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'Thermoelectrics' Could One Day Power Cars

sciencehabit writes: "Fossil fuels power modern society by generating heat, but much of that heat is wasted. Researchers have tried to reclaim some of it with semiconductor devices called thermoelectrics, which convert the heat into power. But they remain too inefficient and expensive to be useful beyond a handful of niche applications. Now, scientists in Illinois report that they have used a cheap, well-known material to create the most heat-hungry thermoelectric so far (abstract). In the process, the researchers say, they learned valuable lessons that could push the materials to the efficiencies needed for widespread applications. If that happens, thermoelectrics could one day power cars and scavenge energy from myriad engines, boilers, and electrical plants."

26 of 174 comments (clear)

  1. power cars? technically no by noh8rz10 · · Score: 5, Insightful

    technically, you would still need an energy source (gasoline, natural gas, batteries) to power the cars. thermo electrics could make it more efficient by recycling waste heat. but the thermoelectrics themselves would not power the cars.

    1. Re:power cars? technically no by ShanghaiBill · · Score: 2

      thermo electrics could make it more efficient by recycling waste heat. but the thermoelectrics themselves would not power the cars.

      If they are sufficiently efficient, they could power a car directly. An internal combustion engine is typically only about 15-20% efficient, so the bar is not too high. Using thermoelectrics directly could have several advantages: being solid state, they would be reliable and require little or no maintenance; and since the fuel is just used to create heat, it could use cheaper grades of fuel.

    2. Re:power cars? technically no by fuzzyfuzzyfungus · · Score: 3, Insightful

      My (admittedly pretty hazy at this point) memory of heat engines is that their theoretical peak efficiency depends on the thermal delta they manage to achieve. Exactly the same resource that thermoelectric materials scavenge (albeit at miserable efficiency) into electricity.

      Anybody who actually has some grasp of the matter want to chime in on where and why you would use thermoelectrics (and how efficient they would have to be) rather than simple insulation or one of the various waste-heat-recovery systems that transfer some amount of the heat remaing in outgoing exhaust gases into incoming working fluids?

      Is the thermoelectric advantage purely that, assuming material reliability is OK, they are a 100% solid state, trivial to scale from 'handle with tweezers and magnification' to 'pretty large', and their output is easy to transfer and useful for all kinds of things after just a little DC-DC cleanup, or are there actually situations where they might be absolutely more efficient than insulation and heat recovery, rather than just easier to tack in almost anywhere in a design that you have a few extra cubic centimeters and expect a temperature difference?

    3. Re:power cars? technically no by ShanghaiBill · · Score: 4, Informative

      If the car is electric it could be powered by waste heat from industrial processes and primary power generation.

      TEs are bound by the same Carnot efficiency limitations as any other heat engine. If you use low grade "waste heat" then you are going to get very little power.

    4. Re:power cars? technically no by Em+Adespoton · · Score: 3, Interesting

      The power plant -- just like in Diesel Electric trains; you have the electric engines that power the train and the power plant that powers the engines. Diesel fuel powers the power plant, and it in turn was powered by solar energy. The sun is powered by hydrogen fusion reactions; the hydrogen fuel was provided by gravitational attraction, which was powered by time and space.

      I'll leave it up to the reader to determine who/what powered time and space.

    5. Re:power cars? technically no by ShanghaiBill · · Score: 2

      There are several problems with your scenario:
      1. Current TEs are no where close to 50% efficient. More like about 5%.
      2. Pu238 is available in very limited quantities from reactor fuel reprocessing
      3. You can't "turn-off" an RTG. They have to run continuously.

    6. Re:power cars? technically no by Guspaz · · Score: 3, Insightful

      1. I realize that they're currently at 5%, the whole point of my scenario was examining what sort of changes a large increase in efficiency would produce... that's the whole point of the article, after all. Efficiency would need to be somewhere around 50% to justify replacing ICEs with thermoelectric engines. Is that possible? I've got no idea, TFA gives zero layman-friendly information about what sort of efficiency improvements are foreseen.

      2. Supply isn't as big a problem as the incredible safety issues. I acknowledge in my post that the idea is totally insane, which is why I doubt that, even with a big improvement in efficiency, you'd probably never see RTGs used outside of military applications.

