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Consumer Hydrogen Fuel Cells

axis-techno-geek writes: "Ballard Power Systems of Vancouver, BC (in Canada, eh), has stated that it will start production this friday of their consumer level Nexa(tm) hydrogen fuel cell (article here). The power module generates up to 1200 watts of unregulated DC electrical power that can keep going as long as it is supplied with hydrogen, and produces no toxic by-products (i.e. you can use it in your home). They also have plans for a 250kW unit. No price as of yet."

23 of 518 comments (clear)

  1. More information on Hydrogen Fuel Cells by Damiano · · Score: 3, Informative

    For those insterested, here's a link to a more technical article on Hydrogen Fuel Cells:

    http://www.altenergy.org/2/renewables/hydrogen_a nd _fuel_cells/hydrogen_and_fuel_cells.html

    1. Re:More information on Hydrogen Fuel Cells by ChrisCampbell47 · · Score: 2, Informative
  2. Not ready for primetime by pbryan · · Score: 5, Informative

    Hydrogen seems like a neat way to store and transfer energy. It's a pure, simple, easy to transport, easy to extract form of energy.

    However, there are number of issues that makes the short-term outlook for hydrogen difficult to justify running out and buying your own fuel cell...

    In order to manufacture hydrogen in any meaningful quantity, "toxic" (environmentalist definition) by-products are an inevitable. To wit:

    1. Electrolytic conversion from water requires electricity. The vast amount of electricity generated comes from icky dirty coal.

    2. Extraction of hydrogen from fossil fuels still generates some toxic pollutants, and is still in relatively early stages of development.

    No matter how meaningful quantities hydrogen are generated, greenheads will hate the fact that mother earth will incur vast amounts of greenhouse gases.
    Shall we address the infrastructure problems associated with hydrogen? The costs of retooling fuel distribution channels to handle hydrogen?

    Another issue conveniently ignored is the storage of hydrogen. Hydrogen, in its current form, is not particularly dense, requiring large tanks to store the equivalent energy stored in fossil fuels.

    In the future, wind and/or solar power could provide the greenhouse gas-free hydrogen generation alternative to make it a sound fuel source from an environmentalist standpoint.

    Advances in storage mediums, extraction and distribution should one day make hydrogen an exceptional fuel.

    --

    My car gets 40 rods to the hogshead, and that's the way I likes it!

    1. Re:Not ready for primetime by Jovian+Sailor · · Score: 2, Informative

      The real technical problem with hydrogen isn't the generation but the storage, transport, and distribution. You can always pick a desert, put up lots of solar cells, and pump water there for conversion. Probably it would be a lot more environmentally friendly than pumping oil.

      Hydrogen storage technology has been making some interesting strides. Sodium Borohydrate (related to Borax; i.e. soap) stores hydrogen densely and safely but releases it from water and the hydrated mineral in the presence of a catalyst. This technology is being developed by Millenium Cell (http://www.millenniumcell.com/). It has near the energy density of gasoline, non-toxic, and the end product can be recycled. The demo movie is very cool. They have also demonstrated their technology in combination with the new cells from Ballard.

      As large energy interests don't see a need (i.e. large profit) for converting to hydrogen it won't happen until circumstances change. This could be due to government intervention, a massive shortfall in oil supplies, or the gradual development of a large enough deployed consumption base to justify serving it.

    2. Re:Not ready for primetime by dragons_flight · · Score: 4, Informative

      Hydrogen is a lot less dense, though. Any idea how many tanker trucks of hydrogen it would take to be equivalent to one tanker truck of gasoline? Not a flame, an honest question...

      Okay, I got curious so, I decided to try and figure this out. I pulled some references and looked online, and the answer really surprised me.

      This reference gives the energy content of Gasoline as 115,000 BTUs/Gallon = 32 MJ/liter

      This reference says that very cold, highly compressed liquid hydrogen has a density 71 g/liter

      Adding to that my reference value of 918 kJ/mol for hydrogen combustion, I arrived at an answer of 130 MJ/liter, or 4 times that of gasoline. We should consider that it takes about 40 MJ/liter to compress and cool the hydrogen down to a liquid form (and more energy if you need to keep it cool for a long time), and also that tanks would likely be smaller in order to accomodate cooling and other apparatus. But that still leaves us with the surprising result that transporting liquid hydrogen is around 2-3 times more efficient than transporting liquid gasoline.

      The key of course is that liquid hydrogen is so much more dense than room temperature gaseous hydrogen (by a factor of nearly 1000, 71 g/L vs 0.089 g/L gaseous at 20 C). Consumer uses will probably focus on compressed hydrogen or extraction from fossil fuels, since liqifying hydrogen is hard to do, but there is no reason energy suppliers couldn't ship liquid hydrogen if it really is that much more efficient than shipping gasoline.

