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A Cleaner, Cheaper Route to Titanium

Burlap writes "Using technology developed at MIT, 4-person startup Avanti Metal hopes to reduce the cost of producing Titanium from the current $40 per pound to a mere $3. The article discusses how a special combinations of oxides and electrolysis separates the titanium metal from the Earth's abundant titanium oxide ore."

74 of 335 comments (clear)

  1. Print Friendly View by layer3switch · · Score: 3, Insightful
    --
    "Don't let fools fool you. They are the clever ones."
    1. Re:Print Friendly View by mjpaci · · Score: 2, Funny

      That's sabotage! In order NOT to get killed in ad costs by being slashdotted, techreview redirected the page-of-slashdottedness back to an ad on Slashdot thus screwing slashdot and something, something, something....

      It made sense when I started typing. It's too damn early...

      --Mike

  2. I'm surprised by Watson+Ladd · · Score: 5, Interesting

    No one found this earlier. The Hall-Heroult Process for aluminium is basically the same,and has been known for well over a century.

    --
    Inventions have long since reached their limit, and I see no hope for further development.-- Frontinus, 1st cent. AD
    1. Re:I'm surprised by qbwiz · · Score: 4, Insightful

      I agree, although the temperatures that they say that this process occurs at are almost twice the temperature you need to refine aluminum. That might explain why it was considered practical for aluminum, but not considered for titanium. They did say that they were having problems with heat.

      --
      Ewige Blumenkraft.
    2. Re:I'm surprised by AtomicBomb · · Score: 5, Informative

      The concept is not new: basically the same as the Hall cell for aluminium production. But, I believe finding a suitable salt is not that easy. In the case of aluminium, cyrolite is used. In titanium, what's the suitable one? Suppose you mix Ti2O3 with another metal salt, you may get another metal instead of Ti. Needless to say, the whole electrolysis process gets quite messy at 1500+ degC.

    3. Re:I'm surprised by Anonymous Coward · · Score: 5, Informative

      Another cleaner, cheaper route for Titanium production has been developed in Cambridge, UK.

      Reach about the FFC Process for Titanium Extraction.

    4. Re:I'm surprised by JohnFluxx · · Score: 3, Informative

      Hmm, 1700C is the temperature a normal (non-energy saving) light bulb works at. At 1700 the efficency is terrible (around 1%). To make light bulbs more efficent, you 'merely' need to increase the temperature. The problem is finding materials that you can do this with.

      To increase the temperature you need a material that won't oxide, react, etc at high temperatures. The best material is tungsten. However this does rapidly corrode. Hallogen lamps and energy saving light bulbs use this. The tungsten is heated to 2400C. At this temperature it has an efficency of almost 4%. However the tungsten corrodes very rapidly. Halogen lamps have the bulb bit made out of quartz, which makes the halogen air inside react with the tungsten that has corroded off, and pushes it back on to the tungsten. So the corroded tungsten is continually put back on.

      Going above 2400C is not simple. Tungsten has a melting temperature of 3400C, but you would need to deal with the corroding at a fantastic rate. Also tungsten is fantastically expensive and rare.

    5. Re:I'm surprised by sirwired · · Score: 2, Informative

      Halogen lamps have the bulb bit made out of quartz, which makes the halogen air inside react with the tungsten that has corroded off, and pushes it back on to the tungsten. So the corroded tungsten is continually put back on.

      Close, but not quite. The bulbs are made of quartz because it can withstand the heat much better than a thin glass envelope. The quartz has nothing to do with the tungsten redisposition. The tungsten redisposition is because of the reaction with the halide gas that the bulb is filled with (iodine or bromine). This is natrually where the name "Halogen" comes from.

      http://en.wikipedia.org/wiki/Halogen_lamp#The_halo gen_lamp

      SirWired

  3. Better processing available by Anonymous Coward · · Score: 4, Funny

    Nobody uses the Titanium. Servers just use a MD Pteron if they want price-performance. And Onroe is just around the corner. Even cheaper Titaniums aren't worth the bother. Ntel can't drop the product line as a matter of face, but consumers just aren't buying it.

  4. Apples and oranges... by THotze · · Score: 4, Informative

    I always love articles like this when they compare the price of MAKING something with the price of SELLING something. Titanium's sold on a market sort of like oil... prices fluctuate based on demand more than they do based on the cost of production.... if the price of titanium is $40 this year, and was half as much last year... last year it was $20, and I'm SURE that people were making a profit selling that, so it was produced for probably a maximum of $15, probably more like $10/lb.

    So yes, this saves money... but it needs to be done in a large scale, 1st. I don't know how they come up with a cost/lb estimate that they consider to be more than VERY ball park estimate... $3 could be $6.

    Its substantial savings, but its not like we're going to be able to start planning our houses with titanium frames in a few years or anything. And that's assuming that demand doesn't keep skyrocketing above supply... in which case we could have the same price (or more!) regardless of how much it costs to produce titanium.

    Tim

    1. Re:Apples and oranges... by Martin+Blank · · Score: 2, Informative

      If, as they say, it can be completed with far fewer messy components, then it is more likely to be approved by a planning council. If that is the case, then there would be more factories built, increasing supply to better meet demand, and reducing the cost of the metal on the spot market accordingly.

