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No Longer "Noble"; Argon Compound Found In Space

mbstone writes "Scientists at the University College of London — where argon was originally discovered in 1894 — have now found spectroscopic signatures of molecules of argon hydride (ArH), said to be produced via explosive nucleosynthesis in a core-collapse supernova in the Crab Nebula. The post-supernova molecular dust was observed by the Herschel Space Observatory shortly before it ran out of coolant in April.."

32 of 110 comments (clear)

  1. Re:What does the comment about "Noble" mean? by DoctorChestburster79 · · Score: 3, Informative

    I don't get the connection between the title and the summary.

    That far right side of the Periodic Table...where Helium, Neon, Xenon, Argon, and Radon live. Those elements have always been taught as being chemically inert (i.e. not able to be combined with any other elements), hence why they are called "noble" gases. This apparently is the first instance where that rule isn't necessarily true.

  2. What's next? by DaTrueDave · · Score: 4, Informative

    Do we categorize Argon as a non-noble gas, or do we redefine what a noble gas actually is?

    Wait, I guess noble doesn't mean what I thought it meant, or there were already plenty of exceptions, as I just read this wiki article: https://en.wikipedia.org/wiki/Noble_gas_compounds

    1. Re:What's next? by jo_ham · · Score: 4, Interesting

      Argon has already been shown to be "non-noble" many years ago - hell, you can buy Argon compounds from chemical suppliers right now (like Argon difluoride).

      The title is simply scientific ignorance.

    2. Re:What's next? by rmdingler · · Score: 3, Funny

      This. Instead of shopping for Christmas before the Baptists get out of church and flood the stores, I am looking up noble gases, then noble metals, and then electric potential on a Sunday morning.... sigh.

      --
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      Ernest Hemingway

    3. Re:What's next? by Tim+the+Gecko · · Score: 3, Informative

      Argon has already been shown to be "non-noble" many years ago - hell, you can buy Argon compounds from chemical suppliers right now (like Argon difluoride).

      I think you mean Xenon difluoride. I can't find any reports of Argon difluoride being produced.

    4. Re:What's next? by jeffb+(2.718) · · Score: 4, Informative

      You are confused. You can buy xenoncompounds off the shelf, but certainly not argon compounds. Nobody has yet made argon difluoride, and I'm not sure current theory supports its existence.

      The first synthesis of an argon compound was reported in 2000, so the first part of the headline is misleading -- this discovery itself doesn't "demote" argon. But it's still interesting news.

    5. Re:What's next? by mysidia · · Score: 2

      Do we categorize Argon as a non-noble gas, or do we redefine what a noble gas actually is?

      We don't necessarily need to do either; the article headline is a little bit misleading.

      Non-reactivity, or the non-existence of molecules is not inherent to the definition of Noble gas. Non-reactivity is a description of what is believed to be true about noble gasses. The noble gasses were long believed to be completely nonreactive; but now, compounds of Xenon, Krypton, Radon.... and now Argon are known. We just need to find some compounds of Helium and Neon, and then.... compounds will be known of all the noble gasses.

      Well, for two: explosive nucleosynthesis in a core-collapse supernova is not exactly your every day chemical reaction.

      For three: Argon is still relatively inert. For the most part; you will not find compounds of argon in nature, or common materials that Argon will readily form compounds with in ordinary chemical reactions.

    6. Re:What's next? by fermion · · Score: 3, Informative

      These things are often oversimplified to teach the basics. For the purposes of a introductory chemistry class, the group 18 elements are not going to play a part in chemical reactions under everyday circumstances. This is simplified down to 8 valence electrons. When one talks about s^2p^6 for everything but He, all the eyes starts going into the forehead and all the other details become lost and questions such as 'is this going to be on the test' get most of the attention. What we are talking about here is not ordinary chemistry, but supernovas, which build most other elements out of the noble gas Helium.

      --
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  3. Re:What does the comment about "Noble" mean? by _Shad0w_ · · Score: 3, Informative

    Only it's not; apparently compounds of the noble gases have been known for a while. The only thing there's no known compound of is helium. At least that's what one my chemistry friends is telling me.

    --

    Yeah, I had a sig once; I got bored of it.

