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A Cleaner, Cheaper Route to Titanium

Burlap writes "Using technology developed at MIT, 4-person startup Avanti Metal hopes to reduce the cost of producing Titanium from the current $40 per pound to a mere $3. The article discusses how a special combinations of oxides and electrolysis separates the titanium metal from the Earth's abundant titanium oxide ore."

28 of 335 comments (clear)

  1. I'm surprised by Watson+Ladd · · Score: 5, Interesting

    No one found this earlier. The Hall-Heroult Process for aluminium is basically the same,and has been known for well over a century.

    --
    Inventions have long since reached their limit, and I see no hope for further development.-- Frontinus, 1st cent. AD
    1. Re:I'm surprised by qbwiz · · Score: 4, Insightful

      I agree, although the temperatures that they say that this process occurs at are almost twice the temperature you need to refine aluminum. That might explain why it was considered practical for aluminum, but not considered for titanium. They did say that they were having problems with heat.

      --
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    2. Re:I'm surprised by AtomicBomb · · Score: 5, Informative

      The concept is not new: basically the same as the Hall cell for aluminium production. But, I believe finding a suitable salt is not that easy. In the case of aluminium, cyrolite is used. In titanium, what's the suitable one? Suppose you mix Ti2O3 with another metal salt, you may get another metal instead of Ti. Needless to say, the whole electrolysis process gets quite messy at 1500+ degC.

    3. Re:I'm surprised by Anonymous Coward · · Score: 5, Informative

      Another cleaner, cheaper route for Titanium production has been developed in Cambridge, UK.

      Reach about the FFC Process for Titanium Extraction.

  2. Better processing available by Anonymous Coward · · Score: 4, Funny

    Nobody uses the Titanium. Servers just use a MD Pteron if they want price-performance. And Onroe is just around the corner. Even cheaper Titaniums aren't worth the bother. Ntel can't drop the product line as a matter of face, but consumers just aren't buying it.

  3. Apples and oranges... by THotze · · Score: 4, Informative

    I always love articles like this when they compare the price of MAKING something with the price of SELLING something. Titanium's sold on a market sort of like oil... prices fluctuate based on demand more than they do based on the cost of production.... if the price of titanium is $40 this year, and was half as much last year... last year it was $20, and I'm SURE that people were making a profit selling that, so it was produced for probably a maximum of $15, probably more like $10/lb.

    So yes, this saves money... but it needs to be done in a large scale, 1st. I don't know how they come up with a cost/lb estimate that they consider to be more than VERY ball park estimate... $3 could be $6.

    Its substantial savings, but its not like we're going to be able to start planning our houses with titanium frames in a few years or anything. And that's assuming that demand doesn't keep skyrocketing above supply... in which case we could have the same price (or more!) regardless of how much it costs to produce titanium.

    Tim

    1. Re:Apples and oranges... by diablomonic · · Score: 4, Insightful

      I agree on the whole "announce a price when we havent even got a commercial demo plant" thing being stupid, but you seem to have missed something. According to the article, supply of titanium is currently very limited due to environmental concerns, while demand keeps going up (and, although I'm not a metalurgist, is there any reason that titanium couldnt replace steel almost entirely if it was cheap enough? thats a lot of demand!). This removes that supply problem entirely if it works of course.

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    2. Re:Apples and oranges... by Andy+Dodd · · Score: 4, Informative

      "and, although I'm not a metalurgist, is there any reason that titanium couldnt replace steel almost entirely if it was cheap enough?"

      In addition to being expensive, titanium is NOT easy to work with.

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    3. Re:Apples and oranges... by big+tex · · Score: 4, Informative

      "and, although I'm not a metalurgist, is there any reason that titanium couldnt replace steel almost entirely if it was cheap enough? "

      One word: welding.

