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Avalanche Effect Demonstrated In Solar Cells

esocid writes "Researchers at TU Delft (Netherlands) and the FOM (Foundation for Fundamental Research on Matter) have found irrefutable proof that the so-called avalanche effect by electrons occurs in specific semiconducting crystals of nanometer dimensions. This physical effect could pave the way for cheap, high-output solar cells. Solar cells currently have relatively low output, typically 15%, and high manufacturing costs. One possible improvement could derive from a new type of solar cell made of semiconducting nanocrystals and could theoretically lead to a maximum output of 44%, with the added benefit of reducing manufacturing costs. In conventional solar cells, one photon can release precisely one electron. However, in some semiconducting nanocrystals, one photon can release two or three electrons, hence the term 'avalanche effect.' This effect was first measured by researchers at the Los Alamos National Laboratories in 2004, and since then the scientific world had raised doubts about the value of these measurements. This current research does in fact demonstrate that the avalanche effect can occur."

34 of 234 comments (clear)

  1. Wait and see by Bananatree3 · · Score: 4, Insightful
    as with all emerging technology, I am going to wait and see as to how this R & D develops into a commercial application.

    However, I'll bet the keys on my keyboard that solar is going to be a lucrative market in the near future. Heck, it already is for solar cell manufacturers.

  2. Manufacturing Energy Costs? by Doc+Ruby · · Score: 5, Insightful

    Manufacturing solar PV cells is usually said to cost quite a lot of energy. But how much exactly (on average)?

    How many joules are consumed from raw materials to a deliverable PV cell of a given output wattage? Of the old "about 15%" (really about 20-25% these days), and of these new proposed "avalance" PV material ones?

    I want to compare that energy cost to the cells' projected energy contribution over their lifetime, which is about 30+ years for today's PV cells. How long would the new ones last in typical service?

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    make install -not war

    1. Re:Manufacturing Energy Costs? by Animats · · Score: 5, Informative

      The head of Applied Materials' solar division said in a 2007 talk at Stanford that their current production process costs about 2 years of output for a solar panel. He thinks they can get that down to 6 months of output; he said some things about improvements to the sputtering process. which is derived from IC manufacturing technology where the wafers are smaller.

      They'll probably do it. What Applied Materials does is improve semiconductor process technology. They're the world's largest maker of semiconductor fab equipment. This led them into making LCD displays, and then solar panels.

    2. Re:Manufacturing Energy Costs? by syphax · · Score: 3, Interesting


      The numbers are all over the place and constantly coming down with new technologies, but you're looking at breakeven after 1-5 years or so.

      This is pretty good (EROEI is >> 1), and will continue to get better.

      --
      Simple Unexpected Concrete Credible Emotional Stories
  3. APDs by Wilson_6500 · · Score: 5, Informative

    Avalanche photodiodes of certain semiconductor materials have been around for a while now. I believe the novel part of this research is that they're confirming other researchers' data showing that lead selenide semiconductors can exhibit electron cascade effects.

    1. Re:APDs by bperkins · · Score: 3, Interesting

      It's hard to say without seeing the article in Nano-letters, but based on the diagram and a vague description, I'd guess that it works something like this:

      A high energy electron hole pair is created by a photon, which then relaxes down to a lower energy state. But, instead of emitting a phonon (heat), it creates another electron hole pair, and you end up with two. I suppose this process could repeat itself, so that many different wavelengths would all produce energy with reasonable efficiency.

      This is in all likelihood facilitated by the complex energy band structure of the (essentially) polycrystalline semiconductor.

      I'm not so sure how directly applicable all of this is. I suspect that some theorist postulated that this could happen, but it was difficult to prove experimentally. It seems to me that the hard work of actually producing an workable device hasn't been done yet.

      From what I can tell, this work is done in PbSe, which I don't think is a suitible for huge volume production.

      But I could be wrong in all this.

  4. Los Alamos by TubeSteak · · Score: 4, Informative

    The avalanche effect was first measured by researchers at the Los Alamos National Laboratories in 2004. Since then, the scientific world has raised doubts about the value of these measurements. Does the avalanche effect really exist or not? This is the Los Alamos stuff they're talking about:

    http://science.slashdot.org/article.pl?sid=04/05/20/1436213

    Solar Cells Get Boost
    Posted by michael on Thursday May 20 2004, @02:15PM
    from the juiced-up dept.
    Science Technology
    An anonymous reader writes "Researchers from Los Alamos National Laboratory have tapped the efficiencies of nanotechnology to double solar cells' potential energy production. The key to the method is the use of lead selenium nanocrystals which can produce 2 electrons where 1 was produced before. Other optical applications can also benefit."
    --
    [Fuck Beta]
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  5. Someone said it before, I will now. by Jane+Q.+Public · · Score: 4, Insightful

    Somebody else said this the last time solar cells were brought up, and it is just as relevant here:

    SOMEBODY PLEASE BRING SOME ACTUAL "IMPROVEMENTS" TO MARKET!!!

