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Chemistry Sets for Adults?

An Anonymous Coward asks "I've been pursuing a few different lines of study, to refresh myself in basic sciences before I return to school. Right now I am reading up on Chemistry, and thought it would be fun to acquire a chemistry set just to play around with and maybe learn a few things from. Do any science geeks here have any suggestions?" My childhood garage probably still has purple and black stains all over it (lucky I was wearing glasses). 300 in one electronics kits, anyone?

134 of 319 comments (clear)

  1. For adults? by Anonymous Coward · · Score: 5, Funny

    I hear those rolling methamphetamine labs are getting pretty popular.

    1. Re:For adults? by Master+Bait · · Score: 5, Informative

      That dude shouldn't get just any chemistry set. He should ignore inorganic chemistry and go for the gold (organic chemistry). He needs to read Phikal first. Then he needs to check out Rhodium and The Vaults of Erowid and a gander at The Lycaeum

      --
      "Only in their dreams can men truly be free 'twas always thus, and always thus will be."
      --Tom Schulman
    2. Re:For adults? by Anonymous+Hack · · Score: 2, Funny

      Too true, and this is precisely the problem. Too many chemicals out there can be used to make drugs and bombs, and that makes the government Very Unhappy.

      I loved chemistry in high school and regret i never followed it up. Actually the real life of a chemical engineer is probably equally boring as that of a computer programmer, but hey i can fantasize. Can't you just see the dinner party conversation? "Crank... um um um um yeah crank yeah crank don't got nothin on my hydropsychotic pseudomethephedrineactose-sulfate-2,4,5... that's like like 245 bpm heart rate and and and "

      --
      I got a sig so you would remember me.
    3. Re:For adults? by morie · · Score: 4, Funny
      Whatever you would classify "Gold" (Au) under, it most certainly should not be Organic Chemistry

      :-)

      --
      Sig (appended to the end of comments I post, 54 chars)
  2. Why do we need these? by packeteer · · Score: 4, Interesting

    So called "childrens" chemistry and electronics sets are perfectly good for adult too.

    --
    unzip; strip; touch; finger; mount; fsck; more; yes; unmount; sleep
  3. Essential oil extraction by MrLint · · Score: 5, Interesting

    When i was in Orgo chem the *best* and coolest thing we did was extract limoene (orange oil). But you need reflux glassware for it.. but i'll tell ya the stuff smells great. and the practical upshot is that you can use it and other essental oils as food flavorings

    1. Re:Essential oil extraction by aardvarkjoe · · Score: 2

      Lucky. They always told us that we weren't supposed to lick the spoon.

      --

      How can we continue to believe in a just universe and freedom to eat crackers if we have no ale?
    2. Re:Essential oil extraction by MegaHamsterX · · Score: 2, Funny

      OR.....you could sell it on tv and be the next Billy Mays(sp)

    3. Re:Essential oil extraction by rworne · · Score: 2

      The notable exception. Just abou anything else you make in organic chem stinks to high heaven.

      People used to know when chem classes were in session just by the smell the lab experients leave on your hair and clothes.

      --
      I tried every decent and legal way I could think of to resolve the issue w/the business before I rented the chicken suit
    4. Re:Essential oil extraction by jayed_99 · · Score: 5, Informative
      *snickers* (Sorry, I was thinking of a time when I saw an idiot put a drop of pure pepeprmint oil on his tongue).

      I wouldn't advocate using most essential oils in food. You could use them in absolutely microscopic amounts -- but most kitchens/chefs don't have the tools, time or inclination to measure out correct amounts of essential oils. And leaving out the "potentially physically unsafe" part of it, essential oils are so strong in flavor and scent that they will easily overwhelm the other flavors in a dish.

      That's why most commonly used "food safe" extracts have an ingredient list that goes something like "distilled water, alcohol, whatever oil". The water provides a buffer.

    5. Re:Essential oil extraction by jcsehak · · Score: 2

      Some time ago, my roommate bought a couple small bottles of this oil, thinking it was the kind you dip bread in. I didn't see why it wouldn't be; it sure smelled good.

      Yuck.

      --

      c-hack.com |
    6. Re:Essential oil extraction by riedquat · · Score: 2, Funny

      I did that for a demonstration once - I only realised afterwards that what I'd been asking people to sniff was mostly benzene...

  4. CBS by radiashun · · Score: 5, Informative

    Carolina Biological Supply has a bunch of learning kits, books, and software that would probably help you out. We get most of our lab supplies through them.

  5. do you really want to do titrations? by black_widow · · Score: 3, Insightful

    Personally, I never learned any practical info in chemistry labs... Come to think of it, high school chemistry is all you're ever going to need unless you're going to be a chem engineer.

    1. Re:do you really want to do titrations? by dwillen · · Score: 2, Insightful

      I didn't learn too much in the required labs, but spending a semester or a summer in a lab doing research you will learn more than any number of classes or books you read.

    2. Re:do you really want to do titrations? by jayed_99 · · Score: 3, Interesting
      Well, at the rarefied heights of "chef" and "pastry chef" there is generally a pretty good working knowledge of a limited subset of organic chemistry as it relates to food and taste. And sometimes a pretty impressive set of knowledge -- find a good pastry chef and ask them about the chemical interactions involved in a loaf of bread...and be ready for a 2 hour long lecture.

      A guy I worked with once told me "if you're cutting up a steak for people to sample, don't cut it into little cubes...cut it into long, thin strips...it tastes better because it provides a greater surface area for {big long enzyme in the saliva} to work with". (He then told me, "I learned that in the Organic-Chemistry-for-Chefs Class that I took last year". (And, yes, he really used the phrase "organic chemistry".)). Of course, I immediately put this to a field test with about 5 people (including myself) as test subjects. Sure enough, he was correct...the same steak -- when cut into long thin strips -- tastes better than the when it's cut into an volumetrically equivalent cube.

  6. Re:Why? by identd · · Score: 2, Funny

    What fun would that be, I mean we all know bleach and amnonoia and bleach is the best chemistry set.
    Just Joking...

  7. Re:Why? by kingkade · · Score: 3, Insightful

    Well a book and hands-on experimentation don't have to be exclusive of each other. Actually performing and validating guided experiments or coming up with your own to answer problems posed or your curiosity can be fulfilling.

  8. Slashdot: News for Dealers... by Quaoar · · Score: 5, Funny

    I think it's about time we added a "hydroponics" category. Honestly, most nerds will probably applaud it.

    --
    I'll form my OWN solar system! With blackjack! And hookers!
    1. Re:Slashdot: News for Dealers... by CableModemSniper · · Score: 3, Informative
      --
      Why not fork?
    2. Re:Slashdot: News for Dealers... by emkman · · Score: 2, Informative

      hah i wish i had mod points ... anyway there are lots of good sites out there already, no need for /.
      check Overgrow for all your hydro,organic,chem, etc needs :)

      --
      Moderation Totals: Flamebait=2, Troll=1, Redundant=1, Insightful=6, Overrated=1, Underrated=1, Total=12. (not mine)
  9. My wife got me one :) by Cybersonic · · Score: 4, Informative

    She saw me reading the Radio Shack 'Getting Started In Electronic's book over and over again and (in between studies for various certifications) and decided to get me a kit.

    She gave me bookmarks after chrismas... :)

    Good list of kits: http://www.hobbytron.net/electronickits.html

    I have the 300-on-1 which is $70 and is solderless.

    Also check out http://www.kitguy.com/ - seems to be a definitive resource...

    --
    Cybie! aka Ralph Bonnell
    1. Re:My wife got me one :) by EvanED · · Score: 2

      I have a 130-in-one; I think I blew a transister and one of the ICs.

    2. Re:My wife got me one :) by EvanED · · Score: 2

      No, but if I remember correctly (it's been a while since I played around with it), I wasn't able to get any circuit that used either the Quad-NAND IC or the top transister to work.

  10. i was gonna mod this up by waspleg · · Score: 4, Funny

    but then i got high err heh

  11. If you realy wan't to.... by oliverthered · · Score: 3, Interesting

    Well, if you wan't to have lots of fun, well kinda, try making some of the chemicals you self or using household goods.

    Amonia isn't that hard to make,
    Ethanol's quite easy too (just don't get caught!)
    Acids are a bit trickier.... but not that hard.

    It'll give you lots of practice nad help if WW3 breaks out(or if you need any 'added-extras' for a night out).

    Things like the anarchists cook book should help point you in the right direction.

    --
    thank God the internet isn't a human right.
    1. Re:If you realy wan't to.... by driftingwalrus · · Score: 5, Informative

      ACK!!! Great stars! Are you *MAD*?! NEVER take anything from the Anarchist's Cookbook. Might as well drink a jug of chlorine, it'll do the exact same thing and save you a lot of time.

      --
      Paul Anderson
      "I drank WHAT?!" -- Socrates
    2. Re:If you realy wan't to.... by Cruciform · · Score: 2

      He's right, some of the recipes in the Anarchist's Cookbook have been doctored so as to cause the "chemist" injury.
      There are more reputable texts out there to learn from.

    3. Re:If you realy wan't to.... by Thatmushroom · · Score: 5, Informative

      To clarify, there are multiple versions of the Anarchist Cookbook, and if that's a copy of the original, just strap some TNT to yourself and light it, it really will save you time in the long run. The original is replete with errors, many chemical, that could cause lots of damage.

