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MIT Study Outlines a 'Perfect' Solar Cell

Daniel_Stuckey writes A new MIT study offers a way out of one of solar power's most vexing problems: the matter of efficiency, and the bare fact that much of the available sunlight in solar power schemes is wasted. The researchers appear to have found the key to perfect solar energy conversion efficiency—or at least something approaching it. It's a new material that can accept light from an very large number of angles and can withstand the very high temperatures needed for a maximally efficient scheme. Conventional solar cells, the silicon-based sheets used in most consumer-level applications, are far from perfect. Light from the sun arrives here on Earth's surface in a wide variety of forms. These forms—wavelengths, properly—include the visible light that makes up our everyday reality, but also significant chunks of invisible (to us) ultraviolet and infrared light. The current standard for solar cells targets mostly just a set range of visible light.

110 comments

  1. Least helpful summary ever? by Anonymous Coward · · Score: 5, Insightful

    Is this the least helpful summary ever on /.? It could be. I read it, and found it really didn't tell me anything I didn't already know, and gave very little clue as to how this study's results might even be helpful. I have a strong suspicion it's clickbait and so am moving along.

    1. Re: Least helpful summary ever? by Anonymous Coward · · Score: 1

      When Cell absorbs the androids, he will become Perfect Cell!

    2. Re:Least helpful summary ever? by suutar · · Score: 2

      I doubt it's the least helpful summary only because it does contain one informative sentence: "It's a new material that can accept light from an very large number of angles and can withstand the very high temperatures needed for a maximally efficient scheme."

    3. Re:Least helpful summary ever? by OzPeter · · Score: 3, Informative

      Is this the least helpful summary ever on /.? It could be. I read it, and found it really didn't tell me anything I didn't already know, and gave very little clue as to how this study's results might even be helpful. I have a strong suspicion it's clickbait and so am moving along.

      Hmmm .. you know .. that could just as easily describe a Bennett Haselton story

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    4. Re:Least helpful summary ever? by DanielRavenNest · · Score: 4, Informative

      Well, going to the abstract of the actual paper, What they have is silicon milled with dielectric cavities (waveguides) that are tuned to the frequency of your solar cell. Hot black bodies can emit any wavelength, but the tuned cavities can only efficiently emit one. Other wavelengths destructively interfere. In that respect they work just like antennas at radio wavelengths.

      The tuned light is efficiently absorbed by the solar cell. Natural sunlight isn't because some of the photons are too high in energy, and the excess gets wasted as heat, and some are too low and don't kick out an electron at all. Thus you get around 25% efficiency in a good cell these days.

    5. Re:Least helpful summary ever? by Mashdar · · Score: 1

      At least they avoided offending any butterflies and Predators.

    6. Re:Least helpful summary ever? by cnaumann · · Score: 1

      So it is just like putting too much air in a ballon!

  2. Might be viable by WillAffleckUW · · Score: 2

    Hard to tell, would depend on how it ramps up in large scale industrial application.

    Interesting 85 percent absorption rate, though. Most of the PV growth in solar has been using cheaper materials, not efficiency of absorption.

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    1. Re:Might be viable by Areyoukiddingme · · Score: 1

      Interesting 85 percent absorption rate, though.

      And highly suspect, considering the theoretical upper limit is 86%. The number of real machines that achieve that high a percentage of their theoretical limit is vanishingly small. Unless Josef Drexler has managed to perfect a nanoassembler that builds solar panels, that 85% isn't happening.

    2. Re:Might be viable by kurzweilfreak · · Score: 1

      Did you mean this guy?

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    3. Re:Might be viable by Areyoukiddingme · · Score: 1

      Did you mean this guy?

      Sorry, yes, Eric. I have no idea why my brain found Josef in that slot in my memory and didn't even question it.

    4. Re:Might be viable by mlts · · Score: 1

      I can see two ways PV can grow.

      The first is when space is precious and every single watt is needed. This can be urban areas, applications in space, even things like a weather monitor in an extremely remote area. Here, it matters less of currency per watt than watts obtained.

      The second is where currency per watt matters, and there are large surfaces that can be covered, be it a rooftop solar array, a tent, windows, and other surfaces where a couple watts here and there lost isn't critical. There are a lot of surfaces that can be used for solar so just getting any amount of energy coming in is important.

    5. Re:Might be viable by kurzweilfreak · · Score: 1

      Buffer underrun, it happens.

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  3. perfect? by polar+red · · Score: 2

    i think the most important feature for this technology would be cost/kwh. does it deliver that ?
    (surface area we have enough of)

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    1. Re:perfect? by Anonymous Coward · · Score: 1, Interesting

      Most important is cost/kwh? How about comparing it to the total cost, over time, of other sources of energy. (for instance, factor in the loss of fossil fuel and pollution or warming of the Earth, or the handling of radioactive waste from nuclear...those typically are not included in the cost/kwh, but should be. Of course, if you're a shiphead and are only interested in money and don't give a ship about anyone else, then yes, cost/kwh is the most important thing.

    2. Re:perfect? by Skidborg · · Score: 2

      Even a high cost/kw would be extremely useful for applications where space and weight are at a premium. Solar powered aircraft, spacecraft, and wearable devices spring to mind.

