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Solar Cells Get Boost

An anonymous reader writes "Researchers from Los Alamos National Laboratory have tapped the efficiencies of nanotechnology to double solar cells' potential energy production. The key to the method is the use of lead selenium nanocrystals which can produce 2 electrons where 1 was produced before. Other optical applications can also benefit."

41 of 108 comments (clear)

  1. Will this work with other materials? by sacremon · · Score: 3, Insightful

    The article seems to imply that the technique would be applicable to existing materials, but also seems to imply that it has only been show to work for lead-selenium nanocrystals. So will the technique of using nanocrystals work with other materials? If not, will incorporating the lead-selenium nanocrystals in a matrix of conventional material, nanocrystal-sized or otherwise, generate two electrons/photon? And finally, does the cost of making the nanocrystals make the whole thing not cost effective, other perhaps in something like spacecraft, where every once saved is of tremendous worth?

    --
    If you can't beat them, embrace and extend them.
    1. Re:Will this work with other materials? by Intrigued · · Score: 3, Interesting
      I simply don't know enough about the physics, but... can this be applied with the other developments like multi-band gap improvements? (New Material for More Efficient Solar Cells) I know that these use different materials but can the same principles be applied?

      If so, it should multiply efficiency. I would love to see multi-band gap using 2-3 times wider percentage of the light to move multiple electrons. You should be able to pull 80%+ efficiency if that is possible.

      Someone contribute some understanding on the physics please.

    2. Re:Will this work with other materials? by Goyuix · · Score: 2, Funny

      Not to mention how far I could overclock my calculator on one of those babies...

    3. Re:Will this work with other materials? by Christopher+Thomas · · Score: 3, Informative

      I simply don't know enough about the physics, but... can this be applied with the other developments like multi-band gap improvements?

      I'm on shaky ground here, but I think the answer is likely "no". The idea behind this technique is that you can use surplus energy from a photon absorption event to release a second electron, while the point of split bandgap cells is that you can absorb light with less surplus energy (more deposited in a useful manner into the first electron).

      Ask a semiconductor physicist to get the correct answer :).

  2. If I had a nickel... by heldlikesound · · Score: 3, Insightful

    for every time I heard about cheaper, more efficient solar cell, I could buy a solar powered calculator. Which is just about all I've seen solar power be good for at the consumer level.

    --


    Cloud City Digital: DVD Production at its cheapest/finest
    1. Re:If I had a nickel... by daeley · · Score: 4, Insightful

      Yeah I guess the outdoor lighting, pool heating, and housing industries (just to name a few), are pretty miniscule consumer applications. :P

      --
      I watched C-beams glitter in the dark near the Tannhauser gate.
    2. Re:If I had a nickel... by LWATCDR · · Score: 2, Insightful

      Well the consumer level is not the end all and be all.
      There is little market for gas turbines at the comsumer level or hydroelectric systems but they are still important.

      Solar panels are finding more wide spread uses all the time. They are very popular with Amature radion operators. Heck I can even buy them at my local Harbor Freight store.

      --
      See my blog http://ilovecookes.blogspot.com/ for light hearted technical information.
    3. Re:If I had a nickel... by taped2thedesk · · Score: 2, Interesting

      don't forget air conditioning... solar cells are perfect for powering air conditioners because they're generally used the most in sunny weather...

    4. Re:If I had a nickel... by Tree131 · · Score: 2, Interesting

      because night is the time we wont get energy

      That's what the batteries / capacitors are for... :)
      And if you live in St. Petersburg, Russia, it's far enough north for them to have white nights.

    5. Re:If I had a nickel... by zero_offset · · Score: 2, Interesting

      While that makes sense (I'm assuming the cells would augment mains power given the huge power consumption of AC systems), I can't say I've actually heard of anything like this -- and I've been reading up on high-quality, high-efficiency HVAC systems since we're wrapping up the design of a fairly large new house.

      Got any names or links?

