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Taking the Ice Bucket Challenge With Liquid Nitrogen

Nerval's Lobster writes As a trend, the ALS Ice Bucket Challenge seems a bit played out—who hasn't yet dumped a bucket of icy water over his or her head for charity? But that didn't stop Canadian chemist Muhammad Qureshi from executing his own sublimely scientific, potentially dangerous variation on the theme: After donating to the ALS Association, he proceeded to douse himself with a bucket of liquid nitrogen. Anyone who's taken a chemistry class, or at least watched the end of Terminator 2, knows that liquid nitrogen can rapidly freeze objects, leaving them brittle and prone to shattering. Pouring it on your skin can cause serious frostbite. So what prevented that bucketful of liquid nitrogen from transforming Qureshi into a popsicle? In two words: Leidenfrost effect. Named after 18th century scientist Johann Gottlob Leidenfrost, the effect is when a liquid comes near a mass that's much warmer than the liquid's boiling point, which (in the words of Princeton's helpful physics explainer) results in an insulating vapor layer that "keeps that liquid from boiling rapidly." In other words, the vapor makes the liquid "float" just above the surface of the object, rather than coming into direct contact with it.

25 of 182 comments (clear)

  1. Re:People who did High School Chemistry know this. by Anonymous Coward · · Score: 5, Funny

    I was educated in the inner city, you insensitive clod. We didn't get any liquid nitrogen at my school because we might make drugs out of it.

  2. I'd have preferred by Rick+in+China · · Score: 3, Informative

    If he were to turn into a popsicle.

  3. I'm starting to wonder... by mark-t · · Score: 5, Interesting

    ... how long will it take before somebody dies?

    I don't mean to sound morbid here, I am just starting to think that this whole thing is pretty darn pointless, If you want to donate money to ALS, do it... but this ice bucket challenge thing is turning into a competition of who can one-up who in how they go about it, and I think it's now only a matter of time before somebody gets seriously hurt or killed.

    1. Re:I'm starting to wonder... by radtea · · Score: 5, Interesting

      ... how long will it take before somebody dies?

      Already happened: http://news.nationalpost.com/2...

      I've stuck my hand in liquid nitrogen (it feels strangely warm) and so can attest to the protective effect of the gas blanket (which is highly insulating) but it is insanely dangerous to pour a bucket of LN2 over your head, and doing so is an invitation to people who aren't as smart or careful as you to do even more stupid and risky things.

      Donate to ALS research [*], by all means! But please, please, don't participate in this ridiculous pyramid scheme of increasingly dangerous stupidity.

      [*] I do not donate to ALS because it is not one of my causes, but I encourage you to think carefully about what you care most about and sign up as a steady, long-term donor to a few causes that are really important to you... this is of far more long-term benefit than episodic giving. If ALS is what matters most to you, go for it!

      --
      Blasphemy is a human right. Blasphemophobia kills.
    2. Re:I'm starting to wonder... by Opportunist · · Score: 3, Insightful

      By weeding out the ones that don't know when to quit.

      --
      We used to have a Bill of Rights. Now, with the rights gone, all we have left is the bill.
    3. Re:I'm starting to wonder... by StormCrow · · Score: 3, Informative

      So IOW, don't give your money to the ALS foundation, since only around a quarter of it at best will go there.

      Demonstrably false with about 5 seconds of Google searching.

      http://www.snopes.com/politics...

  4. Re:it tingles by 93+Escort+Wagon · · Score: 5, Informative

    In my old job we used a lot of liquid nitrogen - mainly to transfer carbon dioxide around in various scientific apparatus (a mass spectrometer, for one).

    Anyone who has worked extensively with the stuff will tell you it is NOT safe unless you are careful. The Leidenfrost effect works... for a relatively short duration. But the co it used application of liquid nitrogen to a specific area rapidly cools the immediate surroundings, and then the effect stops working - especially if the nitrogen doesn't have a way to skitter away on that layer of gas (if you were to pour it into a cupped palm, for example).