      3. That's not necessarily a problem. They conveniently provide power that can be used for active cooling. Cooling them in a vacuum is an issue (hence the giant heat dissipation fins), cooling them in an atmosphere isn't as much of an issue.

      I suspect that sufficiently efficient thermoelectrics might find their way into military UAVs, which could remain airborn for extended periods of time, for example. Or as an alternative to shipping diesel to remote outposts (although they're currently looking into robotic trucks to solve that problem).

    7. Re:power cars? technically no by tragedy · · Score: 2

      1. Current TEs are no where close to 50% efficient. More like about 5%.

      The article was about new, higher-efficiency materials. Still not high enough, and not near 50% efficiency, but certainly getting up there. Good enough so that, if you could get hold of the material, you could at least use it to charge your electric cars batteries currently, even if you couldn't power the car directly. Of course, at present, you'd be better off with a Stirling engine.

      3. You can't "turn-off" an RTG. They have to run continuously.

      Presumably, you could plug them into the power grid in most places you park them

    8. Re:power cars? technically no by tragedy · · Score: 2

      A detonation doesn't neccessarily release more power than a deflagration. That's apples to oranges. It's more a matter of intensity. For example, ANFO detonates, and has a specific energy of something like 3.7 MJ/kg whereas a gasoline/oxygen mixture in an engine typically deflagrates (although it can also detonate under the right conditions, which isn't good for the engine, as you point out) and has a specific energey of something like 9.7 MJ/kg (counting the gasoline plus the oxygen needed for combustion). Clearly averaged over time you can get more power out of an equivalent mass of gasoline/oxygen than from ANFO. Although, if you slice time thinly enough you can say that you get more instantaneous power out of the ANFO because you can get all of the power out of it faster than you can from deflagrating the gasoline/oxygen mixture.

    9. Re:power cars? technically no by dbIII · · Score: 2

      I suppose so but that sounds very impractical since a bunch of candles would give you a larger heat difference. However I don't think many would call it a thermoelectric car just as a diesel-electric train is not called electric and a Prius is not called electric. It's probably best to accept that some people won't accept your proposed terminology and move on to discuss more than just semantics.

    10. Re:power cars? technically no by MachineShedFred · · Score: 2

      you might see the military using RTGs.

      Yeah, I can't wait to have explosive ordinance being flung at vehicles powered by a giant box of ionizing radiation. Great idea.

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    11. Re:power cars? technically no by MachineShedFred · · Score: 2

      I wish I hadn't already posted, or I'd be giving mod points just for the image that went through my mind of a vehicle that used ANFO as fuel...

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  2. Hotter Earth by neonv · · Score: 4, Funny

    We better speed up this global warming thing so we can power our thermo cars!

    1. Re:Hotter Earth by ShanghaiBill · · Score: 4, Informative

      We better speed up this global warming thing so we can power our thermo cars!

      That doesn't work. TEs aren't powered by heat, but by heat gradients. So if everything is uniformly heated by the same amount, there is no benefit.

    2. Re:Hotter Earth by ShanghaiBill · · Score: 2

      So... sink a steel pipe half a mile into the ground, it isn't that hard to create a heat gradient.

      That would give you enough of a gradient to generate a micro-watt from a ton of TEs. In a perfect ideal TE, the efficiency is (1 - Th/Tc) where Th= Hot side in Kelvins, Tc = Cold side in Kelvins. Existing TEs are no where close to ideal, and the earth's heat gradient is about 0.025K/meter. A negligible amount of heat would flow through the TE, and far less than 1% of that would be converted to electricity.

  3. New in the US, not elsewhere by Anonymous Coward · · Score: 3, Informative

    Several vehicle manufacturers have been experimenting with supplemental power generation systems in their cars. BMW for instance has a steam turbine. Honda's doing thermal recovery more efficient than regenerative braking.

  4. Ah, the clickbait by Anonymous Coward · · Score: 2, Informative

    Now, scientists in Illinois report that they have used a cheap, well-known material to create the most heat-hungry thermoelectric so far

    Because it's soooooo hard to actually state what the well-known material is

    Ultralow thermal conductivity and high thermoelectric figure of merit in SnSe crystals

    Oh, I guess it's not hard at all. A salt made of Selenium and Tin.