      However, I doubt that's the original, since the original is extremely rare (if you don't see something about the bridges in NYC, you're not looking at the original). Still, it's not a wise move to perform chemical experiments using instructions from a book that's designed to cause destruction, chaos, and anarchy.

      If you're really just looking to win a Darwin award, however...

      --
      You zap the moderators with a wand of humor! The moderators resist!
    4. Re:If you realy wan't to.... by panurge · · Score: 2
      "Ammonia isn't that hard to make"

      If you are so good with high pressure process plant, building catalyst beds, pumping hot nitrogen and so forth, that ammonia isn't hard to make, you hardly need a Chemistry 101 kit.

      Of course, if you just mean "extract from something that already contains it", that's a piece of cat's piss. Literally.

      --
      Panurge has posted for the last time. Thanks for the positive moderations.
    5. Re:If you realy wan't to.... by Muad'Dave · · Score: 2

      ...practice nad help...

      What is "practice nad help"? Is that like test Viagra or something?

      --
      Tiller's Rule: Never use a word in written form that you've only heard and never read. You will end up looking foolish.
  12. sugestion by larry+bagina · · Score: 4, Funny

    ask your local meth lab if you can do some intern work.

    --
    Do you even lift?

    These aren't the 'roids you're looking for.

  13. My All-time favorite by Superfreaker · · Score: 5, Informative

    Edmund Scientific
    http://www.scientificsonline.com

    My dad used to take me there when I was a kid, a very trippy place. It got me through all of my science classes with pre-made projects.

    1. Re:My All-time favorite by jayed_99 · · Score: 5, Funny
      Some of my favorite childhood memories are negotiating with my father about what I could select as a Christmas/birthday gift from the Edmund's catalog.

      Me: "I want one of those ruby-laser kits."
      Him: "No. What about a prism?"
      Me: "I want one of those sets that has all the chemicals."
      Him: "No. What about a prism?"
      Me: "I want one of those magnets that can lift a small car."
      Him: "No. What about a prism?"

      I got a *lot* of prisms. By the time I was eight, I had about a dozen of varied shapes and sizes.

    2. Re:My All-time favorite by srhuston · · Score: 2

      Yes, and have you been by there lately? I live somewhat near Barrington NJ, and thought I'd entertain my wife and show her one of the neat places of my childhood. She's a Girl Scouts leader and a teacher, and thought she might find some interesting ideas or kits for making up projects.

      The store is gone.

      In its place is now "Anchor Optics" or something like that; basically the shop and outlet for any of their scratch-and-dent optical supplies that can't then be sold through Edmund Industrial Optics division. No more rows of science kits, wall of microscopes and lasers and optical toys, *no more surplus room*.

      *sigh* I shed a tear on the way home. That place was the best.

      --
      Three dits, four dits, two dits, dah!
      Radio, radio, rah rah rah!
    3. Re:My All-time favorite by Superfreaker · · Score: 2

      OMG, the store is gone!
      Sooo sad.

      I can remember even further back they had an exhibit hall with all kinds of light experiements that were insane in this huge black room.

      When they took that away, i was sad. Then the periscope stopped working, etc, not its gone!

      Wahhh!

  14. alright by pummer · · Score: 3, Funny

    first, you buy a textbook, like the one you had in 11th grade. Then, you place it under your pillow and learn by osmosis.

    or

    you take a big ol' jar of gasoline, add styrofoam until you get a play-doh like mixture. what you have is napa----------

    oops, you were asking for suggestions. I thought you wanted to know what I did.

    1. Re:alright by Jacer · · Score: 3, Informative

      it isn't *really* napalm, it's just a very-very fun, flamable paste

      --
      --fetch daddy's blue fright wig, i must be handsome when i release my rage
    2. Re:alright by hackstraw · · Score: 2

      Yeah, it is fun, especially when it "drips" fire :)

      Anyway, back to the notion of "learning by osmosis", where the hell did this come from? Osmosis is the transfer of _water_ through a semi-permiable membrane. So "learning by osmosis" is as silly as learning by drinking water, because I guess the water between you and the book is going to make you smart right? Would "learning by diffusion" make a better joke, or does osmosis sound like a smarter word?

    3. Re:alright by Jacer · · Score: 2

      well, i'll explain that quickly, the term comes from a grossley inaccurate garfield poster where garfield (the cat mind you) ties many, many books to himself and proclimates he's learning by osmosis

      --
      --fetch daddy's blue fright wig, i must be handsome when i release my rage
  15. I just got my own adult chemistry kit. by pi_rules · · Score: 4, Funny

    It's actually a little bit of biology mixed in with a bit of chemistry; but it's really fun to play with.

    It's a home-brew kit for making my own beer :) I could entertain myself for hours with this thing.

    1. Re:I just got my own adult chemistry kit. by pi_rules · · Score: 3, Interesting

      If by "kit" you mean those "Mr. Brew" things you can find in most stores, don't bother -- that beer is terrible. Instead, find your local brewery supply store and get the proper items. If, on the other hand, you mean a "kit" from your local brewery supplier that includes the necessary items you need for brewing, then great. My roommate made a batch of homebrew earlier in December, turned out really good.

      Nah.. I got the real deal. I helped a buddy do a Mr. Brew thing because he's not too quick on the uptake with reading directions and sterilization, but I went out and got the real deal. Four gallon pot for boiling wort, 2 6.5 gallon buckets, one for fermentation and one for bottling, bottle capper, hydrometer, proper thermometer, siphon tubing, etc.

      It'll be a week and a half before the first batch is done, but damn do I have fun watching the little CO2 bubbles coming out of the airlock :)

    2. Re:I just got my own adult chemistry kit. by Osty · · Score: 2, Interesting

      I hear that a glass bottle works better (flavor-wise) for fermentation than the plastic buckets. May just be hear-say, though. Anyway, that's pretty much what my roommate has going -- pot for boiling wort (4gal is probably overkill, since you don't need the full amount of water while you're boiling your wort), 5gal glass bottle for fermentation, 5gal bucket for bottling, all the trappings for sterilization, bottling, etc. Makes a good brew. I'm slowly working my way through this first batch while he's out of town on vacation. Mmm ... beer for me.


      For me, it's too much work, but he's into it. Sounds like after the next batch of pre-packaged wort, he's going to try his hand at doing everything from scratch. Fine by me, since even a bad homebrew is better than a Bud.

  16. limonene by SweetAndSourJesus · · Score: 3, Informative

    Uh, limonene isn't a good thing to be eating.

    It smells fantastic, but it's a pretty potent solvent and can irritate the hell out of your digestive tract.

    --

    --
    the strongest word is still the word "free"
    1. Re:limonene by MrLint · · Score: 4, Informative

      Right from that page : Limonene is also used as a flavour and fragrance additive in food, household cleaning products, and perfumes. Im not advocating shugging this stuff straight. Butl ike with any extration of essential oil be it spearmint, peppermint, orange oil, of capsicum the idea it to not over use it.

    2. Re:limonene by Muad'Dave · · Score: 2
      That's funny - my Make Your Own Bubblegum Kit (Which is a chemistry set all its own) says that bubble gum manufacturers use limonene and rubber for the bubblegum base.

      --
      Tiller's Rule: Never use a word in written form that you've only heard and never read. You will end up looking foolish.
  17. Modern chem sets useless by Walt+Dismal · · Score: 4, Insightful

    Modern chemistry sets are crap; they have been gutted because of fear of lawsuits. So the materials and the experiments are bland and useless unless you're 8 years old.

  18. Blow Stuff Up! by thenovacrisis · · Score: 2, Interesting

    It's obvious why this guy wants a chemistry set... The same reason we all wanted one:

    To blow things up.

    There is a solution, though.

    A hand full of sodium + a large lake = very nice explosions.

    You can learn the importance of keeping alkaline metals away from water, the amount of energy created with the mixing of H2Oand sodium, and why you should never stick sodium in someone's bathing suit.

    Can you say, "Win Win."

    --

    -----.----.-------
    I'll .sig you!
    1. Re:Blow Stuff Up! by Binestar · · Score: 2

      I do hope your kidding about the "hand full" of sodium...

      Yeah, it should be "handful" of LITHIUM...

      --
      Do you Gentoo!?
    2. Re:Blow Stuff Up! by messiertom · · Score: 2

      BTW, raw sodium is pretty dangerous to handle. The same properties of sodium that cause great loads of fun with lakes can cause some not-so-fun effects with the moisture on your skin (or in the air).

    3. Re:Blow Stuff Up! by Nogami_Saeko · · Score: 2

      Exactly ;P

      I was toying with the old "blowing stuff up" bit when I was in highschool. Decided to whip up a batch of ammonium nitrogen triiodide in the basement.

      I managed to procure some pure iodine crystals from a drugstore (I still don't know why (a) they had them, or (b) why they sold them to me).

      Unfortunately my ammonia wasn't strong enough to react particularly well, but it was good enough that I got the reaction going a bit - I left it in the sink tub and went off to watch TV for a bit - while I was gone, everything dried out...

      When I was going back into the room, I flipped the lights on and heard something between a pop and a bang. It's amazing how unstable that stuff is - certainly not good to play around with...

      Turns out that if I had borrowed some ammonia from my friend's blueprinting machine, I probably would've got a much better reaction (it was enough to knock him out cold when he decided to smell the ammonia).

