Artificial Leaf Could Provide Cheap Energy
sciencehabit was one of several readers to tip news of a sunlight-harvesting artificial leaf, writing:
"Nearly all the energy we use on this planet starts out as sunlight that plants use to knit chemical bonds. Now, for the first time, researchers at the Massachusetts Institute of Technology have created a potentially cheap, practical artificial leaf that does much the same thing—providing a vast source of energy that's easy to tap. The new device is a silicon wafer about the shape and size of a playing card coated on either side with two different catalysts. The silicon absorbs sunlight and passes that energy to the catalysts to split water into molecules of hydrogen and oxygen. Hydrogen is a fuel that can be either burned or used in a fuel cell to create electricity, reforming water in either case. This means that in theory, anyone with access to water can use it to create a cheap, clean, and available source of fuel."
There's only so much insolation to harvest. If this is cheaper and higher efficiency than existing solar cells, then great. Based on the article, it's only 5.5% efficient, so meh. But even if it were 100% efficient, it's not some magical free energy machine, and never can be. While it's true that "nearly all the energy we use on this planet starts out as sunlight", a lot of that energy arrived at earth several millenia ago. In the long run, we're going to need to either use less energy (preferably by making things more efficient, not making do with fewer things) and/or get some near-unlimited fuel source, like fusion.
Get excited.
Read comments.
Excitement crushed.
San Francisco Photographers
So, unless there's a pretty substantial price benefit to the cell, where's the benefit?
As you have discovered, the economics are precisely the key to solar energy. The power density (Watts/m^2) is unimportant, except for installations with unique constraints (e.g. spacecraft). For terrestrial applications, Watts/$ is the most interesting term.
Similarly, for economic reasons, I don't think electrolysis (or H2) is likely to succeed on a wide scale. The dirty secret of the H2 "economy" is that the hydrogen fuel cell cycle has a round trip efficiency of about 25%. A fuel cell is effectively a battery, and we already have substantially better batteries at a tiny fraction of the cost.
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