      OK, I'm drunk, but bear with me. I weld best this way, so explanations should work as well.
      Welding steel is easy, really easy. It can be done outside, with nothing but a constant-current power source and some flux coated rods (SMAW,or 'stick' welding). This requires a minimal amount of skill. Move on to some better equipment, say wire feeders and constant-voltage machines, and we can weld sheet metal like it's nothing (GMAW) or lay down some structural fill in a hurry (FCAW or SAW). I can teach someone to weld FCAW in a few hours, provided they're smart enough not to burn themselves and not look at the bright lights without a shield.

      Titanium oxidizes like a little bitch. Basically, the largest part of welding technology is creative ways to keep oxygen, hydrogen, and those other things in the air away from the weld puddle. This can be done by flux (SMAW, FCAW, SAW), or by shielding gasses like CO2, Ar, He (GMAW, FCAW, GTAW). The only good way to weld titanium is by using TIG (GTAW). This is the most skilled, labor-intensive, slowest process going. I can lay down steel welds for bridge in pounds per hour, but titanium takes hours per pound.

      Now, more available titanium should lead to a titanium MIG (GMAW) process, but that's still small potatoes compared to SAW, GMAW, and it can't really be done outside. (I don't want to hear about the trailer you welded in your driveway. Try it two stories up in the wind, or on a barge, and we'll talk). To provide another point of reference, the high production and field processes (SAW, FCAW, SMAW) don't work with Aluminum, the 20th century's miracle metal, because they are flux-based and Aluminum doesn't do flux-based, flat out. Titanium will be the same way.

      In summary, titanium is kept in limited used in industry because it's hard to weld, not because it's expensive.

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    4. Re:Apples and oranges... by scheme · · Score: 4, Informative
      In addition to being expensive, titanium is NOT easy to work with.

      Just as an illustration, welding titantium in a normal atmosphere will cause it to become brittle. You need an inert atmosphere (e.g. argon) at the weld point and on the cooling joint to protect it. Any iron or steel contamination will also screw things up.

      --
      "When you sit with a nice girl for two hours, it seems like two minutes. When you sit on a hot stove for two minutes, it
    5. Re:Apples and oranges... by modecx · · Score: 4, Informative

      Just as an iustration, welding titantium in a normal atmosphere will cause it to become brittle. You need an inert atmosphere (e.g. argon) at the weld point and on the cooling joint to protect it.

      You're right, you need a good supply of argon to keep hot titanium from forming oxides or nitrides with atmospheric gas. It's an amazing thing, nearly *all* of the non-aviation titanium welds I've seen were not done right, and they have either an amber tint (not good) or a blue tint (really not good), and often a little rainbow of colors somewhere inbetween. The one exception I've noted is the race car industry. They actually do it right, and lives depend on it, so it's a good thing. The aftermarket parts for cars though? Holy shit, that stuff is ALWAYS FUBAR, and if it were to serve a purpose like strut bars for race/street cars, I imagine they'd crack if they were actually used for a few good hours. The funny thing is that I'm sure they think those colors are pretty!

      Anyway...

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    6. Re:Apples and oranges... by modecx · · Score: 5, Insightful

      In summary, titanium is kept in limited used in industry because it's hard to weld, not because it's expensive.

      Just wanted to add to all of the great stuff you said by also pointing out that titanium is also a pain to work with in pretty much every other way. It's tough to machine, it's also a bitch to use as sheet metal--it's springy and not as malleable as steel or aluminum at room temperature. You've often got to heat it signifigantly if you need to make tight bends... Plus, all of that is compounded by the alloys of titanium which are even harder to use and form than the pure stuff.

      --
      Constitutional rights may be respected, repealed, or modified; but they must never be ignored.
    7. Re:Apples and oranges... by bigpat · · Score: 5, Insightful

      Let's think of this from a business standpoint: patent the process. Produce titanium in small numbers to prevent market saturation. Charge the same amount as everyone else, but at 10% the production cost. I don't see the savings being passed to the consumer anytime soon.