      To add to the problems, the iodine crystals slowly sublimed over a few weeks while in the container on my shelf, turning the container a nasty red/purple color, and probably didn't do me much good as I inhaled the stuff...

      N.

      --
      "Nothing strengthens authority so much as silence." - Charles de Gaulle
    4. Re:Blow Stuff Up! by Kj0n · · Score: 2

      There has been an earlier article on /. about a guy who did that: look here.

  19. Learn to home brew� by (H)elix1 · · Score: 5, Insightful

    I'd be real careful about buying 'chemistry' kits these days. If the war on drugs does not send the suits to your door, I'm sure the war on terror will.

    Brewing - wine and beer are a good start. A fair amount of chemistry (and biology) involved when you think about it. Taking the alcohol content above 15% or so lets you play with even more toys.

    Best college experience was making moonshine from captain crunch in the dorms. A bit of enzymes to convert the starch to sugar, let bubble, then we pulled out the still. Nothing like a mass spectrometer to assure you don't go blind....

    1. Re:Learn to home brew� by Raiford · · Score: 2
      You will have a difficult time buying reagent chemicals too ! Most supply houses will not sell to private individuals.

      --
      "player 4 hit player 1 with 0 stroms"
    2. Re:Learn to home brew� by Innominate+Recreant · · Score: 2

      Brewing - wine and beer are a good start. A fair amount of chemistry (and biology) involved when you think about it. Taking the alcohol content above 15% or so lets you play with even more toys. Not to nitpick, but brewing is zymmurgy, not chemistry or biology.

    3. Re:Learn to home brew� by Chewie · · Score: 2

      You're right. Zymurgy is not chemistry or biology. Instead, as the parent to your comment said, it's chemistry and biology, applied towards the end result of brewing beer that's given the term "zymurgy". Saying that zymurgy has nothing to do with bio and chem is like saying that biology has nothing to do with chemistry, and that chem has nothing to do with physics. To believe it stands on its own implies ignorance (note I said implies, not shows).

      --
      49 20 68 61 76 65 20 74 6F 6F 20 6D 75 63 68 20 66 72 65 65 20 74 69 6D 65 2E
  20. 300 in One Electronics Kits by oldzoot · · Score: 3, Interesting

    The experimenters labs are good for starting out - having a structured set of experiments to build, and yes, you can even go beyond those simple experiments and build simple experiments which are not in the book. For the most fun, however, I like the prototype breadboards. One of those with appropriate power supplies and other test equipment is good for analog, digital or combination circuitry. Add a few experimenters parts kits from Jameco and you are in business.


    As for Chemistry kits, I think just buying the labware you need and the various chemicals etc. is a better way to go than a pre-fabricated kit.


    The real interesting stuff however would be a molecular biology lab. Slice and splice DNA and build your very own new and interesting critter! Yes, you too can build your own miltary grade anthrax, plague or even smallpox. Add the THC gene to corn! Create that perfect paisley rose! Be the envy of everyone on your block! hmmmm I better quit now. Seriously, it is probably not all that hard to build a DNA synthesizer. Why not convert an ink-jet printer ? DNA = 4 molecules, many printers have 4 ink tanks. How tiny of a drop can you print???



    Z
    --
    enough is too much
  21. As a Chemist.... by BadlandZ · · Score: 5, Insightful
    You asked for recommendations, so here's mine. As a chemist, I recommend not getting one at all. There is nothing that fun in a chemistry set anymore (for legal reasons, almost everything fun is dangerous, so not in any set). You'll probably find more stuff in your own kitchen cabinet now days anyway if you know what your looking for.

    I would recommend a molecular model kit though if you really want something to play with, or if you want to be more geeky, you can get some molecular modeling software.

    1. Re:As a Chemist.... by iggymanz · · Score: 2

      Working with *real* reagents one can learn that in the real world reactions don't have 100% yield, real reagents have impurities, improper techniques can lead to erroneous results......I think that playing with sticks & balls or modelling electron clouds on a PC is fine, but it's only one very tiny part of chemistry.

      Take the first quarter or semester of general chemistry at a local two year community college...if you like it, then finish the general coursework, then figure out if you next want to take physical, organic, inorganic......

  22. Do it piecemeal by elnerdoricardo · · Score: 3, Informative

    Here's an idea.... Here in Toronto we have a great store downtown called Active Surplus. You can buy just about anything there. They have a pretty good glassware section where you can get most of the things you need... stopcocks (*snicker), flasks, beakers, pipettes, etc. I would think that most major metro areas have a similar store. Great place to get all the glassware you'd need. I would think another great source of info and leads would be the local highschool. Go in some day and have a chat with the Chem Teacher. I would think they'd have catalogues and suggestions for what you should have to get started!

    --
    IN SOVIET RUSSIA, sig changes you!
  23. Forget the chem set by grub · · Score: 2, Interesting


    and thought it would be fun to acquire a chemistry set just to play around with and maybe learn a few things from

    If you want an adult-style chemistry set, try one of those home beer brew kits or a home winemaking kit. You get to monkey around with various ingredients and after its all done you reap the rewards. err.. "Reap Responsibly"..

    --
    Trolling is a art,
  24. One Word by serutan · · Score: 2

    SODIUM !

  25. Do they even still sell chemistry sets? by Cyno01 · · Score: 2

    I havn't seen serious chemistry sets in years, i figured they stopped making them cuzza people like me, same with real lawn darts.

    --
    "Sic Semper Tyrannosaurus Rex."
  26. Re:sig by EvanED · · Score: 2

    It's /.'s anti-horizontal scrolling thing...

  27. Re:sig by packeteer · · Score: 2

    EvanED is correct. The space is there so that "page-widening-trolls" cant mess up some browsers width setting. Browsers such as IE will make it very hard to read slashdot if its too wide.

    --
    unzip; strip; touch; finger; mount; fsck; more; yes; unmount; sleep
  28. Re:Why? by Simon+Field · · Score: 5, Informative


    I agree. Building your own chemistry set would be more fun, and you would learn more.

    The best way to learn is to teach. Collecting a bunch of good chemistry experiments, and the sources for the materials, would make a great project.

    And you aren't the only one who benefits...

    Some places to start:
    Delights of Chemistry
    Demonstration Lab
    Lecture Demonstrations
    Chemistry Resources

    Some Sources of chemicals:
    CHEM Scientific
    Fisher
    Sagent Welch
    Carolina

    I am certain you will get lots more from other Slashdaughters...

  29. Re:sig by packeteer · · Score: 2

    For a while text url's were immune to the widening code. Trolls then went out and would put things like:

    http://www.asdasd.com/asd/asd/asdsd/gfdf/ger/gdc v/ b/hg/ytrhytruj/gfhjn/ghjytjhg/nbv/jytr/jgfhnbv/wef rqw/rqegfdscbv/xcbtru/yghjhgnmbv/njht/edr/gxc/v/we rtg/dgfhcvb/nygf/uj/ytj/nb/cvb/gser/twer/g/xcf/bvr d/yh/fg/n/cbv/sdf/we/tyf/gj

    in their post... now those are broken up too

    --
    unzip; strip; touch; finger; mount; fsck; more; yes; unmount; sleep
  30. Re:sig by EvanED · · Score: 2

    I've seen that question asked a hundred bajillion times, so I thought I'd step in...

  31. Re:Why? by Jucius+Maximus · · Score: 2
    "Why do you need a chemistry set to go back to school? If you want to prep for school just get a nice book so you don't have a tough time grunting the equations (and then you'll be able to adequately enjoy the labs)."

    Doing actual experiments is important for chemistry in particular because otherwise learning the nomenclature is next to impossible. This is not the case as much for intro physics.

    When I was learning all that stuff, we had all these tables with the IUPAC naming conventions and such, and none of it really connected togething into something coherent. But once you actually get working with a dozen chemicals at once, you have to catalogue your results some how and then the real relationships between anions, cations, acids, bases, etc are made clear to you. It's even better if you to chemistry experiments with a friend helping. (Joke not intended ;-) You have to coordinate your plans and communicate results to each other.

    I know from experience that it is at least 10X easier to learn chemistry in terms of the nomenclature, methods, and overall properties of different structures by lab work than by reading.

    And it works. It's been two years since I've had to take a chemistry course and I still know all my common anions (formula, charge, name) including the names for versions with up to one extra or two less oxygens off my heart.

  32. Oh... my... by Lethyos · · Score: 2

    My childhood garage probably still has purple and black stains all over it

    Usually those stains are kind of yellowish. What the hell are you?

    --
    Why bother.
  33. If you want good chemistry experiments, by joelt49 · · Score: 2, Funny

    I would definitely recommend the Anarchist's Cookbook. Full of fun stuff, ie thermite and other stuff I can't remember. Just don't get caught with it, though. If you do, I never posted this (uh, well, you know what I mean :)

    1. Re:If you want good chemistry experiments, by benson+hedges · · Score: 3, Informative
      ask any chemist you know about the anarchist's cookbook, or show them if they don't know it - 40% of the stuff in it doesn't work, 40% will blow up yourself, 15% are urban legends, and the rest may work if you do it right.. if you are interested, get some real books, like "Explosives" by Rudolf Meyer...

      be warned however, creating explosives, or drugs for that matter, is nothing a chemistry kit could archieve most of the time.. the only synthetic drug I am aware of that could be made this way would be GHB, which can be easily produced by mixing two chemicals, then heating them carefully. As for explosives.. creating things that go boom without the exact knowledge of what you do often result in the quick and impressive end of the creator's life. :)

      --
      Karma : Soylent Green (Mostly due to eating junk food and mocking religion)
    2. Re:If you want good chemistry experiments, by Idarubicin · · Score: 2
      There are various versions of the Cookbook circulating in print and on the web; some contain gross inaccuracies, some have been corrected--partially. Consult a chemist, or a real textbook, before you try anything.

