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Protecting Unexposed Film from Cosmic Radiation?

iblink asks: "Last year Fujifilm stopped producing a color slide E-6 sheet film called Velvia 50. It has unique color characteristics that I love so I decided to purchase the remaining stocks in Europe. I now have hundreds of boxes that need to be stored for up to thirty years. A number of film experts assured me that freezing the Velvia would stabilize the dyes for long term use. However, they all mentioned that cosmic radiation would eventually fog the film, and they offered little help in finding a relatively inexpensive barrier. I found various ideas on proton cosmic radiation barriers — a big bucket of water, lead, certain plastics — but nothing convincing or sufficiently detailed (which plastic? How thick?). The film is currently in a freezer, unprotected. Any ideas?"

39 of 142 comments (clear)

  1. Four Astronauts by vjmurphy · · Score: 3, Funny

    I prefer using a fantastic group of four astronauts to block cosmic radiation. It seems to work well.

    --
    Vincent J. Murphy
    Spandex Justice
  2. What does tha manufacturer say? by mjpaci · · Score: 4, Interesting

    Were any of the film experts from FujiFilm? They may have some guidance for you. As them how they store film stocks.

    --Mike

  3. dark hole by The_Mr_Flibble · · Score: 3, Funny

    You could use a very deep cave or mine, however this then presents other radioactive issues.

    1. Re:dark hole by VitaminB52 · · Score: 2, Insightful
      however this then presents other radioactive issues

      ... like radioactive radon seeping from the ground. The amount of radon depends on your geographical location.

      So you not only need protection against cosmic radiation, but also against terrestrial radiation. You could use a ventilation system to minimise the radon problem, but this will cost you a lot of money if you want to store the film for 30 years.

      Also make sure your construction material isn't too radioactive; materials like wood, cement, stones, iron etc. all have a (low) level of natural radioactivity; stones from different sources have different natural radioactivity levels. Even very low levels won't do any good to films stored for 30 years. Bring a Geiger counter with you when selecting your construction material.

    2. Re:dark hole by Gromius · · Score: 2, Interesting

      you joke but thats pretty much what you do when you want to minimise cosmic ray interference. To be honest your second best bet due to the natural radioactivity you mention is the stick it in a tunnel under a moutain .

      Seriously its actually really surprising how many cosmic rays are hitting you right now. They are also extremely penetrating, often being muons (by the time they reach us). Basically its already got through 120km of atmosphere which although isnt that dense, it sure is thick so you're going to need a lot of shielding. And in 5 minutes at least one has hit you. Over 30 years that builds up. To really drive it home, it you are ever never CERN, stop in and see their microcosmin, look at the cosmic ray detector there and be amazed at how often it goes off.

    3. Re:dark hole by DerekLyons · · Score: 2, Insightful

      Bring a Geiger counter with you when selecting your construction material.

      That's a waste of time and money - because the material can have an activity level an order of magnitude below the counters detection threshold, and still have enough activity to be threatening to the film on the timescale of years. It's the accumulated (chronic) damage that matters here, not the acute damage.
  4. Premature by Phanatic1a · · Score: 5, Informative
    Fujifilm recently said they were bringing Velvia 50 back:

    Valhalla, NY, November 14, 2006 - FUJIFILM U.S.A., Inc. is pleased to announce plans to re-introduce an ISO 50 Fujichrome Velvia professional film, tentatively named Velvia II. Fujichrome Velvia (RVP 50) was the first high color saturation, high contrast transparency E-6 compatible film when it was introduced in 1990 and was a favorite among photographers. Its discontinuation was announced last year due to difficulties in procuring some of the raw materials used to produce the emulsion.

    "Since we announced the discontinuation of Velvia 50, we have been inundated with requests from photographers worldwide to continue production," said Christian Fridholm, Director of Marketing, Picture Taking, Imaging Division, Fujifilm USA. "They had used Velvia for many years and consider it unmatched in terms of quality and character. One of Fujifilm's main priorities is to nurture the culture of photography, so we took those requests very seriously."

