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Direct Observation Of Chemical Reactions

Mouth of Sauron writes "I saw on C|net that researchers with IBM have devised a way to directly observe chemical reactions as they occur in a liquid with an electron microscope. Frances Ross of IBM was awarded the Burton Medal by the Microscopy Society of America. Researchers say this could lead to a better understanding of chemical reactions and could have impact far beyond the computer industry."

9 of 29 comments (clear)

  1. They could already do this in dry environs by Elwood+P+Dowd · · Score: 4, Informative

    The new advantage is that they can make 30 fps observation of chemical reactions in a liquid. Previously, they could get 30 fps in gas or solids, and they could get 3 fps in liquid, but now they can get both at high speed.

    Really interesting. I want to hear what they're learning.

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    1. Re:They could already do this in dry environs by Henry+V+.009 · · Score: 5, Funny

      High speed? 30 fps is the bare minimum for me. I won't even watch a chemical reaction until it's at least 60 fps. And do you know if they put the 3DMax scores into the paper?

  2. how about a nuclear reaction? by axxackall · · Score: 3, Funny

    And finally I wanna see those quarks - otherwise it's hard to believe they exist.

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  3. quantum interfearence by JDizzy · · Score: 4, Interesting

    Would the use of electron bombardment cause the classical quantum conundrum where direct observation of particles affects their quantum state, and I suppose their non-quantum existance? I'm actually suprised this hasn't happened already. Electron microscopes normally have to look at very still stuff, and a chemical recation isn't still by any measure. But photographing moving stuff would seem to be the next logical step (still pictures, motion pictures). I'd like to see some microscopic movies of fire (combustion) in action! ;)

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  4. Re:Priorities by Smidge204 · · Score: 4, Funny

    Well, if you bothered to RTFA, it talks specifically about how the process was used to study interactions with copper atoms, and how they are going to apply it to improving chip manufacturing.

    So yeah, I guess they did consider that this is going to impact the computer industry. :P
    =Smidge=

  5. beyond? by Transcendent · · Score: 4, Interesting

    Researchers say this could lead to a better understanding of chemical reactions and could have impact far beyond the computer industry."

    Since when did all science work in the favor of just the computer industry? You make it sound like we apply all new knowledge and then worry about the rest afterward. I would think that the computer industry would be one of the last to benefit. FIRST you would go through cleaner chemical processing, better-made biodegradable materials, more advanced propulsion systems (more efficient, really), better food processing, stronger materials.... and then maybe someone will apply this to semiconductors.

    The most obvious applications do not envolve computers... I hope everyone else here has a more open mind.

  6. Profound discoveries? by Anonymous Coward · · Score: 3, Funny

    ...could lead to a better understanding of chemical reactions and could have impact far beyond the computer industry.

    We already know mixing alcohol and driving can cause huge impacts!

  7. silicon nitride? by js7a · · Score: 3, Interesting
    ...transmission microscopes--which shoot electrons through micron-thin samples of materials and then form an image from data about the resulting paths of the electrons--depend on placing the sample in a strong vacuum. That's fine for observing reactions between solids and gases, but it doesn't work for reactions with or inside liquids.

    "In ordinary circumstances, the liquid would just boil away," Ross said.

    Biological samples viewed under a transmission electron microscope have to be initially dehydrated, which can change their shape.

    To get around that problem, IBM devised a cell chamber that captures a layer of liquid and the elements to be studied between two silicon nitride membranes.

    "You can think of the cell as an extremely sophisticated (microscope) slide," she said.

    How come a silicon nitride membrane strong enough to hold a liquid away from a vacuum doesn't diffract or deflect electrons? Is there something special about silicon nitride that makes it transparent to electrons?

    Neat trick, but I'm not sure if I'm willing to believe it without an explanation. Si3N4 has a dielectric constant of 7.5; what gives?

    1. Re:silicon nitride? by tsa · · Score: 3, Informative

      The use of SixNy (almost never really Si3N4 because of its huge internal stress) for membranes for transmission electron spectroscopy is quite common. You can make very thin membranes (in the order of 50-100 nm). They are very strong and thin enough for the electrons to tunnel through. With two of these layers placed very near each other you can keep the liquid in between them and still use them for TEM. And because they are non-crystalline they don't show up in the pictures that much.

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