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Australian University Unveils New Carbon-Trapping Bricks

FirephoxRising writes "A research pilot plant in Newcastle will trial world-first technology that turns carbon emissions into bricks and pavers for the construction industry. More efficient and stable than storing gas in the ground, the new method will sequester carbon and can work anywhere, unlike geo-sequestration which is site specific."

25 of 142 comments (clear)

  1. Bringing coal to Newcastle! by Anonymous Coward · · Score: 5, Funny

    From TFA: "capture carbon dioxide emissions and turn them into rock." We all know what rock is made from carbon...

    So they're bringing coal to Newcastle -- specifically, artificial coal bricks and pavers!

    1. Re:Bringing coal to Newcastle! by Cryacin · · Score: 2

      Meh, put a brick in it.

      --
      Science advances one funeral at a time- Max Planck
    2. Re: Bringing coal to Newcastle! by Anonymous Coward · · Score: 2, Informative

      OP here. It's not, of course, coal, else it would be used for fuel. It's some flavor of carbonate.

      It takes all the energy initially extracted by burning the coal in the first place to convert the CO back into coal, whereas making nice stable carbonates is (depending on the metal's original form, of course) likely exothermic.

    3. Re:Bringing coal to Newcastle! by noh8rz10 · · Score: 2

      my rule is to read the first six words of a summary and make all my judgments from there. saves time from reading!

  2. Turning CO2 into what? by edibobb · · Score: 4, Insightful

    The article fails to mention what they intend to convert the CO2 into, or how much it will cost. Maybe the primary function of the company is to win government grants.

    1. Re:Turning CO2 into what? by YrWrstNtmr · · Score: 3, Insightful

      The article fails to mention what they intend to convert the CO2 into, or how much it will cost. Maybe the primary function of the company is to win government grants.

      "Maybe"?

    2. Re:Turning CO2 into what? by thegarbz · · Score: 2

      Looks like the "company" which developed the technology is backed by the University of New South Wales. That's not an institution that normally backs vapour-ware. Typically these are attempts to monetise research and as such typically result in at least pilot trials.

    3. Re:Turning CO2 into what? by noh8rz10 · · Score: 2

      this seems like a nonsequiter to me. how does it relate?

    4. Re:Turning CO2 into what? by pm3003 · · Score: 2

      From the US DOE : "Direct mineral carbonation has been investigated as a process to convert gaseous CO2 into a geologically stable, solid final form. The process utilizes a solution of sodium bicarbonate (NaHCO3), sodium chloride (NaCl), and water, mixed with a mineral reactant, such as olivine (Mg 2SiO4) or serpentine [Mg 3Si 2O 5(OH)4]. Carbon dioxide is dissolved into this slurry, by diffusion through the surface and gas dispersion within the aqueous phase. The process includes dissolution of the mineral and precipitation of magnesium carbonate (MgCO3) in a single unit operation. Optimum results have been achieved using heat pretreated serpentine feed material, with a surface area of roughly 19 m 2 per gram, and high partial pressure of CO2 (PCO2). Specific conditions include: 155C; PCO2=185 atm; 15% solids. Under these conditions, 78% stoichiometric conversion of the silicate to the carbonate was achieved in 30 minutes. Studies suggest that the mineral dissolution rate is primarily surface controlled, while the carbonate precipitation rate is primarily dependent on the bicarbonate concentration of the slurry. Current studies include further examination of the reaction pathways, and an evaluation of the resource potential for the magnesium silicate reactant, particularly olivine. Additional studies include the examination of various pretreatment options, the development of a continuous flow reactor, and an evaluation of the economic feasibility of the process. "

  3. Calcium carbonate by manu0601 · · Score: 4, Informative

    CO2 is carbon at its maximum oxydation level (you cannot burn it anymore). Limestone is made of calcium carbonate (and magnesium carbonate in a lesser extent), it is also carbon at its maximum oxydation level. The transformation seems smart, but it requires water (easy part) and calcium. Where will that calcium come from? The usual source is limestone...

    1. Re:Calcium carbonate by fuzzyfuzzyfungus · · Score: 4, Funny

      Fluorine considers your 'you cannot burn it anymore' assessment to be a sign of weakness and defeatism. Oxygen may be the 'kleenex' of Oxidizing agents; but it is far from the most competent one...

  4. Turning CO2 into carbonates? by Immerman · · Score: 5, Insightful

    A good question, though I'm less cynical about the presumed answer. They did say something like they were recreating the Earth's natural processes, so probably something like calcium carbonate (CaCO3), the stuff that egg and seashells are made of.

