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U.S. Nuclear Cleanup Carries Major Risks

Roland Piquepaille writes "New Scientist reports in this pretty alarming article that there is a 50-50 chance of a major radiation or chemical accident during the cleanup of the dirtiest nuclear site in the U.S. There are indeed lots of things to clean at the Hanford complex in Washington state: 67 tons of plutonium and 190 million liters of liquid radioactive waste stored in underground tanks. A third of them, dating from the Cold War, have already leaked 4 million liters in the environment, contaminating the groundwater and a river. Meanwhile, officials at the DOE, who'll spend $50 billion between now and 2035 on this cleanup, seem less worried than the different specialists interviewed by New Scientist. Please read this overview for selected quotes from the article and from the Hanford site. You'll also find a slide from the DOE showing the timeframe for the cleanup."

33 of 522 comments (clear)

  1. Re:Why not compare it with coal-fired plants? by strictnein · · Score: 2, Informative

    Newer coal plants trap most of the coal dust and many of the other polutants. They're actually getting much cleaner.

    It's the old ones (especially in places like China) that are the problem.

  2. Curses! Fooled Again! by bshroyer · · Score: 4, Informative

    I've got to start reading the submitter's name more often. Every time I click through on a story Roland's submitted, I feel I've been duped. You're welcome, RP.

    Is there any way I can configure my slash options to ignore his stories altogether?

    --
    The cure for cancer is coming: Reovirus
  3. River by cyocum · · Score: 5, Informative
    "A third of them, dating from the Cold War, have already leaked 4 million liters in the environment, contaminating the groundwater and a river."

    I do not usually comment but I would like to remind everyone that the river mentioned would be the Columbia River since Hanford is within sight of the river and a large number of fish spawn there every year.

    1. Re:River by forevermore · · Score: 4, Informative
      Mod the parent up! This river is not only a major spawning ground, but supplies irrigation water to many eastern Washington and Oregon farms, and has hundreds of people living on its banks (including big cities like Portland, OR).

      Hanford PR people claimed for years that it would take decades for their waste to filter into the Columbia, until some scientists pointed out that the waste had already been flowing into the Columbia for years.

      --
      Do you really need reason for beer? Wingman Brewers
    2. Re:River by geomon · · Score: 3, Informative

      Yep and there are also kraft paper mills, aluminum plants, power generation facilities (hydro dams) and orchards.

      That means you have dioxins, coal tar pitch, PCBs, and arsenic in the water that NEVER came from Hanford.

      --
      "Rocky Rococo, at your cervix!"
  4. 67 tons of Pu... by andreMA · · Score: 5, Informative

    ...was the lifetime production of the facility, not material to be cleaned up as implied.

  5. DO the submitters actually read the articles? by CrimsonAvenger · · Score: 5, Informative

    There are indeed lots of things to clean at the Hanford complex in Washington state: 67 tons of plutonium

    Actually, from the article, the 67 tons of Plutonium were the product of the Handford site, not a side-effect left littering the place.

    Note, before anyone starts whining about nuclear power not being clean, that Hanford isn't about nuclear power, but about nuclear weapons.

    --

    "I do not agree with what you say, but I will defend to the death your right to say it"
  6. Necessary evil by cyberzephyr · · Score: 4, Informative

    Considering the fact that the material has to be moved, every consideration must be made to properly secure the material from accidents and theft.

    DOE is more than capable of doing this and have done so for many years. Admittedly there have been a few problems but it never started a real situation of calamatious proportions.

    I almost signed up to work for DOE in this team capacity after i got out of the Army as a RANGER and i was very impressed with the security, armament and professionalism these folks have at hand. I just did not like the hours.

    +++Warning to any fool that thinks it's easy to steal radioactive material from one of these teams. You'll die twice before you get to pull your trigger once!+++

    Cyberzephyr

    --
    I'm here for the experience, not the Hyperbole.
  7. Re:Ouch by HBI · · Score: 4, Informative

    Hanford isn't a nuclear plant, it was a nuclear weapons research facility that also mass-produced plutonium for nuclear weapons.

    Moreover, Hanford was one of the places where we found out about dangerous isotopes and how to handle them. It wasn't run properly and in fact hardly could have been. Not to say that there weren't huge screwups there, but comparing this to a well run nuclear power plant is just wrong.

