Natural Gas "Cleaning" Extracts Valuable Waste Carbon
Al writes "There's been a lot of focus on "clean coal" lately, but a Canadian start-up called Atlantic Hydrogen is developing a way to make natural gas more environmentally friendly. The process involves using a plasma reactor to separate hydrogen and methane in the gas. The procedure also turns carbon emissions into high-purity carbon black, a substance that is used to make inks, plastics and reinforced rubber products. Utility companies could potentially sell the carbon black, making the process more financially attractive."
Let the Taco Bell jokes commence.
See my journal for slashdot ID's by year. Mine created in 2005. http://slashdot.org/journal/289875/slashdot-ids-by-year
You are still going to run out of gas eventually, this just means that we don't hurt the environment as much in the process.
Laughter is the best medicine, except if you have a broken rib.
Now, this is the best example of something to call "organic" in a positive way.
A lot of technologies are being developed to reduce the CO2 emissions at source, which is useful. However, are there any industrial process that will reduce the already-emitted CO2 in the atmosphere?
Before somebody says "a tree", we might need an alternative.
This process would produce tons of useful nanoparticles (like nanotubes, buckballs etc) but it would be mixed in with a lot of 'junk' molecules. Once / if an efficient process for separating and sorting the good stuff is developed, this would be a real gold mine.
After reading the article it is mentioned in the last paragraph that:
"Chibante and his research team are working with carbon-black maker Columbian Chemicals to identify a market for Atlantic Hydrogen's carbon, which has "very interesting carbon nanostructures that we just don't see from industrial production," he says. An early study shows that the material has a high surface area and thin chicken-wire structures called graphene stacks, making it potentially ideal in the production of high-performance batteries and ultracapacitors and for structurally reinforced products."
So this sound like it has additional benefits other than just reducing the total CO2 released by burning natural gas.
Time to offend someone
Current processes
Carbon black production
Hydrocarbon + O2 -> C (carbon black) + H2O + CO2 + other carbon-containing waste
Hydrogen production by steam reforming (requires energy input)
CH4 + H2O -> CO + 3H2
"New" process (also requires energy input)
CH4 -> C + H2
So looked at as a method of carbon black and hydrogen production, it certainly seems better, but it depends on the relative amounts of energy used for steam reforming versus the "new" process. But if you basically throw away the hydrogen by mixing it back in with the natural gas (as the article suggests), you're wasting a lot of the gain that would be achieved by displacing the steam reforming process.
I'm not really buying the idea that hydrogen-enriched natural gas will burn more cleanly. It will produce less CO2, true, but at the price of less energy per unit volume. And natural gas can already be burned less completely.
I put the scare quotes around "new" because this isn't a new process. According to Wikipedia, not only was it developed (by Kvaerner) in the 1980s, it's actually already in use in Norway for producing hydrogen and carbon black.
Oh, that's right - fossil fuels, and a lot of coal.
Nice.
And, remember, this counts against your energy return on energy invested. How much energy does it take to do this, and then mark it against the energy produced by the natgas. And the transportation of the natgas to this machine and then to the customer. And you get hydrogen out of the deal? Great - a gas so small nothing can really hold it, and due to its physical structure always requires more energy to break its bonds and contain it than what you get from burning it.
At least you get lamp black out of the deal.
Sigh. NEXT!
RS
Shoes for Industry. Shoes for the Dead.
Cognitive dissonence anyone?
Soy-Based Toner Cartridges?
God: When you do things right, people won't be sure you've done anything at all.
Then what you need is some way to convert coal to methane.
a lot of schemes like this look great on paper, until you consider the energy expenditure involved in running the thing
who knows, maybe carbon black is worth more than the extra methane it costs to run the thing. that would make it financially friendly. but its certainly not environmentally friendly, when you consider the extra methane consumption
intellectual property law is philosophically incoherent. it is your moral duty to ignore it or sabotage it
1. I don't doubt that this would lead to cleaner gas. It's hard to get soot, CO2, PAH's from hydrogen. It even puts out less NOx.
2. Energy for running the plasma doohickie could easily come from renewables. The production process could be a pretty a flexible load.
3. I don't see us running out of methane calthrates for natural gas. There might even be some deposits we would like to mine since they are approaching istability.
4. Maybe we could make some diamond with that plasma.
5. Yes there would be a 5% to 10% hit on BTU/ft^3. I don't know if pressure regulator upstream of my meter could be tweaked that much?
6. Is that J/l @ STP in metric? Kcal/22.4l @ STP?
7. A possible low CO2 hydrogen source.
8. What happens to carbon black today? Land fill of painted products? Incineration of toner on paper? We can probably sequester the carbon a little longer though.
9. I doubt that the price for carbon black would stay very high for long with this. It might still be more valuable than coal for smelting metals and cement making. It could set a trading ceiling for carbon trading shares.
9. Is a big pile of carbon black pyrophoric like a big pile of coal left to sit too long and catch fire?
10. This really does make me think about carbon foot print. If I go through 20 tons/year of natural gas/H2, then what happens to my annual ton of carbon? Construction material? clothing? A new Tesla? A huge pile of batteries, tires and vaulting poles?
Ignoring efficiencies which would likely make the process less interesting..
burning H2 yield 286 kJ/mol
buring Methane yields 890 kJ/mol
Now, one problem with H2 is energy density ... Ie amount of energy per unit volume which is directly proportional to moles.
If we were to produce 2 units fo H2 from one unit of Methane we would have 64% of the total energy and 32 % of the original energy density. This ignores the carbon cost of generating H2 form Methane.
The plasma is generated from electricity obviously that has a carbon cost that needs to be factored in when counting the carbon it has removed. Since they cite 7%, we are lead to believe that for whichever energy source they are using as a baseline they claim they claim they leave slight more energy in the stream than it took to de-carbon it.
So, all in all. This technology should be treated sceptically. It may work roughly as they say which is not great. It will not improve much from here if the technology even works as well as claimed.
You can haz any colour you like as long as it's black
"I like it when the red water comes out.."
is powered by pixie dust and unicorn magic extruded from a magic time-plum which fell to earth from space a million years ago and emits soothing barry manilow renditions when not in use.
Good people go to bed earlier.
And who would buy sawdust just to throw it in a pit?
Why do you have such a hard-on for anything that reduces CO2 production?
one point for the canadians, thats 10 points for the canadians and zero for the americans!!!
But to do this with bio gas would be dumb.
Biogas is carbon neutral
The biogas burns cleaner their way: Less nitrous oxides and whatnot, less smog, cleaner air: Good.
You can't take the sky from me...