission but store it in molecular form (I believe that it's mostly used in dial-a-yield weapons).

      As to why it makes a better fusion fuel than the classic H-2 + H-3, it's because deutrium-tritium fusion releases energy and a high energy neutron. Neutrons are messy things to play with, they tend to stick onto nuclei and change their isotope numbers, making the surrounding materials radioactive (sometimes dangerously so). This observation, in fact, led to the "mad scientist" myth. It was noticed that certain radioactive materials could activate other things just by being put into contact with them. This "radioactive infection", it was reasoned, could then spread to other materials, until the entire planet was a fissioning mass of radioactivity. A single scientist with a briefcase of this material and a grudge could destroy the world!

      Ahem, OK, getting back to He-3, The fusion of He-3 and H-2 produces He-4 and a high energy proton. Fast protons don't activate their surroundings, and it's easy to extract energy from them. The result is expected to be a much cleaner-burning fusion fuel.

  11. Re:Who named them buckyballs by pe1rxq · · Score: 2
    No he didn't he designed dome shaped structures whit a similar structure as the bucky balls, the guys theorizing about the carbon molecules were inspired by his work.

    Grtz, Jeroen

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  12. Re:Who named them buckyballs by kenydl · · Score: 2

    They are named after Buckminster Fuller, a arcitect who designed spherical structures out of hexagonal and octagonal frames. These were identical to the buckyballs (Carbon 60) structure.

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  13. The purpose of science... by slothbait · · Score: 3

    ...is not to find theories that are true, but rather to find theories that are less wrong.

    Scientists understand this. It is the mass media, and the general populace who do not. Scientists are charged with creating models that are more accurate than the previous model. They understand that it too will be replaced by an even more accurate model in time.

    Science says nothing of truth. We do not "know" that our laws of physics are "right" or "true". All we do know is that they fit the data very well. That's really all that we can ever hope for: to fit the data. If a theory or model fits the data, then it is useful and we use it.

    This is a rather subtle point, that I think is lost on the masses. I think that most lack the scientific education needed to really grasp this. At this point, I could go off on a rant about American education, but I'll leave that to other Slashdot readers.

    Still, your point is well taken. People that buy into the current theory wholesale are misleading themselves. However, I maintain that scientists don't buy into them wholesale. They know that such theories are fleeting. Its the largely uneducated media who distorts the picture.

    --Lenny

  14. Interested in more? by pen · · Score: 3
    More information here, here (video clip included), here, and here.

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  15. Any Org. Chems out there? by jabber · · Score: 3

    Several years ago, I took an Organic Chemistry course. Very cool stuff..

    One of the conclusions I came away with is pretty obvious: The more geometrically balanced a molecule is, the more stable it is. Typically, more stable molecules are also harder to create. Entropy tends to dictate lower energy structures.

    Think of a water molecule. It has a positive dipole where the Oxygen sits, and a negative dipole where the hydrogen sits. The number of electrons in a bond, and the charges of the atoms involved dictate a certain geometry to the molecule.

    A buckyball is pretty much spherical, composed of cyclohexane and cyclopentane (six and five-carbon rings) like a soccer ball. This is a very stable structure. It would take tremendous energy to break it. Contrast most other hydrocarbons, like octane, which are long chains of carbon, and are easily broken.

    So using buckminsterfullerene to deliver Oxygen to charcoal is not going to work well. But, what it is being considered for is the encapsulation of radio-active isotopes for injection into the human body, for example. This way, a radioactive tracer is still useful, but keeps the bad stuff confined, and not bonding with other molecules.

    As a side note, Arthur C. Clarke proposes that bucky-tubes (buckyballs, openned and connected with nanotubes - built up from individual atoms by nanites) could be used to make extremely long, extremely strong and extremely light cables for building an elevator to orbit.

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  16. VRML Bucky Ball by philj · · Score: 3

    If you don't know what a Bucky Ball is, Here's a VRML model of one that you can look at in your browser.

  17. Helium 4 by Robert+Link · · Score: 3
    Mostly true. It turns out that most of the 4He around also dates back to the big bang. Although 4He is produced in stars, much of that is either further processed into heavier elements, or it is trapped in the stellar remnant. Consequently, the present-day abundance of 4He is not too different from its primordial value of about 1/4.