  4. Re:What does the comment about "Noble" mean? by rubycodez · · Score: 4, Informative

    But worth explaining for others that either didn't have chemistry class or maybe snoozed through it. The atoms of "noble" gases have their outer electron shell full so are very non-reactive, they usually don't make chemical bounds with other elements except under extraordinary circumstances requiring a lot of energy. Helium, neon, argon, and radon are probably the ones most people have heard mentioned at some time in daily life.

    http://en.wikipedia.org/wiki/Noble_gas

  5. Re:What does the comment about "Noble" mean? by Anonymous Coward · · Score: 4, Informative

    This isn't even a compound, though. It's a molecular ion, ArH+. If you added an electron to it, it would fall apart, since ArH (neutral) is not bound.

    A similar molecular ion exists for helium, HeH+. This ion is very important for the evolution of the early universe, since it can emit IR radiation to cool gas clouds, allowing stars to form from the nearly-pure H/He clouds that existed after the big bang.

  6. Re:What does the comment about "Noble" mean? by DaTrueDave · · Score: 3, Informative
  7. Re:What does the comment about "Noble" mean? by nbritton · · Score: 5, Informative

    Noble as in inert - it's not supposed to react to form a stable molecule.

    Noble doesn't imply non-reactive, all of the noble elements can be ionized, with enough energy, just like any other element. What it means is they have a stable electron configuration. Helium, Neon, Argon, Krypton, Xenon, and Radon all have there outermost electron orbital shells filled. This means they're not inclined to give, borrow, or take electrons from other elements, this is why there called noble.

    The fact that argon hydride was found in space implies that krypton, xenon, and radon hydride can also be found in space.

  8. xenon not so noble either by Gothmolly · · Score: 2

    xenon will combine with halogens. anything will combine with anything, you just need enough juice.

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    1. Re:xenon not so noble either by hardtofindanick · · Score: 2

      Still trying to figure out if that is a dirty comment.

    2. Re:xenon not so noble either by jeffb+(2.718) · · Score: 4, Informative

      Anything will combine with anything -- it just won't stay combined. You can rip as many electrons off (say) neon as you like, throw it in with another species, and watch them stick together long enough for neon to nab the electrons it wants -- but you won't get a compound that persists. Similarly, you can force xenon and anything together, but only a few pairings will produce compounds stable at even cryogenic temperatures.

  9. Re:What does the comment about "Noble" mean? by gstrickler · · Score: 4, Interesting

    The fact that argon hydride was found in space implies that krypton, xenon, and radon hydride can also be found in space.

    Probably, but since the quantities of those elements will be dramatically lower than argon, detecting them will likely be much more difficult.

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  10. Re:What does the comment about "Noble" mean? by gstrickler · · Score: 2

    You mean my plans to build an Argon bomb and take over the world aren't going to work?

    You'll just have to use 39Ar or 42Ar, and probably need a H-fusion reaction to detonate it.

    --
    make imaginary.friends COUNT=100 VISIBLE=false
  11. Re:What does the comment about "Noble" mean? by Dcnjoe60 · · Score: 2

    I don't get the connection between the title and the summary.

    That far right side of the Periodic Table...where Helium, Neon, Xenon, Argon, and Radon live. Those elements have always been taught as being chemically inert (i.e. not able to be combined with any other elements), hence why they are called "noble" gases. This apparently is the first instance where that rule isn't necessarily true.

    Of course it took the energy of the collapse of a star to produce those compounds, so for practical purpose, those gases are still all pretty noble.

  12. Re:What does the comment about "Noble" mean? by wonkey_monkey · · Score: 5, Funny

    That far right side of the Periodic Table

    Also known as the fascist elements.

    --
    systemd is Roko's Basilisk.
  13. Re:What does the comment about "Noble" mean? by Deadstick · · Score: 2

    Helium, neon, argon, and radon are probably the ones most people have heard mentioned

    Everybody's heard of krypton, although most of them think it's a planet and Tom Clancy couldn't spell it.

  14. El NIÑO by smittyoneeach · · Score: 3, Funny

    Noble In Name Only
    I thought we could rely on these gasses to stay true to their column on the periodic table, but, no, they've sold out, just like that whorish oxygen and hydrogen, which will twerk with even the most sordid elements of society.
    We're just going to have to look elsewhere for the stability we crave at all levels.

    --
    Get thee glass eyes, and, like a scurvy politician, seem to see things thou dost not.--King Lear
  15. Except by justthinkit · · Score: 2, Insightful

    they're not inclined to give, borrow, or take electrons from other elements

    Except these aren't the words used on the wiki page. The word I was taught is "share". For example, Hydrogen has one electron and desires two for stability. So it shares one from Oxygen or Carbon, etc. And in that sharing, Oxygen (desiring two) gets its needs satisfied by sharing one each with two Hydrogens.