    --
    HBI's Law: Frequency of calling others Nazis is directly correlated with the likelihood of the accuser being Communist.
  8. why worry about it? by jest3r · · Score: 2, Informative
    Plutonium doesn't sound all that bad ...

    Despite being toxic both chemically and because of its ionising radiation, plutonium is far from being 'the most toxic substance on earth' or so hazardous that 'a speck can kill'.

    On both counts there are substances in daily use that, per unit of mass, have equal or greater chemical toxicity (arsenic, cyanide, caffeine) and radiotoxicity (smoke detectors).

    more: http://www.uic.com.au/nip18.htm

  9. Re:Told ya so! by ryanwright · · Score: 2, Informative

    Weren't we telling the nuclear power industry

    The contamination isn't from nuclear power. It's from producing nuclear weapons, and general experiments. You must remember, a large amount of our nation's nuclear research was done at Hanford, including the world's first man-made, sustained nuclear reaction. The mess is from this activity, conducted decades ago when we didn't know as much as we do now.

    This has nothing to do with nuclear power generation.

    --
    -Ryan, with the unoriginal sig
  10. Re:Cheap houses by Anonymous Coward · · Score: 2, Informative

    I grew up in this town. Surprisingly, the population is incredibly pro nuke. The town is booming now, due to the fact there is so uch waste to clean up.

    My high school mascot was a mushroom cloud.

  11. Half Right by geomon · · Score: 4, Informative

    The production schedule for the new Vitrification Plant is far ahead of the basic science and engineering that form the foundation for its construction. Although I do not think that they will operate it with the risks for steam explosion that the article alludes to, it is more likely that the tax payers will pay more than the estimated $7B to construct it.

    You heard it right, folks - $7B.

    As for the groundwater contamination, that is nothing new. A tritium plume extending from the 200 Areas (where plutonium separation was performed) to the Columbia River has been in place since production started. It has fluctuated in size according to the politics of weapons production. The facilities have been shut down since the early 90's and are in various stages of decommissioning.

    The issue of iodine-129 is a sticky point. It has a long half-life and had been dumped to the soil column without too much worry about the transport properties of the nuclide. It travels at the same rate through the vadose and groundwater as nitrate. It is very mobile. The toxicity of the isotope is in come dispute. I can get a higher radiation dose from a urniary test than I can get from consuming contaminated Hanford groundwater. I can also dispose of the contamination through my municipal water treatment facility, a practice prohibited for Hanford contractors.

    As for the cesium-137 and strontium-90, those isotopes bind to soils high in the vadose and rarely reach groundwater. The are confined to zones near the surface, far from the river, and will be left in place to decay to background beneath low permeability covers. This is not a practice that the USDOE is forcing on the local community, but is a treatment alternative that is accepted by the USEPA and Washington Deparment of Ecology.

    --
    "Rocky Rococo, at your cervix!"
  12. people are big dumb panicky animals by rh9shrike · · Score: 2, Informative

    I live right next to the Idaho National Engineering lab. (INEL) we have 53 reacotrs out there, among them were the first to produce electric power, and the first breeder (plutonium producing) reactor. There is also one other interesting piece of tech out there- a calciner. This calciner takes liquid waste and makes it a solid. Litle balls about the size of cookie sprinkles. The stuff is still radioactive (no fix for that) BUT it can no longer seep inot groundwater, it no longer eats away at its container, it is much more stable with regard to the environment. Hanford has to know about this and I imagine they didn't do it because it would be a major pain to get the stuff here to calcine it, or it was expensive. (Most likly both transporting "hot" nuclear materials is probably the biggest paperwork nightmare I can imagine. one last point- the people who work there don;t want to die anymore than you do. These people know what they are doing- (but managment is the one that makes the papers.) And even if their managment tells them to do something stupid- the guy on the ground wants to go home to his family tonight. I serously doubt there will be a problem- I have lived here my whole life without problem, and plan to stay.

  13. Re:Why not compare it with coal-fired plants? by AKAImBatman · · Score: 5, Informative

    Plutonium's chemical toxicity is minor compared to its radiological abilities. IF plutonium reaches soft tissues (like your lungs), its alpha emissions will begin to systematically destroy your tissues and DNA. By the time the chemical toxicity comes into play, you'll be long dead from radiation exposure.