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    3. Re:perfect? by polar+red · · Score: 1

      How about comparing it to the total cost, over time, of other sources of energy

      solar and wind already have won that race. they already are cheaper than any of the other technologies, even without factoring the externalities. so the question is : is this new solar tech cheaper than the currently-on-the-market panels

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    4. Re: perfect? by Anonymous Coward · · Score: 0

      the cost of handling radioactive waste is included u in the price of nuclear energy

    5. Re:perfect? by tomhath · · Score: 3, Informative

      solar and wind already have won that race

      The US Dept of Energy does not agree with you. Look at the "Total Levelized System Cost", Solar is the highest cost by far, although Wind does pretty well in good locations.

    6. Re:perfect? by K.+S.+Kyosuke · · Score: 1

      There was this interesting development that caught my attention. Sure the efficiency isn't great right now, but organic dyes and cellulose can't possibly need anywhere near the energy levels necessary for producing even polycrystalline silicon, much less monocrystalline one.

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    7. Re:perfect? by Anonymous Coward · · Score: 0

      Cost/kWh is the most important aspect because everything else about solar is available in abundance: Raw materials and places to put the panels are not scarce. You can compensate for low efficiency by simply making and putting up more panels. Increasing the efficiency of solar panels only matters if it lowers the cost per kWh.

    8. Re:perfect? by MrL0G1C · · Score: 4, Interesting

      With solar panel prices now at $500 per KW, most of the system cost is now the installation cost. So improving efficiency lowers installation cost (less panels). Current panels being sold are about 15-18% efficient, best lab panels are over 40% efficient and the theoretical peak is about 65% efficient. Improvements in installation systems and in panel efficiency could easily lead to solar generated electricity being sold for less than $0.04 per kWh from the current $0.08 per kWh (including subsidies).

      Panel technology improvements:
      http://bxhorn.com/wp-content/u...

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    9. Re: perfect? by Cunk · · Score: 1

      Large solar collectors are required and the material needs to withstand 1500K so I don't think it will be useful for those applications.

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    10. Re:perfect? by MrL0G1C · · Score: 4, Informative

      Those figures are completely wrong and very out of date. Power Purchase Agreements have recently bought wind energy for $0.0365 per kwh - that is half the figure on the table linked. That cost includes subsidies, the actual agreement was $0.025 per kwh. For solar the PPA is for $0.05 per kWh (0.08 inc subsidy), with the price of solar falling rapidly I'd expect cheaper PPA's to be struck going forward.

      http://cleantechnica.com/2014/...
      http://cleantechnica.com/2014/...

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    11. Re:perfect? by reboot246 · · Score: 1

      It will be perfect when it can make electricity from moonlight. :)

    12. Re:perfect? by Mr+D+from+63 · · Score: 3, Insightful

      PPAs are wholesale price, not cost. True cost is skewed by subsidies.

    13. Re:perfect? by MrL0G1C · · Score: 1

      I gave figures including subsidies. PPAs are a good way to look at price because that is what the utility is paying for the energy.

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    14. Re:perfect? by Mr+D+from+63 · · Score: 1

      Paying = price. Yes, they are good for looking at price, but not cost of production. Gas drives those prices in the US, and is the reason they are low. The .05% of our electricity that is solar generated is not really a factor.

    15. Re:perfect? by Mr+D+from+63 · · Score: 1

      CORRECTION O.5% Solar. My typo.

    16. Re:perfect? by MrL0G1C · · Score: 1

      Gas drives those prices in the US

      Eh?

      The .05% of our electricity that is solar generated

      0.23% in 2013 (EIA), There are many GW's of solar capacity being added, that figure will double and treble etc. Solar PV is perfect for areas that use a lot of air-conditioning which accounts for a sizable chunk of electricity usage in the US.

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    17. Re:perfect? by Mr+D+from+63 · · Score: 1

      Natural Gas prices are what is driving US electrical wholesale prices downward. Its no big secret. Fracking has had a huge impact.

      I corrected by error in a followup post, meant to type 0.5%.

    18. Re:perfect? by DanielRavenNest · · Score: 1

      One producer expect $400/kW in a few years: http://www.pv-tech.org/news/su...

      Panel prices are already well into very affordable ranges. As you say, the real work now is getting all the other parts of the cost down (wiring, mounting racks, inverters, labor, land, and paperwork - permits, planning, etc.)

    19. Re:perfect? by MrL0G1C · · Score: 1
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    20. Re:perfect? by angel'o'sphere · · Score: 1

      The US Dept of Energy is irrelevant.
      Relevant is the price you pay if you buy solar panels or wind mills on the market. And your parent is right. Solar is even cheaper than wind right now, and both are significantly cheaper than coal.
      Go figure!

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    21. Re:perfect? by Mr+D+from+63 · · Score: 1

      That's why they keep drilling more, till prices get below about $3.5/MBTU, wait till prices rise, then start drilling again. Who knows when that cycle will break.

    22. Re:perfect? by MrL0G1C · · Score: 1

      I don't think the fracking boom will last long, the cheapest wells are typically done first, and if the price of gas rises much then renewables are a lot cheaper.

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    23. Re:perfect? by Anonymous Coward · · Score: 0

      What about solar subsidies?