      Please do check my math since this was only just cobbled together.

  3. NOT dangerous.. by mindstrm · · Score: 5, Informative

    Yes, Hydrogen can burn, when it reaches appropriate fuel/air mixture.. just like many other chemicals.

    Propane or Natural gas are more dangerous than hydrogen.

    Everyone thinks hydrogen is severely dangerous because of the Hindenberg disaster... which modern science attributes NOT to the hydrogen in the blimp.. but to the canvas covering of the ship that was, unbeknownst to them at the time, coated in a reflective paint made of SOLID ROCKET FUEL (they did not know that aluminum-oxide and some other chemicals were explosive)
    The hindenberg got screwed up because a spark ignited the coating... which quickly spread across the whole ship.

    Another fact.. people report seeing huge orange flames billowing from it.. but hydrogen burns as an almost invisible blue flame.... of course, the hydrogen added to the fire... but wasn't the cause.

    1. Re:NOT dangerous.. by Anonymous Coward · · Score: 1, Informative

      "Correct me if I'm wrong but I thought it was powdered aluminum and some other chemicals.
      If the aluminum had already oxidized then it would have been less dangerous"

      It was powdered aluminum. Problem is, aluminum oxide is different from rust - rust keeps going 'til all the iron is gone. Once a film of aluminum oxide forms, though, the process stops. That's why aluminum backyard furniture doesn't dissolve away like the old steel stuff does.

    2. Re:NOT dangerous.. by Anonymous Coward · · Score: 1, Informative

      While I have no doubt that your experience with the balloon is true, please check this:

      http://www.pbs.org/wnet/secrets/flash/interview2 .h tml
      (

    3. Re:NOT dangerous.. by Hanzie · · Score: 4, Informative

      Sounds like the balloon was actually filled with an Oxy/hydrogen mixture.

      I was present at an H2 balloon burning demonstration at Idaho State University a short time ago. The one filled with pure H2 went whoosh!, and a pretty mushroom cloud went up to the ceiling.

      The prof then announced the next one was filled with a proper mixture of H2 and 02. I covered my ears, and felt the overpressure 35 feet away. My ears rang, even though my fingers were in them.

      I think that's what you experienced.

      Had the LZ-129 been filled with an oxy-hydrogen mixture, there would have been no flames, just a big hole in the lakehurst field.

      --
      ********* sig: If you don't like the law, get filthy stinking rich, and buy a better one.
  4. Re:Fuel cells are the way to go, but... by Junks+Jerzey · · Score: 5, Informative

    Unfortunately the hydrogen problem's not solved yet... Would people feel OK if they've got a highly flammable and explosive gas cannister in their home?

    You mean as oppposed to having natural gas piped into their home that would fill the house with gas if the pilot light just happened to go out while you on vacation? Tens of millions of families are living with this every day.

  5. Re:Fuel cells are the way to go, but... by Walter+Wart · · Score: 5, Informative

    It's really not bad, certainly less dangerous and less explosive than the propane tanks and natural gas we have learned to accept. Much less so than tanks full of gasoline.

    The most famous evidence of the unacceptable dangers of hydrogen was the Hindenburg explosion. A close look at the film shows some interesting results. The hydrogen went up (literally). The huge fire was caused by the diesel from the engines burning.

    Then too, you have to consider "normal accidents" as well as the flashier exceptional ones. Burning hydrocarbons produce things link carbon monoxide. Not good. Very poisonous. Very insidious. Burning hydrogen produces water vapor. Much less nasty.

    Of course, if you get your hydrogen by electrolyzing water and use electricity from burning fossil fuels you are still producing unpleasant stuff. But smokestacks are easier to track down and fit with scrubbers and other anti-pollution devices.

    --
    The man who never alters his opinion is like the stagnant water and breeds Reptiles of the Mind -- William Blake
  6. It's not magic and it's not usable tomorrow by maggard · · Score: 5, Informative
    Coupla basic points:

    • The fuel cells are fueled from "... methanol, natural gas, petroleum or renewable sources." That means this isn't some magic battery one can plug in anywhere.
    • The price has not been announced but it's predicted to be high, possibly very high. Also nobody has said anything yet about TCO - how much regular maintenance will this require, what about consumables, what's the duty cycle and what's the lifetime.
    • These are competing with established power generating systems. It has the advantage the it's not producing anything directly toxic (though I wonder about the various nasties already in it's fuel, it's not like the sulphers and all just go poof) but same as they it requires an infrastructure.
    • Local codes will have to be updated to recognize these, insurance companies will need to set premiums, fueling and venting and all of the other standards and bits of bureaucracy will need to be done. You may well be able to buy one of these reasonably soon, just not use it legitimately.
    • On the other hand (and this is a common myth where folks always bring up the Hindenburg) hydrogen isn't inherently any more dangerous then any other energy-rich fuel. Indeed it's probably slightly safer as it's lighter then air and so doesn't "pool" and become concentrated.