      --
      You can never go home again... but I guess you can shop there.
    2. Re:Apples and oranges... by diablomonic · · Score: 4, Insightful

      I agree on the whole "announce a price when we havent even got a commercial demo plant" thing being stupid, but you seem to have missed something. According to the article, supply of titanium is currently very limited due to environmental concerns, while demand keeps going up (and, although I'm not a metalurgist, is there any reason that titanium couldnt replace steel almost entirely if it was cheap enough? thats a lot of demand!). This removes that supply problem entirely if it works of course.

      --
      watch "the money masters" on google video
    3. Re:Apples and oranges... by autophile · · Score: 3, Informative
      Well, according to this US gov't report on titanium prices, titanium has never been cheaper, and consumption is generally up. I could find any market for titanium futures, BTW. Not COMEX, not FOREX, nothing. I wonder why that is?

      --Rob

      --
      Towards the Singularity.
    4. Re:Apples and oranges... by PackerX · · Score: 2, Insightful

      This removes that supply problem entirely if it works of course.

      Let's think of this from a business standpoint: patent the process. Produce titanium in small numbers to prevent market saturation. Charge the same amount as everyone else, but at 10% the production cost. I don't see the savings being passed to the consumer anytime soon.

    5. Re:Apples and oranges... by Andy+Dodd · · Score: 4, Informative

      "and, although I'm not a metalurgist, is there any reason that titanium couldnt replace steel almost entirely if it was cheap enough?"

      In addition to being expensive, titanium is NOT easy to work with.

      --
      retrorocket.o not found, launch anyway?
    6. Re:Apples and oranges... by big+tex · · Score: 4, Informative

      "and, although I'm not a metalurgist, is there any reason that titanium couldnt replace steel almost entirely if it was cheap enough? "

      One word: welding.

      OK, I'm drunk, but bear with me. I weld best this way, so explanations should work as well.
      Welding steel is easy, really easy. It can be done outside, with nothing but a constant-current power source and some flux coated rods (SMAW,or 'stick' welding). This requires a minimal amount of skill. Move on to some better equipment, say wire feeders and constant-voltage machines, and we can weld sheet metal like it's nothing (GMAW) or lay down some structural fill in a hurry (FCAW or SAW). I can teach someone to weld FCAW in a few hours, provided they're smart enough not to burn themselves and not look at the bright lights without a shield.

      Titanium oxidizes like a little bitch. Basically, the largest part of welding technology is creative ways to keep oxygen, hydrogen, and those other things in the air away from the weld puddle. This can be done by flux (SMAW, FCAW, SAW), or by shielding gasses like CO2, Ar, He (GMAW, FCAW, GTAW). The only good way to weld titanium is by using TIG (GTAW). This is the most skilled, labor-intensive, slowest process going. I can lay down steel welds for bridge in pounds per hour, but titanium takes hours per pound.

      Now, more available titanium should lead to a titanium MIG (GMAW) process, but that's still small potatoes compared to SAW, GMAW, and it can't really be done outside. (I don't want to hear about the trailer you welded in your driveway. Try it two stories up in the wind, or on a barge, and we'll talk). To provide another point of reference, the high production and field processes (SAW, FCAW, SMAW) don't work with Aluminum, the 20th century's miracle metal, because they are flux-based and Aluminum doesn't do flux-based, flat out. Titanium will be the same way.

      In summary, titanium is kept in limited used in industry because it's hard to weld, not because it's expensive.

      --
      I think I need a new sig here.
    7. Re:Apples and oranges... by scheme · · Score: 4, Informative
      In addition to being expensive, titanium is NOT easy to work with.

      Just as an illustration, welding titantium in a normal atmosphere will cause it to become brittle. You need an inert atmosphere (e.g. argon) at the weld point and on the cooling joint to protect it. Any iron or steel contamination will also screw things up.

      --
      "When you sit with a nice girl for two hours, it seems like two minutes. When you sit on a hot stove for two minutes, it
    8. Re:Apples and oranges... by modecx · · Score: 4, Informative

      Just as an iustration, welding titantium in a normal atmosphere will cause it to become brittle. You need an inert atmosphere (e.g. argon) at the weld point and on the cooling joint to protect it.

      You're right, you need a good supply of argon to keep hot titanium from forming oxides or nitrides with atmospheric gas. It's an amazing thing, nearly *all* of the non-aviation titanium welds I've seen were not done right, and they have either an amber tint (not good) or a blue tint (really not good), and often a little rainbow of colors somewhere inbetween. The one exception I've noted is the race car industry. They actually do it right, and lives depend on it, so it's a good thing. The aftermarket parts for cars though? Holy shit, that stuff is ALWAYS FUBAR, and if it were to serve a purpose like strut bars for race/street cars, I imagine they'd crack if they were actually used for a few good hours. The funny thing is that I'm sure they think those colors are pretty!

      Anyway...

      --
      Constitutional rights may be respected, repealed, or modified; but they must never be ignored.
    9. Re:Apples and oranges... by modecx · · Score: 5, Insightful

      In summary, titanium is kept in limited used in industry because it's hard to weld, not because it's expensive.

      Just wanted to add to all of the great stuff you said by also pointing out that titanium is also a pain to work with in pretty much every other way. It's tough to machine, it's also a bitch to use as sheet metal--it's springy and not as malleable as steel or aluminum at room temperature. You've often got to heat it signifigantly if you need to make tight bends... Plus, all of that is compounded by the alloys of titanium which are even harder to use and form than the pure stuff.