    As a result, Fujifilm research and development teams have developed substitute raw materials and new manufacturing technologies that enable the company to restart production. The new film is expected to be available in late spring 2007. The characteristics of the new emulsion will mirror that of the previous product.


    I note that it's now past late spring 2007.
    1. Re:Premature by Anonymous Coward · · Score: 3, Funny

      AHAHAHAHAH! You're my hero.

    2. Re:Premature by Dan+East · · Score: 4, Funny

      The press release fails the mention that Fujifilm felt there was an ample stock of film across Europe, but suddenly hundreds of boxes - enough to last a photographer for at least 30 years - disappeared from stores and warehouses. Fujuifilm was then inundated with requests from photographers, prompting them to resume production.

      6 months into the future...
      FUJIFILM U.S.A., Inc. is sad to announce that they are ceasing production of Velvia II after massive stocks of surplus first-generation Velvia film - enough to supply a photographer for 30 years - inundated the market. The film's sensitivity to cosmic radiation severely limits its shelf life, forcing Fujifilm to stop production so existing stores could be consumed before radiation damage occurs.

      Dan East

      --
      Better known as 318230.
  5. Re:What you need is mass by elrous0 · · Score: 2, Insightful

    You do that and you'll probably end up with just as much radiation from Radon, uranium, etc.

    --
    SJW: Someone who has run out of real oppression, and has to fake it.
  6. Fujifilm are forever... by joto · · Score: 3, Insightful

    I think that I should warn you that everything eventually decays. Nothing lasts forever. And film, just like fruit, is best served fresh. If you really want to continue using Velvia in, say 600 years, I would recommend that you try to come up with some way of getting it fresh in the future. Just because Fuji stopped producing it, shouldn't mean that they won't be able to produce a small batch of it (at ridiculous high prices) if you make a special order. A different option, is to simply ask for the "recipe" (possibly by signing an NDA or similar contract), and get an independent laboratory to produce it when you need it. The last (and the only sane) option, is to try to find something else that fits your need. Such as analysing sample pictures, and coming up with a photoshop color filter that does the same thing.

    1. Re:Fujifilm are forever... by cmowire · · Score: 2, Insightful

      You'd like to think that.

      Sadly, the layers of patents, trade secrets, and other such fun bits make it that the only two companies able to make a film of the level of quality of Velvia 50 are Kodak and Fuji. If you want the silver film grains to be the correct shape, you need to accurately control the growth of silver halide crystals and that means custom, proprietary mixing machines.

      Also, Fuji does not make every last bit of the film. Many of the chemicals and components involved have many uses besides making film... but they can be discontinued for a variety of reasons.

      Finally, film recipes are not an exact science. If you change the mixing kettle, you need to adjust the recipe. They never figured out why, but if you change anything, you need to tweak the formula. It's more like making cheese than an exact product.

  7. Re:Faraday cage by VitaminB52 · · Score: 3, Informative

    A Faraday cage won't stop particle radiation, nor will it protect against short wavelength radiation like gamma rays (unless you build a Faraday cage from massive lead plates, without any holes in it).
    It also won't protect you against radioactive radon gas seeping out off the ground.

  8. Meh.. by evel+aka+matt · · Score: 3, Informative

    Forget about Velvia 50 & just move onto Velvia 100F like the rest of us have. 50 has little to no (most people would say the latter) advantage over 100f.

    1. Re:Meh.. by PsndCsrV · · Score: 3, Informative

      Ugh, holy crap. Don't shoot Velvia 100F and expect it to look like Velvia 50. It doesn't. Shoot Velvia 100 (notice the missing F). It's pretty darn close to Velvia 50 (close enough that I was willing to switch, saving myself from the need to stockpile).