    --
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  16. Re:What does the comment about "Noble" mean? by Anonymous Coward · · Score: 4, Informative

    No, noble != inert

    When I first learned about the elements many years ago, the description for those elements in the rightmost column was "inert". This means completely non-reactive.

    Later on, when chemists made compounds of xenon, they realized the elements might not be so inert, after all. They gave the elements a new name: noble. They were not truly inert, but tended to have that tendency. Like other noble elements--such as gold or platinum--the elements in the rightmost column were disdainful of mixing with the hoi-polloi. It didn't mean they couldn't combine with other elements; they are just disinclined.

  17. If... by mha · · Score: 4, Informative

    ...you want to 1-up him you'll have to go for the quantum mechanic explanation of bonds. As far as *useful* models for chemical bonds go, even chemists use something pretty far from the "truth" . There are valence bond theory, orbital hybridization, resonance, and quite a few more.

    When it comes to explaining nature, you use the model that is most USEFUL for what you want to explain, not for the most complicated one possible to impress your peers because you are so smart. :) That is why in many books atoms are still represented by red, white, blue "balls" and no one complains about it.

    And by the way, the in the oxygen-hydrogen bond oxygen actually does sort of "borrow" the electron - the probability distribution for the location of that electron shifts towards the nucleus of the oxygen. That is why water molecules, while actually neutral (if not ionized), still act polar - the oxygen is essentially negative, the hydrogens positive. There is no equal "sharing".

    1. Re:If... by RockDoctor · · Score: 2

      Water acts polar because of the nature of the oxygen atom itself.

      Sort-of true. It's actually a consequence of the symmetries of p and s orbitals. Hybridising one s and three p orbitals (each oriented on one of the x, y and z axes gives you four "sp^3" orbitals. But that's true for any atom, not just oxygen. The symmetries involved - well can you think of a way that orients four directions in space in a maximally symmetrical manner and which doesn't end up with a tetrahedral orientation of the resultant orbitals.

      That tetrahedral orientation of the sp^3 orbitals is what leads to the asymmetry of water and therefore it's dipole moment (and incidentally ammonia, hydrogen sulphide and phosphine, but not methane, silane and the halides of hydrogen).

      This was all worked out in the mid-1930s, but I recall people struggling with it in the mid-80s when I was a student. It's not stunningly difficult, but it's not the easiest thing in the world either.

      --
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  18. This summary is unhelpful. by dandelionblue · · Score: 4, Informative

    The significant parts of this discovery are:

    - a noble gas has been found in space (this confirmed people's expectations that argon-36 could be found as part of a supernova, even though argon-40 is much more common on Earth - note that argon-36 is also available on Earth, just in smaller quantities, it's not a new isotope)
    - a noble gas molecule has been found in space (previously, argon compounds were only detected following Earth-based lab experiments)

    The significant part of this discovery is not:

    - that a noble gas can form a compound. Argon has had known compounds since 2003. Xenon has had known compounds since 1962, some of which are even stable at normal room temperature/pressure.

  19. Re:What does the comment about "Noble" mean? by rubycodez · · Score: 2

    There are the "fullerene compounds", like He@C60, where noble gas atom is trapped inside carbon fullerene. that @ sign means trapped atom. they have distinct chemical properties even though the inside noble gas isn't chemically bonded but instead surrounded by carbon. Argon, Krypton and Xenon ones exist also.

  20. Re:What does the comment about "Noble" mean? by Sique · · Score: 3, Informative

    Actually, it's much more complicated. The gas Argon got its name from greek "argos", which means inert. The chemical group got the name of "noble gases" at the end of the 19th century from William Ramsay (Nobel prize in 1904). The first compound of a noble gas was discovered in 1962 by Neil Bartlett. Argon was the last noble gas for which a compound could be synthesized (2000).

    --
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  21. Give Argon A Break... by krisamico · · Score: 4, Funny

    ... It's not always easy to be noble under extreme conditions. Happens to the best of us!

  22. Re:What does the comment about "Noble" mean? by Zynder · · Score: 3, Funny

    You are both wrong. You have to use Illudium which must be detonated with a Q-36 Explosive Space Modulator. If you don't, you won't have an Earth-shattering Kaboom!

  23. Noble gas molecular ions have long been known by Anonymous Coward · · Score: 2, Interesting

    Argon molecular ions were known well before that. The helium analogue, HeH+, was discovered in 1925!