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Scientists Attempt to Replace Crude Oil With Sugars

amigoro writes with a link to the Press Esc blog, discussing a possible replacement for crude oil in plastics, fuels, and other industrial uses. The post outlines findings to be published in an upcoming issue of the journal Science. Essentially, researchers at the Institute for Interfacial Catalysis are attempting to process the sugars in plant matter into an oil-like compound, a daunting challenge. "Glucose, in plant starch and cellulose, is nature's most abundant sugar. 'But getting a commercially viable yield of HMF from glucose has been very challenging,' Zhang said. 'In addition to low yield until now, we always generate many different byproducts,' including levulinic acid, making product purification expensive and uncompetitive with petroleum-based chemicals. Zhang, lead author and former post doc Haibo Zhao, and colleagues John Holladay and Heather Brown, all from PNNL, were able to coax HMF yields upward of 70 percent from glucose and nearly 90 percent from fructose while leaving only traces of acid impurities."

33 of 179 comments (clear)

  1. A better idea by gEvil+(beta) · · Score: 5, Interesting

    What about the guys who wanted to convert dead people to fuel?

    --
    This guy's the limit!
    1. Re:A better idea by drinkypoo · · Score: 2, Funny

      And make shit-burgers, and get an apology out of Union Carbide (didn't succeed in that, but did make them look like the assholes they are.) Personally I think that's a great idea, though; I'm not going to be using my fat ass when I'm dead. Someone might as well use it to take a road trip.

      --
      "You're right," Fisheye says. "I should have set it on 'whip' or 'chop.'"
    2. Re:A better idea by mark-t · · Score: 2
      I'd be inclined to conclude that the energy involved in converting dead people into fossil fuel likely outweighs the energy you'd get out of it.

      That happens even with existing fossil fuel too... it's just that we happen to get existing fossil fuel energy for "free" because the earth has been soaking it up from the sun and accumulating it for a few hundred million years before we even started to tap it.

    3. Re:A better idea by brunascle · · Score: 2, Funny

      couldnt we do the same thing? have the dead-guy furnace fueled by burning dead-guys? seems like that would work until we run out of dead-guys. we'd have to keep making more dead-guys.

      this is getting a big crass.

    4. Re:A better idea by bill_mcgonigle · · Score: 2, Funny

      What about the guys who wanted to convert dead people to fuel? [wired.com]

      Exxon Green? (is people)

      --
      My God, it's Full of Source!
      OUTSIDE_IP=$(dig +short my.ip @outsideip.net)
    5. Re:A better idea by Gospodin · · Score: 3, Funny

      "Would you like to Biggie-size that? Remember, by doing so you'll be reducing our dependence on foreign oil!"

      --
      ...following the principles of Heisenburger's Uncertain Cat...
  2. That big of a deal? by ArcherB · · Score: 4, Insightful

    Does that much crude go into plastics? I figured that the majority of oil was going to fuels. Would it be better for these guys to work with the current projects that are turning sugars into fuel rather than plastics?

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    There is no "I disagree" mod for a reason. Flamebait, Troll, and Overrated are not substitutes.
    1. Re:That big of a deal? by GreyPoopon · · Score: 2, Informative

      Would it be better for these guys to work with the current projects that are turning sugars into fuel rather than plastics?

      Erm, fuel was included alongside plastics.
      --

      GreyPoopon
      --
      Why is it I can write insightful comments but can't come up with a clever signature?

    2. Re:That big of a deal? by cyclopropene · · Score: 3, Informative

      TBH I'm more worried about running out of copper and silicon. I can understand copper, but why are you worried about running out of silicon? It makes up something like 25% of mass of the earths crust.
      --
      Shouldn't you be doing something useful?
  3. Comparison to existing products by grahamsz · · Score: 4, Interesting

    NatureWorks have been producing plastics from corn for quite a few years now.

    Their food containers look just like traditional ones and i've got a few pairs of Teko Ingeo socks that are really comfortable.

    It's certainly an interesting field

  4. Oh Goody, let's use food stocks... by Jinker · · Score: 4, Insightful

    ...as inputs for ALL our industries!

    If we could wrap our heads around the idea of conservation, I think we'd be a lot better off.

    Unfortunately, since we've defined consumption as economic success, preaching conservation ends up sounding like austerity.

  5. here's a thought by brunascle · · Score: 5, Funny

    hemp.

    what were we talking about again?

    1. Re:here's a thought by GeckoX · · Score: 4, Informative

      Flamebait? I think the mods are the ones smoking the stuff, sheesh. Someone revoke that moderators privileges, total abuse there.