    --
    I don't read ACs: If a post isn't worth so much as a nom de plume to its author then I wont bother either.
  7. Re:72 Decibels at one METER?? by xcmr · · Score: 3, Informative

    This means the sound should be about 400 times less at 20 meters or about 46 dBA at 20 meters. Another way to look at it is that this should be about as loud as a car 20 meters from you when you are one meter from this unit which should be rather quiet. That is unless you drive an old VW bug. :)

  8. Re:Fuel cells are the way to go, but... by fish+waffle · · Score: 2, Informative

    You mean as oppposed to having natural gas piped into their home that would fill the house with gas if the pilot light just happened to go out while you on vacation?

    Most pilot lights on gas appliances have a thermocouple that will shut off the gas supply if the flame goes out.

    Of course the last gas stove i used didn't seem to have this feature (though it was quite old)...

  9. powerball.net by jms · · Score: 5, Informative

    Many people are commenting about the difficulty of storing and transporting hydrogen gas. Here's a company with an interesting idea:

    powerball.net

    Their idea is to use a low-pressure tank filled with water and "powerballs" -- small plastic covered spheres of sodium hydride.

    When the system wants to create more hydrogen gas, it uses a mechanical cutter to cut one of the powerballs in half. The sodium hydride instantly reacts with the water in the tank, producing sodium hydroxide and hydrogen (and a fair amount of heat):

    NaH + H2O --> NaOH + H2 gas

    When all of the sodium hydride spheres are used up, the result is a tank full of sodium hydroxide. The tank is then returned to their factory, where the sodium hydroxide is converted back into sodium hydride, so there's no waste stream from the process.

    The cool thing about this system is that the hydrogen is stored and transported in solid form -- as metal hydride spheres, so you don't have the danger of high-pressure hydrogen to work with. The hydrogen is generated as needed at low pressure.

    The site hasn't been updated in a while, so I have no idea if they've successfully brought a product to market, but I thought that this was a really interesting idea, and it would probably work fairly well with these sorts of fuel cells.

  10. GE Homegen by jmichaelg · · Score: 5, Informative
    General Electric has been advertising a 7KW home fuel cell for over a year now at their homegen website The unit is ostensibly being built for GE by Plug Power but apparently they've run into some difficulties. The product was supposed to be on market by this past summer - in fact New Jersey Power has been touting the fuel cell for delivery.

    Unfortunately, the latest word is next summer at the earliest. Plug Power reported a $30 mil loss as of their past fiscal year and their press releases talk more about financial transactions rather than actual sales or product delivery so things aren't looking all that great for GE or Plug Power's offering right now.

    What's worse for Plug Power is their initial offering doesn't take advantage of the fact that the fuel cell produces hot water as a waste product. Were they to design the unit to feed the hot water to a water heater, the fuel cell efficiency would be greater than 70%. Supposedly, the water capture feature won't appear until the second generation offering which makes you wonder who would buy the first one - especially at $15k a pop.

    By coincidence, Chevron Oil in San Ramon, CA fired up their 200 KW unit today for the first time. That puppy set them back $850,000 or around $4,250 per KW. More info is available at
    SF Chronicle.

    Notice the odd ratios - The Chevron unit that's real and online cost about twice what GE's not-available unit is supposed to come in at. Maybe there's a hint there as to why Plug Power can't deliver.

  11. Well.. by mindstrm · · Score: 3, Informative

    The hour long episode on Discovery seemed rather concise and definite. They tested a sample of the hindenberg covering.. they checked the formula used... etc.

    It's not an urban myth.

    As for diesel.. the diesel fuel is at the *bottom* of the ship.. nowehre near where the huge, orange flames were shooting from.

    I'm not saying Hydrogen can't explode.. it certainly does. But the Hindenberg didn't explode. It burned.

  12. Re:More, Not ready for primetime by Boulder+Geek · · Score: 5, Informative
    Not true! Solar panels are currently nasty silicon things made with all sorts of toxins. That would be OK if they would last forever, but they are generally on the five year plan.

    Modern solar panels have 20 year warrantees.

    Mirror/boiler schemes show more promise, but scraping togeter megawats from 22 watts per square meter is not easy and pilots worry they will be blinded flying over them!

    The solar energy density at the Earth's surface is approximately 1000W/m^2, not 22W/m^2. The latter figure is for a particularly inefficient solar panel, say one from 20+ years ago.

    Flying over a mirror/boiler facility shouldn't be much of an issue, because the mirrors are pointed at the boiler, not straight up.

    You did not mention biomass conversion as an indirect solar, but corn was made for eating!