    The key here is that Plutonium is rather hard to get into your system. In order to get it into your lungs, it has to be powderized AND airborne. Both are very difficult as Plutonium is hard and heavy. Ingestion is another possibility, but it seems that the Pu is generally passed through without ill effects. Again, it's very hard to disintegrate, so your body often fails to digest it. This makes Plutonium very dangerous on one hand, yet very, very safe on another. You could keep a piece of it in your pocket, and in general there will never be any ill effects.

  14. "a" river? by peacefinder · · Score: 4, Informative

    The contaminated river in question is the Columbia. As the second-largest river (by flow) in the lower 48, and the largest to drain into the eastern Pacific ocean, I think it merits a mention by name.

    But then I'm a local, so I'm biased.

    Thankfully, the large flow means that the contamination is pretty dilute. The bad news, of course, is that said contamination flows through quite a few populated areas (including Portland), the river is used to irrigate and transport zillions of tons of wheat and other edibles, and lots of fish get pulled from the river and eaten.

    --
    With reasonable men I will reason; with humane men I will plead; but to tyrants I will give no quarter. -- William Lloyd
  15. Re:Nuclear waste leaks by Animats · · Score: 2, Informative
    Plutonium is made by transmutation in a nuclear reactor. Transmutation produces not just plutonium, but a whole range of transuranic elements. These are then separated chemically.

    Both uranium and plutonium extraction are very messy processes from a chemical engineering standpoint. They involve highly corrosive materials, including fluorine and acids. During the chemical processing, the corrosives become mixed with radioactive byproducts. So you get liquid mixtures which are both corrosive and radioactive.

    Worse, early on, Hanford went in for diluting these liquids with water. "Dilution is the solution" was an early phrase. This gets the corrosiveness down, but now you have huge tanks of low-level radioactive solutions. Some of the cleanup effort today focuses on re-concentrating those solutions so the more dangerous components can be vitrified in glass for long term storage.

    And, yes, they did put this stuff in metal drums, which were then buried. And they rusted, then leaked. Now they're being dug up.

  16. Re:Curses! Fooled Again! by JohnGrahamCumming · · Score: 4, Informative
    Not only is this YARPA (Yet Another Roland Piquepaille Article) which annoys me like all the others, it fails to add any value to the original New Scientist piece, and introduces erroneous statements like (my emphasis):

    Over the last 50 years nine reactors at the 1500-square-kilometre site have produced 67 tonnes of plutonium for the US nuclear weapons programme. In 2002 the US Department of Energy (DOE) embarked on a 30-year, $50 billion clean-up, which includes emptying more than 190 million litres of liquid radioactive waste from 177 underground tanks.

    In this Hanford overview, the numbers are slightly smaller than the ones provided by New Scientist, but are still worrisome.

    Physical challenges at the Hanford Site include more than 50 million gallons of high-level liquid waste in 177 underground storage tanks,

    Let's Ask Google Calculator. Oh. 50m gallons is 190m litres.

    John.
  17. Re:Nuclear waste leaks by hakioawa · · Score: 5, Informative

    IAAHG ( I am a hydrogeologist ), or at least was an one point. People do not understand the effects of time on engineerd materials. Most engineered materails have a usefull life of a few decades or less. You new roof is water tight today, but come back in 50 years and it will leak like a sive.

    The uinderground environment is a hostile one. There water continually percolating through the ground. This water may or may not be acidic, and may or may not be under perssure. Almost no rock is impervious. It may only leak a little but over 100s or 1000s or yeah a little becomes a lot.

    Anything will leak. The questions are:
    -At what rate
    -And where will the leakage go
    -What happens when some idiot archeaologist 500 years from now opens it up?

  18. Re:Ouch by Anonymous Coward · · Score: 1, Informative
    And Rad for Rad is the only one that counts. If a cop pulls over two drivers, and one drank a pint of whiskey and the other drank a quart of beer, he doesn't say to the beer drinker: I'm hauling you in too in because you drank twice as much as this lush.

    The natural thorium and uranium in coal is about 6 orders of magnitude less potent than fission waste.

  19. Re:Ouch by Anonymous Coward · · Score: 3, Informative

    ...if the reactors in question were nuclear plants, then so was the small research reactor at the Univ. of Washington.

    The link in one of the parents was trying to relate the activities at Hanford (creation of nuclear materials for weapons and research) vs those of a commercial power-generating nuclear reactor.
    The parent article to yours was dismissing this link, and then you try to casually deconstruct it and say, essentially, that any nuclear reactor is a nuclear plant.