      --

      Slashdot quality declines as the number of hot grits posts decreases. - Provolt's Law, Apr-09-2005

    6. Re:If I had a nickel... by the+real+darkskye · · Score: 2, Informative

      Here's a few in the uk, i'm sure if this permantly overcase and rainy island has them the rest of the world does!

      It seems the parent site doesn't like linking to the actual search results only the heading, Que Sera Sera

      --
      Music is everybody's possession.
      It's only publishers who think that people own it.
      Fuck Beta
      ~John Lenno
    7. Re:If I had a nickel... by WindBourne · · Score: 2, Interesting

      Here in colorado, a number of mountain homes(outside of vacation spots) have Solar. As these get higher efficiencies AND there costs drop, we will see more and more places swtiching to them.

      --
      I prefer the "u" in honour as it seems to be missing these days.
  3. Electrons are not "produced" by solar cells by I_Love_Pocky! · · Score: 4, Interesting

    Solar cells harness engergy by absorbing photons, which cause electrons in an atom (which are already there) to move to a higher energy state. This technique moves two electrons per photon, rather than one. The point I am making is simply that electrons are being moved, and not created. That would have amazingly different implications, as that would be creating matter from the energy in a single photon, which would only work with very high energy photons.

    1. Re:Electrons are not "produced" by solar cells by SandSpider · · Score: 4, Informative

      I have to say, this is a little picky. First of all, the article description states that the new substance "...can produce 2 electrons where 1 was produced before", so it does not imply a change in the fundamental mechanism so much as the yield. Anyone who knew how solar cells worked before reading this description would be able to make the leap that no laws of physics were being violated to produce this electron.

      Second, the description does not say that the electrons are being created at all. The dictionary definition of the word produce indicates, in the first entry, that produce means "To bring forth; yield", which is good enough, but skim the third entry and its example, "To bring forth; exhibit: reached into a pocket and produced a packet of matches". I think the first is more accurate, but the second indicates just how far the definition of produce does not imply creation.

      =Brian

      --
      There is nothing so good that someone, somewhere, will not hate it.
  4. The holy grail of solar power by n1ywb · · Score: 3, Interesting

    This is it folks, this is what we've been waiting for. As it is, solar panels are a pretty marginal energy source for most applications. We've all seen the specially built vehicles that are basicly a big solar panel on wheels (some of us (like me) have even built one). We've all seen the houses with the roof covered in solar panels and they still have to buy all whacky expensive 12v high efficiency appliances and forget about an electric drier. With solar cells like these, solar power just lept from impractical to practical. Make way for the days of solar powered PDAs and cell phones, cars, houses, buses, airplanes, you name it. This is the breakthrough that will lead the way. Unless it flops, of course.

    --
    -73, de n1ywb
    www.n1ywb.com
  5. Earth is bad for the environment by Anonymous Coward · · Score: 5, Funny

    Earth is bad for the environment. It contains lethal amounts of lead, selenium. Dangerous amounts of dihydrogen oxide (which kills many thousands a year) have accumulated on its surface.

  6. Re:bad for the environment by n1ywb · · Score: 3, Insightful

    I think you're trying to make a funny, but in case you aren't... They are nano crystals. That probably means that while they're made from lead, there still isn't much lead in each cell. Also, solar cells can easily last for 100 years, it's not like they're disposable. Not to mention the fossil fuels they displace.

    --
    -73, de n1ywb
    www.n1ywb.com
  7. Re:number of responses in /. by Palverone · · Score: 2, Insightful

    See the problem is this article made no mention of Linux or how evil Microsoft is. This is /. after all. If you want to get more posts, make a comment about how Microsoft's new OS is going to natively support solar sell power management and that Linux needs to create another Sourceforge project to provide it for free.

    I think the majority of the people not lurking and posting are people who actually feel passionate about free energy. I am just waiting for a Linux geek touting that he is running a Beowolf Cluster on 100% solar power.

  8. Price? by phlack · · Score: 4, Insightful
    Unfortunately, the article didn't mention price, at least not directly. It stated "would become practical in 2-3 years", which I can only assume means they'd be the same price as today's cells.