      --
      Constitutional rights may be respected, repealed, or modified; but they must never be ignored.
    10. Re:Apples and oranges... by bigpat · · Score: 5, Insightful

      Let's think of this from a business standpoint: patent the process. Produce titanium in small numbers to prevent market saturation. Charge the same amount as everyone else, but at 10% the production cost. I don't see the savings being passed to the consumer anytime soon.

      Well the patent holder would want to maximise profit, so will have to produce enough to make it worth while. So, this would increase supply at least somewhat and thus likely decrease prices. And it is very likely that the patent holder would just want to license the process to current companies instead of actually getting capital to start their own plant. So, they would have incentive to license the process to as many companies as possible. At which point it only takes one company to decide that it needs to increase production to increase market share in order to have an effect of lowering prices. Of course, there can always be anti competitive price fixing, but that is illegal and can't go on forever.

    11. Re:Apples and oranges... by vijayiyer · · Score: 3, Informative

      Titanium, while strong per unit weight, has a relatively low modulus of elasticity, making it "flexible". Thus it is often not well suited to applications requiring high rigidity. Steel is more rigid per unit volume, and aluminum per unit weight.

    12. Re:Apples and oranges... by vmcto · · Score: 2, Funny


      This quite possibly the most informative post I have ever read on Slashdot. Seriously.

      Please endeavor to learn other areas of technology so you can continue to inform me.

    13. Re:Apples and oranges... by modecx · · Score: 2, Interesting

      Oh, the colors are beautiful, I can't disagree. I've seen paintings from the 70s that apparently used an electrified brush that acted as anode, and the technique would build an oxide layer on the surface of the Ti. The really cool thing was that by varying the thickness of the oxide layer, any color from white to yellow to blue to dark brown could be achieved because of the way light plays with titanium oxide... And there were no other compounds but Titanium and Titanium Oxide used for the whole painting! I've always been impressed with that stuff.

      --
      Constitutional rights may be respected, repealed, or modified; but they must never be ignored.
    14. Re:Apples and oranges... by LunaticTippy · · Score: 2, Insightful
      The company might make more money selling 10 times as much at 1/5 the price.

      Lower profit margin but more profit.

      --
      Man, you really need that seminar!
    15. Re:Apples and oranges... by John+Hasler · · Score: 2, Interesting

      > Ti is an American strategic resource, none of which is found in the U.S.

      Titanium is the 9th most common element in the Earth's crust and is found everywhere, including the US. While the US presently imports titanium (from Canada and Australia, for example) domestic production could easily be increased.

      --
      Warning: this article may contain humor, sarcasm, parody, and perhaps even irony. Read at your own risk.
  5. Great for chainmaillers by Kabuthunk · · Score: 4, Interesting

    Sweet! I'm sure this will likely have a significantly higher impact on pretty much all products as is, but this will affect me in a slightly different way. I'm one of the few that make chainmail as a hobby. Titanium chainmail is significantly lighter, rusts less, etc, etc. Significantly better for metalcraft than stainless steel or galvanized steel or anything like that in my opinion.

    So, having cheaper working materials = excellent for people like me :}

    --
    Planet Zebeth - Metroid with a twist
    1. Re:Great for chainmaillers by PainBreak · · Score: 2, Funny

      Sweet deal, that's what.. +4, +5 against illegal immigrants?

      No, seriously. Who would buy titanium chainmail? Some pretty serious D&Ders in here...

      Oh well, at least it'll drive down the price of the MacBook.

    2. Re:Great for chainmaillers by CracktownHts · · Score: 2, Interesting

      Forgive me for commenting on something I know next to nothing about, but would you actually be able to work with titanium the way you work with whatever you normally use (I assume steel)? I believe Parker (the pen company) had to cancel their titanium pen (the T-1) in the early 1970s because it was too difficult to work with. They only made it for a few months and the surviving ones trade hands for around a thousand bucks these days.

    3. Re:Great for chainmaillers by misleb · · Score: 2, Funny

      Normally I hate getting chain letters, but at $40/lb, it might not be such a bad deal. I'm not worried about bad luck so I'd just sell them when the price is high. Shall I email you my snail-mail address?

      -matthew

      --
      "THERE IS NO JUSTICE, THERE IS ONLY ME." -Death
    4. Re:Great for chainmaillers by Nefarious+Wheel · · Score: 4, Funny

      Yep, I've got a friend who makes maille too, says the same thing (unless you're him, K?). I tried to sell him on the idea of Unobtanium, but he said his customers prefer either Titanium or Expensium. Hardtoobtainium is pretty good too, but suffers from consistency of supply issues.

      --
      Do not mock my vision of impractical footwear
    5. Re:Great for chainmaillers by Wooster_UK · · Score: 2, Funny
      It's also good when you need a knife that can operate in an environment where you can't use tools that react to magnetic fields.

      Like airports?

  6. Oh, cool... by __aaclcg7560 · · Score: 2, Funny

    Now I can buy the colorful lights for the warp drive engine instead spending all the money on plating the hull with expensive titanium. Warp 1 has never been so cheap!

  7. Steel Age by pete-classic · · Score: 4, Funny

    Thank God! I thought the Steel Age was never going to end!

    -Peter

  8. WOO HOO! by GrumblyStuff · · Score: 5, Funny

    Titanium foil hats HERE WE COME!

  9. Re:Whoo Hoo by Tribbin · · Score: 2, Insightful

    For the harddrive and other parts not to break, the laptop better have some sort of buffer to break the fall instead.