      Well the patent holder would want to maximise profit, so will have to produce enough to make it worth while. So, this would increase supply at least somewhat and thus likely decrease prices. And it is very likely that the patent holder would just want to license the process to current companies instead of actually getting capital to start their own plant. So, they would have incentive to license the process to as many companies as possible. At which point it only takes one company to decide that it needs to increase production to increase market share in order to have an effect of lowering prices. Of course, there can always be anti competitive price fixing, but that is illegal and can't go on forever.

  4. Great for chainmaillers by Kabuthunk · · Score: 4, Interesting

    Sweet! I'm sure this will likely have a significantly higher impact on pretty much all products as is, but this will affect me in a slightly different way. I'm one of the few that make chainmail as a hobby. Titanium chainmail is significantly lighter, rusts less, etc, etc. Significantly better for metalcraft than stainless steel or galvanized steel or anything like that in my opinion.

    So, having cheaper working materials = excellent for people like me :}

    --
    Planet Zebeth - Metroid with a twist
    1. Re:Great for chainmaillers by Nefarious+Wheel · · Score: 4, Funny

      Yep, I've got a friend who makes maille too, says the same thing (unless you're him, K?). I tried to sell him on the idea of Unobtanium, but he said his customers prefer either Titanium or Expensium. Hardtoobtainium is pretty good too, but suffers from consistency of supply issues.

      --
      Do not mock my vision of impractical footwear
  5. Steel Age by pete-classic · · Score: 4, Funny

    Thank God! I thought the Steel Age was never going to end!

    -Peter

  6. WOO HOO! by GrumblyStuff · · Score: 5, Funny

    Titanium foil hats HERE WE COME!

  7. Awesome! by eric434 · · Score: 4, Informative

    I took Sadoway's class last year. Awesome guy -- this is right up his alley (making things more environmentally friendly).

    Here's a PDF presentation on the process:
    http://web.mit.edu/dsadoway/www/MOE_Ti.pdf

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  8. One of my first jobs by IamNotAgeek · · Score: 5, Interesting

    I worked at a titanium manufacturing plant where I analyzed samples for nitrogen contamination. Even though it was a pretty low level repetitive job, I still felt like a scientist working in a lab wearing a lab coat and the head chemist was a guy from Sweden named Jurgen (?sp). I also remember that the titanium tetrachloride was so volatile that just a spoonfull released into the atmosphere would create a huge white cloud and the fire department would show up and management would have to fill out an incident report. Good memories, except for the time I got hydrofluoric acid on my fingers, very painfull, and of course when I accidently breathed in some vapors and had frequent nosebleeds for several years afterwards.

    --
    All generalities are dangerous except ones that start with "All /.ers"
    1. Re:One of my first jobs by Beltonius · · Score: 4, Informative

      I'm currently working at a company specializing in Ti and Ti alloys/composites.
      I have little to no faith in this actually producing anything substantial within the next several years.

      Why? I have read about this same guy pitching his process for the past several years, and my company has a file on him going back almost a decade; he's been saying his process will yield results 'soon' for far too long for me to readily believe him.

      Last year, even, I read a presentation he gave, and it consisted of little more than a brief high-school chemistry explanation of electrolysis (which is all this is, same process that produces hydrogen and oxygen from water) and stating a hope that they will build an experimental cell soon. Apparently he's gotten that far, but 200 mg aren't going to help much to combat the currently sky-rocketing Ti prices.

      And yes, they are very high right now. Half our work is focused on improving Ti recycling processes so that scrap can be used more widely; the rest of the work is biomedical applications where cost is not an issue.

      The point is: Yes, if this works it could mean a much cheaper/environmentally friendly (I'm a little doubtful of this; yea, there won't be concentrated TiCl or Cl gas lying around, but it's an electrolytic process, it will use lots of electricity, and that will produce extra waste) process. This is a conceptually simple process; basically it requires experimentation to get the parameters right. He has spent very little time actually experimenting.