    24. Re:perfect? by rahvin112 · · Score: 4, Interesting

      There's a bunch of research going into reducing the costs. There are huge areas where the installation cost can be reduced. Integrated and standardized framing, cheaper roof mount systems or even integral mounting systems that become the roofing material, flush roof mount with tracking, integrated, cheaper and more efficient micro-inverters, etc. In fact solar city just dumped about 50 million bucks into some heavy research on just that and the beauty is that because they are an installer and directly involved in the research they can test each idea directly and have first hand knowledge on where the expensive parts of the process are and what works and what doesn't. The quickest way to drive down install costs is to get the inspectors, the engineers, the installers and the panel designers all in the same room which they can do. If they can drive down the install cost they'll be greatly simplifying the install process which will in turn drive down the inspection costs and a bunch of similar follow on costs. And of course they aren't the only one pouring money into installation cost reduction.

      There's a ton of waste in residential installs right now because they are using 100 year old methods. With real research going into this I expect they'll be able to at least halve the installation costs. If they succeed at that they'll drive solar power prices below the cost of coal almost immediately. This doesn't include the other things that are being researched like technology that will heat the panel just enough to dump snow in the winter, better heat tolerance and things like automatic tracking without having to move the panel (tilting the cell in the frame or focusing lens/prisims).

      There's so much money being poured into research it's pretty darn cool IMO. Solar PV is getting more research than almost any other industry out there because of it's potential. Companies like Solar City have been turning down investment money because so much is pouring in that they can't invest it all.

    25. Re:perfect? by Anonymous Coward · · Score: 0

      Get rid of coal regulations so that natural gas could compete against solar in the markets...

    26. Re: perfect? by Anonymous Coward · · Score: 0

      It's called a girl friend

    27. Re:perfect? by Anonymous Coward · · Score: 0

      And what about solar panel subsidies in China?

    28. Re:perfect? by mlts · · Score: 1

      Even with current advances, there are still a bunch of links with the solar chain. For example, micro-inverters are one innovation which minimize the effect of shade on a panel (where just shading one cell causes the whole panel's incoming energy to drop by half or more.)

      Once solar roof shingles become inexpensive and standardized to the point where replacing those is as easy as conventional shingles, this will dramatically increase energy gain. Similar with solar window tint on south (or north depending on what hemisphere one is in) facing buildings.

      Of course, is always a use for installs that can be used in an on-grid manner (inverters feeding the grid), off-grid (batteries charged), and being able to transition between the two states. The advantage of having a set of batteries always charged up and ready means that a circuit or two would have UPS-like power protection, and a low-draw circuit could be completely kept on the batteries.

    29. Re:perfect? by mlts · · Score: 1

      There is room for improvement, especially with charge controllers. Charge controllers are more for off-grid, but there is still room for improvement. Cheaper MPPT [1] charge controllers would be useful, as well as ones that are better equipped for higher voltages (so thinner gauge wires can be used or more panels stacked up in series.) Controllers able to handle higher amperages don't hurt either, since we are getting to the point where it doesn't take many solar panels to hit amp limits on a lot of controllers.

      [1]: maximum point power tracking... they take a higher voltage, and change it to a voltage/amperage best for the batteries, as opposed to a PWM charger which doesn't use any energy above the voltage level it chooses for the batteries. With a PWM charger, a 100 watt solar panel putting out 24 volts will only function as a 50 watt panel (assuming the controller is using 12.0 volts just for example's sake), while a MPPT charger will step down the voltage and step up the incoming amperage.

    30. Re:perfect? by swb · · Score: 1

      Storage cost is expensive. Or is it merely meant to be a daytime use to cut utility consumption?

    31. Re:perfect? by MrL0G1C · · Score: 1

      You mean large/grid scale storage? I think that could become cost competitive when matched with renewables going forward, more R&D is required. Pumped Hydro is of course already highly economical but it is not feasible everywhere.

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    32. Re:perfect? by swb · · Score: 1

      No, home scale.

      I've been looking at very basic power systems for a small boat to provide nominal battery based power on the water and between inverters and batteries the solar side of it is trivial. It's the storage side that gets expensive.

    33. Re:perfect? by MrL0G1C · · Score: 2

      AFAIK home battery storage solutions are just starting to come out, I read an article recently where one of the home solar PV installation companies will start to include batteries as part of the system as standard. Battery prices will likely go below $200 per kWh of storage in the next 2-3 years. The battery and solar markets are crazy with innovation right now, Tesla's battery 'Giga-factory' is rumored to want to produce more batteries than just for cars.

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    34. Re:perfect? by dbIII · · Score: 1

      Solar PV is perfect for areas that use a lot of air-conditioning

      Which is a bit backwards IMHO since solar thermal is a damn good way to drive a big heat pump. Little ones not so much, but it would be perfect for large office buildings and shopping malls.

    35. Re:perfect? by dbIII · · Score: 1

      There's also been stuff like solgel around for a while too which only needs temperatures available in domestic ovens. For now silicon still wins despite the massive energy input due to piggybacking on the huge economy of scale of semiconductor production. Vast amounts of energy consumed per ton ends up as hardly anything per square metre of very thin wafer.