    Can anybody say how various carbonates compares energetically to oil and CO2? My chemistry is pretty rusty. Since the final cycle would be oil -> CO2 -> carbonate the maximum net energy would be that from a hypothetical fossil fuel -> carbonate transition, which would tell us how energetically feasible this is with the right catalysts. If it's an endothermic reaction this is a complete non-starter except as part of some hypothetical future atmosphere-scrubber (and I do really hope we have the tech ready if it comes to that).

    If the reaction is exothermic though then there's hope, especially if it's a significant portion of the (presumably larger) oil -> CO2 energetic gap. If we could complete the fossil fuel -> brick transition while generating even half as much power as currently then this could be a real game-changer. Every coal- or oil-fired power plant could have it's adjacent brick factory and become carbon neutral. We could stay on fossil fuels for centuries without aggravating the global climate, even as oil and gas run out - we have truly massive coal reserves to fall back on. Of course we'd need to really shift the attention back to general environmental protection again, and get serious about that, otherwise the search for fuel could get *really* ugly. Coal mining isn't exactly environmentally friendly

    --
    --- Most topics have many sides worth arguing, allow me to take one opposite you.
    1. Re:Turning CO2 into carbonates? by aliquis · · Score: 3, Insightful

      Every coal- or oil-fired power plant could have it's adjacent brick factory and become carbon neutral. We could stay on fossil fuels for centuries without aggravating the global climate

      Or we could run on thorium for thousand(s?) years.

      Or we could build those damn solar cells on the moon and not care any more (though I assume that bring some more energy here which will contribute to.)

      Since we're in a fucking hurry best thing to do now would be to stop consume items until we've catched up with solutions.

      Those barren (oil producing) lands look like shit if you ask me.

      Wish we could get rid of all the damn plastic. It's kinda ok if you burn it but all obviously isn't burned.

    2. Re:Turning CO2 into carbonates? by ceoyoyo · · Score: 5, Informative

      It's been a while since I did chemistry, but calcium carbonate can be made from calcium oxide and carbon dioxide in the presence of water. I think that's more or less how it's done in sea creatures. So you've got:

      CaO + H2O + CO2 --> CaCO3 + H2O

      I believe the reaction takes place spontaneously when you dissolve calcium oxide and CO2 in water. To check, add up the standard enthalpy of formation for both sides. The water cancels, of course, leaving:

      635 kJ/mol + 393.5 kJ/mol --> 1207 kJmol

      Right is more negative than the left so the reaction is exothermic. Calcium carbonate is basically limestone or marble, so a nice building material, mixed with other stuff to stabilize it against acid rain. Leaving the question of where you get the CaO.

      Having done all that work, I found this: http://www.globalccsinstitute.com/publications/novel-co2-capture-taskforce-report/online/54351.

      Looks like the reactions are all exothermic, but you have to come up with the minerals, which means mining a ton and a bit of rock for every ton of coal you burn. But you get building materials out of the bargain too.

    3. Re:Turning CO2 into carbonates? by Anonymous Coward · · Score: 2, Informative

      Calcium carbonate and acid rain equals water soluble gypsum. Not cool to use as an exterior material.

    4. Re:Turning CO2 into carbonates? by Anonymous Coward · · Score: 5, Informative

      A bit of digging finds that they are reacting Olivine (Magnesium silicate) with CO2 giving Magnesium Carbonate.

      This reaction has been studied for years as a sequestration reaction for CO2 but traditionally it needs high pressure and moderate temperature to get reasonable
      conversion of the Olivine. The team at Newcastle Uni have come up with a method to produce Magnesium Carbonate (Dolomite) at much more modest reaction conditions.

    5. Re:Turning CO2 into carbonates? by Savage-Rabbit · · Score: 2

      A bit of digging finds that they are reacting Olivine (Magnesium silicate) with CO2 giving Magnesium Carbonate.

      This reaction has been studied for years as a sequestration reaction for CO2 but traditionally it needs high pressure and moderate temperature to get reasonable
      conversion of the Olivine. The team at Newcastle Uni have come up with a method to produce Magnesium Carbonate (Dolomite) at much more modest reaction conditions.

      So how much CO2 is being produced with this process per ton of CO2 sequestered? There is hardly any point in an exercise like this if the ratio isn't smaller than one.

      --
      Only to idiots, are orders laws.
      -- Henning von Tresckow
    6. Re:Turning CO2 into carbonates? by Immerman · · Score: 2

      Oh, no argument that going to thorium, solar, etc. would be preferable. We're not faced with a technological problem though, but a business one. If we could profitably eliminate CO2 emissions from fossil fuels we could buy ourselves another 50-100 years for the conversion, allowing the alternative tech to become more viable for the developing nations where the current cost premium is a stumbling block.