    1. Re:Ah, the clickbait by rogoshen1 · · Score: 5, Funny
      "Illinois scientist uses this one weird trick to generate free electricity from waste heat; oil companies hate him"

      That's about what that sentence sounded like to me =/

    2. Re:Ah, the clickbait by K.+S.+Kyosuke · · Score: 2

      A salt made of Selenium and Tin.

      Apparently, the author is a lunatic from some tinpot university.

      --
      Ezekiel 23:20
  5. Not so fast, Thermodynamic laws are pesky things by bobbied · · Score: 4, Informative

    I debunked this LAST time it was posted..

    Look, these things are NOT going to get you thermodynamic efficiency gains on anything of value. Any system which is designed to be efficient now, will not benefit from this kind of heat to electricity device. Thermodynamic rules demand a maximum efficiency that is as good as you can do. Most industrial scale energy production is pretty darned good compared to the maximum possible. So you are NOT going to be able to just hook up these things and get electrical energy for *free* (even without the device costs). Any energy you manage to get, will be lost someplace else because you put these devices in the heat flow. Don't even bother trying this, it simply won't work. Don't let them fool you with all this "waste heat" garbage, at least until you understand the Thermodynamic laws that govern all this and can explain what a heat engine is.

    As I concluded before, in situations where you have less than ideal conditions, like in cars with internal combustion engines, you MIGHT get a little bit of energy, but I ask you is it going to be worth it? Are you sure you are going get enough gain to make it worth the weight, cost and complexity? Where I'm not so sure that answer is a good one, I'm willing to entertain that it *might* be possible for internal combustion engines. Go ahead and work on that idea, but I'm fairly sure it's not going to work very well.

    I'd also suggest that there are more efficient heat engines you might consider. These heat flow direct to electricity devices are horribly inefficient compared to the ideal.

    --
    "File to fit, pound to insert, paint to match" - Aircraft Maintenance 101
  6. E = (T2-T1) / T1 by Animats · · Score: 3, Informative

    E = (T2-T1) / T1

    Everyone with an engineering degree knows this. Trying to extract much energy from low-grade heat at the output end of an engine is inefficient. This was figured out a long time ago. Here it is in The Manual of the Steam Engine. It's possible to increase steam engine efficiency by compounding, where the exhaust from each cylinder feeds a larger, lower pressure cylinder. This is cost-effective up to about 3 cylinders ("triple expansion"). Engines up to quintuple-expansion have been built, but the additional power from the last two cylinders in the chain isn't worth the trouble.

    1. Re:E = (T2-T1) / T1 by joe_frisch · · Score: 2

      In mobile systems (cars, planes, etc), the extra hardware to extract energy from the waste heat adds weight and can reduce the overall efficiency of the vehicle. In fixed power-plant type applications they already extract energy down to pretty low discharge temperatures.

      This idea has been around for a LONG time - I remember in the early 70s reading an article in popular science on a system to extract waste heat from car engines. It "worked" but the added weight and expense made it not worth the effort.

      An interesting tidbit is that modern aircraft jet engines are LESS efficient than piston aircraft engines in terms of mechanical energy delivered for the fuel used. Almost all modern transport aircraft use jets because the power to weight is so much higher than for piston engines that the overall efficiency of the aircraft is better than with piston engines.

  7. Re:Not so fast, Thermodynamic laws are pesky thing by bobbied · · Score: 2

    Any energy you manage to get, will be lost someplace else because you put these devices in the heat flow.

    You sir, are ignorant . It's a sad comment on the state of affairs that a clueless bullshit comment like your could be moderated informative.

    We've been extracting energy from waste heat, without incurring extra losses, for over a century now - i

    Calm down and think about what I said. Your average power plant is pretty darn good efficiency wise (which is what I said if you don't mind reading), which is exactly what you are saying too. Yea, we've come a long way from just dumping waste steam, we have optimized things very well actually. I'm saying that there is very little room for improvement left at this point and there is NO FREE LUNCH here. These devices that convert heat flow directly to electric power are NOT going to increase the efficiency of industrial scale power plants. These devices are simply NOT EFFICIENT enough and will disrupt the current efficiency we've already designed in, they will only disrupt the heat flow, raise entropy and result in less power output for the same input. They don't help.