    36. Re:perfect? by dbIII · · Score: 1

      It's getting there on the home scale merely due to massive price gouging by energy utilities with no sign of a halt to the increase in prices. We're heading for a crossover point even if batteries do not continue to drop in price.

    37. Re:perfect? by skids · · Score: 1

      Actually thermophotovoltaics, like stirling engine collectors, have the advantage that you can use them as a an electricity generator from natural gas at night instead of using a dedicated natural gas plant. Not sure if TFA is a technology that enables that use case, but it has been looked at as a way to combine the installation costs of solar arrays and natgas plants. Also there's been speculation as to whether they can be made into a more efficient way for hybrid cars to burn gas than an ICE.

      TFA, though seems like it is more focused on photo-thermo-photovoltaics. No pun intended.

    38. Re:perfect? by swb · · Score: 1

      Roughly 5 kilowatt-hours of usable deep cycle agm battery is like $2,300 and by "usable"I mean draining it to 50% -- I would suspect that's on the optimistic side if you want long life.

      I have no idea what my non-full-sun needs would be, but maybe 30kw-h if you exclude central air conditioning.

      Obviously a home system designed around 48v would be more efficient than a 12v based system but it's still close to $18k for 30kwh of 48v battery.

      To make it at all realistic you would have to get super compulsive about re-engineering your entire energy use patterns. Which might not be bad, but that may mean things like no DVRs, a very small fridge, etc.

    39. Re:perfect? by losfromla · · Score: 1

      yeah! and lets pump all the byproducts from all unregulated coal plants and mines into your house.

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    40. Re:perfect? by MrL0G1C · · Score: 1

      Car batteries are far cheaper, see:
      http://green.autoblog.com/2014...
      $5500 for a 24kWh battery, hopefully prices like this will make it to home systems soon. Tesla's battery $20,000 for 85kWh, about the same per kwh.

      30kWh is a lot of electricity, maybe you could shave a big chunk off of that with more efficient appliances, lights and standby settings. UK households average around 12kWh/day.

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    41. Re:perfect? by Anonymous Coward · · Score: 0

      Similar with solar window tint on south (or north depending on what hemisphere one is in) facing buildings.

      I live on the Equator you insensitive clod!

    42. Re:perfect? by swb · · Score: 1

      30kWh is just a guess based on a minimum of 12 hours without maximum solar output.

      You're right, I could shave some of it off but then the lifestyles start changing. DVRs get shut off, computers (which I access remotely in a professional basis) need to get moved to paid hosting (which amounts to paying someone else for electricity).

      I've done some of it -- lights are already 90% CFL or LED. Fridge is 3 years old and likely reasonable in terms of power consumption. Clothes dryer, furnace and stove are natural gas, although furnace is forced air which requires a blower motor. A number of common lights are on timers or motion switches so they're not left "on" when unneeded.

    43. Re:perfect? by Anonymous Coward · · Score: 0

      PPAs reflect the cost of the development, including transmission and site development. They are project specific and consequently add on additional factors than just the cost of the cell. The PPA levelized price is heavily influenced by the term and the credit rating of the producer. A producer able to borrow at 5% for a 30 year contract will have a significantly different price than a producer developing the same project with a 12% rate over ten years.

  4. Uses blackbody emission by wierd_w · · Score: 5, Interesting

    This system uses blackbody emission to re-radiate absorbed photons within a specific bandwidth, which can be selectively optimized for.

    However, since it uses blackbody emission, it does not explicitly NEED light as the energy source. Any kind of heating will suffice. This is really just a very fancy means of converting entropic energy into something useful. Could be very useful when coupled with radio-isotope decay systems, for instance. (This, coupled with existing RTG tech, could produce more efficient RTGs)

    Sadly, it requires that large numbers of useful photons be produced from the emitting blackbody source, which means it needs some pretty non-trivial temperatures. This isn't going to be something that is used in normal residential settings.

    1. Re:Uses blackbody emission by Amtrak · · Score: 2

      I wonder if it could use the waste heat from an internal combustion engine though? It would be interesting to see that put into a hybrid to try and gain back some efficiency from a gas burning engine used to charge a battery. Probably not small enough or efficient enough though.

    2. Re:Uses blackbody emission by Anonymous Coward · · Score: 0

      it does not explicitly NEED light as the energy source

      Their claim is that the crystal is heated by light of various wavelengths striking it from various angles. So it does need light.

    3. Re:Uses blackbody emission by Anonymous Coward · · Score: 0

      Orbital stations beaming power down via microwave comes to mind.

      Posting as AC because I used mod points already in this thread.

    4. Re:Uses blackbody emission by Zorpheus · · Score: 2

      Interesting concept. I think it should also be compared to a conventional heat engine which is driving a generator. Though this device is surely better for small power plants.

    5. Re:Uses blackbody emission by thegarbz · · Score: 1

      Sadly, it requires that large numbers of useful photons be produced from the emitting blackbody source, which means it needs some pretty non-trivial temperatures. This isn't going to be something that is used in normal residential settings.

      Could it be an alternative for solar concentration?

      But then I have to ask why not just melt salts and store them so you get energy storage as well.

    6. Re:Uses blackbody emission by DanielRavenNest · · Score: 1

      But then I have to ask why not just melt salts and store them so you get energy storage as well.