      Poster was actually completely on topic...though obviously too stoned to remember to provide any reasonable details. Maybe they'll fill in the blanks when they come down ;)

      Links:
      http://www.hempplastic.com/
      http://www.treehugger.com/

      http://www.hempmuseum.org/

      Just for starters.

      --
      No Comment.
  6. Plants that grow plastic... by xxxJonBoyxxx · · Score: 3, Informative
  7. Billy Wilder's a genuis by General+Lee's+Peking · · Score: 2, Funny

    He used something like this as a premise for the movie ``Sabrina'' with Audrey Hepburn and Humphrey Bogart. At first I thought I was just going to have to suspend my disbelief because plastic from sugar seemed stupid. Now the only problem I had with the movie has been erased. The part where a gorgeous young woman goes for a dumpy looking nerdy old guy---now that I can buy.

  8. Too small by bill_mcgonigle · · Score: 4, Insightful

    If we could wrap our heads around the idea of conservation, I think we'd be a lot better off.

    Conservation is good, but doesn't solve the problem. If 4/5th of the world weren't needing to be brought up to our standards, and the population was static or decreasing, and oil wasn't going to run out, and our oil purchases weren't funding the guys who kill our troops, and we didn't have greenhouse effects to worry about, conservation would be all we need.

    Conservation makes all those problems a little bit better. But we need to solve them completely. And until we can get them solved we should absolutely conserve as much as we can to decrease the time until implementation of a real solution.

    Actually, I think the best plan is to save oil for very remote vehicle operation and plastics, such that we can cut our production down to the point where domestic sources are more than enough, so using sugar for plastics is probably the last thing that needs addressing.

    --
    My God, it's Full of Source!
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  9. suger based polymers... by sjs132 · · Score: 5, Interesting

    Umm... Correct me please...

    Suger based polymers... This is a statement that I've been told is in the screws and plates used to hold my son's head together. (He had a major surgery and my daughter just had the same this past wednesday.) Anyways, when I hear "Suger based polymers", I assumed pastic from sugar. Isn't "polymer" a fancy way of saying plastic? The side benifit for my children are that the screws/plates are then reabsorbed by the skull as it grows/heals.

    So this Sugar/Plastic would A) reserve fuels and B) biodegrade better?

    Dibs on a name, I call it Slastar or Slastic... (c) 2007, me. :)

    --
    --- Relax, that mass muderer is just trying to reduce our carbon footprint, one fetus at a time...
    1. Re:suger based polymers... by sjs132 · · Score: 2, Interesting

      Rude? Yes and no...

      Asking is not rude... I think the method to the question was. PC is not the answer (and I hate it.) but a little TACT goes a long way. But I'll answere anyway.

      Yes, My wife is the carrier of some type of defect. We've had some genetic tests done, and although the physical anomalies match a few syndromes, none match 100% and there has been NO genetic match that the've found. The closet thing is Saethre-Chotzen Syndrome, but again... No genetic match found yet, just physical characteristics.

      Some Links:

      http://www.faces-cranio.org/Disord/Saethre.htm
      or
      http://en.wikipedia.org/wiki/Saethre-Chotzen_syndr ome

      My wife had it first, no other members of her family... and she has such minor characteristics, that it was never caught until after after our first child was born and we realized something was slightly different about our wonderful little boy. Being that there was a 50/50 our other children would be normal, we had one more. This time a girl. (Serenity, and named after the ship on firefly, look at previous slashdot post somewhere in the ethernet...) She also has the same S-C Syndrome, so at this point we've made a contious decisioun not to have any more children because of the emotional and physical stress on the children, ourselves, family, and the cruility of others, such as by uninformed pigs that ask questions so rudely and point, stare, and whisper.

      (Maybe some parents should make the same decisions instead of blindly procreating because of the 10 second act that may produce offspring of limited tact such as those of the original questioneer.)

      I'm open to people that ask, because EDUCATION is the key to fear. You cannot fear somthing you know and understand.

      Anyways, S-C characteritics include Craniosynostosis where the sutures of the skull grow closed too soon. Because the brain's first 3 years of growth is made to push the plates of the skull apart during growth, closed sutures = no growth = preasure on the still growing brain = damage to brain or death. So the operation opens the sutures up, move the plates forward to provide growth.

      And before you ask... My wife is an M.E , and both children are above their peers in development tracts. (early speaking, walking, intuitive, memory, etc..etc.. ) So I'll take my wife and children with their higher inteligence over any "normal" kids that spend most of their time plugged into TV.

      With that being said, feel free to visit the family site:

      www.shimatzki.com

      --
      --- Relax, that mass muderer is just trying to reduce our carbon footprint, one fetus at a time...
  10. Re:How about this: by scrotch · · Score: 3, Insightful

    Obviously we should be conserving energy.
    Obviously we should be creating less CO2.
    And obviously there isn't going to be one single solution to this mess.