  9. Re:Aluminium? by Deadstick · · Score: 5, Informative

    Twice as strong vs 1.6 times as heavy, higher melting point, better resistance to corrosion and fatigue.

    rj

  10. Re:Not exactly by DeadChobi · · Score: 5, Insightful

    Not to be pedantic or anything, but you would actually fare worse in a car wreck in a Titanium car, as it wouldn't give as readily as steel. The more time the impact lasts, the less force the passengers experience. So in a wreck between a titanium Geo Metro and a steel Geo Metro, the passengers of the titanium car could be extracted faster but would be more likely to die. There are more considerations to engineering than just weight and efficiency. If something cant get you from point A to point B as safely as the less-efficient alternative, than the less-efficient alternative bears at least some looking into.

    --
    SRSLY.
  11. Re:Not exactly by Eccles · · Score: 4, Insightful

    Not to be pedantic or anything, but you would actually fare worse in a car wreck in a Titanium car, as it wouldn't give as readily as steel.

    So why don't we make cars out of cotton wool or balsa wood?

    You want crumple zones, yes, but surrounding a stiff inner structure. That's why doors have stiff cross-beams in them, race cars have roll cages, etc. No titanium for the crumple zones, sure, but you want it for the roll cage.

    --
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  12. Re:Aluminium? by Frangible · · Score: 5, Informative

    Several reasons:

    1. Insulation; titanium is less condutive of heat/electricity. This can be a benefit or detriment depending on the application.
    2. Strength; the same amount of Ti/Al alloys to support a specific load can be made with a lighter weight of Ti. An equal volume of Ti is heavier than Al, though.
    3. Fatigue life; titanium, like iron, has infinite fatigue life. Aluminum does not. What this means is you can make a spring from Ti but Al will fail if repeatedly stressed.
    4. Corrosion; titanium is more corrosion resistant than Al because it oxidizes rapidly in contact with air
    5. Social reasons; titanium has significantly more percieved value than Al, moreso than the material differences. Further Ti has a unique color as well.

    Sometimes aluminum will still be better; in many applications the relative strength difference doesn't matter and thus a lighter equivalent volume of Al is advantageous. Also, the high conductivity of Al is a good thing in many situations.

    The most common Ti alloy, Ti-6Al-4V, actually has 6% Al in it.

  13. modern swords by bodrell · · Score: 4, Interesting
    Know anyone who makes swords? I've heard that the metallurgy that goes into a modern metal blade is quite impressive, and that modern swords -- despite being made almost entire by hobbyists -- are far superior to the swords of antiquity.
    You weren't addressing me, but regardless . . .

    My brother knows one of these modern-day master swordsmakers. One of the new tricks is to use high quality braided cable as a starting material. You flux it or something, then heat and pound. Like starting out with a Damascus or samurai style laminated blade, but woven instead of folded. Sounded pretty cool to me.

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    Si la vida me da palo, yo la voy a soportar Si la vida me da palo, yo la voy a espabilar
  14. Inexpensive Russian Titanium.. by thesupraman · · Score: 4, Informative

    Of course they are carefully looking at the AMERICAN price for titanium production..

    It is much much cheaper in Russia, as it is basically produced as a side effect of steel production there due to the different ores available.
    Most significant titanium users source their titanium from Russia, and there is little interest in other sources as Russia just has the right ores anyway.

    Oh well, good try though.

  15. Re:Ad problem. by afidel · · Score: 4, Interesting

    Actually that durability can be one of the biggest problems with Titanium rings, trauma sheers can't cut them so if you have any kind of severe sweeling problem there's a good chance of digit loss because the ER won't be able to remove the ring. That and the fact that my father gave me his ring are the reason I didn't get a titanium one. (He hadn't worn his in 20 years due to working with the machining industry and seeing several people lose their hands in machines due to wedding bands).

    --
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  16. Re:Ad problem. by RockModeNick · · Score: 4, Informative

    Thats incorrect. Any good steel shear, including the wiss tinsnips in my tool drawer, will cut a titanium ring apart easily. Titanium may have a better strength to weight ratio than steel, but steel is much harder at simular or even smaller actual size and as such will easily shear titanium.