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New Solar Panel Technology Gaining Momentum

jessiej writes, "Even though copper indium gallium selenide (CIGS), a newer type of solar panel, is less efficient than its silicon counterpart, millions are being invested in manufacturing. From the article: 'CIGS panels use far less raw material than silicon solar panels and the factories themselves cost less to build,' $25 million compared to $230 million in one example. These types of panels could even be made into a t-shirt logo."

31 of 181 comments (clear)

  1. I can see it now by also-rr · · Score: 5, Funny

    A debian logo on your shirt powering a small bewulf cluster of wearable computers computing Pi to many, many decimal places. What a talking point! How will the girls resist!

    1. Re:I can see it now by Anonymous Coward · · Score: 4, Funny

      They won't need to resist, they would be busy with solar powered toys of their own...

    2. Re:I can see it now by Simplulo · · Score: 2, Funny

      more easily than men resist women's old-fashioned silicon-based enhancements.

    3. Re:I can see it now by Herger · · Score: 2, Funny

      It's a great idea, until the girls start throwing themselves at you, blocking the panels and crashing your cluster. New tech is so fraught with peril!

  2. Silicon shortage? by in2mind · · Score: 2, Insightful
    FTA,
    Shortages of silicon have crimped sales in the solar industry.

    I thought silicon was abundant ..

    1. Re:Silicon shortage? by Zarniwoop_Editor · · Score: 4, Informative

      It is. Unfortunatly, to build solar cells you need crystalline silicon. These crystals have to be carefully grown and are quite expensive to produce.

      There is more info at ... http://www.howstuffworks.com/solar-cell.htm

      --
      - F1 NEWS
    2. Re:Silicon shortage? by hankwang · · Score: 2, Interesting
      I thought silicon was abundant ..

      I suppose it is the production capacity of the 99.99999% purity grade silicon they're talking about.

    3. Re:Silicon shortage? by Anonymous Coward · · Score: 3, Informative

      Yes. Si is the second most abundant element on the surface of the Earth, next to oxygen.

      And that's the crux of the problem too. Silica (SiO2) is abundant (quartz sand), but SiO2 is a BITCH to break apart (the usual reaction is with carbon in an almost 2000 deg C arc furnace), you have to partially melt it or transform it into gaseous silanes (e.g., HSiCl3) to remove impurities, and then you have to grow the Si crystals in high temperature furnaces in very clean conditions. Some of the impurities have to be reduced to the parts per billion range for some applications. It is an energy-intensive and expensive process, and the demand for Si for computer chips cuts into supply for solar cells.

      Here's some info on making polycrystalline silicon, and wafer production, including crystal growth. All of that happens before the solar cells or chips get made.

      If we lived on a planet without any oxygen, maybe it would be easier :-)

    4. Re:Silicon shortage? by theshowmecanuck · · Score: 4, Informative
      but SiO2 is a BITCH to break apart (the usual reaction is with carbon in an almost 2000 deg C arc furnace)

      You are partially right... I worked on a project where we were testing a new arc furnace design for smelting silicon (it was a DC furnace as opposed to AC). Wearing one of my hats on that project I wrote a computer model program of the mass and energy balances that took place in the furnace.

      My application of the physical chemistry and calculus have passed the haven't used it/lost it point, but if I remember some of the basic things correctly... basically yes it is a real bitch to actually split the silicon (Si) from the oxygen (however, silanes are not involved). It takes a tremendous amount of energy to do so. One of the reasons silica (SiO2) is so abundant is that it is so stable. Being so stable means that it is hard, thermodynamically and every other way, to break it apart. So while Silicon (Si) in the form of Crystaline Silica (SiO2, e.g. quartz, silica sand) is VERY abundant, Si on its own is VERY VERY rare. SiO2 is so much more stable than Si.