    --
    If you mod this up, your slashdot background will turn into a beautiful sunset!
  10. Oblig. Response by Dachannien · · Score: 2, Funny

    I say your 3-cent titanium tax doesn't go too far enough!

  11. Awesome! by eric434 · · Score: 4, Informative

    I took Sadoway's class last year. Awesome guy -- this is right up his alley (making things more environmentally friendly).

    Here's a PDF presentation on the process:
    http://web.mit.edu/dsadoway/www/MOE_Ti.pdf

    --
    This .sig temporary until a better .sig can be constructed.
    1. Re:Awesome! by Hoi+Polloi · · Score: 2, Insightful

      Environmentally friendly isn't just for making tree huggers like me happy, it generally means the elimination of waste, expensive materials, and extra processing that means greater efficiency and lower costs. Chemical plants and foundries are full of nasty processes that can kill or injure employees or even neighbors. Then there are all of old plants that have left toxic swaths of land behind, usually in areas that once were the outskirts of cities but today are smack-dab in the middle of suburbs. The cost of cleaning these up is generally left to the public (tax $) since usually the companies have long since folded. Researchers like Sadoway are helping make industry not just better for the environment (which includes us) but it is also good for profits.

      --
      It is by the juice of the coffee bean that thoughts acquire speed, the teeth acquire stains. The stains become a warning
  12. Re:Not exactly by timeOday · · Score: 2, Informative
    I don't see titanium soda cans or anything on the horizon (bikes, probably. Planes... maybe partially.)
    You gotta be joking. Titanium has been used in bicycles for years, and in aerospace for decades. So the question is not whether titanium will be used, but how much more widely it will be used.
  13. One of my first jobs by IamNotAgeek · · Score: 5, Interesting

    I worked at a titanium manufacturing plant where I analyzed samples for nitrogen contamination. Even though it was a pretty low level repetitive job, I still felt like a scientist working in a lab wearing a lab coat and the head chemist was a guy from Sweden named Jurgen (?sp). I also remember that the titanium tetrachloride was so volatile that just a spoonfull released into the atmosphere would create a huge white cloud and the fire department would show up and management would have to fill out an incident report. Good memories, except for the time I got hydrofluoric acid on my fingers, very painfull, and of course when I accidently breathed in some vapors and had frequent nosebleeds for several years afterwards.

    --
    All generalities are dangerous except ones that start with "All /.ers"
    1. Re:One of my first jobs by Beltonius · · Score: 4, Informative

      I'm currently working at a company specializing in Ti and Ti alloys/composites.
      I have little to no faith in this actually producing anything substantial within the next several years.

      Why? I have read about this same guy pitching his process for the past several years, and my company has a file on him going back almost a decade; he's been saying his process will yield results 'soon' for far too long for me to readily believe him.

      Last year, even, I read a presentation he gave, and it consisted of little more than a brief high-school chemistry explanation of electrolysis (which is all this is, same process that produces hydrogen and oxygen from water) and stating a hope that they will build an experimental cell soon. Apparently he's gotten that far, but 200 mg aren't going to help much to combat the currently sky-rocketing Ti prices.

      And yes, they are very high right now. Half our work is focused on improving Ti recycling processes so that scrap can be used more widely; the rest of the work is biomedical applications where cost is not an issue.

      The point is: Yes, if this works it could mean a much cheaper/environmentally friendly (I'm a little doubtful of this; yea, there won't be concentrated TiCl or Cl gas lying around, but it's an electrolytic process, it will use lots of electricity, and that will produce extra waste) process. This is a conceptually simple process; basically it requires experimentation to get the parameters right. He has spent very little time actually experimenting.

  14. For those that took 3.091 by Zackbass · · Score: 2, Informative

    Looks like Sadoway may just be on his way to that Nobel prize he's been obsessed with. :P

    For those that aren't familiar with MIT's most pimp chem prof you can enjoy a full semester of his lectures right here: http://ocw.mit.edu/OcwWeb/Materials-Science-and-En gineering/3-091Fall-2004/LectureNotes/index.htm

    --
    You gotta find first gear in your giant robot car
  15. Re:Aluminium? by Deadstick · · Score: 5, Informative

    Twice as strong vs 1.6 times as heavy, higher melting point, better resistance to corrosion and fatigue.

    rj

  16. Re:Not exactly by DeadChobi · · Score: 5, Insightful

    Not to be pedantic or anything, but you would actually fare worse in a car wreck in a Titanium car, as it wouldn't give as readily as steel. The more time the impact lasts, the less force the passengers experience. So in a wreck between a titanium Geo Metro and a steel Geo Metro, the passengers of the titanium car could be extracted faster but would be more likely to die. There are more considerations to engineering than just weight and efficiency. If something cant get you from point A to point B as safely as the less-efficient alternative, than the less-efficient alternative bears at least some looking into.

    --
    SRSLY.
  17. Re:Aluminium? by th77 · · Score: 2, Funny
    I think Bender put it best:


          Bender: I'll miss you, Leela. I know you're just a carbon-based
                      life-form, but I'll always think of you as a big pile of
                      titanium. [Sniffles]
              Fry: What Bender means is, you're really brave, and smart and
                      beautiful and a great friend.
          Bender: Just like titanium. [Sobs]
            Leela: This is all a big load. I was the one trying to save
                      the Popplers. You [Points at Fry] were sucking them
                      down like the fat hog you are, and you [Points at
                      Bender] were stepping on them for fun. You both should
                      be in here instead of me.
          Bender: Someone's acting awfully aluminum.
    --
    Your favorite sig sucks
  18. Re:Not exactly by Eccles · · Score: 4, Insightful

    Not to be pedantic or anything, but you would actually fare worse in a car wreck in a Titanium car, as it wouldn't give as readily as steel.