    Don't let them fool you with all this "waste heat" garbage, at least until you understand the Thermodynamic laws that govern all this and can explain what a heat engine is.

    Before cautioning others to educate themselves, first pull your head out of your own ass and educate yourself.

    What on earth did I say that was incorrect? I admit to having struggled with thermodynamics class, but I believe I captured the essence of heat engines and efficiency. So you want to step down off the pedestal and discuss exactly what you think I have wrong in my understanding of thermodynamics? Or are you going to stay up there and keep yelling about how stupid everybody else is?

    --
    "File to fit, pound to insert, paint to match" - Aircraft Maintenance 101
  8. Re:Not so fast, Thermodynamic laws are pesky thing by Immerman · · Score: 2

    The maximum limit on an an arbitrary heat-conversion system is that doesn't break accepted theory is the Carnot-cycle heat engine, where eff 1 - T_cold / T_hot (as measured from absolute 0). But it's a rare real-world engine that gets anywhere near the Carnot efficiency limit - a car engine might run at 1100K for an ideal efficiency of around 73%, but the reality in most cars is closer to 25%. Being solid-state a thermoelectric device could potentially operate at very near the ideal (no mechanical losses), roughly tripling the efficiency. Assuming 90% efficient electric wheel motors the total system efficiency could be nearly as high.

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  9. Re:Not so fast, Thermodynamic laws are pesky thing by bobbied · · Score: 2

    Before you make a bigger ass of yourself, please look up what "waste heat" actually is and familiarize yourself with the "Thermo" in thermodynamics.

    Engines run HOT. Every bit of heat that travels into the metal and outside the engine is lost energy. Capturing bits of that lost energy and putting it to good use is the concept here. This is waste heat, so it is free, just as eating food out of the garbage bin is "free food" -- someone else paid for it, but they threw it out so it is "free" for you. It's not disobeying thermodynamics any more than burning a gallon of gasoline to make a car move 30 miles is disobeying the laws of thermodynamics.

    For other automotive-related things that defy your idiotic concept of physics, please see turbochargers and hybrid cars.

    If you read my post.... (and apparently you didn't) ... I specifically stipulate that automotive applications *might* be successful and worth of investigation. The reason I say this is because of the huge amounts of heat transferred out the tail pipe and radiator in a modern internal combustion engine at sometimes very high temperature differentials leaves something to recover. This is totally unlike a modern power plant, where heat transfer has been carefully engineered to be as efficient as possible, thus leaving little room for thermodynamic improvement. However, my doubts about automotive application are over costs, weight and complexity not about the Thermodynamics of the application.

    --
    "File to fit, pound to insert, paint to match" - Aircraft Maintenance 101
  10. Re:Not so fast, Thermodynamic laws are pesky thing by bobbied · · Score: 2

    The maximum limit on an an arbitrary heat-conversion system is that doesn't break accepted theory is the Carnot-cycle heat engine, where eff 1 - T_cold / T_hot (as measured from absolute 0). But it's a rare real-world engine that gets anywhere near the Carnot efficiency limit - a car engine might run at 1100K for an ideal efficiency of around 73%, but the reality in most cars is closer to 25%. Being solid-state a thermoelectric device could potentially operate at very near the ideal (no mechanical losses), roughly tripling the efficiency. Assuming 90% efficient electric wheel motors the total system efficiency could be nearly as high.

    Don't be fooled that "hey they are solid state and convert directly to electricity". Deep down, it's still a physical process that produces electricity, even if the moving parts are not something you can see. In actual practice, what happens with these things produces horrible efficiency.

    These electronic devices are semiconductor junctions that you get heat to flow through in hopes the electrons will bounce their way across the junction into the cooler side and get stuck... They are not efficient from a thermodynamic perspective, and unless my physical understanding of how they work is totally wrong, they are never going to approach the efficiency of even an internal combustion engine, from a thermodynamic perspective anyway.

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    "File to fit, pound to insert, paint to match" - Aircraft Maintenance 101