    It is indeed a shame that more interest in this technology doesn't exist. The lack of responses to this article is pretty disappointing, especially since I would think /.ers would be one of the main supporters. Doubling the output of cells is a definite improvement.

    I remember reading somewhere (IIRC one of the Real Goods Source Books) that had the phrase similar to "Solar Panels will never become widely accepted until they are available from your local Home Depot." This definitely rings true. Aside from the solar powered walkway lights (total garbage), they have very little to offer there. Solar Cells need to be cheaper and more powerful if people are going to use them.

    It's good to see that progress is being made, though, as this article describes. Perhaps one day it will indeed become practical to use solar panels. Until then, we're stuck with calculators.

  9. Not quite there yet by Retric · · Score: 5, Insightful

    From what I can tell there not manufacturing solar cells using "lead selenium nanocrystals" but rather they found a method of detecting "impact ionization" via the delay between the photon impact and electron emissions. They then tested several substances and discovered that lead selenium nanocrystals produced impact ionization on close to 100% of photon impacts.

    So if you really want to know what's going on you need to discover how efferent lead selenium solar cell's are and what it takes to mass produce lead selenium nanocrystals in a cheep long lasting solar cell.

    So it's a long way from producing 60+% efficient solar cells but it's still cool.

    1. Re:Not quite there yet by Christopher+Thomas · · Score: 3, Informative

      So if you really want to know what's going on you need to discover how efferent lead selenium solar cell's are and what it takes to mass produce lead selenium nanocrystals in a cheep long lasting solar cell.

      Nanocrystal films would typically be grown by chemical vapour deposition (chemical constituents react as a gas at low pressure, seed crystals grow in-flight, and grow further after being deposited).

      The problem is that it's very hard to produce crystals that small (they tend to keep growing after being deposited, because the source materials are still present - this is how you normally do CVD, actually). You also have difficulty producing a narrow range of sizes, because that requires that the growing environment of each crystal be identical.

      Still an interesting discovery, though. The fabrication problems will eventually be solved.

      What's especially interesting is looking at what happens when you fabricate oher types of semiconductor microstructure or nanostructure by more conventional techniques. As the size of a feature shrinks, you can no longer pretend it's near-infinite in extent when figuring out what the energy levels are within the crystal. This has already been used to alter the properties of silicon (fabricating LEDs in silicon, which normally emits very poorly due to having an indirect bandgap). Quantum wells, wires, and dots are an extreme case of this (dimensions comparable to a few electron wavelengths). When lithographic feature sizes start approaching this range, lots of new devices will be possible in mass-market chips that are only possible now if you have an e-beam lithography setup handy.

  10. Re:bad for the environment by cmpalmer · · Score: 2, Insightful

    All true, but it in no way invalidates the grandparent post -- sillier things than that have drawn the ire of environmentalists.

    On a more reasonable note, remember that the manufacturing processes for many "green" technologies are themselves polluting and producing dangerous and toxic byproducts.

    --
    -- stream of did I lock the front door consciousness
  11. Storage Storage Storage by tino_sup · · Score: 5, Interesting

    Renewable energy has made phenomenal leaps, but the storage restriction is the crux. Efficiency is great, and is a move in the right direction. What remanins is the development of efficient and economical storage devices. Imagine your car operating for a week on a one hour solar charge stored in a device the size of 4 D sized batteries.

    --
    I am me...I think
    1. Re:Storage Storage Storage by Christopher+Thomas · · Score: 2, Informative

      I think hydrogen may have potential in that application. It's a reasonably efficient way to move energy around. You have to use some kind of energy to produce the hydrogen, and it would be far better to do it with solar than with fossil fuels.

      Solar cells are actually very good for this purpose, as electricity is produced directly, as opposed to having to be converted from another energy form (like heat, in the case of a coal or oil fired power plant).

      You can produce hydrogen from fossil fuels fairly efficiently by "reforming", though. What this essentially does is strip hydrogen off of hydrogen-rich hydrocarbons, giving you carbon-rich hydrocarbons and hydrogen gas. The hydrocarbons can still be burned in a suitably tuned power plant, and the hydrogen gas can be used in fuel cells.