    So why don't we make cars out of cotton wool or balsa wood?

    You want crumple zones, yes, but surrounding a stiff inner structure. That's why doors have stiff cross-beams in them, race cars have roll cages, etc. No titanium for the crumple zones, sure, but you want it for the roll cage.

    --
    Ooh, a sarcasm detector. Oh, that's a real useful invention.
  19. Re:Aluminium? by r00t · · Score: 2, Informative

    Titanium doesn't corrode as much, and it's non-poisonous. It's one of the few things that is safe to implant in a human body. The oxide is use to make foods white.

    Meanwhile, aluminum has issues. At best it makes your soda taste yucky after a while. Maybe it contributes to Altzheimer's disease. If you cook tomatoes in an aluminum pan, you'll get holes in the pan.

  20. Chainmail by Mark_MF-WN · · Score: 3, Interesting
    You make chainmail? Truly, a geek among geeks. You ought to be careful -- if the amount of geekosity in a given area of space gets too high, it can collapse into a dork-hole.

    Just jeffin' ya. Sounds like an interesting hobby. Know anyone who makes swords? I've heard that the metallurgy that goes into a modern metal blade is quite impressive, and that modern swords -- despite being made almost entire by hobbyists -- are far superior to the swords of antiquity.

  21. Re:Ad problem. by Namronorman · · Score: 2, Informative

    Or eyewear. Titanium: Light, durable, and not too many people that I know of are allergic to it because it's low in allergens. In fact, I wear a pair of DKNY Titanium Frames with "Featherwates" lenses... 0.7 ounces, or roughly 19.84 (ooh spooky) grams!

    --
    $fortune
    Tomorrow has been canceled due to lack of interest.
  22. Re:Ad problem. by Doppler00 · · Score: 2, Interesting

    Then why not get a ring made out of Tungsten? It's pretty expensive too and twice as dense as gold.

  23. Re:Not exactly by kfg · · Score: 2, Informative

    You gotta be joking. Titanium has been used in bicycles for years, and in aerospace for decades.

    Bought a titanium bike frame made by Teledyne in '74. They used the same facilities to build the bike that they had developed for making Space Shuttle bits. Nobody else has yet made a titanium bike quite like this one because Teledyne was able to make everything, such as tubing and fork crowns, custom in house, without relying on purchasing parts. I miss that bike. Traded it for a steel Cinelli. Took 28 seconds of my 10 mile TT PB the first time I rode it. Stiffness never was one of the virtues of the Teledyne, but it rode like a dream. The best long hauler I've ever ridden. Could have used some damping material injected into the fork or something. It could flex sympathetically on washboard roads.

    Been thinking about getting a Spectrum, which is actually made by Merlin to Tom Kellog's specs, but I've known Ben Serotta since he was a 21 year old kid opening his first bike shop, and he started making titanium frames awhile ago and I figure I should give them look over.

    Shit's old hat.

    KFG

  24. Re:Aluminium? by corngrower · · Score: 3, Informative

    And it maintains it's strength at high temperatures. Steel tends to weaken quite a bit as it gets hot.
    This is why titanium is used in things like the turbine blades of jet engines, and the leading edges of supersonic aircraft.

    About two years ago the folks at Oxford University developed a process for producing the metal from
    its common ore more cheaply that the process commonly in use. I think it's now being tested
    commercially at at least one company here in the U.S. I'ld bet that the MIT process is very
    similar to the one developed at Oxford.

    Titanium oxide is commonly used as a white pigment for paints.

  25. The Sheffield and it's aluminum superstructure by erice · · Score: 2, Informative

    The Sheffield was lost in the Falkland Islands conflict. It is popularly beleived that this was due to the alumiminum superstructure catching fire. However, it seems that the Sheffield did not have an aluminum superstructure and the Sheffield was lost for other reasons.

    http://www.hazegray.org/faq/smn6.htm#F7
    http://www.alfed.org.uk/templates/alfed/content.as p?PageId=111

    It is also worth noting that any metal can catch fire if you get it hot enough, even steel.

  26. titanium anti-corrosion coating by cyfer2000 · · Score: 2, Funny

    Mean while the price of titanium anti-corrosion coating will increase from $3 to $40 per pound.

    --
    There is a spark in every single flame bait point.
  27. Scotty? by shoolz · · Score: 2, Funny

    Was it he who dropped this info to the startup? Did he also drop the transparency trick too? Please say yes.

  28. Re:Aluminium? by Frangible · · Score: 5, Informative

    Several reasons:

    1. Insulation; titanium is less condutive of heat/electricity. This can be a benefit or detriment depending on the application.
    2. Strength; the same amount of Ti/Al alloys to support a specific load can be made with a lighter weight of Ti. An equal volume of Ti is heavier than Al, though.
    3. Fatigue life; titanium, like iron, has infinite fatigue life. Aluminum does not. What this means is you can make a spring from Ti but Al will fail if repeatedly stressed.
    4. Corrosion; titanium is more corrosion resistant than Al because it oxidizes rapidly in contact with air
    5. Social reasons; titanium has significantly more percieved value than Al, moreso than the material differences. Further Ti has a unique color as well.