    If all the "improvements" to solar cell manufacturing I have read about in recent decades became actuality, we would all have homes and cars powered solely by a 1-meter-square panel on the roof and the panels would cost $1 apiece.

    Please, either DO SOMETHING with this, or stop making predictions!

    1. Re:Someone said it before, I will now. by jberryman · · Score: 5, Insightful

      We need to wake up, and start the new Manhattan Project for energy; I don't think we can wait on the Free Market for this one.

    2. Re:Someone said it before, I will now. by mhall119 · · Score: 3, Insightful

      Why can't we have a leader pledge to reduce America's dependence on oil by 50% in 10 years? Sounds just as possible to me as Apollo XI would have in 1960. And it's obviously more practical. It's significantly harder if you go and think it through. The Apollo project required the efforts of maybe several thousand people, where as reducing consumption of oil will require the efforts of millions of Americans. The Apollo project required the construction of several facilities and large infrastructure in only a handful of locations, where as reducing fossil fuel use will require a nationwide architecture upgrade, and at least hundreds of large facilities.

      If the Apollo program were at the scale required for reducing oil consumption, we'd have colonized most of the moon by now.
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      http://www.mhall119.com
  6. Thermaldynamics? by mlts · · Score: 4, Interesting

    Without violating thermaldynamic laws, I wonder how much electricity output this will add. I don't think it would double the current flow with 2-3 electrons popping out for each photon that strikes the array, but I know this should add a significant amount of efficiency.

    I just hope all these advances, especially ones that make solar cells cheaper to manufacture go into production. There are huge chunks of the world that are lifeless desert, and would be perfect for large solar and wind arrays, assuming one could find a way to transport the generated electricity to cities without too much current loss. Perhaps some chemical reaction that pulls carbon from the air directly to make ethane, then another reaction that converts the ethane to ethanol to be piped to places that can burn the ethanol for electricity. Yes, the chemical reactions to pull carbon from the air, and get it into ethanol are wasteful, but for very long distance transfer of energy (100-200+ miles), it would be less wasteful to do that, than to use standard power transmission lines. Even though the ethanol electricity generating plants would be adding carbon into the air, it would be carbon neutral due to the carbon being extracted at the solar/wind site.

    1. Re:Thermaldynamics? by Anonymous Coward · · Score: 5, Funny

      I frequently try to break the laws of thermaldynamics. Especially ones involving Intropy and the Carnal Cycle.

    2. Re:Thermaldynamics? by Yetihehe · · Score: 4, Interesting

      Perhaps some chemical reaction that pulls carbon from the air directly to make ethane, then another reaction that converts the ethane to ethanol to be piped to places that can burn the ethanol for electricity.
      Would methane be ok? If so, it is already done with CO2 and sunlight.
      --
      Extreme Programming - Redundant Array of Inexpensive Developers
  7. Developing nations by William+Robinson · · Score: 3, Interesting

    This is great news, especially for developing nations whose energy demands are on rising trend. Countries like Indonesia, India and other middle east countries, where sun light is available in abundance, will benefit most.

  8. Let's be realistic by actionbastard · · Score: 5, Insightful

    Whether they're hairy, nanotube, or amorphous, cheap, efficient solar cells are always going to be thirty years away as long as there is 'cheap' oil around.

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    1. Re:Let's be realistic by Chuck+Chunder · · Score: 5, Funny

      Since next year!

      --
      Boffoonery - downloadable Comedy Benefit for Bletchley Park
    2. Re:Let's be realistic by Anonymous Coward · · Score: 5, Insightful

      Since when is $135/barrel "cheap"? @ $135/barrel, people are still wasting energy left and right. So it is still cheap.
  9. Penny wise, pound foolish by hyades1 · · Score: 5, Insightful

    We seem to cavil about a few million dollars, or even a few hundred million, being spent to jump start emerging energy technology, but we have no problem spending billions on oil industry subsidies.

    We need to acknowledge that any new tech investment involves high risk. Success brings high rewards. We accept exactly this reasoning when oil executives tell us that oil exploration is expensive and risky, and therefore requires continuing subsidies even when record profits are rolling in. A few million spent on alt energy research that tanks, however, is usually reported as a "this is what happens when you listen to the tree huggers" story.

    An attitude adjustment as 'way overdue, and a rediscovery of our spirit of adventure and innovation. Perhaps putting some money into finding out whether this kind of solar cell works and can be mass produced would be a place to start.

    --
    I've calculated my velocity with such exquisite precision that I have no idea where I am.
    1. Re:Penny wise, pound foolish by LynnwoodRooster · · Score: 4, Informative
      We seem to cavil about a few million dollars, or even a few hundred million, being spent to jump start emerging energy technology, but we have no problem spending billions on oil industry subsidies.