      --
      Experiments must be reproducible; they should all fail in the same way.
  9. I won't be the same by BenEnglishAtHome · · Score: 2, Insightful

    If they bring it back with "substitute raw materials and new manufacturing technologies ," it won't be the same thing. Emulsions and our attachments to them are delicate things. Any change, however subtle, will kill the effect. The new film may be just fine. It may be sort of like the old film. But it won't be the same.

    Think "New Coke." It was supposed to be the same, wasn't it? In fact, some bottlers changed formulas and put New Coke in remaining stocks of old cans. The first time I tried one of those, I literally did a spit take. It might have been a perfectly fine soda, but it was different. It wasn't what I expected and I could tell that a change had been made.

    The human senses are far more sensitive than people realize. New Coke didn't fool me. A change in materials in a film emulsion won't fool they eye of a photographer who loved the old formula.

    Now I'm going to go do some research to help this guy. He really does need to arrange good long term storage for his film.

    1. Re:I won't be the same by impossiblerobot · · Score: 2, Insightful

      New Coke wasn't supposed to be the same. New Coke was supposed to be Pepsi.

      --
      Impossible Robot
    2. Re:I won't be the same by s4m7 · · Score: 2, Insightful

      New Coke didn't fool me. New Coke was a distraction so you wouldn't notice that Coke Classic changed from cane sugar to corn sweetner. Do you still drink Coke?
      --
      This comment is fully compliant with RFC 527.
    3. Re:I won't be the same by BenEnglishAtHome · · Score: 3, Interesting

      The change in sweetener is a more subtle thing than trying to pass off New Coke in the old Coke cans. No, I didn't notice the change. How long ago was it?

      OTOH, ask those Dr. Pepper fans who live near and dote on the output of the one Dr. Pepper bottler in the U.S. who still uses cane sugar. They'll tell you they can easily tell the difference.

    4. Re:I won't be the same by porcupine8 · · Score: 2, Informative

      A quick google of dr pepper cane sugar revealed: Dublin, TX - and they sell it online.

      --
      Warning: Apple/Nintendo fangirl. Likes her electronics cute & cuddly. May be rabid.
    5. Re:I won't be the same by ravenshrike · · Score: 3, Insightful

      This is because you don't grow nearly as much corn up in canada, and subsequently you didn't have a corn lobby to lobby for tarriffs on outside sugar. Fucking corn lobby.

    6. Re:I won't be the same by SydShamino · · Score: 2, Informative

      In additional to the Dublin Dr. Pepper already mentioned, most grocery stores here in Austin sell Mexican Coke (heh) and Sprite, and others on occasion. It has real sugar instead of corn syrup as well.

      --
      It doesn't hurt to be nice.
    7. Re:I won't be the same by 198348726583297634 · · Score: 3, Informative

      Sadly that is part of the family of urban legends surrounding the New Coke fiasco. It is not true. Coke actually switched from cane sugar to HFCS several months before the introduction of New Coke. (You can still get Coke made with cane sugar in the U.S. if you get the glass-bottled kind imported from Mexico.) But in general, no one noticed or cared. New Coke came later and was an entirely different fiasco.

      Snopes, as per usual, has good info on this subject.

      Thanks,

  10. Other strategies by Toffins · · Score: 3, Insightful
    Trying to shield your film stock against high-energy cosmic rays is an impossible task unless you consider storing it somewhere deep underground. And putting up shielding materials to protect your film may in fact make the fogging worse because very high energy cosmic rays hit the shielding material creating secondary radiation that will fog your film even more quickly.

    If you are concerned about being able to use Velvia film in the long term, it might be easier and cheaper to get together with other like-minded folk and find a cheap contracting manufacturer somewhere like China or India who can copy the Velvia manufacturing process (if they bother follow licensing protocols...) to provide a supply of fresh film.