    Sometimes aluminum will still be better; in many applications the relative strength difference doesn't matter and thus a lighter equivalent volume of Al is advantageous. Also, the high conductivity of Al is a good thing in many situations.

    The most common Ti alloy, Ti-6Al-4V, actually has 6% Al in it.

  29. Re:1,700 degrees Celsius by erice · · Score: 2, Funny

    Unless you were to construct a nuclear power plant to directly heat the titanium oxide mixture using the reactor pile itself.

    Unfortunatley, the world market for radioactive titanium is rather small.

    You will need some sort of high temperature heat exchanger that will not, itself, become radioactive. I don't think water will do. Actually, you may have trouble just running the reactor that hot. I think you will need a gaseous core reactor.

    http://gif.inel.gov/roadmap/pdfs/non-classical_rea ctor_systems.pdf

    That's rather beyond the current state of the art.

  30. modern swords by bodrell · · Score: 4, Interesting
    Know anyone who makes swords? I've heard that the metallurgy that goes into a modern metal blade is quite impressive, and that modern swords -- despite being made almost entire by hobbyists -- are far superior to the swords of antiquity.
    You weren't addressing me, but regardless . . .

    My brother knows one of these modern-day master swordsmakers. One of the new tricks is to use high quality braided cable as a starting material. You flux it or something, then heat and pound. Like starting out with a Damascus or samurai style laminated blade, but woven instead of folded. Sounded pretty cool to me.

    --
    Si la vida me da palo, yo la voy a soportar Si la vida me da palo, yo la voy a espabilar
    1. Re:modern swords by LordNightwalker · · Score: 3, Interesting

      Yup, I helped a friend make small strips of that for use in knifemaking. It's relatively easy; all you need is a gas forge (he helped me make mine, there's not much to it actually), an anvil, borax, steel cable, a welding machine and some large forging pliers to hold the hot piece of metal while beating it with a hammer. Oh, and you need a decent hammer too; one with hardened faces; soft ones won't do.

      The process is simple; you tie off one end of the cable with some wire, before the point where it starts to untangle. You then cut off the untangled part relatively close to the point where you tied it off. Then weld the end fixed, so it won't untangle again. Repeat the same process a bit down the cable; how far depends on how long a strip you want to create. You then fire up your gas forge, wait for it to heat up completely, and just put the rod in. Wait untill it glows the right shade of red, take it out of the fire, then either throw borax on it using a large salt-shaker type of thing, or just roll the rod into a large bowl of borax. This will form a layer of borax around the rod. Back into the forge, the borax will seep between the strands of the cable, eating away at the impurities contained within. Repeat this process a couple of times... actually, a lot of times... The borax will drip into your forge, and it will eventually eat through the hull, so you better use one with a decent ceramic coating to prevent or slow down this process. Anyway, after you've repeated this process enough times, it's time to start welding the cable into a proper strip.

      Make sure you wear decent protection, because when you hit that cable with your hammer, borax might shoot out, and hot borax will leave wounds that will ooze puss for days when it hits your bare skin. Even if you don't care about a couple of scars and some temporary discomfort, at least be smart enough to wear eye protection. Great, let's get on with it. Take the rod out of the forge, it's best to work in pairs so one can hold it with the pliers while laying it on the anvil, while the other smashes away at it with the hammer. Start beating it at one end, and do a couple of centimeters at a time. At first your goal is to create a rod with a square cross section; once you have that, you repeat the process, this time flattening it into a strip. Every time the metal cools off (starts glowing dimmer), put it back in the forge, and when it's heated up enough again, repeat the process, but start where you left off, slowly working your way from one end of the rod to the other. You'll notice that the metal will warp under the blows of your hammer; this is perfectly normal. Just turn it around, and you can smash it straight again. First hammer it on four sides to a square cross section, when you've covered the whole rod, repeat but this time beating it only on two sides so you end up with a strip.

      Eventually, you'll end up with a rudimentary strip of cable damascus a couple of millimeters thick. Flatten it with a belt sander or whatever you have at your disposal, cut it into a straight strip, and you have a nice piece of cable damascus for stock removal production of knives (meaning you file the shape of the knife out of the bare strip, leaving the edge about 1mm in thickness, heat treat it, then polish and sharpen it). Of course you don't have to go the stock removal route; if you're more inclined to actually forge your knife/sword out of the rod, then work towards the shape you want for your knife/sword instead of a straight strip, and finish it off by belt sanding it to its final shape, heat treating it, then polishing and sharpening it.

      You can find lots of info on knife/sword forging online if you google around a bit, and there's tons of books written on the subject. I'm just lucky I have a couple of friends who inducted me into this obscure art, though I wish I had more time to actually finish the designs I started... ;)

      For those interested in this kind of stuff, a good starting point might be the knife makers forums on bladeforums.

      --
      Install windows on my workstation? You crazy? Got any idea how much I paid for the damn thing?
  31. Re:Aluminium? by bodrell · · Score: 2, Interesting
    Meanwhile, aluminum has issues. At best it makes your soda taste yucky after a while.

    Sorry, but there's no direct contact between the soda and the metal. The cans are lined with a thin coating of some sort. Otherwise the soda would indeed dissolve the can.