      Well equipped university libraries should have books on the chemistry of fireworks--they're not a bad source of ideas. Information on explosives can be found at schools with good chem. eng. or mining programs.

      Be very careful with organic synthesis of any kind, in any quantity. Plan ahead--have a fire extinguisher on hand, and work where there is good ventilation. Don't work where nobody will hear you scream. A litre of solvent triggered with a blasting cap will throw shards of glass a couple hundred feet, except for the bits that are slowed down by your body. Less spectacular errors can be just as fatal. Consider yourself warned.

      --
      ~Idarubicin
  34. Re:sig by gilroy · · Score: 2
    Blockquoth the poster:

    obviously, the page-widening was an undesirable effect, so the Slash code was modified to insert spaces into long character strings so that they would word wrap - effectively averting that problem.

    Couldn't the original .sig holder work around this by simply inserting a space after one of the semi-colons? What's wrong with

    unzip; strip; touch; finger; mount; fsck; more; yes; unmount; sleep
  35. Re:Why? by Gorobei · · Score: 5, Interesting

    Exactly - that was the experience I had with my old 300-in-1 chemistry set about 27 years ago.

    I did 30 pages of book/guided stuff. E.g. filtering a sand and salt solution, then spending 2 hours getting the salt out of the solution... at the end, guess what? I had salt again!!! Gee, that was fun.

    I switched to my own guided experiments soon after that: KnO3 is cool, magnesium burns pretty well, sulfur smells bad, but hydrogen sulphide is even better! My father (a chemist) banished my experiments to the garage.

    Next month, I told my parents I needed a pound of sodium chlorate as a desiccant. My father managed to keep a straight face, but bought it for me anyway.

    Many more self-directed experiments were performed, and I found myself learning in leaps and bounds: I learned about the surface area of reactants when I thoughtlessly substituted powdered charcoal for granulated sugar in a simple propulsion experiment. Haha, skin and hair grow back.

    Chemistry is cool, but make sure your set has fun compounds... I mean, what the hell fun is copper sulphate, etc?

    Also, keep a lab book: it makes for pretty fun reading later in life ("4oz nitrocellulose," what was I thinking?) and is helpful if you screw up and the doctor/bomb-disposal unit needs to figure out what was going on.

  36. 300-in-one, I mean 299-in-one, I mean 298... by diamond0 · · Score: 2, Interesting
    Those 300-in-one sets frequently encouraged you to experiment by modifying the circuits...let me tell you, replacing the components when they burned up wasn't exactly the most fun thing to do, particularly when you couldn't readily determine which ones aren't working the way they're supposed to. I suppose an experienced engineer could readily do that, but a 12 year old kid trying to learn?

    Sure was fun to have my own 10mw-ish AM station, though.

    Frankly if I were to do it all over again I'd just go buy a bunch of components, a soldering iron and a few prototyping boards. They still make those prototyping boards, don't they?

    --

    --
    There is no hatred more pure and true than that expressed by children.
    1. Re:300-in-one, I mean 299-in-one, I mean 298... by bigberk · · Score: 2
      Frankly if I were to do it all over again I'd just go buy a bunch of components, a soldering iron and a few prototyping boards. They still make those prototyping boards, don't they?

      I'm sitting right beside a 300 in 1 kit (or, from where I'm looking at it, "300 in 1 elektronische projektdoos"). Prototyping boards are great, definitely more flexible. They have spring-loaded ones with horizontal and vertical tracks so you just "plug in" your components. No soldering needed. I've been using these a lot!

      I had a flashback to my first crystal set radio. I ran a big wire (antenna) to a tree to pick up strong signals. Then the radio works without any battery. How can anyone say that's not neat!

      If you have some time to kill, go build one!

  37. Re:Chemistry Set by Anonymous Coward · · Score: 5, Informative

    If you are serious about doing synthetic work, I
    would see about taking several lab courses at a
    local college. They are already set up with
    sources for the reagents, safty equipment (ie,
    hoods, glove boxes, safe storage for the reagents,
    safe disposal of the reagents, plus more
    analytical instrumentation so that you will be
    able to confirm that what you made is what you
    intended to make.

    If you really insist on seting up a lab at home,
    make sure that you set up a safe lab. Please do
    the following:

    1) Ensure that you can safely store, handle and dispose of any reagents.
    2)Be sure to join an amateur scientist oganization, and find some help, if only to double check that you are doing #1 correctly.
    3) consider the legal difficulties
    -in the state of texas it is a felony to own
    certain common glassware without a permit.

    Just to be safe, check your local laws along
    with the fire codes.

    4) If you can legally own glassware, consider
    buying the microscale equipment. It should
    be the same price or less for it, however
    you'll use smaller volumn of reagent.

  38. Re:Jackboots and Uzis? by kenthorvath · · Score: 2

    Paranoia is what prompts many laws to be passed that should never have even been contrived. That, and an overwhelming desire for power. It's not so much a matter or paranoia as a genuine mistrust for federal law enforcement. There are countless examples of abuses and after hearing enough of them, it becomes deafening.

  39. environment, geology by g4dget · · Score: 4, Interesting
    Measuring and monitoring the presence and amounts of chemicals in the environment and in food might be a good area to get involved in. You can get by with limited resources, the experiments tend not to be dangerous, it teaches excellent laboratory technique, and you can accomplish something useful. You could pick a problem that interests you personally (oxygen levels, organic matter, pollutants in a local lake), or you might look around for a volunteer organization to get involved in--they might even be able to provide laboratory facilities and train you.

    Other areas that involve chemistry and makes a good hobby are geology and mineralogy. You can collect samples, characterize them, learn about crystallography, and also analyze the samples chemically.

    And if you get seriously involved, you can actually accomplish new science in areas like those, even with fairly modest resources. There are lots of publications dedicated to both the hobbyist and the professionals in those areas; look at them at your local university library to get some ideas.

  40. Check out the Student Science Service by Avionics+Guy · · Score: 5, Informative

    By all means, check out the Student Science Service (http://www.tri-esssciences.com) in Burbank, California. They sell a few high-end chemistry sets of their own design (these are not kiddie sets). Ira Katz and his daughter, Kim, are the owners and are easilly accessable via e-mail. They're also one of the largest suppliers of pyrotechnic special effects to the local movie studios. Can't recommend 'em enough. -Kevin

  41. Keep a Lab book? Yes! by Vinson+Massif · · Score: 5, Insightful

    Keeping proper care of a --bound-- lab logbook is something I'll carry with me always, regardless of my career path. I still hand-number RH pages in ink; TOC in front; notes on left page; --dated-- documentation on the right. My only backslide is the occasional use of pencil. (I no longer wrangle instruments, now sysadmin.)

    Good logbook habits avoid the WTF syndrome.

    --
    "Remember, any tool can be the right tool." -- Red Green
  42. How to win a Darwin Award by John+Miles · · Score: 3, Funny

    1. Make nitroglycerin from a recipe written by someone who can't spell the names of the chemicals ("sulferic acid") required.
    2. Light fuse.
    3. Get away.
    4. (Your heirs) profit!

    --
    Dahlmann tightly grips the knife, which he may have no idea how to use, and steps out into the plain.
  43. Re:Jackboots and Uzis? by Monkelectric · · Score: 3, Interesting
    I'm not trying to troll, or seem naive here, but is paranoia in the US seriously that high?

    YES! My uncle had a friend buy what he called a "nautical generator" for his boat on ebay (he's not very computer inclined). And a few months later the FBI came to the guys house and they wanted to know what he wanted it for and where it was etc ... Kind of weird because its difficult to think of any nefarious uses for a generator.

    --

    Religion is a gateway psychosis. -- Dave Foley

  44. Expect company unasked by Julian+Morrison · · Score: 2

    If you get a chemistry set, expect intrusions from nosy and thuggish bastards in ninja suits, who are operating on the assumption that you are making drugs, of which for some daft reason they disapprove.

  45. Re:Jackboots and Uzis? by limekiller4 · · Score: 2

    Stillman writes:
    "Do you honestly think "suits" would turn up at someone's door over such a thing?"

    Buying hummus and charcoal can get the suits at your door, man, much less a chemistry set.

    Besides, do you realize that 7,600 people died last year from non-steroidal painkillers (eg, asprin)? Do you realize that between deaths resulting from cirrhosis of the liver and drunk driving fatalities there are about 48,000 deaths a year in the U.S.? Have you seen the hysteria over ecstacy?

    Yes, ordering things from chemistry supply companies can get a suit at your door.

    And if they did, would it be a problem if you had nothing to hide?

    If we have to resort to this logic we're already screwed ...we do, and we are.

    --
    My .02,
    Limekiller
  46. Re:sig by packeteer · · Score: 2

    I see nothing wrong with doing what you say other than the fact if i was going to fix my sig there would be much more to do. There are more erros in my sig than many people notice and i think its funny when i get flamed for it. People think they are smart by pointnig things out when they are proving that they actually know less than me.