  11. Re:Faraday cage by bohlke · · Score: 2, Informative

    Cosmic Radiation is very very very very short wavelength.... light for example is just nanometers order. Cosmic radiation is even shorter. Gamma Rays are as far (or close, it depends which side you are ;-) as 10e-16 meters (pico meters or less).

    http://en.wikipedia.org/wiki/Electromagnetic_radia tion#Electromagnetic_spectrum

  12. Kodak says... by BenEnglishAtHome · · Score: 2, Informative

    Obviously, there's a problem, know-nothing slashdot smartmouths be damned. Here's what Kodak says:

    Ambient-Background Radiation

    (effects on raw stock)

    Ambient gamma radiation is composed of two sources: a low-energy component which arises from the decay of radionuclides and a high-energy component which is the product of the interaction of cosmic rays with the earths upper atmosphere. The radionuclides responsible for the low-energy photons exist in soil and rock and are carried into earth-derived building materials, such as concrete. Upon exposure to ambient-background radiation, photographic negative materials can exhibit an increase in minimum density, a loss in contrast and speed in the dark areas, and an increase in granularity. The changes in film performance are determined by several factors, such as the film speed and length of time exposed to the radiation before the film is processed. A film with an exposure index of 500 can exhibit about three times the change in performance as a film with an index of 125. While this effect on film raw stock is not immediate, it is one reason why we suggest exposing and processing film as soon as possible after purchase. We recommend a period of no more than six months from the time of film purchase before processing, provided it has been kept under specified conditions. Extended periods beyond six months may affect faster speed films as noted above, even if kept frozen. The only way to determine the specific effect of ambient-background radiation is with actual testing or measurements and placing a detector in the locations where the film was stored. The most obvious clue is the observance of increased granularity, especially in the light areas of the scene.

  13. Don't bother by PhysicsPhil · · Score: 5, Insightful

    The cosmic radiation in question has enough energy to travel across the galaxy, blast through several kilometres of atmosphere, penetrate your building's roof and walls and then punch through the box holding your film before actually interacting with the film. Seems unlikely that you'll be able to do much more to keep the film fresh.

    1. Re:Don't bother by cosinezero · · Score: 3, Funny

      So does light, but I can stop that with the sheer force of my hands.

    2. Re:Don't bother by ceoyoyo · · Score: 2, Interesting

      Nope. A nuclear bunker won't do it. You need one of these: http://www.sno.phy.queensu.ca/images/mine.GIF.

      The box will give some protection, the metal of the freezer some, a lead box some, a 2km deep mine some... how much do you want? All radiation cannot be shielded because your shielding material will invariably be radioactive. Although, you can cut down that effect a bit by purchasing very expensive ancient lead from Roman shipwrecks. You'll be competing with a couple of observatories though.

  14. Ceramics by Waffle+Iron · · Score: 3, Funny

    I've heard that if you stack a bunch of red Fiestaware dinner plates, and then store your film sandwiched in layers between them, then cosmic radiation won't be an issue at all.

  15. A trivial detail... by mridoni · · Score: 4, Insightful

    Did you also happen to buy and store a 30-years-worth supply of chemicals (and a processing machine) for E-6?

  16. Another Idea by bohlke · · Score: 2, Insightful

    this just came to my mind:

    you can try to protect with some kind of magnetic shield, to maybe trap these evil particles in some kind of "magnetic swirl" or like that....

    hummm, but fast spining particles will radiate any way....
    and probably you will need a lot of power (i mean $$$$) to produce a strong enought "force field"

    well, just a few ideas.

  17. The place to go by BenEnglishAtHome · · Score: 4, Informative

    Like lots of photo buffs, the first thing I thought of was the Rochester Institute. And that led me to an answer.

    I'm not going to put directly on Slashdot the name and phone number of a real person. However, if you visit the Image Permanence Institute web site and poke around, you'll find a name and phone number you can call to get in touch with an expert on these subjects who will either know the answer or know where to find it.

    1. Re:The place to go by MobileTatsu-NJG · · Score: 2, Insightful

      "I'm not going to put directly on Slashdot the name and phone number of a real person."

      Ah yes, the best way to hide personal information from Slashdot. Put it in an article!