      If you're using a fuel cell for storage, as opposed to generation, though, you'd just keep the water produced when you feed hydrogen and oxygen in it, and break that down to get your source gases back out (though you'd probably dump the oxygen instead of storing it, since you can pull more out of the atmosphere easily).

      The real problem with hydrogen as a storage medium is difficulty storing it at any reasonable density (cheaply - we can't afford palladium storage cells, and they're horribly heavy anyways).

      Or it might be a way to bridge the energy gap in ethanol (either for combustion or in fuel cells), where currently you have to burn an amount of fossil fuels to produce the ethanol, some say more than you get out.

      You'll always use more feedstock than you get ethanol out, so I assume you're talking about power spent converting the feedstock to ethanol.

      I actually think that alcohol makes a better storage medium than hydrogen, because it's easy to store, can be burned in internal combustion engines, and can be reformed (see above) and used fairly efficiently as a fuel for fuel cells. The only catch is that it's annoying to synthesize. Methane can be synthesized relatively efficiently, and you can partially burn it to produce methanol, but that's still not very efficient.

      Probably efficient enough for many applications, though (you don't care much if your notebook takes twice as much power to charge as you get stored in the battery, even if you do care for things like your car, and even more so for a city's "week of bad weather" power reserve).

      At the moment I'm more worried about being in thrall to a rather unstable part of the world for oil than I am about the atmosphere's CO2 load, but it is also pretty scary.

      I'm somewhat puzzled by this situation, as it appears to be one of choice as opposed to necessity. Here in Canada, we could get all the oil we'd need for quite some time from Alberta, and there are enough offshore natural gas reserves to satisfy that demand as well. Last I heard, the gas reserves off the US's coasts were *huge*. We'd see a price increase switching to local supplies (maybe even a hefty one), but nothing that would bring western society crashing down.

      After those ran out, a century or two down the road, Canada has enough uranium to last us indefinitely, and the political will to use it for power. The US would need a creative political gimmick to be able to use it now, but a century is more than enough time for public opinion to change. Even without a breakthrough in power production, I don't see any serious problems.

    2. Re:Storage Storage Storage by ChrisMaple · · Score: 2, Informative

      Imagination is the only domain in which your comment can ever be real. Even at 100% efficiency, 1 hour of solar energy will run a small car at highway speeds for less than one hour. Even the most powerful chemical reactions cannot store enough energy in the size of 4 D cell batteries to run a car for a week.

      --
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    3. Re:Storage Storage Storage by Moderation+abuser · · Score: 2, Interesting

      Hydrogen would be great if it wasn't so inefficient to produce.

      The battery problem has been solved for vehicles. It was solved when NiMH batteries became available. The issue is the cost of manufacture and actually getting someone to build the things.

      Seriously. These guys have viable vehicles:

      http://www.solectria.com/products/accomp.html

      249 miles on a single charge for their *in production* Solectria Force car, my petrol car does about 240 miles before I have to fill up. They have a prototype called the Solectria Sunrise which can do 373 miles on a single charge. That's almost a week's worth of commuting for me.

      It's all down to demand and the cost of production, which will fall with mass production.

      --
      Government of the people, by corporate executives, for corporate profits.
  12. Re:No...it's not the "holy grail" by n1ywb · · Score: 2, Insightful

    You do realize that you don't see the point? This isn't an article about energy storage, it's an article about energy generation. Fuel cells are great, how do they relate to the article?

    --
    -73, de n1ywb
    www.n1ywb.com
  13. Here. Have twenty nickels, buy a clue. by Spamalamadingdong · · Score: 2, Interesting

    There's at least one user in California who got on a time-of-day net-metering rate program and installed a bunch of solar panels on his garage roof. His panels are cranking out watts during all of the high-rate hours (afternoon), and he gets credited at the retail rate. At night he charges his electric truck off the grid, and pays for those KWH at the off-peak rate. It's win/win; his panels pay for themselves, and the utility needs less peaking capacity.