    --
    unzip; strip; touch; finger; mount; fsck; more; yes; unmount; sleep
  47. Re:Jackboots and Uzis? by AlphaHelix · · Score: 2
    Dude, you're a crack monkey. The article you referenced didn't offer evidence that anybody was targeted by the Feds for buying "charcoal and hummus." It didn't even say there existed a person who bought "charcoal and hummus." "Charcoal and hummus" are used as examples of grocery items that might have been on the list of frequent-shopper records that got turned over to the Feds by an overzealous marketroid. The article doesn't cite a single instance of anybody being visited by the Feds as a result of their shopping habits. I'm as anti-frequent-shopping cards as the next Slashdot nerd, but, seriously, get your panties unbunched and try to use some of those reading comprehension skills that you had to demonstrate on the SATs (not to mention some good old-fashioned common sense) next time you start to make wild-eyed conspiracy-theory-esque leaps of logic.



    Aside from that, whether or not buying chemicals will get the Feds at your door depends strongly on what you buy. If you buy potassium chloride, probably not. If you buy sulfuric and picric acid, you should probably expect to be hearing the pitter pat of little feet on your doorstep.

    --
    * mild mannered physics grad student by day *
    * daring code hacker by night *
    http://www.silent-tristero.com
  48. sciplus by beej · · Score: 4, Interesting
    Cheap beakers and things, as well as a variety of cheap cool geekstuffs: http://www.sciplus.com/

    Warning: prepare to spend at least an hour looking at this site.

  49. Re:Why? by neverkevin · · Score: 2, Funny

    The best way to learn is to teach

    I guess you never went to public school :)

  50. you might learn more by SHEENmaster · · Score: 2

    but ordering a bunch of chemicals makes you look like a terrorist.

    --
    You can't judge a book by the way it wears its hair.
  51. Photo Darkroom: the adult chemistry set by sakusha · · Score: 5, Interesting

    Get into developing and printing your own photos. You know, the old analog kind. Even better, study some old antique photo processes like Cyanotype or Platinography. I make my own photo papers using these antique methods, and it is satisfying enough to keep me interested, and I was an Honors Chem major until I switched to art, majoring in photography).
    Making your own printing papers and photochems is a ton of fun, and yields tangible results (unlike most things you could do with a chemistry set).

  52. Interesting experiments: Silvering a mirror by jms · · Score: 5, Interesting

    One of the most interesting and rewarding reactions you can study as an amateur is mirror silvering using Tollens' reagent. I had an arc lamp reflector that needed resilvering, and decided to do it myself.

    After a lot of web research, I found that this website had the best directions (and the best safety warnings!):

    http://lerch.no-ip.com/atm/Silver.htm

    The only chemicals I had any trouble finding were silver nitrate crystals, which can be purchased from photography supply stores, such as:

    http://www.photoformulary.com/

    or ebay, and concentrated nitric acid, which can be purchased from lithography supply stores, such as:

    http://www.rembrandtgraphicarts.com/13_rga_cat.h tm l

    The hazmat shipping charge for the nitric acid will exceed the cost of the chemical.

    The process is somewhat complex, involves a number of stages, but isn't too difficult to do. It's an interesting reaction to watch, and the result is cool and useful. I created a perfect mirror coating on the inside of a bottle on the second try, and successfully coated my reflector mirror immediately thereafter.

    Everything worked for me, except that I found that I had to heat the muriatic acid in order to make the solder dissolve when creating the sensitizing solution.

    That's my recommended interesting experiment.

    1. Re:Interesting experiments: Silvering a mirror by shepd · · Score: 2, Insightful

      This reminds me of something else you can do for fun, with chemistry.

      Develop your own photographs (fun, but not tedious enough). Better yet, create your own PCBs (fun, and very tedious). As with the mirrors, you end up with something worthwhile when you're done.

      If you're just looking for some pointless fun, drop round pennies in Tinning solution. See how many people you can trick into thinking it's a nickel.

      --
      If you could be told what you can see or read, then it follows that you could be told what to say or think - BoC
    2. Re:Interesting experiments: Silvering a mirror by ckedge · · Score: 2


      Make the silvering solution the same day your going to use it, Discard it by pouring it down the drain with LOTS of water the same day.

      Ummm, can someone comment on this method of disposal?

      I ask because the Toronto sewer system goes right into Lake Ontario, which oddly enough is where we get our drinking water. The sludge from the treatment plants is poured onto farmers fields.

      Don't give me any shit about "it's only a tiny drop". There's a reason that the photo stores have collection containers in them for your worn out NiCd/etc batteries and cities have "dangerous chemical collection days" at city facilities.
      .

  53. adult chemistry set? by po_boy · · Score: 2

    I've got one. Mine has extasy, lube, body oil, edible paint, and all kinds of stuff that adults like to play with.

  54. The Kitchen Cabinet by LionKimbro · · Score: 2

    I thought about working through the kitchen cabinet. My only worry is, "What about all that other stuff they put in there?" Bleach isn't just Sodium Hypochlorite (or whatever it's supposed to be- it's been ages), it also has a bunch of other stuff in it. I always worry about the unknown additions reacting with other unknown additions and making something terribly wrong.

    1. Re:The Kitchen Cabinet by BadlandZ · · Score: 3, Informative
      You actually have a lot to worry about with "pure" chemicals also. I wouldn't recommend doing anything without having a fire extinguisher, goggles, a lab coat (or something that can easily be ripped off of you if you spill something on yourself) and an eyewash and fume hood.

      I suppose being outdoors would substitute for the lack of a fume hood, and a garden hose would be ok for eyewash. However, your never suppose to work alone in a lab, because if something goes wrong you don't have anyone to help you. How do you find your way to an eye wash when you can't see?

      A freshman lab manual from any college bookstore will give you an idea what some simple experiments are, and what you learn from them. Reading through one would be a good place to start to figure out what you would want to try. But, it's still best if your assisted somehow. And I won't recommend anything to do on your own...

      There are some people who need to actually see something happen in order to believe it's true or let it sink in, and that's where lab work really helps learning. But, the number of people I've seen cut themselves, spill stuff, or start accidental fires pretty much tells me, it's best to do in a lab, with an instructor. At least the instructor knows the risk of each experiment, and knows what to do when things go wrong.

      The goal of chemistry lab classes is more to teach good lab techniques and lab safety. Learning chemistry in the lab is only a secondary benefit, most of the learning actually comes from books and lectures. It's the physical skills of handling materials that's learned in lab, and without instruction there isn't much learning you can do on these skills on your own.

  55. Who needs it? by Tuxinatorium · · Score: 4, Informative

    You can get all the chemicals you need at hardware stores, etc.

    Examples: ammonia (cleaning), potassium nitrate (fertilizer), calcium cloride (road salt), ammonium nitrate (fertilizer), various petroleum distillates (everything), all sorts of metals, various exotic metal oxides (dry paint powders and ceramic glazes), sodium hypoclorite (bleach), hydrofluoric acid (for glass etching), hydrochloric acid, calcium sulfate (gypsum), etc... you can get almost any chemical you need for any purpose from common products, or manufacture it from common products. You just have to know what you're doing.

    1. Re:Who needs it? by Graff · · Score: 5, Informative
      IAAC (I am a chemist)

      You can get all the chemicals you need at hardware stores, etc.

      I totally agree with this. Most "modern" chemistry sets are so sickeningly-safe that they do not truly allow any chemistry to be done. I would collect your own chemicals, maybe buying a chemistry set to give you some guidance.

      There are several cautions that I would keep in mind. First of all, chemistry is highly dangerous. Many of the "first" discoverers of a chemical compound of process have actually turned out to be the second, third, etc. The true first discoverers literally killed themselves in the attempt and were thus not able to make their claim to fame! The first inventor of gunpowder, the first discoverer of fluorine, chemistry is riddled with those that tried something without understanding the consequences of their actions.

      Get several good chemistry texts and read them all the way through. Start off with simple, harmless experiments. Do not try anything potentially explosive, corrosive, or vapor-producing. Keep several neutralizing agents on hand, such as baking soda, lime, sand, a good multi-purpose fire extinguisher. Perform your experiments in an extremely well-ventilated area that has been fireproofed and is far away from any living or eating areas. A separate shack is a good place. Use goggles, a heavy rubberized and/or canvas smock, solid leather shoes, disposable gloves and face masks for some experiments.

      Never leave an experiment unattended. Never dump the results of your experiments in the same place, they can sometimes cross-react and form a dangerous mixture. Do not store anything which has the potential to become unstable, many nitrogen and phosphorous compounds can spontaneously react and cause extreme heat, vapors, or explosions.

      Make sure of the purity of your ingredients. If you get ordinary bleach for the sodium hypoclorite be careful - perfumes, surfactants, and other agents are often added to them which can cause unwanted reactions to occur. The same goes for household ammonia cleaning solutions. Most metals you will get will be alloys, always understand the elements in the alloy and how they may react in an experiment.

      Yeah, it's a lot to keep in mind, but chemistry is truly a dangerous business. I've been working in chemical labs for over 10 years and I've seen professional chemists with doctorates have accidents that you wouldn't believe. Explosions, runaway reactions, improperly ventilated experiments, splashes of highly corrosive compounds, forgetting to turn on or off some crucial bit of equipment, a lot of people get hurt even in the safest laboratory. I'm very careful simply because every exposure to some of these chemicals shortens my life-span. Many of the chemicals will take up permanent residence in your bones, will leave holes in your liver, will cause you to go blind, or even will make you go sterile. Lots of them have a cumulative effect so every exposure increases the risk, no matter how much time has passed.