    Thousands of tons of organic matter suitable for generating methanol or methane are produced and collected in our cities every day in the form of sewage and food waste. All we have to do is collect it.

    --
    A well-crafted lie appears unquestionable - Dama Mahaleo
  13. Re:distributed power by BlackGriffen · · Score: 2, Informative

    Even better, you can use solar cells to split water and/or natural gas in to some H2.

  14. Re:What are the effects on Global Warming? by CaptainCarrot · · Score: 4, Informative
    That will seriously reduce the amount of Oxygen in the air, turning it into water, and plants can't breath water.

    Plants can't breathe oxygen either. They breathe carbon dioxide and produce oxygen. And some arboreal plants do indeed rely on the water in the air to survive.

    I have no numbers to hand, but a fuel cell is much more efficient than any internal combustion engine currently available, and mole for mole uses half as much oxygen as hydrogen. I'd say it won't make much of an impact, expecially compared to IC engines, which also use plenty of oxygen but spew toxic fumes.

    You don't have to produce your hydrogen as you're describing, and carbon dioxide is not necessarily going to be the byproduct even if you use hydrocarbons. You can also get your hydrogen via electrolysis of water, which produces oxygen as a byproduct. This process uses electricity, but it seems to me a well-designed system would use tidal flows to produce the power. You need to add an electrolyte to water for electrolysis to work, so sea water would be ideal, which means you might as well locate your hydrogen plants along the coast. A further byproduct would be the minerals originally dissolved in the water, which could then be put to good use. Such plants could be small and discreet, and need not place any strain to speak of on the local environment.

    Come to think of it, such a system could be a boon for poor countries with a coastline and good tides but few other resources. They would become energy and mineral exporters.

    I'd love it if someone could give this idea a good critique.

    --
    And the brethren went away edified.
  15. PlugPower/Ge 7kw Microgen by mestreBimba · · Score: 3, Informative

    GE will be marketing a fuel cell designed by PowerPlug next year. It uses natural gas or propane, and doubles as a space heater and water heater. These units are not any more dangerous to own or operate than a natural gas forced air heater.

    Some Specs Are:
    System Performance

    Natural Gas 40% @ 2 kW output
    Natural Gas 29% @ 7 kW output
    LP Gas 38% @ 2 kW output
    LP Gas 27% @ 7 kW output

    Cogen Efficiency >75%

    Fuel Cell Operating Temperature 160F
    Exhaust Temperature (simple cycle) 220F
    Power Quality IEEE 519 Compliant

    Emissions
    NOx 1 ppm
    SOx 1 ppm

    More info can be found at
    www.plugpower.com

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    Fly Fish? Participate in our forum
  16. Re: Hemp. by Christopher+Thomas · · Score: 3, Informative

    This would be a good time to jump in and say "What about hemp?"

    Last summer a group of young scientists drove an unmodified, diesel engine Mercedes Benz across country to promote hemp for fuel. They ran the car entirely on fuel created from hemp seeds. Although mileage was slightly impaired, the amount of pollution generated was greatly reduced because, unlike gasoline refining, which adds many noxious and dangerous chemicals, hemp fuels rely on natural methods.


    This fuel "created from hemp seeds" was almost certainly just an alcohol. You can make alcohol by fermenting just about anything organic.

    The problem is that both the growing of the plants and the fermenting are not terribly energy-efficient. Direct synthesis by burning CO2 in a hydrogen atmosphere would almost certainly be a better option.

    The other thing that they might have produced from hemp is something vaguely resembling diesel fuel. This too can be produced fairly readily from many types of plant (think "low-grade vegetable oil").

    The problem is that burning long-chain hydrocarbons cleanly is very difficult to do. This would probably not be a viable fuel source even if you weren't stuck with plants' energy efficiency.

    The "...which adds many noxious and dangerous chemicals" line is mainly trolling on the part of whatever source gave you this information. The most dangerous things coming out of a gasoline engine are sulphur and nitrogen oxides. The sulphur came straight from the ground with the fuel, and the nitrogen oxides are a natural byproduct of burning any hydrocarbon under engine conditions. Hemp deisel would contain as much sulphur as the hemp did (all plant and animal matter contains some of it; at least one of the amino acids uses it). Hemp alcohol wouldn't... but I don't see any reason to use hemp alcohol over direct-synthesis alcohol.

    In summary, I don't see any real advantage to using hemp as a fuel.

  17. Turn water into H2 with solar heat by alexgp · · Score: 1, Informative
    Australia's CSIRO is doing research into turning steam and natural gas into CO2 and H2 by applying concentrated sunlight (achieving temperatures of around 800 degrees C).

    Effectively, you are electrolysing water while adding value to the natural gas. You can also capture the waste CO2 more easily.

    Go here for more

    Alex