    In case you're doubting, here's the experiment that showed me what's up: Wash two soda cans. Score the inside of one of the cans, just a tiny scratch going all the way around, to penetrate the protective coating. Then fill both cans with an acidic solution and let them sit around a few hours. Dump out the acid, and you can tear apart the scored can as if it were paper. Chemistry magic trick.

    --
    Si la vida me da palo, yo la voy a soportar Si la vida me da palo, yo la voy a espabilar
  32. Re:like aluminum? by Forbman · · Score: 2, Informative

    No, what made Aluminum(aluminium) valuable was whoever figured out how to cast it in a mold without leaving the funky wavy lines in the casting where the aluminum didn't "flow" against the mold completely. Before that, it was a curiosity, because all those funky mold defects really weakened it even more.

  33. Re:Aluminium? by r00t · · Score: 2, Interesting

    You can tear apart an unscored can as if it were paper. They are really thin these days.

    Steel was once used, but we had to switch to aluminum because Coke ate through the steel too fast.

  34. Inexpensive Russian Titanium.. by thesupraman · · Score: 4, Informative

    Of course they are carefully looking at the AMERICAN price for titanium production..

    It is much much cheaper in Russia, as it is basically produced as a side effect of steel production there due to the different ores available.
    Most significant titanium users source their titanium from Russia, and there is little interest in other sources as Russia just has the right ores anyway.

    Oh well, good try though.

    1. Re:Inexpensive Russian Titanium.. by A+beautiful+mind · · Score: 2, Informative

      Yeah I remember the soviet-era bartel processes in my country. Hungary would sell bauxit ore to the SU, and receive something else. The explanation was that Hungary didn't have good enough facilities to manage production, but of course the soviets just wanted the titanium in that bauxit.

      On the tangent a bit, the current hungarian PM owns a lot of those bauxit mines - they've been used as a toxic dump since the last decade or so. Shady dealings.

      --
      It takes a man to suffer ignorance and smile
      Be yourself no matter what they say
    2. Re:Inexpensive Russian Titanium.. by John+Hasler · · Score: 2, Insightful

      > It is much much cheaper in Russia, as it is basically produced as a side effect of
      > steel production there due to the different ores available.

      The cost of the ore is a minor part of the cost of production of titanium metal.

      > Most significant titanium users source their titanium from Russia, and there is little
      > interest in other sources as Russia just has the right ores anyway.

      More likely it's th lack of pollution controls.

      --
      Warning: this article may contain humor, sarcasm, parody, and perhaps even irony. Read at your own risk.
  35. Re:Ad problem. by afidel · · Score: 4, Interesting

    Actually that durability can be one of the biggest problems with Titanium rings, trauma sheers can't cut them so if you have any kind of severe sweeling problem there's a good chance of digit loss because the ER won't be able to remove the ring. That and the fact that my father gave me his ring are the reason I didn't get a titanium one. (He hadn't worn his in 20 years due to working with the machining industry and seeing several people lose their hands in machines due to wedding bands).

    --
    There are 4 boxes to use in the defense of liberty: soap, ballot, jury, ammo. Use in that order. Starting now.
  36. All a matter of perspective by Dutchmaan · · Score: 2, Insightful

    "Using technology developed at MIT, 4-person startup Avanti Metal hopes to reduce the cost of producing Titanium from the current $40 per pound to a mere $3."

    What business people read:

    "Using technology developed at MIT, 4-person startup Avanti Metal hopes to increase the profit of producing Titanium by $37 a pound!"

  37. Yet another non-answer to a non-problem by Ancient_Hacker · · Score: 2, Informative
    Um, no. These guys should have talked to a mechanucal engineer, or metallurgist before going off on this quest for cheqaper titanium.

    The cost of producing Titanium isnt even the 5th most prominent reason that it's not used more. Here's a few more significant reasons:

    • Steel is about $40 a ton, and can be blended and treated for a wide range of strengths, flexibility, ductility, and other desireable properties. Titanium costs 100 to 1000 times more, and isnt as versatile.
    • Steel and other metals can be heated up, hammered, forged, drilled, milled, scarfed, ground, chamfered, put through dies, bent, hammered, case-hardened, sputtered, peened, and plated. Over and over again. Titanium doesnt like most of those processing steps.
    • Most metals gladly alloy themselves with various useful elements, such as copper, molybendum, chrome, carbon, etc, to improve their strength, ductility, or springyness. Titanium doesnt.
    • Most metals tolerate a little variation in processing time, temperatures and rates of change. Titanium doesnt.
    • Most metals can tolerate being splashed with various environmental contaminants, like water, road salt, acid rain, paints, glues, waxes, etc. Titanium is so sensitive to contaminants, just *touching* a titanium bolt with a chrome or cadmium-plated wrench is enough to make the bolt very brittle! Just writing on a titanium sheet with a (horrors!) felt-tip marker is enough to embrittle the sheet.

    given the choice of using steel or aluminum, versus using titanium at 100x the cost, 10x the likelyhood of the part breaking if touched by the wrong stuff, most engineers will go with anything but titanium.

  38. Re:Ad problem. by RockModeNick · · Score: 4, Informative

    Thats incorrect. Any good steel shear, including the wiss tinsnips in my tool drawer, will cut a titanium ring apart easily. Titanium may have a better strength to weight ratio than steel, but steel is much harder at simular or even smaller actual size and as such will easily shear titanium.

