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Scientists Formulate New Method To Create Low-Cost High Efficiency Solar Cells (phys.org)

An anonymous reader quotes a report from Phys.Org: Scientists from the Energy Materials and Surface Sciences Unit at the Okinawa Institute of Science and Technology Graduate University (OIST) believe they've found a winning formula in a new method to fabricate low-cost high-efficiency solar cells. Prof. Yabing Qi and his team from OIST in collaboration with Prof. Shengzhong Liu from Shaanxi Normal University, China, developed the cells using the materials and compounds that mimic the crystalline structure of the naturally occurring mineral perovskite. They describe their technique in a study published in the journal Nature Communications. Perovskite offers a more affordable solution, Prof. Qi says. Perovskite was first used to make solar cells in 2009 by Prof. Tsutomu Miyasaka's research team at Toin University of Yokohama, Japan, and since then it has been rapidly gaining importance. The fabrication method he and his research team have developed produces perovskite solar cells with an efficiency comparable to crystalline silicon cells, but it is potentially much cheaper than making silicon solar cells.

To make the new cells, the researchers coated transparent conductive substrates with perovskite films that absorb sunlight very efficiently. They used a gas-solid reaction-based technique in which the substrate is first coated with a layer of hydrogen lead triiodide incorporated with a small amount of chlorine ions and methylamine gas -- allowing them to reproducibly make large uniform panels, each consisting of multiple solar cells. In developing the method, the scientists realized that making the perovskite layer 1 micron thick increased the working life of the solar cell significantly. In addition, a thicker coating not only boosted the stability of the solar cells but also facilitated the fabrication processes, thereby lowering its production costs.
The team is now working on increasing the size of their newly designed solar cell prototype to large commercial-sized panels that can be several feet long. They have reportedly built a working model of their new perovskite solar modules, thanks to funding from OIST's Technology Development and Innovation Center, but "the process of upscaing has reduced the efficiency of the cells from 20% to 15%," reports Phys.Org. "[T]he researchers are optimistic that they will be able to improve the way they work in the coming years and successfully commercialize their use."

35 comments

  1. What Gas? by mentil · · Score: 2

    the substrate is first coated with a layer of hydrogen lead triiodide incorporated with a small amount of chlorine ions and methylamine gas

    Great, now smurfs will be stealing solar cells so they can be used in methamphetamine production.

    --
    Corruption is convincing someone that the selfless ideal is the same as their selfish ideal.
  2. Cue the Republicans to tell us sun isn't reliable by Anonymous Coward · · Score: 1, Funny

    Like that's their job or something

  3. Re:Cue the Republicans to tell us sun isn't reliab by Excelcia · · Score: 1

    Actually, the Republicans will love it and want to invest. After all, increased solar output is responsible for global warming, and that makes this a great investment.

  4. worst decision I ever made by Anonymous Coward · · Score: 0

    was not pulling out, if I did you wouldnâ(TM)t exist

    1. Re:worst decision I ever made by Anonymous Coward · · Score: 0

      Your half-incher couldn't impregnate a toddler.

  5. Lab demonstrations leave a lot to be desired by DanDD · · Score: 5, Interesting

    In developing the method, the scientists realized that making the perovskite layer 1 micron thick increased the working life of the solar cell significantly.

    Typical good quality crystalline silicon solar cells lose as much as 1% per year in efficiency, and lose as much as 15% efficiency in the first few months of deployment. This is why a 100 watt panel will typically produce as much as 120 watts for the first month or so, then taper off to 100 watts, then degrade slowly thereafter. This is one of the reason that to meet code, wiring for a solar installation must exceed the specs of the panels by around 20%. Now, my apologies if this isn't perfectly accurate, I've been intentionally hand-wavy as I've been out of the PV world for a bit.

    Amorphous silicon is much, much worse, as it degrades as much as 10% per year, until they become opaque sheets of glass. This is why cheep Harbor Freight solar panels are cheap. Soon, they'll be just colored glass.

    The manufacturing technique described in this article is similar to that of amorphous silicon, and the quoted sentence above glosses over a lot of ifs in the article. Still, I hope these researchers succeed.

    Even if they don't, traditional silicon solar and some CdTe technologies are already at grid parity, so the current state of the art can already economically offset burning stuff to keep the lights on, or charge the electric car.