    It seems to me it's a lot better to be using and burning something renewable and localizable that actual absorbs CO2 before harvesting rather than something nonrenewable and poisonous that has to be shipped halfway around the world. This research could very well help. Just like conservation helps. Just like solar and wind and wave and other power sources will help.

    Personally I'm sick of people ranting that some alternative source of energy (or plastic) or conservation or whatever isn't worthwhile because it's not going to solve every problem all by itself. Be serious! It's going to take work on a lot of different fronts to fix this mess. There will not be one magic solution.

  11. Re:How about this: by GreyPoopon · · Score: 4, Informative

    How do they not get this yet, you burn stuff you produce CO2. I don't care what you burn, CO2 is given off.

    Uh, begging your pardon, but that's simply not true. CO2 is only produce by burning things that contain carbon. Burning hydrogen, for example, produces water.
    --

    GreyPoopon
    --
    Why is it I can write insightful comments but can't come up with a clever signature?

  12. Only part of the story by bill_mcgonigle · · Score: 2, Informative

    instead of using hydro-electric, wave power, or tidal- all of which are viable.

    They're all viable, but together they can't produce enough to supplant fossil fuels, solar, and nuclear energy. If I had my notebook with me I could give you a good number, but, roughly, the technologies you mention can create up to 10% of the power we need.

    While many countries (e.g. China, India) may agree that CO2 is a bad thing for us to produce in massive quantities, they're also not interested in stopping, because they don't have a better alternative (they don't view the agrarian society as acceptable).

    --
    My God, it's Full of Source!
    OUTSIDE_IP=$(dig +short my.ip @outsideip.net)
  13. Carbon Neutral by grahamsz · · Score: 4, Insightful

    Burning something that was grown to be burned is the very essence of "carbon-neutral", not the credit-buying al gore approach.

    The plant takes in CO2 when it grows and gives it out when it's burned.

  14. Plastic ok... but fuel? by narced · · Score: 2, Interesting

    I can understand making plastic from sugar based polymers, because it may yield some new and interesting properties, as well as be able to break down over time. Imagine if all the plastic in landfills was able to breakdown in 20 years. That seems like a good thing.

    Using sugars to make fuel, however, just seems like perpetuating an already out of control problem. Internal combustion is a very inefficient way to convert matter into energy. And like previous posters stated, it still creates CO2. I am pretty sure sugar based fuel will never be a big thing, as corn oil based biodiesel is already here. As far as alternative fuels go, this is not exactly what I'm hoping to see the future bring.

  15. Hemp Plastics by Anonymous Coward · · Score: 2, Insightful

    http://en.wikipedia.org/wiki/Bioplastic

    First sentence makes mention of using hemp plastics derived from the oil within the seeds. Hemp seems like a heartier plant than corn...it is a weed. If I recall correctly Henry Fords model T had a dashboard constructed using hemp plastics, but the Model T wikipedia entry makes no mention of it. Also hemp would reduce the demand on lumber for paper and can even be pressed into beams that do not rot as easily as traditional lumber.

    But I think we all know this will not happen...as hemp is too easily produced and would therefore destroy the industrial community.

    1. Re:Hemp Plastics by Anon-Admin · · Score: 2, Informative

      Save your breath, the government will never give up the war on drugs!

      Hemp is a great solution, Making 3800 gal per acre in bio-diesel from the seed, lbs of hemp flour from the remains of the seeds after pressing the oil (And hemp flour can be used in place of wheat flour)Fibers from the stalks, etc. The yield from a single acre is amazing. One acre will yield the same amount of paper as 10 acres of trees, it is easier to harvest and may be easier to process.

      It is too sad that the government and many in the general population of the US are so afraid of it.

      Oh and it has one of the highest Co2 fixation numbers I have seen, processing Co2 to O2. Processing in the order of 5x the Co2 of trees and up to 7x the Co2 of grass (The kind in your yard)

      We could reduce the planets Co2 levels, reduce de-forestation, reduce dependence on foreign oil, convert many of the non-biodegradables (plastics) to bio-degradable hemp products, and reduce the federal budget by over 8 Billion Dollars if only the government would stop the war on drugs.

      Oh well.

  16. Re:How about this: by John.P.Jones · · Score: 3, Insightful

    Hey smart boy, what do you think people's metabolisms do with the fuel? I'll tell you, they burn it (in a controlled fashion) and release (gasp) CO2!

    The advantage of biofuel techniques is we are releasing CO2 that has been recently removed from the atmosphere versus large sums of it that has been stored away for millions of years (oil). That is a profound difference because its sustainable, rather than using up limited resources at an unsustainable rate and changing our environment.