      Because crushed stone is even cheaper than salts or oil for thermal storage. Not much is cheaper than that. You circulate air through a heat exchanger and the rock bed to store heat, and reverse the flow to extract heat. The heat exchanger in turn gets hot fluid from the focus of a solar concentrator. Melty stuff like oil or salts need liquid-tight tanks. A hot rock bed can be a concrete lined ditch filled with rock, but doesn't need to be perfectly air tight, just about as tight as most ventilation systems. A sheet metal lid covered with insulation should be good enough.

    7. Re:Uses blackbody emission by lgw · · Score: 2

      Some larger trucks already do something like this (via the Peltier effect IIRC). 0.1 MPG is an important improvement for a big rig.

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    8. Re:Uses blackbody emission by Overzeetop · · Score: 1

      Wait, what? Blackbody radiation is broad spectrum, with a peak defined by the body temperature. There is no bandwidth selectivity, it's a continuous curve. (One which peaks at visible wavelengths for the solar bb temp which,not surprisingly, most earth creatures have evolved to see.)

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    9. Re:Uses blackbody emission by wierd_w · · Score: 2

      True, however the steepness of the peak is relevant.

      Compare the spectral footprint of sunlight at sea level:

      Clicky

      With the typical power curve of pure blackbody emissions:
      Clicky

      The latter one has a single peak. The former has a much "flatter", but also noisier distribution. One can optimize at the near infra-red band, where the blackbody emission peaks consistently, and harvest the vast majority of the emitted photons. Especially since this band is also very close to the innate emission/capture band of pure silicon.

      clicky

      This means that PV cells tailored for near-IR and IR capture will be WILDLY efficient with this setup.

    10. Re:Uses blackbody emission by Anonymous Coward · · Score: 0

      Right, but the salts and other materials are used due to the phase change, and large amount of heat that can be stored with a relatively lower temperature change. Takes a LOT of energy to take that solid salt into a liquid, even though you only raise the temperature slightly. So you have much better power storage density.

    11. Re:Uses blackbody emission by Anonymous Coward · · Score: 0

      We would be better using a six-cycle engine (Crower cycle, for example) design for that, where there is a pass where water is injected into the hot cylinder which turns the residual heat into steam and saves ~40% on burnable fuel. Yes, a water tank would be needed, and the engine designer will have to deal with water and its corrosive properties, but we have almost solved that problem with engines that are Flex-Fuel and deal with E85.

      I wonder about this system for the exhaust, especially with larger diesels.

    12. Re:Uses blackbody emission by thegarbz · · Score: 1

      That's a problem already well taken care of. On the Cresent Dunes project the hot and cold storage (cold being a figurative word given the salt in that tank is still upwards of 180degC) were only a tiny fraction of the cost of the plant. The word salt is figurative too as typically what they pump around is more like fertiliser than actual salt.

      Anyway you're missing a very VERY big gotchya with your idea. Air is a horrendous medium to transfer energy. In any plant design cooling towers or fin fans are the absolute last resort once you've eliminated all other possible avenues of liquid-liquid contact. Molten salts are used due to their incredible energy densities and high boiling points (air = bad remember).

  5. Optimal rather than perfect by tomhath · · Score: 4, Interesting

    As I read the MIT statement the researchers claim is that their technique collects energy as heat from all available wavelengths. Then a conventional solar cell is used to generate electricity from the photons emitted from the heated collector. I didn't see anything about how much more efficient this is than generating electricity directly, but presumably it's better since the solar cell responds best to a specific wavelength which can be controlled by using the heated collector. Obviously to make it work need a concentrator.

    1. Re:Optimal rather than perfect by GoodNewsJimDotCom · · Score: 2

      Well at first it was better than perfect. He was actually getting 150% energy from the sun converted into electricity. He was actually creating energy, but he looked at the ramifications of having too much energy on Earth and figured heating the atmosphere wouldn't fly with environmentalists. And the people who read his scientific paper wouldn't take him serious if was claiming that his device created energy. So he cut back some features and now its only perfect so it pleases everyone.

    2. Re:Optimal rather than perfect by Maury+Markowitz · · Score: 1

      > I didn't see anything about how much more efficient this is than generating electricity directly,
      > but presumably it's better since the solar cell responds best to a specific wavelength

      Single-junction cells have a single band-gap energy that defines the minimum energy of a photon that will cause photoemission. In the case of silicon that's about 1.1 eV, which corresponds to light in the near infrared (really near, basically red).

      When white light shines on a cell, every that's red-or-higher can cause photoemission. This process is surprisingly efficient, real-world numbers are on the order of 90% or better. Some of those re-combine or get lost in other processes, so in terms of *current* something like 50% or better is what you aim for.

      The problem is that the extra energy in, say, a blue photon will not make it to the collector on the surface of the cell. Along the way it will interact with other particles in the material and give up its extra energy, mostly as heat. So blue light, which has twice the energy of red, comes out the same as red light. So you're not losing current, you're losing voltage. This is the major loss mechanism in conventional PV.

      So it's not that the cell is more *efficient* if you shine red light on it. The power coming out would be exactly the same as if you shone the same amount of white light on the cell. If you shine 1000 photons on the cell you'll get about 500 0.5V electrons out, and it doesn't make a difference what energy those photons are, as long as they're over the band gap. The difference is that it would take more energy to generate 100 photons of blue than red, but you get the same energy back out in either case - so that's a loss.