    --
    "Every time I see an adult on a bicycle, I no longer despair for the future of the human race." - H. G. Wells
    1. Re:Lab demonstrations leave a lot to be desired by aevan · · Score: 2

      Well, going by his.. other team? (Dr. Liu), these types of cells apparently don't even make two years. So either they have to be dirt cheap and easily replaced, or they'll have to work on extending the life. Personally though, more interested if the materials involved aren't as... well.. 'Chinese Lakes of Toxic Sludge'. I'd count that as a win, regardless the rest.

    2. Re:Lab demonstrations leave a lot to be desired by Chas · · Score: 1

      Nah. Because you're still stuck with megatons of landfill over time...

      --


      Chas - The one, the only.
      THANK GOD!!!
    3. Re:Lab demonstrations leave a lot to be desired by Anonymous Coward · · Score: 0

      It's a serious problem, but still the lesser evil compared to anything that releases emissions into the atmosphere.

      A localized toxic landscape is a manageable catastrophy. It's not like Chernobyl is a major global problem. It's just "locally impractical."

      If we can replace emissions with something that builds a toxic mountain right now we should.
      We can replace it with something even better later.

    4. Re:Lab demonstrations leave a lot to be desired by Squirmy+McPhee · · Score: 5, Informative

      In developing the method, the scientists realized that making the perovskite layer 1 micron thick increased the working life of the solar cell significantly.

      Typical good quality crystalline silicon solar cells lose as much as 1% per year in efficiency, and lose as much as 15% efficiency in the first few months of deployment. This is why a 100 watt panel will typically produce as much as 120 watts for the first month or so, then taper off to 100 watts, then degrade slowly thereafter. This is one of the reason that to meet code, wiring for a solar installation must exceed the specs of the panels by around 20%. Now, my apologies if this isn't perfectly accurate, I've been intentionally hand-wavy as I've been out of the PV world for a bit.

      You're still correct on the basic principles, but the figures you give for crystalline silicon cells describe low-quality cells these days. Typical warranties these days are 2-3% degradation in the first year and 0.5%/year thereafter. The vast majority of field data is not public and that that is public suggests that plenty of modules conform to this sort of warranty and plenty don't, but for what it's worth, reinsurance companies (who actually have access to the highest volumes of field data) are willing to take on the risk of underwriting such warranties.

      The manufacturing technique described in this article is similar to that of amorphous silicon, and the quoted sentence above glosses over a lot of ifs in the article.

      Degradation in amorphous silicon has to do with the structure of the material itself, not the manufacturing process. That said, perovskite does have its own very serious degradation problem -- much worse than amorphous silicon, in fact -- that needs to be solved (or at least improved) before it will become practical as a major energy source. Even if it can be made cheaper than crystalline silicon, it's hard to see it gaining much traction outside of consumer gadgets and specialized short-term applications if the cells die after 5 years. Someone could still make money that way, but it wouldn't address much of our energy demand.

      That said, what I've seen of this work is promising because the scientists are at least making an effort to address many of the issues that have to be solved to commercialize perovskite cells. There is increasing attention paid to that, but it seems to me that many researchers still prefer to chase headline-grabbing efficiencies. I wish them luck, but I do firmly believe they will struggle to create a successful commercial product if they don't make some strides on longevity.

    5. Re:Lab demonstrations leave a lot to be desired by K.+S.+Kyosuke · · Score: 1

      Typical good quality crystalline silicon solar cells lose as much as 1% per year in efficiency, and lose as much as 15% efficiency in the first few months of deployment.

      Not necessarily, really. One might argue that making them look "good as new" even after two decades really should be the next goal for the PV industry.

      --
      Ezekiel 23:20
    6. Re:Lab demonstrations leave a lot to be desired by Anonymous Coward · · Score: 1

      Typical good quality crystalline silicon solar cells lose as much as 1% per year in efficiency, and lose as much as 15% efficiency in the first few months of deployment. This is why a 100 watt panel will typically produce as much as 120 watts for the first month or so, then taper off to 100 watts, then degrade slowly thereafter. This is one of the reason that to meet code, wiring for a solar installation must exceed the specs of the panels by around 20%. Now, my apologies if this isn't perfectly accurate, I've been intentionally hand-wavy as I've been out of the PV world for a bit.