      So be careful!
    2. Re:Who needs it? by pclminion · · Score: 2
      ammonium nitrate (fertilizer), various petroleum distillates (everything)

      Funny. That's what Tim McVeigh used on the Murrah building. Ok, so it wasn't petroleum distillates but close enough for government.

      It sucks how you have to watch what you say these days...

    3. Re:Who needs it? by revery · · Score: 2

      Never leave an experiment unattended. Never dump the results of your experiments in the same place, they can sometimes cross-react and form a dangerous mixture.

      Of course the only danger here is that you or some hapless passerby
      will be endowed with super powers...

  56. Alfa Aesar by Galahad2 · · Score: 4, Informative

    Alfa Aesar sells chemicals en masse. They'll even send you a catalog for free. I'm not sure, but you probably have to have a license to buy anything from them.

  57. May I suggest a book instead? by MickLinux · · Score: 4, Interesting

    You of course will need chemicals and chemistry equipment. I expect that you could call the local high school and find out where to get them -- and the high school teacher could suggest where you might get a nice sampling. I can't help a lot there.

    But perhaps I could suggest a book, instead:

    Laboratory Experiments for General Chemistry, 4ed
    by Hunt, Block, and McKelvy
    http://www.amazon.com/exec/obidos/tg/deta il/-/0030 32906X/qid=1041495102/sr=1-1/ref=sr_1_1/103-128032 3-3723057?v=glance&s=books

    This one is extremely useful in that it:

    (1) Lists the equipment needed for each (so you can go through, find the experiments that you can do)
    (2) Lists tons of safety and first-aid information, with standardized icons for each item
    (3) provides lab reports to fill out, which will help you understand the experiments
    (4) The experiments are actually rather standard; not all of them require special equipment.

    One word of caution: After produced the book, my brother noted that one of the experiments, standard to most College Chemistry Lab courses, is wrong:

    Experiment 13, the Burning of a Candle.

    My brother claims that the experiment purports to demonstrate the stoichiometry of combustion; in reality, it demonstrates the heat given off by candles, and the ideal gas law PV=NRT. He said that he demonstrated this by attempting the experiment in several different ways, one with 3 candles close together (burning hotter), one with three candles farther apart (burning cooler).

    I haven't done that experiment myself in his way. But I thought I should mention that.

    --
    Correct Horse Battery Staple: 72 bits of entropy. Enter "Correct H" into google. When it generates the phrase, that's
  58. Wear your goggles! by Devil's+BSD · · Score: 2

    Just some advice from CmdrTaco's web site. (it's one of his cartoons.)

    --
    I'm the Devil the Windows users warned you about.
  59. Buy old ones off Ebay by Pinball+Wizard · · Score: 2
    The only way to get a "chemistry set" that doesn't have plastic beakers and anything more fun than baking soda and vinegar is to get an old one made in the 50's or 60's. My old roommate found lots of good stuff on Ebay.

    Another good source of chemicals are some of the fertilizers you can get at a local nursery. If you have a good local nursery you can find things like ammonium nitrate, phosphoric acid, sulfur, etc. Professional growers often need to mix specific fertilizer "recipes" with these ingredients, which happen to have lots of other uses besides growing plants.

    --

    No, Thursday's out. How about never - is never good for you?

  60. Contact explosives! by xercist · · Score: 2

    You need ammonium hydroxide (amonia cleaner from the store) and iodine crystals (used for swimming pools, and cleaning horses, but also for making meth, so sometimes hard to get). Put the iodine in a coffee filter and pour ammonium all over it for a while. When it dries you get ammonium triiodide. Highly unstable, keep in separate small amounts, don't look at it funny.

    Ahh home chemistry is great

    --

    --
    grep "xercist" /dev/random ...you'll find me in there someday
    1. Re:Contact explosives! by gte910h · · Score: 3, Funny

      Keep it wet, and it doesn't go boom. :) I had a rackful of this stuff drying in the back of a chemistry class when I was a chem aid. Needless to say, I heard it down the hall (in english class) when the next period's chem aid set it off when moving the rack (which to my credit was marked "Contact explosive, do not touch"

      --
      Want to see every step I took to start my company? http://www.rowdylabs.com/blogs/pitchtothegods
  61. Re:Why? by rve · · Score: 2

    I agree. With a chemistry set you can do 19th century chemistry. It will be of no use whatsoever to prepare for a return to school.

    A much better preparation for a chemistry course would be brushing up your statistical mathematics and linear algebra, mixing chemicals is engineering, not chemistry nowadays.

  62. Sodium is weak. Potassium is better. by forii · · Score: 2
    Sure, sodium reacts strongly with water, but if you put a chunk of it in water, you're going to get a piece of floating metal setting the released hydrogen on fire. Nifty, but not as impressive as it could be.


    That's why you need to do this with Potassium, which reacts even better. That gives you the real cool explosions.

  63. Re:sig by TheMidget · · Score: 3, Informative
    If you want to post really long URL's take a look a http://shorl.com. This is a site that provides shorter alias to URL's that you supply. The alias can then be posted to newsgroups, slashdot, etc, without fear of being broken up. There is also http://tinyurl.com, which does the same thing.

    Of course, as moderation of this post shows, both of them are unfortunately also rather useful for trolling, so I'm not sure how long you'll be able to use these.

  64. Re:Why Chemistry? Chemistry is imitation of physic by joto · · Score: 2
    If you want to be a scientist, there is only one science, physics.

    Yes, of course. As we all know, science isn't about trying to find out about the world. It is about being able to recite formulas.

    Chemistry, Engineering only imitate simple formulas of physics.

    Sure. As a matter of fact, it turns out even social scientists uses "formulas" to describe the world. What a bunch of loosers they are, who try to copy this from physicists.

    But, to really understand atoms, molecules etc, you really need to understand quantum physics (the way it is taught to physicists).

    Yes, physicists usually have a much better understanding of the fundamental forces involved in single-body problems. The fact that this becomes largely irrelevant due to the computational difficulties involved in calculating anything useful for chemistry is something we can ignore for now. Actually measuring phenomena that is too hard to calculate is only for lesser beings.

    Ph. D. level Chemists and maybe Chemical Enginners, study quantum mechanics but it's at the level of undergraduate junior/senior level physics majors.

    Yes, and physics majors study chemistry, but only as chemistry 101. So what's your point?

    I'm not trying to be a jerk, but it is true that Chemistry or most of Engineering degree require very minimum level of math.

    Actually, that is true. But not because the math isn't there. It's because the math is too fucking complex to be able to do at all. But if you like math, I'm sure a course in physical chemistry would satisfy you.

    I've always felt Chemistry boring for this reason.

    So do I, but that doesn't make it any less of a science.

    True science is understanding nature from quantitatively, no vague, but exact; anything qualitative in nature is vague and waste of time.

    True science is about understanding nature. If things are too complex to study quantitatively at the moment, we must do a first approximation to it, and study qualitatively first. Just because something is difficult, doesn't mean you shouldn't do it.

    From a Doctorate level physics graduate student.

    I seriously doubt that. Most physicists I've met have a sound modesty about the importance of their subject, and a better understanding of science than you.

  65. Saltpeter by herbierobinson · · Score: 2

    Go to the drug store and get some Saltpeter. You will also need carbon and sulfer.

    Use outdoors.

    --
    An engineer who ran for Congress. http://herbrobinson.us
  66. Extraordinary Chemistry or Ordinary Things by InfiniteWisdom · · Score: 2, Informative

    My dad (a chemist) had got me this book ages ago. I believe its in its 4th edition now! A great read

  67. Nitrogen triiodide by MillionthMonkey · · Score: 4, Informative

    Agreed. If you've never seen the Anarchist's Cookbook, it's rather like a long "Overrated" Slashdot post printed on paper with pictures and a handsome black cover. The guy doesn't really understand most of the things he discusses and is on the firmest ground when he sticks with safe topics (guns and knives). It was written during the Vietnam era by a pissed-off draft age guy. Now he's turned to Jesus and says he wishes he hadn't written the book at all. Another mind lost to religion.

    The best explosive recipe in the book is one that the author discounts in passing- nitrogen triiodide, or NI3. (Actually, the structure is NI3-NH3, where the NH3 is bound to the NI3 electrostatically by what resemble hydrogen bonds.) According to the Cookbook a fly landing on it will set it off (which is probably true, although I never succeeded in getting a fly to cooperate). It claims it's too useless for any serious consideration when planning your anarchy. It might not be good for that, but it's great for pranks. I've had so much fun with that stuff. The secret to NI3 is DO NOT MAKE TOO MUCH OF IT. That way you can keep your fingers. A gram is way too much. Just take a few iodine crystals and put them under ammonia, and presto, it turns into this black powder. If you keep it under the ammonia, it's actually quite stable. When not under ammonia (even when under pure water) it might go off at any moment. Pick it up from the ammonia with a plastic eyedropper, and deposit the black sludge on some surface. Once dry it rapidly loses its NH3 adduct and becomes extremely sensitive to shock, decomposing explosively producing N2 and I2. Don't get traces of it on your clothes or skin, or you'll be treated to a continuous snap-crackle-pop of microscopic explosions (quite annoying).