      --

      "I like to lick butts!" by MobileTatsu-NJG (#32700246) (Score:5, Informative)

  18. Graded Z shielding by mollymoo · · Score: 3, Informative

    You may want to investigate "Graded-Z shielding". The name comes from the fact that it uses layers of shielding with decreasing atomic numbers. You might first have a layer of lead, then a layer of tin, then one of copper. The lead stops the cosmic rays (protons, electrons, light atomic nuclei), but generates X-rays in the process. These X-rays might also fog your film. The X-rays produced as the lead absorbs the cosmic rays have a characteristic energy (88keV) which is not well absorbed by the lead itself - that's where the tin comes in. Again, the tin stopping the X-rays from the lead generates X-rays with a lower characteristic energy (29keV, which is in medical X-ray energy territory), which it doesn't absorb too well. The copper absorbs the X-rays from the tin and again emits X-rays with a yet lower characteristic energy. I don't know if the 9keV X-rays produced by the copper are a problem for Velvia. If they are, you'll need a yet lighter layer; a glance at the periodic table shows aluminium is a likely candidate.

    I have no idea about the sensitivity of Velvia to cosmic rays or X-rays, so can't suggest thickness of the materials. My wild-ass-guess is somewhere in the 10s of mm. 30 years is a hell of a long time though. There are companies which specialise in shielding of this type (search for 'radiation shielding', 'graded-z shielding' and the like), they may be able to provide advice and sell you enclosures.

    --
    Chernobyl 'not a wildlife haven' - BBC News
  19. How about... by alta · · Score: 5, Funny

    Q: My film is being destroyed by cosmic death rays, what can I do about it?
    A: Digital camera, Raid 5, good backups.

    Q: But only velvet#50 has the unique qualities I'm looking for. I can't reproduce that with digital.
    A: Photoshop CS7, Filters -> Artistic -> Velvitize.

    Q: But I have to have REAL velvet#50 for all these Elvis and Bengal tiger prints I'm doing. I can't print on velvet with an inkjet!
    A: I heard fujifilm has a good film that does this, see if they still make it.

    --
    Do not meddle in the affairs of sysadmins, for they are subtle, and quick to anger.
  20. My long-term film storage experience by Toffins · · Score: 2, Informative

    About 20 years ago I had a small surplus stock of Kodak E6 professional transparency film left over at the end of a project. The storage recommendations from Kodak were to store E6 cold and dry, so I bagged and sealed the films and put them in low-humidity cold storage. As an experiment I left the films there. The films developed ok at 8 years age with excellent quality, and again at 15 years age, but by then slight fogging was visible. Maybe the fogging was due to cosmic rays, or perhaps the photochemicals had degraded. Anyway, the experiment ended when the E6 processing lab I used to use closed down (soon followed by its rival firms). I kinda miss E6. Really excellent true color reproduction and high resolving power (IIRC, over 100lines/mm).

  21. Re:This too will pass by Zcar · · Score: 2, Informative

    Note that he's talking about sheet film, not 35mm. He's presumably using 4x5" sheets with a field or view camera which generally don't have any electronics in them.

    We're talking about something like this or this.

  22. Shielding can make things worse by CBM · · Score: 2, Interesting

    It's counterintuitive, but shielding can actually make more radiation. The problem is that when a high energy cosmic ray strikes a nucleus, it can make a whole bunch of secondary particles which still have a lot of energy. Then those particles interact again, and so on, producing a "shower" of particles that can interact with your film. Sensitive neutrino experiments go far under the earth's surface to avoid cosmic rays, and even there they get a fair number of (low interacting) muons. I helped test a large space astronomy observatory and we regularly got blatted by cosmic ray showers, even though the observatory was inside a pressure vessel with thick steel walls. Proper shielding is an art.

    Burying your film underground may make things worse too... if you live in an area rich in radioactive soil or radon gas. Building materials like concrete can often also be contaminated with uranium.