  39. Re:Where do you find these metals (or ores)? by Hoi+Polloi · · Score: 2, Insightful

    I'm no geologist but from what I gather for metals to be profitably mined requires deposits with high enough concentrations of the metal to make it worth while. Iron can be found almost everywhere but in certain places it is so concentrated that it is much cheaper to mine and extract (i.e. hematite deposits around the US Great Lakes). Many metal deposits come from place that have experienced volcanic activity in the past where superheated water has carried metal compounds in solution through cracks in rocks. Ultimately you get metal ore "veins". The copper deposits in Cyprus are an example of this . They may have been fundemental to the advancement of civilization in that area. Another hot spot for copper is the Andes which are also riddled with volcanoes. Iron deposits are even older and many were formed by the reduction of iron in water when the first oxygen producing bacteria and algae appeared on earth. The iron deposits around the Great Lakes and in Sweden are in very old rocks. Sweden also happens to be a good source for rare earth metals.

    Diamonds are another material that depends on volcanic activity but it requires powerful upwellings of material from near the upper mantle to bring them up. These deposits either have to be mined (South Africa) or can get eroded and washed into river deposits (West Africa).

    You won't get metallic lumps of iron (except in meteorites) due to the ease it oxidizes but you can find lumps of copper, silver, and gold in things like quartz viens.

    I think the UK's iron industry is not due to the location of Iron (they can get that from Sweden) but due to the coal deposits in Wales that provide the other part of the equation for smelting, energy.

    Personally, one thing I'd like to know is why certain places have deposits of uranium. Why just that and not, say, copper too? How did it become seperated from other ores to such a degree?

    --
    It is by the juice of the coffee bean that thoughts acquire speed, the teeth acquire stains. The stains become a warning
  40. Re:Ad problem. by smellsofbikes · · Score: 2, Informative

    Steel *can* be harder, but it isn't necessarily.
    Pure ti ranges from 35,000 PSI to 100,000PSI yield strength, depending on the route of manufacture. Some ti alloys go as high as 250,000PSI. (Converted from the article's 1725 MPa datapoint.)
    I've found references to steel having a yield strength in excess of 2000 MPa, but Wikipedia claims that titanium alloys are harder.

    With all that said, I cut ti with a hacksaw, and snips for sheet, on a regular basis. It's no problem. It's *much* harder to cut than gold or silver, and somewhat more than platinum, so *standard* ring-cutting tools might not, well, cut it, but any jeweler can get a sawblade through the inside of a ti ring and cut it in under half a minute.

    --
    Nostalgia's not what it used to be.
  41. Re:Ad problem. by weiserfireman · · Score: 2, Informative

    I work in a machine shop and I am an EMT.

    We work with Titanium all the time in the shop. We have learned what works and what doesn't. Some of our machinists actually like working with Titanium. They tell me for instance, that it turns nice on a lathe for them. Not gummy like aluminum.

    Cutting a ring of someone's finger in an ER is a different story. Ring cutters were designed with soft metals, like gold and silver, in mind. ER can pop a normal gold wedding band quick as a flash with a ring cutter. A platinum or titanium band is significantly harder than gold or silver and their ring cutter may not work. True, the maintenance guy may have something in his toolbox that will work, but your nurse or doctor in the ER may not think about it. Also remember, ring cutters are designed to protect your finger from the blade as your ring is cut off. The maintenance guys wire cutters aren't.

    There are ring cutters on the market that can cut titanium, but they aren't common in hospital settings yet. The old manual ring cutters are $10-20 each. The new electric ones are an order of magnitude more expensive.

  42. Re:Yet another non-answer to a non-problem by theycallmeB · · Score: 2, Insightful

    Unless they work in the aerospace industry, in which case every extra pound of airframe weight costs $500 to $1000 a year to lug around for the rest of the airplane's service life (up to 40 years), about the same cost increase for spacecraft expect with those you pay in one lump sum at launch time. Still, titanium use is limited by cost and supply, though by limited I mean about >10% by weight of the upcoming Boeing 787, slightly less (by percent weight) in an Airbus A380.

    A titanium part that is built right weighs in at a fraction of a comparable steel part. The cost differences are reduced somewhat because aircraft tend to use stainless steel to get some corrision resistance whereas titanium is essentially corrision-proof in aircraft applications (stainless steel and aluminum are not) and must not be quite as sensitive as you make it seem (or is treatable with proper unlimited-life coatings, I honestly don't know, AE not MME), otherwise they could never let in out on the same ramp as the idiots who like to spear aircraft with the bagagge loaders.

    Now what could make this a non-answer to a non-problem is that parts that migrated to titanium years ago for strength/weight purposes are not migrating to carbon fiber composites (>50% of a 787 by weight), though not into areas requiring high temperature operation.

  43. Re:Ad problem. by smellsofbikes · · Score: 2, Interesting

    Rockwell numbers are kind of arbitrary. What the hell does 57 on Rockwell C mean in real-world terms? Think about what Rockwell and the like test: you apply a known force to a ball or diamond of a known cross-section and measure the resultant deformation. Force per unit area... is PSI. Or KPa. Those are non-arbitrary terms, or at least they're one level less arbitrary than Vickers or Rockwell numbers. "The yield strength in tension is about 1/3 of the hardness" and yield strengths are measured in KPa (if you're in a civilized country) or PSI (otherwise).

    --
    Nostalgia's not what it used to be.