    FWIW, Cobalt-60 is probably even more dangerous than Pu-238, as are any number of non-nuclear chemicals. A drop of some organophosphates on the back of your hand can kill you within 10 minutes.
    Malathion is a mild organophosphate. It is much easier to buy Malathion than it is plutonium.

    While it is fine to worry a bit about this, it is probably safe to say that the concentration of naturally occuring radioactives in coal fly ash is probably a bigger, much more widespread deal.

    Hanford's problems look sexy and dangerous, but are they really? Is the population of the Tri-cities, Portland, Kelso and Longview suddenly at a huge risk of getting various forms of cancer compared to all the other existing environmental factors?

    The US Government managed to clean up the Rocky Mountain Arsenal and Rocky Flats, in Colorado...

    Besides, the DOE has been worrying and trying to figure out this problem for at least 20 years. A former boss of mine's father used to punch test and monitoring wells all over the area, long before I knew him. A former girlfriend worked on a research program to help figure out a way to monitor the most notorious tank.

    a big problem is that they simply do not know what they are dealing with in the tanks. It's toxic, it's radioactive, a couple of them vent hydrogen, but they do not even know if the mere act of taking samples at various depths in the tanks might disturb them enough to cause problems...

  20. Re:To the sun! by Rorschach1 · · Score: 2, Informative

    First, there's cost. Getting a payload to geosynchronous orbit will cost you about $5,000 to $10,000 a pound. That's NOT the sun. And you CAN'T just 'push it toward the sun' and expect it to get there. Remember, we're orbiting the sun at a pretty good clip. The energy required to cancel that velocity and drop a payload into the sun is something like 18 times what's required to put it in Earth orbit.

    And of course there's the issue of launch failure. Current failure rates are around 5% to 20% for expendable launch vehicles (depending partly on what you're counting as a failure), and for our safest manned vehicles, around 2%.

    Of course, it'd be just stupid to throw away perfectly good plutonium, so we're probably talking about lots of bulky contaminated secondary waste anyway. Really, it's a whole lot safer, cheaper, and more practical to bury the stuff under a mountain in Nevada than to try to shoot it into space.

  21. Re:Nuclear waste leaks by cluckshot · · Score: 4, Informative

    Having an Uncle who for some years was in charge of the cleanup at Hanford and noting that he lives in Kelso I would tend to discount the FUD a lot. (About 99.999999999% or more.) Having two other Uncles who were reactor operations officers for US Nuke Subs makes me have a bit of family based info on the topic. I just am not as worried as most people are because I know generally what the problem is and how big it is.

    To be sure the mess at Hanford is a serious mess. It involves largely the chemicals used to refine the various elemements after reactor actions. The reason they liked plutonium for bombs is that it could be bred out of lesser stuff and was easily chemically isolated. This gave rise to a lot of radioactive chemical wastes which bluntly were pretty reactive stuff.

    The problem was storage was at best using technology we had at the time rather than trying to deal perminanently. The problem is that many of these chemical wastes are liquid and they are stored in containers that are failing or have started to fail.

    The containers in many cases were about equal to swimming pools or to 55 gallon drums. Another problem is some of these elements migrate quite easily through barriers. They form all sorts of funny deposits which if struck are prone to catch fire.

    With all of this said, the whole problem is one more of time and effort than danger. The location is really pretty unlikely to see a lot of migration outside Hanford and if it does go into the Columbia River it will be diluted well below any level of concern. The river is not small. At nearly 100,000 CFS flow and shortly diluted to 200,000 CFS average flow, this stuff is gone... gone... gone.

    To explain a bit more, the problem here is largely one of timing and events. Most of this waste developed right during and shortly after WW2. Shall I say that priorities and for that matter knowlege have changed in the intervening years.

    Actually the biggest problem in the cleanup owes to the need not to actually create more contaminated waste than absolutely necessary while doing the clean up.

    --
    Never Politically Correct ~ I prefer the facts If you don't like what I say, get a life, or comment yourself.
  22. Re:Question... by timothyf · · Score: 3, Informative

    I did a short research paper on Hanford, so I think I might be able to answer this a bit.