      But yeah, we're reaching the point that available fossil fuels are getting increasingly environmentally devastating to extract, so if we go that route we will absolutely need to get downright militant toward environmental protection or we'll be faced with an even worse situation.

      I'd much rather see something like Gen4 style fully sealed nuclear reactors being deployed where solar,etc isn't viable - if they can hit their projected cost then the lifetime cost of the entire sealed reactor will actually be comparable to an equivalent energy capacity worth of coal (average market price, some places can get coal much cheaper). The problem of course is that nobody buys 10-20 years worth of coal all at once, so we'd need to get serious about organizing cheap and easy energy financing if we want to go that route.

      --
      --- Most topics have many sides worth arguing, allow me to take one opposite you.
  5. Re:Seems like overkill by aardvarkjoe · · Score: 5, Funny

    I bet you could get a lot of investors on board with a plan to use solar power to convert atmospheric CO2 into building materials. Just don't tell them that the super-secret device that does so is called a "tree."

    --

    How can we continue to believe in a just universe and freedom to eat crackers if we have no ale?
  6. Speaking as a fungus... by fuzzyfuzzyfungus · · Score: 2

    Your proposal to add massive amounts of cellulose and lignin to the environment is relevant to my interests...

  7. Re:Uh.... What? by lxs · · Score: 2

    Are they black? black won't sell. nobody wants black bricks.

    If ebony and ivory live together in perfect harmony side by side on my piano keyboard, oh Lord why don't we?

  8. Re:Seems like overkill by SoftwareArtist · · Score: 2

    Centuries may seem like a long time to you. Just like it did to people a few centuries ago, for whom "not until the 21st century" might as well have been "forever". But it's not really very long. Especially compared to this technology, which can store it stably for millions of years.

    --
    "I'm too busy to research this and form an educated opinion, but I do have time to tell everyone my uninformed opinion."
  9. Re:Carbon burns! by dbIII · · Score: 2

    Graphite crucibles are used for holding molten metal at high temperatures. Looks like you were a bit quick to yell "idiots" :)

  10. Re:Uh.... What? by Jeeeb · · Score: 2

    Dear AC,

    TFA shows that the bricks are a light brown. Should go quite well in warm, sunny climates (like... you know Australia!). Although even if they were black, I'm sure they could be painted with a reflective coating.

    Are they flammable? The only compressed carbon i know offhand is coal. Nobody will want flammable bricks.

    Diamond is another famous form of compressed carbon. These aren't coal or diamonds though. They are a carbon compound. If you stopped to think for a few seconds, you'd realize that they are almost certainly not flammable. High flammability means it has lots of energy stored. This rock is being made from the waste product (CO2) left over from extracting energy.

    Are they cheap? It's hard to beat concrete for price.

    Probably not but if the cost can be offset through carbon trading schemes like those active in Australia*, Europe and China they might be quite cost effective. The entire point of TFA is that they have found a way to make the conversion method practical.

    Also btw. if you are worried about heat absorption, then you don't want to use concrete as a building material!

    Solve those three potential problems and you might have something. And if they do you might want to forget about bricks and pavers and replace the cement block with them. That would sell. Billions of them.

    Would it have been so hard to read the article and think before posting?

    (*Technically Australia has a carbon tax but will be converting to an emissions trading scheme)

  11. I think I know what this is about. by Hans+Adler · · Score: 3, Informative

    The article says they have spent 6 years researching the technology. 6 years ago is also when German researchers published their discovery: http://en.wikipedia.org/wiki/Hydrothermal_carbonization (The German version of the Wikipedia article is much more informative.)

    As far as I know, it started with a researcher wondering how exactly the Earth produced coal and oil and discovering that for almost a century nobody had done any new experiments. So he did some, adding some of today's knowledge.

    It turns out that if you put water and basically arbitrary organic waste (wood, grass cuttings, leaves, entire weeds, whatever) into a pressure cooker, add some citric acid as a catalyser and then heat it to 200 degrees Celsius, then you get an exothermic reaction which makes the stuff keep that temperature without further input of energy. Provided you are not using an ordinary pressure cooker (which will explode) but some special thingy.

    You stop the reaction after 8-12 hours and filtrate the water to get the product. Depending on the precise time you stop, you can create topsoil, oil, brown coal or low-quality stone coal. While the method doesn't seem to produce any excess heat, you can theoretically make an industrialised country CO2 neutral by treating all of its green waste that way and storing the resulting low-quality coal underground, e.g. in an old coal mine.