    Other than that, I agree with your general statement that biofuel is overrated and alternative fuels are underutilized and that we can do better.

  17. Great idea... by MadTinfoilHatter · · Score: 4, Funny

    ...I'm going to try it out by putting some sugar in my gas tank. If it works well I'll increase the amount. With a little luck I'll be able to save lots of money on gas. :-)

  18. glycerine by MillionthMonkey · · Score: 2, Interesting

    the energy involved in converting dead people into fossil fuel likely outweighs the energy you'd get out of it.

    Maybe the energy wouldn't be worth it, but there is lots of glycerol in people which is an expensive ingredient because products containing real glycerol are hard to find. There is considerable market demand for it, and its shoddy alternatives have developed a very bad reputation. Stuff usually has propylene glycol instead which is cheaper but doesn't taste as good, or ethylene glycol which is cheaper still but causes kidney failure so they might as well put "glycerine" on the label and take your money while you're still alive. If you have a large supply of human beings dying with statistical regularity, you can saponify their bodies in sodium hydroxide over heat and become a major producer of cheap glycerol which can be used for stuff like glue, shampoo, lotions, shaving cream, soap, mouthwashes, toothpaste, cough syrups, and food products. Alternatively you can make it from biodiesel.

    1. Re:glycerine by MillionthMonkey · · Score: 4, Funny

      I once worked at a place where my boss rediscovered the formula for dynamite. They were trying to do a selenium assay on vitamin pills. RDA for selenium is micrograms per day and for the atomic absorption test you have to dissolve the sample in acid so the spectrometer can spray it into a flame and check absorption/emission wavelengths of elements in the sample. But if you dissolve a vitamin pill in acid the selenium becomes too dilute to measure.

      He was basically trying to liquify a multivitamin, which has all kinds of crap in it. Generally you use a mixture of concentrated sulfuric and nitric acids to liquify something. The pills wouldn't dissolve when he tried digestion on an open burner, because the temperature at 1 atmosphere won't get high enough. They make steel digestion bombs for this kind of situation. They're like soup cans with stainless steel armor one inch thick around a ceramic liner inside. If the temperature exceeds 50 atmospheres a little safety valve on top pops to relieve the pressure. So he decided to buy 5 of these things, to let the pressure and temperature rise without losing any contents of the five sample tablets as he dissolved them under concentrated acids.

      This turned out to be a cardinal error. The tablets had a binder made of sodium benzoate. If you heat benzoate at high temperature and pressure under concentrated sulfuric and nitric acid, it turns into trinitrobenzoate which dissolves in water all right but is also a class A explosive. So they put the five vitamin tablets in the acids, sealed the bombs, and put them in the oven at 105 C which they actually had set up in a conference room where people would write up experiments. I was across the hall with a clear line of sight to the oven when the first bomb exploded inside. It sounded like someone took 5000 dinner plates and smashed them on the floor all at once, and the oven turned into a pile of kitty litter and silicate and asbestos and the conference room filled up with brown nitrogen dioxide. Then two more exploded and fired off in different directions. One penetrated the HR office next door (they moved upstairs the next week) and one buried itself in the wall of the conference room while people were still running outside. (The other two were duds.)

      I almost got killed by a multivitamin that day. You know, you live your life, day in and day out, and you don't realize how fragile life is until one day you almost get killed by an exploding vitamin tablet. In an interstellar burst I am back to save the universe.

      Not being a native English speaker, of course my boss gets on the phone with 911 and tells them that his bombs exploded.

  19. This will dissappear.. by SilverBlade2k · · Score: 3, Interesting

    We all know that any and all technologies that can be used to reduce our consumption of oil eventually vanishes, or the people sell out to big oil. This will be no different.

  20. Sugar in the tank (prank) by Kozz · · Score: 2, Funny

    Reminds me of a car prank I heard from Car Talk on NPR. If you want to easily ruin someone's day, yet do no real harm, get a bag of sugar half-full, sprinkle some on the ground beside their car's gas tank, leave the bag sitting in plain view on the ground beside it. BUT -- don't put any sugar in the tank! That'd be property damage.

    Instead, just let them worry about it, get it checked out at the local garage (paying for an inspection), all to find there's no damage whatsoever. :)

    --
    I only post comments when someone on the internet is wrong.
  21. Re:Plant-based plastic by netik · · Score: 2, Informative

    Maybe you haven't worked with celluloid or Bakelite before?

    It works as a plastic, but it's very brittle and no where near as strong as most commercial plastics derived from hydrocarbons.

    You're certainly not going to get ABS to PEG from sugars right now (but maybe PEG, commonly found in water bottles is a good candidate to start with)

  22. It could never work by Gription · · Score: 2, Insightful

    Using dead people for oil production would just drive up the price of Soylent Green.