      The other effect that comes into play is the thermal coefficient. If you simply shake something, electrons inside will start moving around. One easy way to do this is heat it up. When this happens you leave behind "holes" which the photoelectrons can get captured by. So there is a relationship between cell temperature and efficiency.

      So if you shine red light on a cell and that causes 50% of the energy to come out, the heating effect is the other 50% (well, less, but you get the idea). If you shine white light on it and get 20% of the energy out (which is about right these days) that means 80% of the energy goes into heating. This will cause the cell to heat up, which will lower efficiency.

      How much? Not *that* much. My 230W panels make about 200W on a good fall day, and maybe 185 during the height of summer.

  6. Carnot efficiency by bob.lansdorp · · Score: 2

    limits the thermodynamic performance of heat engines to n=1-T_ambient/T_solar ~=1-293K/1000K=70%. Now there are going to be losses converting hot liquid into useful work (electrical energy), so actually probably around 30% efficiency will be achievable. High performance photovoltaics can reach 40% efficiency, and therefore this article is highly misleading.

    1. Re:Carnot efficiency by wierd_w · · Score: 1

      Not a heat engine.

      This is a black body emission system.
      http://en.wikipedia.org/wiki/B...

      Basically, it is the result of the conservation of energy being employed. As an object heats up in a vacuum, it sheds the heat energy as increasingly more energetic photon emissions. Any substance that is not at absolute zero will emit blackbody photons. These are usually in the far infra-red spectral band, though under very high temperatures more energetic photons will be emitted. This is how your typical tungsten filament incandescent light bulb works.

      This approach uses the specificity of the heated material to emit blackbody photons within a specific wavelength, regardless of the wavelengths of the light used to heat it up. However, it does not fix certain things:

      1) Blackbody radiation is emitted from all sides of the emitter; it cannot be made directional. This means that the design that MIT has created, with the collector sandwiched against the emitter, will be at most 50% effective (When used with a light-source derived heat source). This is because some non-trivial portion of the re-emitted light will be beamed off the back of the device, where there is no collector to catch it!

      2) To be a useful device, an enormous number of blackbody photons will have to be emitted. This means the emitter has to be bitching hot.

      3) To be really efficient, the device must be as heavily insulated against thermal loss as possible. This means it wont be thin and light.

    2. Re:Carnot efficiency by bob.lansdorp · · Score: 1

      Actually, solar thermal uses heat engines to convert the heat into useful work. The sun is like a black body (5800K). The absorber will also be a black body, but at a much lower temperature (probably ~1000K). The "absorber" will actually emit some IR light due its blackbody radiation. But not much. So effectively almost all of the energy will be absorbed, and a minimal amount re-radiated back into space. But the heat has to be converted into useful work. At that point, there is a relevant Carnot efficiency, which is what I spoke of. Let me know if you have more basic physics questions!

    3. Re:Carnot efficiency by angel'o'sphere · · Score: 0

      Thermodynamics has nothing to do with photovoltaic.
      There is no physical (as in laws of physic) limit that prevents a photovoltaic cell to be 100% efficient.

      Why are americans so obsessed with 'laws of thermodynamic' and have no clue about them?

      --
      Cost free eBook I read (by iBook/Kobo/Amazon/ObookO/Gutenberg etc.): "The Green Odyssey" by Philip Jose Farmer.
    4. Re:Carnot efficiency by bob.lansdorp · · Score: 1

      Thermodynamics has nothing to do with photovoltaic. There is no physical (as in laws of physic) limit that prevents a photovoltaic cell to be 100% efficient.

      Why are americans so obsessed with 'laws of thermodynamic' and have no clue about them?

      Read the article. It's not for photovoltaics, it's for thermophotovoltaics.

    5. Re:Carnot efficiency by angel'o'sphere · · Score: 1

      Does not change a thing.
      It is still based on photons, only in the IR band :)
      Thermodynamics is about heat exchanges, consider a heat reservoir and a heat sink. Does not matter if it is a fluid or a gas. It is 'mechanic' in the sense of real materials involved, not a spooky photon radiation ;)

      --
      Cost free eBook I read (by iBook/Kobo/Amazon/ObookO/Gutenberg etc.): "The Green Odyssey" by Philip Jose Farmer.
    6. Re:Carnot efficiency by Anonymous Coward · · Score: 0

      All we need to do is invent a photovoltaic cell that doesn't have a temperature!

    7. Re:Carnot efficiency by Daetrin · · Score: 2

      Where are you getting the impression that the heat is going to be transferred to a liquid which will be used to perform work? Both the MIT page and the wikipedia page on thermophotovoltaics seem to indicate the conversion is pretty much straight from heat to electricity. The wikipedia page in particular uses the same heat engine equation as you but comes up with a result of 83%. I'm not sure what the difference is between their number and yours is, but even if your 70% is correct a 70% conversion into electricity is still a lot better than the 40% for regular photovoltaics that you cite.

