Slashdot Mirror
Using Sun's Energy to Split Water Means Solar Power All Night
phorm writes "Reuters is carrying an article about a recent MIT development which may pave the way for solar-energy to be collected for use in low-input periods. According to Reuters, the discovery of the a new catalyst for separating hydrogen+oxygen from water requires only 10% of the electricity of current methods. This would allow storage-cells to function as a form of battery for other forms of energy-collection, such as solar panels. The new method is also much safer (and likely environmentally friendly) than current methods, which require the use of a dangerously caustic environment, and specialized storage containers." sanjosanjo points out coverage of the process at EE Times, which features the MIT group's press release.
For one, professors have to get grants to do their research, so they are sometimes given to overstatement to that end. They are, after all, only human which means that not all of them are honest. Also, some are simply unrealistic. They think they can do something, so they announce it, even though they have no idea how to get there, and then maybe never end up doing so. Finally sometimes shit just ends up being impossible. It looks good, seems like things will work, however in the end you can't make it happen. That happens with research. You can spend millions only to realise you've been down a dead end and there's nothing to be done about it.
I agree an announcement from a major university is much more credible than some startup, but don't think things out of universities aren't overstated at times.
15 amps? 120 watts?
No, most houses have 100-200 amp service. At 120 volts. Which works out to 12000-24000 watts, peak. Average electricity consumption is right around 1 kilowatt, so the poster who said to divide by 5 was right.
Dan Nocera is one of the top ten names (American, anyway) in this field right now, and he has been working on this with several of the others (such as Jay Winkler and Harry Gray). I've sat through probably 10 of his seminars at American Chemical Society conferences in the last two years, and he was pretty close in April (and seemed really excited about a new development, too). My guess is that he's spent the intervening time repeating the experiments, to guarantee it works. And as to corroborating sources, I'm sure that his cohorts from CalTech, etc. are double-checking everything, too.
Anyway, I guess where I was going with this is that this isn't some fuel pill, or Al Gore rambling on about things he doesn't understand. Nocera is to water splitting what Miyamoto is to video games, and if he says that he's done it, I'm sure he's done it.
My sister opened a computer store in Hawaii. She sells C shells by the seashore.
Indeed, Nocera has been working on this for what must be at least 15 years by now. I remember he had some catalysts four or five years ago that worked using only the ambient intensity of sunlight, but were far too expensive to be practical (so I heard).
I also work in catalysis, and one of my friends is doing water splitting, so I've read a few papers on the topic. The materials used don't surprise me, cobalt is approximately as good as you can find. Also, I would note that this catalyst (I downloaded the paper) is releasing oxygen and gradually producing HPO4, which can then later be oxidized to (presumably) release energy. I'm not familiar with using phosphoric acid as a fuel, but the paper sounds extremely plausible.
I would also suggest that, based on my reading of the paper, any real world applications would be 5-15 years away, depending on how well they're able to coat their electrodes.
The paper is published in a peer reviewed journal. It's patented, not secret.
They used ITO glass as an electrode with a neutral KPi electrolyte with 0.5mM Co^{2+} at 1.29V. They tried it with CoSO4, Co(NO3)2, and Co(OTf)2 as the cobalt source. It also works on FTO glass, as well as with a NaPi electrolyte.
The description of the processing method is extremely detailed. I would have little difficulty duplicating this experiment. (YIAAS)
It's rather snotty to flatly contradict a statement you disagree with, and then claim to have "fixed" it.
-jcr
The only title of honor that a tyrant can grant is "Enemy of the State."