      Maybe because most alternative energy sources are big money losers? Take a look at page 16 of this report for the actual numbers about subsidies...

      I predict once you can start to get alternative energy sources like solar and wind down an order of magnitude or so in terms of cost you'll see things turn around. However, for now they're getting somewhere around 100X the subsidy per Megawatt-hour that "Big Oil" gets.

      An improvement from 15% to 40% simply isn't enough - natural gas and oil get around $0.25 per MWhr, while solar and wind get 100 times that amount per MWhr. And remember, those nasty "Big Oil" companies also pay over $3 in direct federal taxes for every $1 in profit. Over $200 billion flows into the Federal government every year in terms of direct taxes and fees (that's not including the taxes you're paying on consumption of their products).

      Right now, and for the last 20 years, wind and solar have been huge money-losers, and only exists BECAUSE of the massive subsidies. If we subsidized wind or solar at a level to get useful output levels, we'd spend literally trillions more per year.

      And then there's that whole baseload thing...

      --
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    2. Re:Penny wise, pound foolish by hyades1 · · Score: 3, Informative

      Your overlook many of the less obvious subsidies. For example, the Army Corps of Engineers routinely dredges canals used by the oil industry at taxpayer expense. The explanation is that they're staying in training. Canals that don't serve oil tankers, regardless of need, do not receive such treatment.

      There are many, many examples of such hidden subsidies, none of which are accounted for in your numbers. I invite you to seek them out for yourself rather than take my word for them.

      An article in Nature 445, 147 (11 January 2007) published online 10 January 2007, and "Money Down the Pipeline: Uncovering the Hidden Subsidies to the Oil Industry" by the Union of Concerned Scientists are good places to start your investigation.

      --
      I've calculated my velocity with such exquisite precision that I have no idea where I am.
  10. Re:Sunlight is better used for heating by phantomfive · · Score: 4, Insightful

    Man, let me tell you about skylights. I have a skylight, and I thought it was cool. Here's how it works: I get free light all day long, except at night when there isn't enough light coming in through the window.

    I get free heating all summer long, but in the winter it's too cloudy to make a difference. Yeah, skylights sound good and all, but give me a solar panel over that any day.

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    Qxe4
  11. Oh, ho ho ho... by Anonymous Coward · · Score: 5, Funny

    This current research does in fact demonstrate that the avalanche effect can occur. Oh boy, that's a good one.
  12. Isn't price the key? by jimmyhat3939 · · Score: 3, Insightful
    I'm often confused when I see articles about how great it is to improve the efficiency of solar cells.

    To me, the big issue is not efficiency but cost per watt. Many regions of the world have plenty of the land, particularly energy guzzlers like the US. What we really need is a super-cheap way to use that land for solar generation.

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    1. Re:Isn't price the key? by dakameleon · · Score: 5, Informative

      To me, the big issue is not efficiency but cost per watt. Read the bloody summary even!

      could theoretically lead to a maximum output of 44%, with the added benefit of reducing manufacturing costs So if the summary is to be believed, you're increasing output nearly threefold, and reducing cost of manufacture. The cost-per-watt ratio moves the right way on both sides.
      --
      Man who leaps off cliff jumps to conclusion.
    2. Re:Isn't price the key? by syphax · · Score: 4, Interesting


      Efficiency matters, for a few reasons, including:

      1. Indirect costs (installation labor, racks, mounts, etc.) scale with the area of the array. The area of array required for a given power output goes with the inverse of efficiency. These costs are pretty significant, so efficiency has a direct impact on installed costs.

      2. There's lots of area available for solar panels, but solar energy is pretty diffuse, so you need a lot of area anyway. If a 1% efficient system cost a dime per watt installed, great, but you'd have to cover huge areas to generate significant amounts of electricity. There are practical limits. Even at 10-20% efficiency, you're still looking at large areas to generate a meaningful amount of juice.

      --
      Simple Unexpected Concrete Credible Emotional Stories
    3. Re:Isn't price the key? by somersault · · Score: 3, Interesting

      Well, the company I work for is building a 1MW tidal turbine that is around 25 metres tall, not sure exactly how large the vent is, but to me that says that solar energy is pretty diffuse compared to the tides. Sunlight isn't that predictable during the day either unless you can get rid of all the clouds?

      --
      which is totally what she said
    4. Re:Isn't price the key? by Bananatree3 · · Score: 3, Insightful
      Where can I sign up? Sounds like good job.

      Tidal/geothermal power are much more constant and predictable sources than solar or wind. However, I think all of these renewable technologies are each a piece of the overall energy puzzle. Solar, Wind, Tidal, Geothermal...they've all got strengths and individual industries working for them. The current model of a dominant source is fading away into a more diversified energy market. "Never put all your eggs in one basket", as they say.