  14. No it's not. by Spamalamadingdong · · Score: 4, Interesting
    The real issue with solar energy isn't watts/m^2 of panel, but watts/$. We have more than enough square footage to power our houses and businesses even at current efficiencies, but the capacity is still so expensive that it is very marginal. If Pb/Se nanodots can be made more cheaply than the same wattage of silicon, we'll be ahead; otherwise we won't be.

    If we get really lucky, this technology will work well at high light flux and high temperatures (~100 C). This would allow use of concentrating collectors and use of the waste heat for space heat and domestic hot water, multiplying the benefit of the collector and making the whole affair much more economical. Imagine a house that powers its own appliances, stores enough hot water for several days of hot showers and its own heating load, and on sunny days has plenty of juice left over to feed to electric cars. This house would be almost completely independent of fossil fuels and offset fuel use elsewhere, and I'll bet that we could build it now if cost was no object - if we can get 50% or even 40% efficient solar cells at $2/watt working at 100 C, we'll be there.

    1. Re:No it's not. by calidoscope · · Score: 2, Insightful
      The real issue with solar energy isn't watts/m^2 of panel, but watts/$.

      Watts/m^2 is still important...

      The economics of solar power get really interesting when the price gets down to $1/w. For a 10% efficiency, the installed cost of the array needs to come in at $100/m^2 (~$10/ft^2) - at 50% efficiency we're talking $500/m^2 (~$50/ft^2). I would hazard a guess that the support structure and glazing would come in around $10/ft^2 (or more). The last point makes low efficiency cells kind of a non-starter, unless made to replace roofing materials.

      --
      A Shadeless room is a brighter room.
  15. Storage can be TOO good by Spamalamadingdong · · Score: 3, Interesting
    Imagine your car operating for a week on a one hour solar charge stored in a device the size of 4 D sized batteries.
    Let's see, if you drive 250 miles a week and get 25 MPG, that's 10 gallons of gasoline or about 60 pounds. Gasoline has about 9 times the energy of combustion as TNT (because TNT carries its own oxygen). So: Imagine the energy of several hundred pounds of high explosive in a device the size of 4 D-size batteries. Not so appealing any more, is it?
  16. Real implications of cheap solar power by justanyone · · Score: 2, Interesting
    Let's look at what the real implications of cheap solar power are:
    • Vast reduction in cost of electrical power
    • reduction in demand for coal products to approx. 5% of current usage due to solar plants supplying grid (excess produced by nuclear);
    • immense pressure to develop better batteries for use by cars;
    • demand for tech to turn electrical power plus (whatever) ingredients into natural gas (cars powered by methane emit only CO2, not other nasty stuff, plus infrastructure there - existing cars can run on natural gas for $300 conversion kit);
    • vast diminishment of political and economic wealth of many arab and persian) nations plus Russia, Venezuela, and some african countries;
    • vast reduction in demand for hydro power in Northwest, hydro dams that are not useful for irrigation & flood control are torn down;
    • home power kits still possible, but since 50% of cost of off-grid solar-cell electrical is electronics (not the cells), this isn't a major factor for most people;
    Feel free to fill in your implications as replies, or refute these...
    -- Kevin J. Rice
    1. Re:Real implications of cheap solar power by jpop32 · · Score: 2, Insightful

      Let's look at what the real implications of cheap solar power are:

      But, the interesting fact is that there are industries, countries and individuals that stand to lose billions of dollars in income if/when such advances in solar energy take place. And billions of dollars they make now buy _a_lot_ of influence. So, don't expect the changes to happen overnight, or any time soon...

    2. Re:Real implications of cheap solar power by calidoscope · · Score: 2, Interesting
      Let's look at what the real implications of cheap solar power are:

      One very valuable use for cheap electricity is desalinating seawater. Normally arid areas bordering on an ocean or large sea (think places like Baja California, North Africa, even Saudi Arabia) will have access to significant amounts of very fresh water - probably won't be cheap enough for rice farming, but certainly cheap enough for moderately high-value crops.