    Finding references on it is difficult- it's almost like people don't want to do research on it. It's probably unstable because the iodine atoms are huge compared to the nitrogen. Congestion around the central N forces the molecule into a planar shape, with repulsive interactions among the three iodines, so it's unhappy for steric reasons. One thing I did find out was that the stuff turns bright orange if you leave it under the ammonia for a long time (like a month). This is probably because it picks up additional NH3 adducts.

    1. Re:Nitrogen triiodide by Anonymous Coward · · Score: 2, Interesting

      I have played with this a good deal in my younger days.

      You should use pure ammonia in solution not some household cleaning product that contains ammonia, or you will most likely be disappointed.

      Filter the precipitate and then wash repeatedly with ethanol (at a pinch, common methylated spirits works fairly well, too). This stabilises the compound much better than leaving it soaking in ammonia.

      Then transfer the wet precipitate to a suitable container preferably made from soft plastic that is alcohol-resistant and with a soft plastic lid with an easily-cleaned screwtop.

      Fill the container TO THE BRIM with alcohol.

      Ensure that the screw threads and cap are completely free of precipitate and that the wet precipitate is then COMPLETELY COVERED.

      In this state the compound appears to be quite stable over long periods of time. It will dry out very quickly when placed on a surface and then become extremely sensitive to vibration etc.

      Oh, don't forget to clean the spoon etc. you used to transfer the precipitate; picking it up absent-mindedly later on will teach you a lesson you will not forget in a hurry, otherwise.

      I would suggest wearing stout gloves anytime you dispense anything from that container, just in case.

      PS: on the topic of explosives, those who fool with chlorate compounds be aware that many have died or been seriously maimed by contaminating screw threads with powder and then when the thread is tightened or loosened, detonation occurs by friction.

      Bear in mind also that ignition due to static discharge has been known to happen.

      If you are going to fool with explosive substances, please don't use containers that will fragment into schrapnel. A soft (polythene) container will rupture quite satisfyingly without creating dangerous shards - so will cardboard. Wear safety glasses at all times and preferably strong gloves, and remember, sooner or later you WILL have an accident. Trust me, I speak from experience, and I was very lucky indeed not to lose my sight. Very lucky... at that point I realised that fooling with dangerous chemicals might be best abandoned.

      I do realise the allure of creating loud and satisfying bangs, and the safest compound I found for this is a 50-50 mixture of powdered magnesium and potassium permanganate. This is incredibly fast burning, much faster than gunpowder, appears to be quite stable and even a drinking straw filled with it will explode quite nicely.

      You do need to powder the permanganate and this is a risky process for your lungs, in particular, so do take care....

    2. Re:Nitrogen triiodide by Tackhead · · Score: 2
      > Don't get traces of it on your clothes or skin, or you'll be treated to a continuous snap-crackle-pop of microscopic explosions (quite annoying).

      s/annoying/funny/g

      When I was a sprogling, Dad brought home some goodies, and I made a wee bit too much (i.e. probably not much more than a gram!), and the stuff on the edges of the filter paper I'd laid out in the middle of the garage blew up before the stuff in the middle had dried out, thereby splattering the floor with really tiny droplets of still-wet stuff and fragments of filter paper.

      I was out of the garage (waiting for it to dry) when it went off. After hearing the *boom* and seeing the filter paper shreds all over the garage, I grabbed a broom and started to sweep up... snap-crackle-pop! I still remember Dad and I both laughing our asses off, while Mom just stood there, shaking her head at us.

      Seriously - NI3 can be fun in small quantities. But as the poster said, (1) SMALL quantities, a few crystals at most, (2) always take safety precuations like safety goggles, disposable coat, no long hair, etc, and (3) if you're sharing the joys of chem with your kids, supervise them, and train them to take safety precuations too.

      As others have said, and as I'll repeat, there's no such thing as being too safe. No fume hood? Some experiments don't get done, and some reagents don't get bought. Period. That's what your imagination, and a pencil, paper, and calculator, are for, and it applies whether you're doing it yourself, or with your kids.

    3. Re:Nitrogen triiodide by MillionthMonkey · · Score: 3, Interesting

      the stuff on the edges of the filter paper I'd laid out in the middle of the garage blew up before the stuff in the middle had dried out, thereby splattering the floor with really tiny droplets of still-wet stuff and fragments of filter paper.

      I used filter paper too, until I found a much better substitute- kitty litter! Specifically, that kind of kitty litter that clumps into a tight ball when it gets wet. Dries the stuff out quickly, confines it really well in a tight clump, and transmits shock evenly to all the precipitate at once- so you get huge noisy explosions with a good report- and disgusting iodinated kitty litter flung all over your backyard! None of the snap crackle business you get when the stuff is exposed to the open air. Of course you shouldn't ever do this, ever.

      Explosions aside, iodine itself is fun. I dropped a crystal on a counter surface once (this was when I was a chemist at a generic drug lab) and I noticed it a few hours later. So I picked it up. Of course by now there was a stain on the counter around where it had been. I wiped it up, but it came back.

      The janitor came in, saw the stain, and wiped it away. Within a minute- the stain was back! So he wiped it again. Scrub scrub scrub. As soon as he turned his back- there it was again! Scrub scrub scrub. It kept coming back- and it was getting darker even as you looked at it! I put a thiosulfate-soaked paper towel on it and told him not to worry about it.

      I felt bad for the people who cleaned that place. One of the tablets they made there was phenazopyridine, which is a drug women take for urinary tract infections (it's a urinary tract analgesic). This is one of the azo dyes, which means it has an -N=N- azo bond in it. All these compounds have an intense color. Pure phenazopyridine itself is a dark red powder, but in trace amounts, or when it's been dissolved in alcohol, it turns an intense yellow. (Which is a good thing, since urine is the same color- actually, that's probably why that compound is used for this purpose.)

      EVERYTHING in that place was yellow. People would track that stuff all over the place. There was a yellow streak going down the center of the hallway, the chairs and tables had yellow marks everywhere, the books had yellow fingerprints on them, it was a thin film all over everything and everybody. Even things at home started turning yellow. The tiniest crystal would get on you and that was the end of it.

      And don't even get me started on my idiot boss at that place, who inadvertently rediscovered the formula for dynamite while trying to come up with an FDA-approvable procedure for a selenium assay on vitamin tablets! What a mess that was! But this post is already getting too long.

      Much later I met someone who told me a story about a friend of theirs, who had some leftover phenazopyridine tablets and had noticed the intense color. She actually dyed her hair with the stuff for Halloween!!! Holy crap! Then (surprise, surprise) she couldn't get it out of her hair, so she eventually called the drug manufacturer to ask for advice. They were no help- in fact they couldn't stop laughing at her! (You can actually kill the stain with a solution of sodium dithionite, but this smells so evil we didn't even consider it an option for cleaning the floors. They should have just told her to shave her head and scrub her scalp with lots of rubbing alcohol.) I couldn't believe my ears when I heard that story. Her whole house must still be yellow.

  68. Books Books Books by Turbyne · · Score: 2, Informative
    I would check out a few textbooks. Make sure you have solution sets to them. Major science ones that I feel are important:
    • Calc 1 & 2 (decent book, 3rd ed. is cheap and plentiful)
      Differentiation & Integration
    • Physics 1
      Newtonian mechanics. Make sure you get a physics book, not an Engineering mechanics book.
    • Chem 1 (Chem for scientists & engineers)
      Find a syllabus for a Mechanical Engineering major. It should be mostly physical chemistry (thermodynamics, stoichiometry, etc.)
    That's the college level stuff that I've found most useful. Review Algebra & Trig if you're not too sure about your skills. Good luck.
    --
    ~A'Ëq'i4d)^'$ÊSÈòB
    1. Re:Books Books Books by Turbyne · · Score: 2, Informative

      Oh and spend some hours doing problem sets. As an engineering student that's what half my life consists of at the moment. Grab a stack of paper from the recycle bin, sit down and do it.

      --
      ~A'Ëq'i4d)^'$ÊSÈòB
  69. Re:sig by packeteer · · Score: 2
    --
    unzip; strip; touch; finger; mount; fsck; more; yes; unmount; sleep
  70. Re:Why Chemistry? Chemistry is imitation of physic by joto · · Score: 2
    s I've been told, the only pure science is maths. Physics is applied Maths Chemistry is applied Physics Biology is applied Chemistry.

    But then you've been told wrong. Math is not a science. It is a study of entirely human constructs. As it turns out, some of these constructs has proven themselves useful in science, but that doesn't make math itself a science. Neither is logic a science. Nobody does experiments in either math or logic.

    As for whether the rest of the argument is true, depends on your own sillyness. Biology is no more applied chemistry than enjoying dinner is applied thermodynamics. While it is true that microbiologists worry a lot about chemistry, there are also other biologists who couldn't care less, and work with entirely other things.

    In the same vein, one could argue for the same hierarchy in computer scientists/engineers. At the top, we have the hardware engineers, then microcode developers, people who write device-drivers, etc, system-level programmers, application-level programmers, scripters, and end-users.

    In reality, the tasks that end-users perform at a computer needs be no more easy than what hardware-engineers do when constructing one (and in doing that, most hardware engineers are also end-users...). The only difference is that it requires a different kind of knowledge.