      --
      This Space Intentionally Left Blank
    8. Re:Carnot efficiency by Chirs · · Score: 1

      Blackbody radiation is emitted from all sides of the emitter; it cannot be made directional. This means that the design that MIT has created, with the collector sandwiched against the emitter, will be at most 50% effective (When used with a light-source derived heat source). This is because some non-trivial portion of the re-emitted light will be beamed off the back of the device, where there is no collector to catch it!

      Couldn't you put the intermediate radiator behind a layer of glass with a coating that is tuned to be highly reflective at the exact frequency that it is re-radiating at? That would reduce the amount of wasted energy.

    9. Re:Carnot efficiency by DanielRavenNest · · Score: 1

      > 1) Blackbody radiation is emitted from all sides of the emitter; it cannot be made directional.

      Emitter is a cylinder heated from the center. Electricity making cells are a larger cylinder around it. Photons emitted from the inside of the hot cylinder will mostly hit another part of the cylinder.

      >2)... This means the emitter has to be bitching hot.

      Make the ratio of cylinder sizes large enough, and your electricity making cells won't melt. They will get pretty warm, and you can extract secondary heat by water cooling their back side. Make hot water or something.

    10. Re:Carnot efficiency by Anonymous Coward · · Score: 0

      Thermodynamics has everything to do with heat to work conversions. It is the most general way to describe the process. The max efficiency will be the Carnot efficiency, and you can bet that in a real system you won't get too close to it.

    11. Re:Carnot efficiency by Anonymous Coward · · Score: 0

      All you need to do is to pour some frosty piss over the cells. Too bad your timing was wrong.

  7. Ho hum... by Billy+the+Mountain · · Score: 1

    This technology is not suitable for the majority of the U.S. because it relies on concentrated solar, i.e. mirrors and if the sun is behind the clouds, then this technology isn't working for you.

    --
    That was the turning point of my life--I went from negative zero to positive zero.
  8. Behind a paywall by tyggna · · Score: 1

    Anyway for a non-student to get access to the full article without paying for it? I'm okay with paying for it if that's what it comes down to. . .

    1. Re:Behind a paywall by 12WTF$ · · Score: 1

      Hints for paywall circumnavigation:
      Google $FirstAuthorsName + $SomeUniquePartOfArticleTitle
      Example: Jeffrey Chou Selective Solar Absorption
      Scan the results and avoid all that steer back to the paywall.
      Find anything? No? That's usual.
      Next try adding the $MagicWord = pdf
      Example: Jeffrey Chou Selective Solar Absorption pdf
      Look carefully at results. Maybe you will find a prepublication copy somewhere?
      This will at least give you a flavour of the research work and might tempt you to support the $BILLION science publishing scam^H^H^H^H industry

      --
      Cryonics - Keep cool and carry on.
  9. The "perfect" solar cell... by macraig · · Score: 2

    ... from whose perspective? At least one perspective holds that the perfect solar cell is one that doesn't even work, a thin strip of plastic made to look like a solar cell that costs a helluva lot less than the real thing:

    Today I was walking home from an errand to a store.I saw the remains of a “Dual Power Calculator” in the gutter; it had an intact solar cell in the top.“Cool!”, I thought; “I’m going to rescue that solar cell for some DIY thing.”I grabbed the top part and tossed it in my bag.

    When I got home, I dismantled it to remove the “solar cell”.I discovered that it was a fake, a thin strip of plastic separate from the body made to look like a solar cell.

    WTF....

    1. Re:The "perfect" solar cell... by Jeremi · · Score: 1

      When I got home, I dismantled it to remove the âoesolar cellâ.I discovered that it was a fake, a thin strip of plastic separate from the body made to look like a solar cell.

      Thin film solar, perhaps?

      The only real way to tell would be to remove the batteries from the calculator, put it in the sun, and see if it works. (and of course if it didn't work, it might just be that it was broken, which might explain why it was left in the gutter)

      --


      I don't care if it's 90,000 hectares. That lake was not my doing.
    2. Re:The "perfect" solar cell... by Em+Adespoton · · Score: 1

      I was thinking that the "perfect" solar cell already existed....

    3. Re:The "perfect" solar cell... by macraig · · Score: 1

      Nope, not thin film. There were no wires, no leads, no solder pads nor terminals. Unless there's wireless solar cells now in that form factor, it was a fake.

    4. Re:The "perfect" solar cell... by CaptainDork · · Score: 1

      Reminds me ...

      Many years ago there was an ad for a device that you plugged inline with the distributor (old car technology) that would amplify the voltage to the spark plugs and give the engine more power.

      It was billed as, "With transistor."

      That was back when transistors were the big buzz word. I was a noob electronics technician and I knew transistors had three leads. How could a transistor possibly amplify when only two leads were being used?

      I found one on the side of the road and I tore it apart and, sure enough, it was "with transistor."

      The transistor wasn't connected to anything. It was just stuck in a wad of tar.

      --
      It little behooves the best of us to comment on the rest of us.
    5. Re:The "perfect" solar cell... by macraig · · Score: 1

      Nowadays they just sell mysterious liquid engine/fuel system "treatments" that cost nothing to make but they can sell at a huge markup.