      • Typically the furnace at its hottest point will be around 5000 degrees C (a carbon monoxide plasma forms there).
      • The silicon metal at the furnace spout where it is tapped/poured from, is typically around 1400 - 1500 degrees C
      • The reaction is SiO2 + 2C -> Si + 2CO
      • The intermediate product includes SiO (silicon monoxide which only exists in gas phase at greater than 1400 degrees C) and SiC (silicon carbide).
      • Most of the actual reaction steps forming the silicon (from silica) happen in gas phase at obviously very high temperature.
      • The actual smelting process (chemically) is similar to smelting iron: reducing the base metal (removing the oxygen) using carbon as the reducing agent at very high temperatures. (Silicon higher than for iron.)
      • There are no silanes involved as you describe in the initial smelting process from SiO2 to Si.
      • With respect to the parent post about silanes: they are possibly created/used later if the silicon needs to be refined to semi conductor grade, but I don't know. I was not involved in this aspect of silicon refining, which is highly proprietary, and which I believe is (or was) protected by laws relating to national security).
      • The greatest use of silicon is not in electronics. It is in the making of synthetic rubber. e.g. silicone
      • Technically silicon is a metalloid... at room temp: non-conductive, 1200 - 1400 C, conductive, for example.
      • When it cools, it forms a metallic silvery solid that is very brittle, similar to bituminous or anthracite (hard) coal... which makes sense as it is in the same family as carbon. If you hit it with a hammer it breaks or shatters.
      • The main raw materials in smelting silicon are typically quartz, coal, and charcoal (and sometimes other more porous carbonaceous materials to improve gas permeability in the reaction bed. The coal and charcoal is for carbon content, not heat. The quartz needs to be quite pure... e.g. no or very very little iron etc in it (brown stains on quartz are typically from iron... not from wayward hikers.
      • In most silicon furnaces the top of the furnace mix is exposed to atmosphere, and is so hot the carbon monoxide (CO) off gas burns to CO2, which is inert/non poisonous (CO is as flammable as methane, but it is so poisonous that it is not practically safe to do so). Granted the large volumes of inert CO2 created is bad, but better than highly poisonous CO.
      • An interesting point is if you spill enough molten silicon onto a piece of iron/steel so that the iron starts to melt, the resulting reaction forming Ferro Silicon is so hot that it keeps reacting until one of the reactants is used up (e.g. until no more silicon or iron), or it hits enough of a heat sink to cool to solidification. We had a spill once that took out about 10 yards of the rail tracks some of our equipment rolled on, as well as some other pieces of steel equipment. All of which we needed to re-install or re-build in a couple of hours. Quite exciting, and a huge pain in the ass.
      --
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    5. Re:Silicon shortage? by arminw · · Score: 2, Interesting

      ....Solar energy is just a temporary feel-good stopgap for the naive......

      Perhaps not solar energy per-se, but just the idea of converting light directly into electricity with expensive to produce materials. Plants have perfected the process of capturing solar energy and converting it into useable energy forms. It seems utilizing this tried and true process to make some kind of bio-fuel would be a preferable way to go for large scale energy production, especially for transportation. Making a flexible fuel, such as bio-diesel from plant material grown on land or sea and then using the existing fuel handling and distribution infrastructure is a more viable way to go for now. Perhaps, 20 years from now (historically ALWAYS 20 years from now) local fusion reactors will become the means of providing abundant energy. Until then, using the fusion reactor which is 93 million miles distant is the only practical long term alternative to the fossil fuels.

      --
      All theory is gray
    6. Re:Silicon shortage? by catprog · · Score: 2, Interesting

      Current the energy to make a solar panel is about 2 years of the panel's output.

      --
      My Transformation Website
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  3. Indium shortage? by in2mind · · Score: 3, Informative
    FTA
    Shortages of silicon have crimped sales in the solar industry. Although some analysts have said indium--the "I" in CIGS and a material used in LCD TVs--could be in short supply at some point, executives in the CIGS business have downplayed these concerns. Indium is actually fairly common in the earth, according to Schuyler.