    While it is true that physics concerns itself more with "fundamental principles" than chemistry, and logic is more "fundamental" than math, this does in no way imply that math is worthless because logic is more "fundamental", or that people should stop studying chemistry, because physics is more "fundamental".

    We cannot, and probably never will, be able to easily and automatically derive all important principles of math from logic, all of chemistry from physics, all of biology from chemistry, all of medicine from biology, all of psychology from medicine, all of social science from psychology, and so on. The value of science is not in it's "fundamentalness". It's in its usefulness (either direct usefullness for applied science, or in it's potential for understanding nature better in the long term for pure science).

  71. what the hell fun is copper sulphate by DrSkwid · · Score: 2

    you can grow coper sulphate crystals with a seed crystal and a solution, they look pretty neat

    --
    There are places where the networks are not touching,and there are places where they are-Boeing's Lori Gunter
  72. Re:Jackboots and Uzis? by MickLinux · · Score: 2, Flamebait

    I'm not currently in America -- but yeah, paranoia is getting bad there... or .. I dunno. Some of it's paranoia, and some of it's justified.

    For example, evidence does show that Vicki Weaver was targeted (read crosshairs, murder) because she was the outspoken racist in the Ruby Ridge incident.

    Donald P. Scott (LA Times, 1991/2) really was murdered for his land.

    A guy named Lamplugh really did have ATF agents burst in in jackboots, crush his kitten to death to make a point, terrorize his family, and he was innocent of anything, just a gun dealer who wouldn't help them set up someone else on false charges, yada yada yada. The list goes on.

    That was *before* Bush. Now, they really are hauling people away to Cuba, in the dead of night, and torturing them there, just like the Argentinan "disappearance squads". How many it is, the government refuses to say. But it *is* happening.

    Is it paranoia? It's hard to tell.

    Considering the flap about the child-abuse cases in the Catholic Church in Boston, I have to wonder how far down the line we Catholics are. I'm not too sure. But when you get to a police state, it does tend to extend its grip.

    --
    Correct Horse Battery Staple: 72 bits of entropy. Enter "Correct H" into google. When it generates the phrase, that's
  73. Blowing things up? How lame.... by Qbertino · · Score: 2

    Some people have posted on blowing things up with various mixtures. A Doctor (Demratologist) I once volunteered for had a large 1000mm whitelight laserscalpel in one of his operating rooms. You could shoot paper on fire or slice it into pieces from across the room. That was cool.

    --
    We suffer more in our imagination than in reality. - Seneca
  74. Get into home brew by dogfart · · Score: 2
    Home beverage making will satisfy most basic home lab needs. Making wine in particular requires a good deal of practical chem - balancing acidity, converting percent sugar into percent alcohol (my fave), recognizing the awful smelly compounds that result when the process goes bad (mmm... mercaptans).

    U.C. Davis has some nice information on the subject. You get to play with pH meters, refractometers, measure specific gravity, titrate total acidity, figure out how much K2CO3 to counter high acidity, etc.

    --

    "dope will get you through times of no money better than money will get you through times of no dope"

  75. looks like what the unabomber would have posted by AssFace · · Score: 2

    I would envision Ted being all frustrated about how hard it is to get kits these days and resorting to /. to help him out.

    At least this poster wasn't ranting on about how technology is ruining the modern world and then inquired about various troll's addresses.

    --

    There are some odd things afoot now, in the Villa Straylight.
  76. Re:This Reminds Me... by istartedi · · Score: 2

    Which is exactly what it was. I bet the guys in the bunker who run Echelon print this out and tape it up in the lunchroom for laughs.

    --
    For all intensive purposes, "whom" is no longer a word. That begs the question, "who cares"?
  77. Re:Jackboots and Uzis? by sjames · · Score: 2

    I'm not trying to troll, or seem naive here, but is paranoia in the US seriously that high?

    Yes, and then some. Even before 9/11 it was getting silly. After the bomb went off at the Olympics in Atlanta, the FBI indicated that we should be suspicious of anyone who had any sort of black powder, pipes, alarm clocks, and/or wire in their basement. IMPORTANT NOTE: Here in the southeast, it is fairly common to load one's own shotgun shells and other ammo, or at least it was until it became too much of a pain to keep the powder around. Of course, pipe, wire, and an old alarm clock is not that unlikely in a basement/junk room either.

    It is now necessary to get a low explosives permit in order to purchace model rocket engines larger than F.

    Most chemicals that could be used for drugs are either 'denatured' (that is poisoned, apparently it's better that you die rather than get high) or no longer available. You can (and will) be investigated if you buy large amounts of fertilizer.

    The really annoying part about all of the above is that they make perfectly legal activities impossible or at least a pain in the ass, but do little to prevent the crimes (or 'crimes' in the case of drugs).

  78. Re:Why? by Oliver+Wendell+Jones · · Score: 2

    As a chemist who has had the misfortune of experiencing chemical burns due to my boss' stupidity, I can't stress the importance of protecting yourself enough!

    As I've stated before, I used to work in a secondary lead refinery. There were massive air filtration units to remove part of the lead dust from the air - we still had to wear respirators - and collect it in large canvas bags that were repeatedly shaken by the collection equipment to get the dust to fall to the bottom of the bags.

    The dust collected in these bags was very fine (large lead particles don't traditionally remain airborne for very long at 1G). Fine metallic dusts are highly flammable when mixed with an oxidant.

    One of the methods we used for determining various elemental levels was to combine a fixed amount of a sample with an equal amount of Sodium Peroxide (which is a highly reactive oxidizer), heat the sample mixture until it became molten and then drop the crucible full of molten reactive material into a beaker containing a fixed amount of de-ionized water. After the rapid reaction of the very hot oxidizer coming into contact with the water, we would fish out the crucible and run the water through an atomic adsorption spectrophotometer which would tell us how much of which element were present. In addition to being a very cool reaction to watch, it would take almost any material and convert it into a water soluble salt so it could be read on the spec.

    Because of the reactivity of Sodium Peroxide (which all by itself will burst into flames when mixed with water) we would only use this method on material that was traditionally non-flammable such as the slag from the various furnaces.

    The person who was promoted to lab manager when the original manager left was not a chemist, and had never taken a chemistry class in his life and didn't understand the basic rules of chemistry (i.e., hot glassware looks exactly the same as cold glassware) and was often times caught doing something stupid.

    One day when the floor supervisor brought in a sample of lead dust from the shaker bags to be tested, Tom (the new manager) got a hold of the sample and volunteered to do the analysis. I watched him weigh out equal amounts of dust and Sodium Peroxide, but before he could combine them in the zirconium crucible I pointed out to him that you really shouldn't mix highly flammable materials with a highly reactive oxidizer.

    He politely told me to mind my own business and that he was the lab manager and he knew what he was doing. I then proceeded to move quickly away from him and watched carefully from across the lab as he not only proceeded to mix the two materials together (luckily without incident) but then proceeded to pick up a pestle and try to grind the two materials together in the crucible.

    For those who have never worked with potentially explosive materials, they can be set off by a variety of sources including, but not limited to, heat, pressure and shock. When you combine two reactive materials in a metal crucible and then proceed to grind them together with a heavy porcelain pestle, you introduce heat, pressure and shock. Needless to say within about two seconds the materials combined together in a very impressively large flash, severely burning the hand holding the pestle and burning off just the upper part of his eyebrows that extended beyond the top of his safety glasses.

    I have never had to bite my tongue so hard before or since in my life to keep from laughing directly in his face.

    This was almost as funny as the time when he got red phosphorous on his asbestos gloves which were already contaminated with sulfur and potassium nitrate and then proceeded to try and dust off his gloves by rubbing them on the front of his (luckily) flame-retardent shirt. He apparently didn't know that sulfur, phosphorous and potassium nitrate is the basic recipe for strike-anywhere matches...

    --
    A computer once beat me at chess, but it was no match for me at kick boxing -- Emo Phillips
  79. Re:Jackboots and Uzis? by MickLinux · · Score: 2
    Sorry. I get my information off the Drudge Report. He in turn took his information from more standard sources like CNN -- but that doesn't mean that they were correct.

    I remember reading about such things as keeping the inmates standing for long periods, sleep deprivation torture, recently. At the time of capture, there was stuff about hauling them in unventilated tractor trailers and leaving them to roast (that from www.rawa.org). To be honest, I have not been there in either location, and do not know for sure whether this is true.

    However, I also read about Jose Padilla -- and I have no reason to believe that is false, either.

    In the end, I go back to my first paragraph: Yeah, there is paranoia. Some of it may be justified; I'm not sure which is and which isn't.

    --
    Correct Horse Battery Staple: 72 bits of entropy. Enter "Correct H" into google. When it generates the phrase, that's
  80. Powdered sugar or flour . . . by j_w_d · · Score: 2

    ...suspended in air will make a nice little flash too. My mother was heard to wonder how all the burn marks got into the kitchen table cloth - paper bag, put small amount powdered sugar in bag, shake well and immediately toss in fire place. Lucky we didn't burn the house down actually.

    --
    ------ The only greater hazard to your liberty than n politicians is n+1 politicians.
  81. Well ovbiously by Tuxinatorium · · Score: 2

    You have to know what you're doing to do it safely. And I do. Pyrotechnics is fun.

  82. I think you're being too literal by gentlewizard · · Score: 2

    The best way to learn IS to teach, because in preparing for a class you have to do the labs themselves and make/anticipate the mistakes. That's all that was meant, I think.