    6. Re:The "perfect" solar cell... by Bob+the+Super+Hamste · · Score: 1

      No it isn't you are in on the scheme to keep the backyard petrochemist suppressed by big oil. I had an uncle who invented a tablet that when added to a tank of gas would allow his 1970 Cadillac Eldorado with the 500 cu in engine to drive from NY to LA on half a tank of gas. He was snatched up by some Arab Sheiks and Dick Cheney during the oil embargo and no one has heard from him.

      Now that I have that silliness out of the way there are a few engine/oil treatments that do solve a specific problem (sticky valves/lifter, oil leaking, excessive oil consumption, water in your tank) but most (excluding the water in your tank issue) are just a temporary fix to what ever the real problem is. I don't believe in the miracle in a can but there seems to be enough people who do. I do find it funny given all of these various devices and additives that if I were to use them all it would seem that I would drive a vehicle that makes gasoline and produces 1500 bhp out of my 2.5L naturally aspirated factory stock inline 6 engine.

      --
      Time to offend someone
    7. Re:The "perfect" solar cell... by Anonymous Coward · · Score: 0

      That article fails at geography, physics, biology, geology, agriculture, climate / atmospheric physics, and probably a few more things -- I quit reading after a while. It's very complete garbage.

  10. The problem isn't energy effiencey but cost. by trout007 · · Score: 1

    Work on getting the $/power down. If you can get energy efficiency gains cheap enough fine otherwise work on making them cheap enough to replace shingles on every house.

    --
    I love Jesus, except for his foreign policy.
    1. Re:The problem isn't energy effiencey but cost. by DanielRavenNest · · Score: 2

      Walmart already puts solar panels on many of their stores: http://cdn2.tekgoblinmedia.com...

      Besides generating electricity, the panels protect the underlying roof from sun exposure, thus extending their useful life. When they run out of rooftops, they can start on the parking lots. This not only generates more electricity, it provides covered parking. In sunny states this is very desirable. Once electric cars become more popular, charging stations powered by panels above the parking lot will be another desirable feature for customers - shop and recharge your battery at the same time.

  11. Not sure it applies by Chirs · · Score: 1

    In the article the intermediate body is simply absorbing heat energy but then re-radiating it at a specific frequency. Would the Carnot effiency rules apply?

    1. Re:Not sure it applies by Overzeetop · · Score: 1

      Which makes it not black body, right? Blackbody radiation is a curve (Plank's spectral distribution of emissive power, 2piC1/(lambda^5(e^C2/lambdaT) -1)

      I don't think Carnot necessarily applies here as it's the limit for thermodynamic cycles. This appears to be similar to a radiative laser, in that you put any radiation in, but what comes out is single wavelength or very narrow bandpass. The challenge, from a logical position, is that this material appears to violate the laws of entropy. Normally, you would need to resort to an active process to increase the order of a system (like Maxwell's demon, iirc).

      It's times like these that I realize how long it's been since I've been in school, and how rarely I use this on a daily basis.

      --
      Is it just my observation, or are there way too many stupid people in the world?
    2. Re:Not sure it applies by dbIII · · Score: 1

      It's not the Carnot cycle so no, they do not, although the final number won't be much more due to other limits.

  12. Dilithium Crystals by Anonymous Coward · · Score: 0

    Maybe...

  13. Installation costs by Anonymous Coward · · Score: 0

    In my case, the majority of installation cost is the PE saying the panels are not going to blow off the roof and the electrician connecting everything, not the 2 person crew who took 4 hours to install the 18 panels

  14. "bare fact"? by Anonymous Coward · · Score: 0

    I know Americans use some odd turns of phrase sometimes (for example, they'd use "anymore" instead of sometimes), but I have no idea what a "bare" fact is supposed to be.

  15. Perfect Cell, eh? by Meneth · · Score: 1
  16. What a horrible article by Maury+Markowitz · · Score: 1

    Holy smokes Motherboard's posts suck. They don't even bother to try to understand the BS they're spewing.

    "Light from the sun arrives here on Earth's surface in a wide variety of forms"

    Light from the sun arrives here on Earth in exactly one form, photons. The only difference between a red photon and a blue photon is its kinetic energy. If a Honda Civic is driving down the road at 20 mph, and then speeds up to 30 mph, would you say those were two different forms of car?

    "The band gap is a feature of photovoltaic solar cells in particular. "

    The band gap is a feature of all semi-conductors, which is *why* they're semi-conductors.

    "This collision delivers a bunch of extra force to those atoms, which respond by shedding electrons"

    Gah.

    'The catch with thermophotovoltaics is that in order to be suitably efficient..."

    Which they aren't. That's why we don't use them. Or the large variety of other up- and down-conversion systems that attempt to do the same thing through different means. Like photo-emissive plastics. Silicon is cheap and getting cheaper, and that's the bottom line.

  17. I discovered this a long time ago by Bengie · · Score: 1

    Many years back, I also came up with the idea that an indestructible 100000% efficient solar panel would be totally awesome! /sarc

    The article seems to give no information about proof that any of this could be done, just "hey, wouldn't this be really cool if we could do this?".

  18. You can cheat and get more by dbIII · · Score: 1

    One thing that has been investigated is films that absorb and re-emit in wavelengths that photovoltaics can use. That way you could get better than 100% of what is available in a narrow band. Then of course there's the obvious of having some sort of cheap collector bigger than the area of the more expensive photovoltaics, for instance fresnel lenses.