      Reverse osmosis is not as energy intensive as you might think - current technology needs 800 psi to desalinate sea water (about a 2,000 foot pressure head) - and 2,000' is about what the Colorado River aqueduct traverses to get to coastal souther California.

      --
      A Shadeless room is a brighter room.
  17. For those curious on how a solar cell works.. by jigyasubalak · · Score: 2, Informative
    --
    The best planning can be done after the project completes.
  18. Re:Net metering.. by fluffy666 · · Score: 2, Insightful

    Although it sounds fine, it really is a problem for the power companies; retail rates not only include generation costs, but the huge effort that goes on in transmission and load balancing. To be realistic, this sort of metering should be generation costs only.

  19. Store it in a spring. by Moderation+abuser · · Score: 2, Interesting

    One which never wears out. Compress air up to 300 or more atmospheres. It's much much cheaper to buy a pressure vessel than it is to buy batteries which hold an equivalent amount of energy and far far more efficient than electrolysis. Most useful for stationary purposes, generators etc due to the size and weight of the pressure vessel. (in fact you're using heat to store the energy)

    P.S. Battery powered cars have been able to run for 250, 300 miles for a good 7 years or so with a battery life of around 100,000 miles. That's with NiMH batteries. With lithium ion or even better, lithium sulphur batteries they should be able to travel further than a petrol driven car. (Google for Solectria Sunrise and Solectria Force)

    P.P.S. why do Americans call petroleum, gas? It's a liquid at ambient temperatures...

    --
    Government of the people, by corporate executives, for corporate profits.
  20. Re:No...it's not the "holy grail" by AKAImBatman · · Score: 2, Interesting

    But energy generation crosses into energy storage. His point was that you could use a hydrogen fuel cell as a way of collecting and storing solar energy while your car is not in use. Most people only drive a few hours per day. The rest of the day their car sits.

    Now there simply isn't enough energy in sunlight to power a car with solar panels. (If there was, we'd all be crispy critters.) But if you can store that energy up over a period of time, you can make your car much more efficient, perhaps even independent of fueling stations.

    It's a nice thought anyway. Until you realize that a large portion of the cars get stored in garages. :-/

  21. Distinction by Spamalamadingdong · · Score: 2, Insightful

    Just because he doesn't fit the profile of the average consumer does not mean that he is not a general consumer; he doesn't have any billing arrangements that are not available to everyone else.

  22. Available at Canadian Tire by denis-The-menace · · Score: 2, Informative

    Canadian Tire doesn't sell 2x4s but they do sell other building supplies and tools apart from car stuff.
    Go here and enter SOLAR as the keyword. (enter postal code: K1J 1J8)

    I found this:

    45W Cottage Solar Panel Kit
    Special Offer
    Product# 11-1588-0
    View larger image
    Price $499.99
    Availability
    In Store Online

    Qty.
    *

    Harness the sun's power to run small appliances (both AC and DC) such as TVs, lights, computers and to recharge your 12V DC batteries in your RV, boat or cottage. The 45-watt Cottage Solar Panel Kit is completely weather-resistant and works under all light conditions.

    * Ideal for charging deep-cycle batteries and running small appliances
    * ICP solar panels are completely weatherproof and can withstand 1/2" hailstones, up to 80C (176F) heat and can operate under 3" of snow (on sunny days)
    * Works under all light conditions
    * Kit includes three 15W solar panels
    * Can run both AC and DC appliances
    * Comes complete with 7A charge controller, ultra-bright fluorescent light and 140W DC to AC power inverter
    * Includes 12V socket with 10' (3m) of wire, PVC frame, mounting hardware and battery clamps
    * Manufacturer's limited 5-year warranty on power output
    * Model No. 10058

    --
    Obama's legacy: (N)othing (S)ecure (A)nywhere and (T)error (S)imulation (A)dministration
  23. evolution by Doc+Ruby · · Score: 2, Insightful

    If fewer neanderthals would whine "if it's so good, why isn't everyone doing it", more people would do it. And we'd get further out of the doomed hole we've dug with our paleolithic energy economy.

    --

    --
    make install -not war