  13. Re:Or great! by Hal_Porter · · Score: 5, Funny

    Solar cells only work outside though.

    You'd have to use a thick black raincoat, a wide brimmed hat and sunglasses to protect yourself from the ultraviolent radiation though. And cover up any exposed spots with SPF 10000 suncream.

    Even then I'd scuttle back into the basement once the batteries had recharged.

    --
    echo -e 'global _start\n _start:\n mov eax, 2\n int 80h\n jmp _start' > a.asm; nasm a.asm -f elf; ld a.o -o a;
  14. Irrefutable? Then it's NOT science! by Mathinker · · Score: 5, Insightful

    There is no such thing as irrefutable in science. In fact, some people attempt to define science as the pursuit of knowledge which can be corroborated and refuted using the "scientific method" (to preempt a lot of comments: I said "attempt to define", because this definition rapidly becomes circular unless you are very careful, and it is not clear that defining the "scientific method" is easier than defining science itself).

    OTOH, I rather doubt that the scientists themselves claimed irrefutability here. The journalists are probably to blame.

  15. Flying Car? by camperdave · · Score: 3, Insightful

    And while your on it ask them what's holding up my flying car?

    Anti-grav units? Powerful downward facing thrusters? Wings? Rotors?

    Truth be told, there's nothing holding up your flying car except the name. It's not a flying car. It's a personal aircraft, and they come in many different sizes and shapes, from ultralights, LongEZs, and autogyros, to Beavers, Cesnas and Learjets.

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    When our name is on the back of your car, we're behind you all the way!
  16. Re:Sunlight is better used for heating by TubeSteak · · Score: 3, Interesting

    Using sunlight for electricity is not particularly attractive, but for the neat 'no moving parts' aspect. It is far better to use solar power for light, water and space heating - those remarkable innovations called windows and skylights for example. Tell that to the entire African Continent which has an abundance of sun & empty space, but a deficit of fresh water, power & air conditioning.

    I look forward to a future with solar powered desalination plants.
    It's a much brighter outlook than continent wide water wars forcefully giving everyone a skylight.
    --
    [Fuck Beta]
    o0t!
  17. Re:Or great! by LynnwoodRooster · · Score: 3, Funny
    And cover up any exposed spots with SPF 10000 suncream.

    You know it also comes in a new convenient spray can!

    --
    Browsing at +1 - no ACs, I ignore their posts. So refreshing!
  18. Decentralize - Decentralize - Decentralize. by dmgxmichael · · Score: 5, Insightful

    Imagine for a moment if we geeks hadn't come up with DNS but instead tried to use a small handful of machines to handle domain name resolution. The Internet would collapse rather quickly no?

    Funny then that to date our power grid is based on a centralized model. Sadly, as much as 20-30% of all power generated is lost during transmission over the grid.

    Now effective solar panels and batteries to go with them would allow us to move to a more decentralized model. Imagine whole neighborhoods creating most - though not all - of their power needs. If the panels can get to around 80% of the needs of the house then the current power plants we have can be the only ones we need for awhile.

    Or even better, instead of having massive plants with a huge footprint make use of smaller pup nuclear reactors - about the size used in a naval ship. One of those could be placed where the power substations are now and pick up the slack that the solar panels can't fulfill. They wouldn't present any real contamination danger as once their fuel was spent after 30 years or so you truck out the entire unit and refurbish (i.e. refuel) it under controlled conditions in a remote area - while in service the internals of the thing aren't opened up.

    These things also wouldn't have to make as much power as the current power stations because, by virtue of being closer to the customers they serve, they wouldn't lose as much power in the lines.

  19. This is far from insightful by Kupfernigk · · Score: 5, Insightful
    Do you have any idea how long it takes to commercialise a technology in volume? Obviously not.

    If you actually read up on solar cells instead of sounding off like an idiot, you would know that the cost per watt is dropping quite fast, durability has doubled in the last 5 years, that Sharp are making cells which are nearly twice as efficient as much of the competition and they are being sold as roof panels, that the recently opened German factory can sell everything it makes for many months ahead.

    Nobody has ever pretended that a 1 sq M panel would power anything large. There is only so much sunlight, and nobody has ever pretended the second law of thermodynamics would be broken. No-one has ever pretended that 1 sq M panels would cost $1 apiece; you could not make a structure to withstand wind loading that cheaply. There is a huge difference between actual forecasts of an eventual $1 per peak watt, and $1 per sq M. $1 per watt works out at about $140 per sq M for a 14% efficient panel.

    To the people who modded this insightful: if you can't tell an obvious troll from engineering reality, plase hand in your geek cards now and go play with Facebook.

    --
    From scarped cliff or quarried stone she cries "A thousand types are gone, I care for nothing, no not one."