    Also, small droplets (such as are generated from the stuff boiling when you're freezing carbon dioxide into a cold finger) don't seem to have much difficulty reaching one's skin, Leidenfrost or no. Most of us in the lab frequently had small burns on the thumb sides of our hands.

    --
    #DeleteChrome
  5. Re:Is it really the Leidenfrost effect? by Anonymous Coward · · Score: 5, Informative

    It really is this time. The Leidenfrost effect comes into play when a surface is much hotter than a given material's boiling point. The Leidenfrost effect explains safe contact of hot skin with liquid nitrogen, wet hands surviving molten lead, and why water skitters on a hot skillet. Any time a liquid contacts a surface much hotter than its boiling point, such that it can be suspended in the air by convection currents, the Leidenfrost effect is responsible. In the LN2 case, your skin is far enough above the -195C boiling point that the nitrogen boils off before it touches your skin. In the molten lead case, the water on your hands must evaporate before your hands can start burning, this creates a temporary steam bubble that insulates your hand much like a winter coat. The water on a hot skillet case is the simplest case, where radiative and convective heat transfer is so intense that hot air and water vapor form a convective bubble underneath the boiling water bubble and instabilities in the air bubble then cause the water bubble to flow towards a theoretical edge and skitter around the pan.

    The firewalking claim is a little dubious, it seems more likely that the short contact time combined with the small surface area exposed during normal walking is responsible for the undamaged feet. Most firewalkers don't seem to sit around getting their feet good and sweaty before firewalking.

  6. I did it first ! by dargaud · · Score: 5, Interesting

    In 1994 I had a liquid nitrogen tube break above my head while preparing an experiment for Antarctica. About 30 liters poured on my head in a second. I felt it go instantly trough my clothing, run over me, and on the floor. Everybody else in the lab ran away, but I couldn't because it formed a dense could, I couldn't see anything and I was behind a lot of equipment and cables. Then the floor exploded: I couldn't see what was going on but very loud cracking and banging noises later proved to be the tiles shattering. Fortunately I was wearing security shoes and just stood my ground. After the fog cleared I saw some faces at the door: "Are you still alive?"

    --
    Non-Linux Penguins ?
    1. Re:I did it first ! by Neil+Boekend · · Score: 5, Funny

      Did you take the chance to reply "I'm not feeling so hot"?

      --
      Well, I might have a way, but it only works on a semi spherical planet in a vacuum.
    2. Re:I did it first ! by MrKaos · · Score: 3, Funny

      Did you take the chance to reply "I'm not feeling so hot"?

      Nah, someone else said - "that was cool!"

      --
      My ism, it's full of beliefs.
    3. Re:I did it first ! by drinkypoo · · Score: 3, Interesting

      Seems kind of dangerous and that this stuff would be buried in the ground (as people would do with a tank of diesel, for instance)

      Which people? Gas stations, maybe. Everyone else stores diesel above ground. It's more stable than gasoline so the thermal cycling isn't as big of a worry, and you literally cannot light diesel on fire. You need a wick of some kind to even produce massive volumes of black smoke, with very little flame. You can extinguish lit cigarettes by dropping them into a can of diesel. It's legal to gravity-feed diesel, but you legally have to pump gasoline. (Obviously not out of a jerrycan, but in terms of tanks.)

      --
      "You're right," Fisheye says. "I should have set it on 'whip' or 'chop.'"
  7. Re:Translation for kids... by Opportunist · · Score: 4, Insightful

    My first reaction when I read this: I think we found the winner of 2014's Darwin Award. No, not that guy. But some copycat who has, unlike him, no clue about Physics and insists in topping the performance.

    --
    We used to have a Bill of Rights. Now, with the rights gone, all we have left is the bill.
  8. Why do German scientists have fitting names? by Opportunist · · Score: 4, Funny

    Serious. Mr. Schwarzschild ("black shield") only kinda-sorta fits his radius, but Mr. Leidenfrost ("suffering frost") really takes the cake here.