    From Wikipedia:

    The use of indium increases the bandgap of the CIGS layer, gallium is added to replace as much indium as possible due to gallium's relative availability to indium. Approximately 70% of Indium currently produced is used by the flat-screen monitor industry. Some investors in solar technology worry that production of CIGS cells will be limited by the availability of indium.

    Iam not sure about where Wiki got the figure from though.

    1. Re:Indium shortage? by brunes69 · · Score: 3, Funny

      I am not sure about where Wiki got the figure from though.

      Me either, but the truthiness of it is undeniable!

  4. Are they messing with units again? by jamesh · · Score: 2, Funny

    First they measure the factory's output in megawatts per year, presumably because a 1m^2 CIGS panel is not the same as 1m^2 Silicon panel (reminds me of a time when it started dawning on CPU marketers that Mhz wasn't a good selling point when your CPU could crunch more numbers at a lower speed than your competitors).

    Then they use megawatts as a measure of how much power a large coal plant could produce in a year.

    Why can't they just stick to libraries of congress? Eg the unit of measure would be that released by burnt all of the books (and furniture) in a library of congress.

    1. Re:Are they messing with units again? by fizzup · · Score: 2, Insightful

      This has got to be the first reasonable usage of the unit megawatts per year. TFA says that they can build a factory to produce "100 megawatts of solar panels a year".

      The astute among us at slashdot always say, "Megawatts per year, eh? Does that mean they increase electric power production by 100 megawatts every year? Duh."

      Well, in this case, yes. Yes it does.

  5. Which logo + no more bribing needed? by BeeBeard · · Score: 2, Insightful

    Or Universal Studios might go after you! Seriously, this is a wonderful innovation. In the past, making a new roof out of solar cells was so prohibitively expensive that states such as California had to offer homeowners incentives in the form of buy-down rebates, tax breaks, and so on--basically footing part of the bill just to get them using the technology. With the advent of CIGS, these kinds of environmentally-conscious bribes may not even be necessary. Cheap solar technology will now be far more accessible to people, companies, and governments. That is a Good Thing[tm].

  6. But can you make roads with it? by gsyswerda · · Score: 3, Interesting
    What we need is a solar panel technology that we can pave roads with. There would be many advantages:

    - The land is already available

    - An industry already exists for keeping it cleared

    - Roads already extend to most places where people need power

    - Electric cars could be charged, and "gas" stations could service them. Same for electric trains.

    - Roads would become revenue producing

    --
    Make a difference: move to a swing state.
    1. Re:But can you make roads with it? by hey! · · Score: 2, Interesting

      Even with the improvements in manufacturing, it's hard to see this being economical, especially counting wear and tear.

      However, roads are _black_. In some places you can fry an egg on them at noontime. Why not some kind of heat exchange pump that converts the noontime heat differential into electricity by using the heat differential between the road and some kind of heat reservoir? Then at midnight, when your photovoltaics are useless, you run your heat exchanger in reverse. This might work in places like Arizona, which have a large daytime/nightime temperature differential.

      --
      Post may contain irony: discontinue use if experiencing mood swings, nausea or elevated blood pressure.
  7. Re:bad units by andykuan · · Score: 3, Informative

    I think they intended those measurements to mean they are capable of manufacturing an aggregate number of solar panels capable of generating X megawatts in total annually. In other words, they're stating the total amount of power output they can output in a year. The confusion arises when the writer attempts to equate the annual output by a CIGS factory (measured in megawatts of power) with the annual output of a coal power plant (measured in megawatt-hours of work). My guess is that they are really stating that a coal power plant can produce 500 MW of power. Of course this indicates a deeper flaw in the discussion in that a coal power plant can continuously produce 500MW of power (presuming a constant supply of coal). Whereas a solar plant can only produce 500MW of power for half the day.

  8. Dangers of solar power by edxwelch · · Score: 5, Funny

    If you deploy too many solar panels in one place you could use up all the sunlight. This has already happened in nothern Scandinavia and during part of the winter they now are in total darkness.