    The problems at Hanford are mainly due to one of two things: age (some of the reactors and processing plants date back to WWII, when the effects of radioactivity was still not well understood) and purpose (Hanford was designed to extract Plutonium (Pu); only one of its reactors ever produced electrical power, and that was a secondary purpose)

    First off, age. Hanford was built in WWII with exceedingly great haste, and disposal of wastes was put on the back-burner as something that can wait until after the war. Then the cold-war began, and while procedures improved somewhat, proper disposal was still a secondary concern. With the reactors themselves, all except one of the reactors there are "single-pass" reactors, meaning that instead of recycling its coolant, it just pumped it in from the Columbia River, sent it through the reactor, then (after letting it cool for a little bit) sent it back to the river.

    The other problem is the Plutonium processing. This generated a lot of highly radioactive and toxic chemical wastes, which were (depending on how radioactive it was) stored in leak-prone tanks (although they have since moved most of the waste to better double-shelled tanks) or dumped directly to the ground.

    So, to answer your question, I would presume that a modern nuclear power plant would be much less of a problem to deal with, since it would be built to use recycled coolant. There is still the problem of the spent feul rods, however (and here I'm not so sure, because I didn't study about modern practices so much) if handled properly from the outset, they could be stored safely enough to avoid environmental contamination. Perhaps someone with knowledge on modern nuclear power plants could better answer that part, though.

  23. Coal-fired plants release radiation.... by tiger99 · · Score: 5, Informative
    Very interesting point, and you may, or may not, be surprised to hear that in fact coal-burning industry, mostly power plants nowadays, has released far more uranium, thorium and radium (plus others?)into the atmosphere than the entire nuclear industry, and they continue to do so.

    This is because coal contains trace amounts of these elements, which are not in the form of particles, but are more likely distributed as individual atoms in individual molecules, maybe combined with carbon, certainly oxygen, and other elements. No known technology can take individual molecules of, say, uranium oxide, out of a chimney.

    Now this release of radionucleides has been going on since serious use of coal began around 1600-1700.

    Interestingly enough, in the UK there is often controversy over so-called leukaemia clusters, now these cases are tragic, but it is alleged that they are due to the nuclear industry, however close inspection shows that every single such cluster, with one exception, is in an area close to or downwind of a large coal-burning plant which either still exists, or was in use relatively recently. Some of these plants were lead smelters, which adds more uranium and other toxic elements. The one exception that I know of, where no industrial presence can be seen, is in Cornwall, around the village of Tintagel, and it is hardly surprising, because the local children no doubt play on their nice beach, and behind the beach are sea caves, with uranium compounds leaching out of the rocks. There will also be a high concentration of radon gas in such places, it mainly causes lung cancer by depositing daughter products in the lungs, but some of the daughter products may indeed cause leukaemia, and may be ingested in other ways.

    At a guess, I would say that similar conditions of radiation release due to coal burning, and the extraction of certain other minerals, will be found worldwide, as presumably volcanic activity had released lots of radionucleides into the atmosphere during the carbiniferous era, which would eventually have found their way into the vegetation, and hence the coal.

    In one particular part of the UK, when germanium transistors were in fashion, soot from factory chimneys was collected because it was rich in germanium, I think you will find that other elements (certainly selenium, which is toxic and carcinogenic, and also cadmium) can be found in significant quantities in some geographic regions.

    So, coal burning will release radioactive, toxic and carcinogenic substances, fortunately not plutonium of course, although in theory an occasional atom might be formed by natural processes. After all, there are these odd atoms of uranium embedded in the moderator, coal instead of pure graphite, so there is the remote chance that a neutron from a fissioning uranium atom might be slowed by the coal, and captured by another uranium atom. But the yield would be incredibly low.

  24. Re:you have to do something about them by david_reese · · Score: 5, Informative

    France does plutonium reprocessing, in fact they reprocess HUGE amounts of waste. It's our current policy of "no reprocessing == minimized proliferation" that is causing this waste nightmare. More about this on this PBS frontline special.

  25. A lot of scary sh1t out at Hanford by Aexia · · Score: 3, Informative

    I worked on a congressional race in the Tri-Cities a few years back and went on a day-long tour of the Hanford facilities with the candidate, got presentations on how they were handling the many different kinds of nuclear waste.

    I don't know what was my favourite. Was it the nuclear waste that was being stored in what amounted to two coffee cans? The containment tubes rated to last 10-20 years that had been holding waste for 50?

    I'm thinking I'll have to go with the underground spillover tanks. There'd be a bunch of series of 5 tanks. When tank 1 fills up, waste spills over into tank 2. Tank 2 fills up, spills into tank 3. So on and so forth until you get to tank 5 where when it fills up, the waste apparently just spills out into the ground. Naturally, they weren't meant to last this long either.