    There is also another way to produce 4He that, while insignificant on a cosmic scale, accounts for most of the 4He in the earth's crust. It turns out that an alpha-particle is nothing but a 4He nucleus, and so alpha-decay produces helium as a byproduct. On earth, helium produced this way gets trapped in pockets in the crust (much like natural gas), and so can't escape into space. Atmospheric helium, on the other hand, tends to escape into space. So, what you have is helium in the atmosphere (including most of the 3He-laden primordial helium) escaping into space, and being replaced by helium produced in radioactive decay (which doesn't produce 3He at all), and that, I believe, is why the abundance of 3He on the earth is lower than in the solar system at large.


    -rpl

  18. Here is the press release by Raindeer · · Score: 3

    The press release can be found here: http://george.arc.na sa.gov/dx/basket/pressrelease/00_20AR.html

    A preview of the article will be posted at: http://www.pnas.org

    It is research so it should be peer reviewed. But the source seems good.

  19. buckyball RAM by b_pretender · · Score: 3

    At Michigan State University, they are theorizing about doubled Bucky Balls, connected with a nanotube (Like a Tylenol capsule). A charged particle sits inside, and determines a value based on which half of the bucky-capsule it sits. According to the poster on the wall, the RAM will use no power to store information, only power to read and change data.

    I tried very hard to find a URL, for this, but the closest I can do is: http://www.cse.msu.edu
    It is the URL for the department where the poster is hanging on the wall.

    It'd be nice for some space gasses to contain these since they would be nearly impossible to mass produce. Does anyone have any other ideas for resources that might be gained from the gas?

  20. How DO they cram all that graham.... by Mostly+Harmless · · Score: 4

    Just thought I'd pass along some interesting information.... The buckyball (or buckminsterfullerene) is technically termed isocahedral C60. It's a molecule made up of 60 carbon atoms arranged to form a sphere consisting of 20 hexagons and 12 pentagons. It was discovered by Richard Smalley and Harry Kroto, and named after Buckminster Fuller for his work on the geodesic dome, which it resembles. Furthermore, the buckyball is an insolator, but can be "doped" to make what is called a dopyball. Scientists crack open the ball with lasers, add other elements (potassium, rubidium, thallium, etc...), and reseal the ball. This is VERY similar to how silicon wafers are doped. These dopyballs are superconductors, but they don't follow most of the traditional rules (i.e., temperature and energy relations, etc). Perhaps superstrong, supercheap (you can make them at home...sort of) computer components can be made from them... think of the possibilities!

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  21. New type of Helium 3, I think not. by Shimbo · · Score: 4
    The sense of the original paper seemed to have got mangled. There is no such thing as 'a different sort of Helium 3'; Helium 3 has a nucleus made of two protons and one neutron, rather than the more usual two of each. That's it. You can't have a slightly different sort.

    Most helium around comes from fusing hydrogen in stars, and ends up as Helium 4. 'Stardust' as Joni Mitchell would have it. Helium 3 on the other hand, has been lurking around since the big bang. Like, 'cosmic', man.

  22. Yahoo and Slashdot have the details wrong by pmc · · Score: 5
    See Nasa home page and NASA's version of the story for the details. Here is the abstract of the article.

    Yahoo (and the Slashdot story) has it wrong in that the helium is extraterristial NOT necessarily from outside the solar system. He3 is in fact found in the solar wind: the crust of the moon, for example, is thought to enriched in He3 from the solar wind.

    He3 does exist on earth (and in the rest of the Solar System for that matter). What is different is the ratio of He4 to He3 on Earth and in most of the rest of the solar system. What the article should say is that

    1) Helium is trapped inside Bucky-balls found in asteriod impact sites and 2) The He4 to He3 ratio is the same as the ratio in the rest of the solar system and is not the same as that on earth.

    This implies that 1) Buckyballs formed in space 2) They can trap gases in them and 3) They can survive extremely violent impact.

    Slashdot - please, please, please check the original sources for stories.