    --
    We used to have a Bill of Rights. Now, with the rights gone, all we have left is the bill.
    1. Re:Why do German scientists have fitting names? by BetterThanCaesar · · Score: 3, Interesting

      Not only Germans. Have you seen the function named after Englishman Oliver Heaviside, which has one light and one heavy side?

      --
      "Stop failing the Turing test!" -- Dilbert
    2. Re:Why do German scientists have fitting names? by BlueLightning · · Score: 4, Interesting

      This is known as "nominative determinism"; here's a somewhat amusing article from a couple of years ago on the subject.

  9. Re:it tingles by phantomfive · · Score: 5, Informative

    In my physics book, the author told about his own personal experiments with the Leidenfrost effect. He would plunge his hand into a bucket of molten lead (after dipping it in water), and pretty soon had advanced to putting liquid nitrogen in his mouth and breathing it out.

    He stopped the last one after it went slightly wrong, and all his teeth cracked. His dentist suggested he not do it any more.

    --
    "First they came for the slanderers and i said nothing."
  10. Re:it tingles by PolygamousRanchKid+ · · Score: 5, Funny

    Anyone who has worked extensively with the stuff will tell you it is NOT safe unless you are careful.

    Gee, and there I was, going to tell those Knoxvillesque folks to try the "Liquid Nitrogen Enema Challenge."

    --
    Schroedinger's Brexit: The UK is both in and out of the EU at the same time!
  11. fuck you and the bucket challenge by ruir · · Score: 5, Insightful

    Idiocracy was right on. The fucking bucket challenge is no better than ow my balls. Mod me down at will.

    1. Re:fuck you and the bucket challenge by Chris453 · · Score: 3, Insightful

      criticizing people who are doing good things.

      Actually no. Doing a good thing would be donating to charity. Most of the people doing this are just doing it because they saw it online or have a friend that did it and they want to be cool. Monkey see, monkey do. I bet a large number of the people doing the "challenge" don't even know the reason behind it. Instead of sharing stupid videos of clowns pouring water over their heads maybe we should be sharing videos of people writing checks to the charity. Of course that isn't as "exciting" for the ADD/ADHD generations.

    2. Re:fuck you and the bucket challenge by thegarbz · · Score: 4, Insightful

      It's slacktivism at its best. Seriously the whole point of the challenge was do something that causes discomfort and donate a little or forgo the discomfort and donate a lot. Yet we have an internet full of loaded celebrities like Oprah (who has a freezer draw of ice in her kitchen, like seriously how much money does one need to make before they can install something like that in their house?) who then go and douse themselves.

      So far the only one I have seen who did it right was Patrick Stewart. Write a big check instead of putting yourself through the discomfort.

      The financial results of the campaign would be amazing if it weren't for the fact that many of the people participating make more money in a year than was donated in the entire campaign.

  12. Re:it tingles by infolation · · Score: 4, Funny

    Then we need to encourage the 'family ice bucket challenge'.

  13. Re:so the T-1000 shouldn't have frozen? by Anonymous Coward · · Score: 3, Informative

    No, it works for a few seconds, the evaporation of the nitrogen still extracts energy from the skin. If you pour it for more than a few seconds your hand will freeze and then crack.

  14. Ultimate Ice Buckey Challenge by chfriley · · Score: 4, Funny

    Hal Finney -an ALS sufferer- did the ultimate Ice Bucket challenge with liquid nitrogen last week (Aug 28, 2014) when he was cryopreserved after passing away from ALS:

    http://en.wikipedia.org/wiki/H...

  15. Re:so the T-1000 shouldn't have frozen? by Zero__Kelvin · · Score: 5, Funny

    Yes. This is the one achilles heal in the whole movie, which was otherwise a flawless portrayal of reality.

    --
    Guns don't kill people; Physics kills people! - John Lithgow as Dick Solomon on Third Rock From The Sun