Researchers Convert Biomass To Hydrogen Using Sunlight (rdmag.com)
New submitter omaha393 writes: Cambridge chemists have developed a new catalytic approach capable of converting biomass into hydrogen gas using only sunlight as an energy source. The method converts lignocellulose, one of Earth's most abundant biomaterials, into hydrogen gas and organic byproducts when in a basic water and in the presence of the cadmium sulfide/oxide nanoparticle catalysts. The new method, published in Nature Energy, offers a relatively cheap fuel alternative that researchers are looking to scale up to meet consumer demands at the industrial level. Per R&D Magazine: "'With this in place we can simply add organic matter to the system and then, provided it's a sunny day, produce hydrogen fuel,' says joint lead author David Wakerley. 'Future development can be envisioned at any scale.'" In addition to lignocellulose, the team was also able to produce hydrogen gas using unprocessed material including wood, paper and leaves. Further reading: New Atlas; ScienceDaily
The Photo-catalyst is Cadmium based.
Solar-driven reforming of lignocellulose to H2 with a CdS/CdOx photocatalyst
The nanoparticle is able to absorb energy from solar light and use it to undertake complex chemical reactions. In this experiment, it rearranges the atoms in the water and biomass to form hydrogen fuel and other organic chemicals, including formic acid and carbonate
Yeah can't see heavy metal contamination being a problem with that witch's brew.
Yeah, if I were going to get hydrogen from water I would take a solar panel and hook it up to a floating platform sitting in the ocean. Underneath there would be two gold or platinum plated electrodes, one of which I would leave free and the other of which I would put in a vertical tube. On top I would have a small pump (also run by the solar cell, or maybe powered by a small wind turbine since there is usually a wind over the ocean) that compressed the hydrogen into a collection tank. That would produce hydrogen at a very, very predictable rate, fully compressed and ready to use. A small hydrogen powered boat (powered indirectly by the same solar cells) could make the rounds every week or so to replace the tanks and bring the tanks ashore for use. The rafts themselves would attract fish and de facto cool the ocean underneath. And best of all, they would produce the hydrogen for only four or five times what the electricity that produced it was worth!
Now to patent this, get a government grant, and fight the NIMBY battle with all of the boaters and fisherpeople who don't want to see the oceans and sounds scattered with floating platforms covered with solar cells and hydrogen gas tanks. I'll be rich!
Oh, wait. You mean that this idea has been around for over forty years now?
https://books.google.com/books...
You mean that it is developed to the point where one could produce hydrogen peroxide, or release the CO2 in the ocean water and capture THAT at the same time we generate the hydrogen (for an even larger multiplier for the actual value of the electricity)? You mean that even a patent troll would have a hard time locking this one down? You mean that there really are some people, somewhere, who have heard of the second law of thermodynamics or the first law of economics (that in business, one's product has to sell for more than the cost of production)?
So what? As long as we have a government, these will not be obstacles...
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Even when the experts all agree, they may well be mistaken. --- Bertrand Russell.