      At least in the USA the reason for the 20% margin on wiring gauge is because of a safety factor, this applies to any device considered a "constant load". I found this out when helping someone install some electric heaters. I found it odd that every heater we saw with a 30 amp plug would consume no more than 24 amps, and 15 amp heaters had 20 amp plugs. When looking at the National Electrical Code these plugs were required to meet code.

      Lots of other loads, like motors and even some lighting, will have a high peak demand when starting up but fall back to a far smaller constant load. I saw this on my furnace when doing some testing, it would draw about 10 amps to get started (possibly higher as my meter may not have the resolution to see the peak) but draw less than 1 amp once running. The wiring and fuses must always be sized to the peak. For most situations this peak is considerably higher than the constant demand but devices like an electric resistance heater, and also sources like a solar panel, the peak current is the same as the constant current.

      If your "100 watt" solar panel is producing 120 watts, and doing so consistently with wiring sized and fused to carry 120 watts, then it is quite likely in violation of the National Electrical Code.

    7. Re:Lab demonstrations leave a lot to be desired by K.+S.+Kyosuke · · Score: 1

      Or you could use silicon instead, which doesn't even build a toxic mountain.

      --
      Ezekiel 23:20
    8. Re:Lab demonstrations leave a lot to be desired by Chas · · Score: 1

      Just so long as you're the first person to volunteer to live on the mountain of unrecyclable panels.

      --


      Chas - The one, the only.
      THANK GOD!!!
    9. Re: Lab demonstrations leave a lot to be desired by Anonymous Coward · · Score: 0

      From the "grid parity" linked article: """assuming,that is, that the federal government maintains the 30 percent solar investment tax credit it currently offers homeowners on installation and equipment costs."""

    10. Re:Lab demonstrations leave a lot to be desired by Anonymous Coward · · Score: 0

      That's not what I've read. I've read many case studies of people taking old panels, testing each cell and finding that 90% of the cells are at nearly 100% of their original rating and that only a few cells actually had flaws that caused them to hamper the entire panel. They just replace the bad cells and they have a panel that is within 95% as good as the day it was made 20 years ago.

      The problem is no one wants to go through the laborious hassle of testing each cell in a panel.

  6. What's the life? by whoever57 · · Score: 1

    I thought the big issue with using perovskite in solar panels is useful life.

    --
    The real "Libtards" are the Libertarians!
  7. Re:Cue the Republicans to tell us sun isn't reliab by Anonymous Coward · · Score: 0

    "But will it make us more money?"...why, yes. Just buy this monorail and your city will prosper...

  8. Since this is coming out of China... by Chas · · Score: 1

    I'll wait until the research comes in.

    --


    Chas - The one, the only.
    THANK GOD!!!
  9. Clever Trump by TJHook3r · · Score: 1

    Waiting for prices to fall before pushing solar energy, as he inevitably will!

    1. Re:Clever Trump by Anonymous Coward · · Score: 0

      Or in other words, nobody's told him to invest in solar yet, and he won't push solar until he can benefit from manipulating prices.

  10. Re:Cue the Republicans to tell us sun isn't reliab by Anonymous Coward · · Score: 0, Interesting

    The sun is not a reliable source of energy. The sun goes down every night, right when demand peaks, and then clouds can come in at any time to reduce output during the day. Addressing this with storage solutions costs money, which means solar power will be expensive even if the solar collectors themselves are cheap.

    Energy storage solutions alone will not save solar power because such storage doesn't care if it is charged from solar power or anything else. Natural gas is a cheap source of energy, and natural gas boilers are a cheap and efficient way to turn that into electricity. The problem with boilers (natural gas, coal, or nuclear) is that they like to run at a nice and steady pace for best efficiency. Pair a boiler with storage and you get reliable power that can follow the changes in load throughout the day.

    Cheap and efficient energy storage could in fact kill solar power, it just would not be able to compete with far more reliable energy sources to charge them up. I'm not sure even if solar power were free that it could compete because the demands for storage would still price it out of existence.

  11. ITYM soral cerr's LOL by Anonymous Coward · · Score: 0



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  12. What is needed is a way by Anonymous Coward · · Score: 0

    to add solar cells to cheap asphalt tiles and still keep them cheap.