    1. Re:Dangers of solar power by hey! · · Score: 4, Funny

      If you deploy too many solar panels in one place you could use up all the sunlight. This has already happened in nothern Scandinavia and during part of the winter they now are in total darkness.

      Silly. You're getting free electricity. Just set up a bunch of bright lights to replace the lost sunlight.

      --
      Post may contain irony: discontinue use if experiencing mood swings, nausea or elevated blood pressure.
    2. Re:Dangers of solar power by ByteSlicer · · Score: 4, Funny
      Just set up a bunch of bright lights to replace the lost sunlight.
      Yeah. And if you point the lights at the panels, you won't need sunlight anymore!
  9. Finally, a solar article about something real by starseeker · · Score: 3, Interesting

    I used to know one of the guys who went to work at Miasolé. He was a sharp guy with a lot of experience in CIGS and related materials.

    Slashdot has had a habit of posting the "next big solar breakthrough" which, in the fine print, is not so big yet but will be RSN. CuInGaSe2, on the other hand, has a long track record and previous commercial attempts have produced some solar panels with usable efficiencies (not great, but usable).

    CIGS has the advantage of being a direct band gap material, but there are some limits to how far you can push it in efficiency as a single layer device that have not been overcome. One serious advantage is that this material has a fairly wide tolerance on relative elemental composition - different ratios of material in the film will still produce a working cell within a fairly wide range. This is important because industrial process control has tolerances, and wider tolerances mean less expensive production. CuInSe2 and related compositions have some rather interesting electrical properties with respect to defect behavior that allow them to work in this fashion. Anyone with a real interest in this should look at some dense but extremely interesting work by Zunger at NREL.

    The biggest problem with CIGS as a production material is probably that it can't "piggyback" on the industry built up for the computer industry. I know that sounds strange, since its lack of reliance on that source of material is also its advantage, but tools to work with CIGS have to be developed more or less from scratch. That's expensive, and the reason that these initial investments are important. The process must be bootstrapped.

    CIGS of course doesn't address other problems with solar adoption, such as durability over time, public acceptance and investment, etc. But CIGS is a real material with real potential, and not simply IPO vaporware.

    Also of longer term interest is the idea of multijunction solar cells, which use different wavelengths of light on each layer and thus can push efficiencies much higher. Unfortunately they are also an EXTREMELY difficult practical challenge for production. However, there is a lot that can still be done. We REALLY need more funding for solar research in this country, and more basic research in general, but that's another post.

    Good luck to the Miasolé team!

    --
    "I object to doing things that computers can do." -- Olin Shivers, lispers.org
  10. Unlikely in the short term by starseeker · · Score: 2, Informative

    If you look at road surfaces, you will see that they are "clean" only in the sense of being free of large scale obstacles. Tire marks, dirt, oil, and other random stuff is all over the road surface.

    Solar panels need optical transparency in their protective layer. Keeping roads clean enough to provide that level of optical clarity is just not going to be workable, except possible with nanotechnology.

    When we get self rebuilding roadbeds then solar roadbeds might be practical, but for now roofs are much more practical as targets - most are slanted, don't have cars running over them, and get rained on periodically to help with self cleaning.

    --
    "I object to doing things that computers can do." -- Olin Shivers, lispers.org
  11. Volkswagens are much more appropriate by bigtrike · · Score: 2, Funny

    The unit of weight of the media, the Volkswagen, is much more appropriate

  12. How will they resist? by gringer · · Score: 3, Funny

    By using a resistor, of course.

    --
    Ask me about repetitive DNA
  13. Cost vs Efficiency by sfm · · Score: 3, Informative

    It is not the efficiency (W/m^2) that needs to go UP in order to make fixed solar generation facilities common, it is the cost ( $/W) that needs to come DOWN.