    So in addition to the nuclear waste, you have to deal with all the contaminated soil and whatnot too. US Gov't really clusterfucked the area. Fortunately, the state gov't(led by AG Gregoire) nailed their balls to an agreement to clean up all this shit.

    That being said, it's a neat facility and everyone was friendly and eager to show what they were doing. There are a lot of interesting plume diagrams showing how the contamination is making its way to the Columbia River.

  26. Re:Why not compare it with coal-fired plants? by Anonymous Coward · · Score: 0, Informative
    "its alpha emissions will begin to systematically destroy your tissues"

    Are you suggesting it is sentient? Perhaps you meant "randomly"?

  27. Re:Ouch by Rei · · Score: 3, Informative

    Another good post by an AC. Coal kills many, many people each year.

    A study by Abt Associates estimated that coal power plants *in the US alone* kill 24,000 people *per year*. That's just the deaths; there were also 38,000 non-fatal heart attacks, 554,000 asthma attacks, and 3 million lost workdays. On the other hand, deaths due to nuclear power plant radiation *in the whole world* (almost exclusively from Chernobyl, which was a patently stupid event from a horribly archaic design) range from the low thousands to the low tens of thousands, and between the upper tens of thousands to the low millions of related diseases - in the 50 years since the world's first nuclear power plant. In the US, nuclear power plant-related casualties are hard to estimate because they're so low. Yes, we use more coal power than nuclear - but nowhere close to the scale of health and environmental damage coal causes compared to nuclear.

    At the very least, nuclear power is *as safe* as coal power. At best, it puts coal power to shame. And then there's the national security interests of nuclear: some of the most concentrated uranium deposits in the world are in our neighbor to the north, Canada. The world's largest deposits are in another ally, Australia.

    --
    SILENCE BLATHERING TOADIES! We are your new masters.
  28. Re:Facts about the Hanford clean-up: by ryanwright · · Score: 3, Informative

    They are talking about this now, too, and they are giving the same completion date, "15 to 30 years from now". That's why I say that apparently nothing has been done, even though they have spent many, many billions.

    The glassification plant is being built right now. Construction started about a year ago.

    --
    -Ryan, with the unoriginal sig
  29. I was told exactly the same thing in the early 70s by Futurepower(R) · · Score: 2, Informative

    Ryan, I was told exactly the same thing in the early 70s. At that time they were planning on doing the glassification inside each tank. Something is very wrong, I think. It sounds like a huge boondoggle, at minimum.

  30. Correct - nuclear power plants are very different. by Jack_Frost · · Score: 2, Informative

    The production and extraction of plutonium uses a very different type of reactor than the Pressurized Water Reactors that are used for power generation in much of the world. A lot of the waste at Hanford isn't due to the reactor operation per se, but rather the chemical extractions that are necessary to recover the plutonium. These extractive processes generate a lot of waste chemicals (like acids that have been used to dissolve fuel) that are contaminated with hot particles. That's the origin of the liquid radioactive waste at Hanford.

    Waste from a PWR is solid and it predominantly consists of used or burned fuel assemblies that are still radioactive but no longer capable of producing electricity efficiently. The fuel assemblies contain the fuel rods which encapsulate the fuel pellets and the daughter products of the fission reaction (various isotopes of noble gases trapped in the fuel rods).

    The mass of waste produced by a nuclear plant in a given year of operation is miniscule compared to the thousands of tons of ash, soot, and greenhouse gases emitted by your typical coal plant with a similar electrical output.

  31. A brief, concise answer to the question by Engineer-Poet · · Score: 2, Informative
    Quoth the poster:
    What I'm getting at is, how much of this waste is comparable (in terms of which specific materials, and in what volumes) to what a nuclear powerplant would produce?
    Not at all comparable. Fresh PWR fuel is pellets of uranium dioxide (a very hard, refractory ceramic) in zirconium tubes; the spent fuel is largely the same with about 3% of the uranium removed and fission products and plutonium added. Swelling of the pellets due to displacement of nuclei from their neat crystal lattices can damage the Zr cladding.

    The Hanford wastes are composed of the byproducts of reprocessing, including organic solvents which were used to do solvent separations of U, Pu and fission products. The concentration of these products is very low vis a vis ceramic fuel pellets so the volumes are comparatively huge, and the solubility/mobility is immensely greater.