  13. Re:Cue the Republicans to tell us sun isn't reliab by Waffle+Iron · · Score: 1

    Natural gas only appears cheap to those who fail to account for the damage caused by CO2 emissions and methane leakage.

  14. Re:How soon before we see them in Mr. Musk's by nospam007 · · Score: 2

    "This new technology alongside the Tesla Powerbank and the Tesla car in my basement are sure to disrupt and revolutionize transportation industry."

    You're doing it wrong.
    The powerbank belongs in the basement, the car in the garage.
    But good news, you're right, the solar singles go on the roof.

  15. Natural gas is only effcient in big chunks by Ungrounded+Lightning · · Score: 1

    are a cheap and efficient way to turn that into electricity.

    At grid scale, yes. At residential scale, not so much.

    Energy storage solutions alone will not save solar power because such storage doesn't care if it is charged from solar power or anything else.

    But the cost of getting the energy to the storage must be included.

    Solar pa

    --
    Bantam Dominique roosters crow a four-note song. Once you've heard it as "Happy BIRTHday" you can't NOT hear it that way
  16. Natural gas is only effcient in big chunks, cont. by Ungrounded+Lightning · · Score: 1

    (Lenovo's touchpad hits "[Submit]" once again...)

    Energy storage solutions alone will not save solar power because such storage doesn't care if it is charged from solar power or anything else.

    But the cost of getting the energy to the storage must be included.

    Large fuel-powered steam generation plants and their distribution networks have had a century of intense engineering and are currently nibbling away at the last slivers of inefficiency between their current state and theoretical limits, such as the Carnot cycle and conservation of energy. Any nontrivial cost-of-power improvements there will come from fuel prices and construction/operation cost improvements. Solar photovoltaic is primarily a semiconductor technology and is still following its own version of Moore's Law, with intermittent breakthroughs (like some announced here recently) combining into a rapid improvement in manufacturing cost-per-watt and with some pad left between current efficiency and theoretical limits.

    At a good solar site, as of a couple years ago, using current moderately-OK storage, photovoltaic power was cheaper than grid power by a factor of three or better before the recent anti-dumping tariffs With the tariffs in place it's still better and by a factor of about 1.5. Add in improved storage and/or continued improvement of panels, and grid, which has already fallen behind, gets left in the dust. This doesn't kill it, but it does leave it powering mostly sites that don't have good solar resources, require larger amounts of power than is available from the sun on the site's building roofing, where capital isn't available for installing the solar equipment, or serving as a backup/peaking supply.

    Solar doesn't need "saving" from natural gas. To a large extent it's the other way around.

    --
    Bantam Dominique roosters crow a four-note song. Once you've heard it as "Happy BIRTHday" you can't NOT hear it that way
  17. Headline a little old by Geoffrey.landis · · Score: 1

    I have to point out that perovskites have been the hot research topic for low-cost solar cells for several years now. It's nice that slashdot suddenly noticed them, but mentioning one research group, while ignoring a hundred other research groups working on perovskite solar cells, is a little misleading.

    For more information, here are 33,000 papers to read: https://scholar.google.com/sch...

    --
    http://www.geoffreylandis.com
  18. Re: Cue the Republicans to tell us sun isn't relia by Anonymous Coward · · Score: 0

    The good news is that the sun's unreliability is reliably predictable. We know when it goes over the horizon to the minute. Massive day-long storms don't just sneak up on us because of 1950s technology called "weather radar"

    Nice FUD though. Grade A over-simplification and extra marks for completely overlooking the fact that natural gas peaking plants that use turbines instead of boilers exist.

  19. Re:Cue the Republicans to tell us sun isn't reliab by crunchygranola · · Score: 1

    Anti-solar FUD from an AC. What else is new?

    It is a thankless task perhaps to take on anonymous BS, the logical fail here is notable.

    Cheap and efficient energy storage could in fact kill solar power, it just would not be able to compete with far more reliable energy sources to charge them up. I'm not sure even if solar power were free that it could compete because the demands for storage would still price it out of existence.

    Wow. Cheap efficient energy storage will kill even free solar energy by pricing it out of existence. Who knew?

    --
    Second class citizen of the New Gilded Age