    I'll argue that for a typical small house (1500 sq-Ft) there is more than enough roof area to generate all the electricity for the house, even with 6-7% efficient solar panels. Unfortunately, buying current solar panels, this much energy would cost you >$35,000 !! (And that doesn't include batteries, tracker, inverter.... etc)

    If these guys can make lower efficiency panels that also have lower cost/Watt, it is a winning situation for everyone. Where do I buy their stock ?

  14. There are other promising techniques. by jelle · · Score: 2, Informative

    There are other promising techniques of harvesting sunlight, to only give a small sample: this one uses buckyballs and gets 5.2% efficiency, and something sort of similar using pentacene has similar promises, and this one uses the all-famous carbon nanotubes to convert it directly into hydrogen (but for now it only works with UV-light)

    If this keeps up, we'll probably have a choice from a whole range of efficiencies, and more importand $/watt.

    There already are companies out there that sell solar shingles. They're not economical yet for most applications, but it's starting to come.

    --
    --- Hindsight is 20/20, but walking backwards is not the answer.
  15. Re:How long to repay their energy debt by Anonymous Coward · · Score: 2, Insightful

    No, producing solar cells requires a huge amount of raw materials, chemicals, and energy- which in the US, likely means it will come from coal and the release of a large amount of emissions.

    The solar panel needs to run around 5 years to produce enough elecitity to make up for the electricty used to make it, and several more years to make up for the emissions produced in transporting, installing, mantaining, and disposing of the device.

    The total emissions released in the entire lifecycle of an energy source, divided by the energy produced, is what you have to look at when comparing the environmental impact energy sources. And in those meaures, current solar and wind technology is not particularly attractive, especially in comparison with hydroelectricity or nuclear. Significant breakthroughs are needed before solar energy can be a viable energy source, and as the original poster said, this technology looks like it will significantly reduce the energy requirements to produce solar cells, and thus reduce its enivronmental impact.

  16. Miasole by ScaredSilly · · Score: 4, Informative

    I've seen the Miasole production facility and had a chat with the CEO and one of the engineers at the end of the summer. There're a few interesting things that TFA doesn't mention. First, Miasole claims the low $25M price tag for a 200MW factory because they build all of their equipment from scratch. When I was on the floor, they were building a single 25MW line which they turned on for testing last month. That cost them a grand total of $4M (in parts) to build. E.g. they've already done one, so the pricing is reasonably accurate. Subsequent lines will be cheaper. This will give them a huge cost advantage over other similar companies.

    Secondly, their production process is cheaper not only because material costs are lower, but also because they use a "reel-to-reel" process in which the semiconductor material is deposited on a sheet of steel which unrolls into the line, and then rolls back up on a reel on the other side. The steel sheets can then be cut and woven into a vinyl enclosure which can be rolled out on your roof like regular roofing shingles. Cool stuff. (They're probably going to attack industrial markets first though...)

    Third, the management team comes from the disk drive industry, and built the Seagate facility that is responsible for ~30% of the world's hard drives (could have the percentage slightly wrong, but is in the ballpark). Hard drives use a similar thin film deposition process, and they have built several other manufacturing systems based on thin film processes. This is why the are able to get such a low cost on their equipment: they have the contacts and expertise to build from scratch.

    For the record, I have not talked with their competitors, so I don't know the whole story, but Miasole seems very well positioned, and their facility is certainly real.

  17. Fusion Reseach is military-driven. by billstewart · · Score: 2, Interesting
    Sure, they talk a bit about using Fusion for power generation and all that other Atoms For Peace hype, and there are a couple of astrophysicists who want to model the insides of stars, but almost all of the fusion research out there is really driven by the military. It's about learning how to build bombs differently or more efficiently or more tunably, and learning things to simulate in their supercomputers that can be used for better modelling of bomb behaviour.


    It would be nice if we could use fusion to generate power, though there are still radioactive waste issues because used reactor parts and containment domes are still likely to get hit with neutrons and therefore become radioactive, but there'd presumably be less of that that with fission. But that's not what most of the research is about.

    --

    Bill Stewart
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