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Bismuth No Longer the Heaviest Stable Element

forii writes "Bismuth-209 was commonly thought to be the heaviest stable element. But now Physicists have discovered that Bi-209 actually is unstable and decays with a halflife of 2*10^19 years. This means that the average 8oz (237ml) bottle of Pepto-Bismol contains one decay event every 36 hours or so."

24 of 78 comments (clear)

  1. I can see the headlines now... by renehollan · · Score: 4, Funny
    Pepto-Bismol DANGER!!!

    [shock-rag wire service] Scientists discover that bismuth, a major component of Pepto-Bismol , is RADIOACTIVE and decays into the TOXIC POISON thallium.

    While the decay rate is the slowest observed to date and, in fact, sets a record, it is noted that NO MINIMUM SAFE EXPOSURE LEVEL has been established for radiation exposure, and there is NO CURE for thallium posioning.

    --
    You could've hired me.
  2. Actually... by Mensa+Babe · · Score: 2, Interesting

    Bismuth-209 was commonly thought to be the heaviest stable element.

    Actually, most of the scientists believed it was stable, however not everyone. (Some of them were considered "crackpots" by the rest of the community, but the point remains valid, even if somewhat less so.) Try a Google search.

    --
    Karma: Positive (probably because of superiour intellect)
  3. 2*10^19? by Niahak · · Score: 3, Interesting

    That's a really long time. I mean, really long. The universe is considered to be 15 to 20 billion years by most who decide to actually guess. That means that, if the universe is 20 billion years old... and 1 g of Bi-209 was produced at the beginning of the universe, it would take another 1.999999998*10^19 years before half of the Bi-209 was left. I wonder if our universe will even reach that age, if the big bang 'cycle' theory holds to be true.

  4. It's dangerous? KILL IT!!! by slittle · · Score: 2, Funny

    OMG, you're right! At one event per 36 hours, it's practically a fucking Omega Particle!

    Someone call Starfleet! *KILL IT! *KILL IT!

    (*read: start a new government agency dedicated to the analysis and monitoring of this tool-of-terrorists; fund a few dozen fact-finding junkets, c/o the taxpayer; draft an array of pointless laws regarding Bi research, don't forget to call the religious end-of-world nutters for their valuable insight; end up hiring a PR agency to divert attention away from the fact that you've accomplished bugger all, were wrong all along, and now have a $30mil mansion on the harbour).

    --
    Opportunity knocks. Karma hunts you down.
  5. For the non-chemists/physisicists like me... by Andy_R · · Score: 2, Interesting

    Does 'stable' mean that decay hasn't been observed, or that it NEVER occurs?

    How does quantum mechanics apply to decay?

    Does an atom decay when a certain set of positions occur within it, and if so why can't the frequency that this would occur at be calculated?

    --
    A pizza of radius z and thickness a has a volume of pi z z a
    1. Re:For the non-chemists/physisicists like me... by metamathica · · Score: 5, Informative
      Disclaimer: my degree in physics qualifies me to paint a general picture here. Technical nitpicks are always welcome.


      In the article, it mentions that people actually have predicted this decay using theory. The nucleus is not completely understood, but the theory of basic decay phenomena is pretty complete.

      Any time you talk about the quanta of physics, you need to use quantum mechanics. The quanta are of course the so-called fundamental particles, including the proton, neutron and electron.

      The nucleus is held together by the strong force. This force must be very strong to keep the protons, whose like charge repels one another, very close together. The strong force only pulls over very short distances: if some nucleons get far enough, their electromagnetic repulsion will continue to push each other apart and they will be separated permanently.

      However, the particles in the nucleus don't have enough energy to get over the hump, so nuclei are stable. This is where quantum mechanics applies. Even if the hump is very tall, the nonlocality of quantum mechanics means that some particles can escape if the hump isn't very wide. Because they have a probabilistic spread in space, some of them can creep to the other side. When they get lucky like this, a nuclear decay occurs. The details of the nucleus determine how high the barrier and how wide the hump, both of which affect the probability of tunneling.

      In stable nuclei, particles are prohibited from escaping. In this case, it's not that the hump is too high, but that it's asymmetrical. If the nuclear force is strong enough compared to the energy of the nucleons, it can dig a deep well for the particles. In this case, having some possibility of getting past the hump doesn't really help: the area on the other side of the hump is prohibited regardless.

      One way to think of this process is to say that quantum mechanics would allow you to borrow the energy you need to jump over a fence as long as you fell back down on the other side, no matter how tall the fence.

      But you can't keep the borrowed energy, so you could never jump to the top of a roof, even if it were no taller than the wall you just jumped over.

    2. Re:For the non-chemists/physisicists like me... by metamathica · · Score: 2, Informative
      I was completely amazed that someone modded me troll until I saw your comment! ;-) I have no complaints about honest dialog though. It may be too late for many others to read this, but at least you seem interested.

      You are right about the role of the weak force. The process you are thinking of is beta decay. In this process a neutron is converted into a proton, an electron and an antineutrino.

      Beta decay is detected by looking for beta particles, also known as electrons. This is another interesting process, but the article mentions that they looked for and found alpha particles.

      I hope this makes things clearer. Incidentally, we've talked about two of the three kinds of radiation here:

      • Alpha Radiation consists of alpha particles, which are helium nuclei (no electrons). These particles are not particularly stable since they are heavy and have high charge. They travel no more than an inch or so in air and are stopped by skin. Alpha sources are not dangerous unless eaten or inhaled. In fact some smoke detectors measure the rate of emission from radioactive americium because alpha particles are stopped by smoke.
      • Beta Radiation consists of beta particles, which are electrons. Beta radiation penetrates your body easily and is quite dangerous. The primary danger is the possibility of genetic damage from beta particles tearing through your body.
      • Gamma Radiation consists of gamma particles, which are photons. These are the particles of light. X-rays, microwaves, ultraviolet, visible, infrared, radio and TV waves, etc. are all systems of photons of varying energies. Gamma radiation is highly dangerous, comparable to beta radiation; X-rays are dangerous in high doses but much safer than gamma rays. Lower frequencies like those of cell phones and microwaves may pose some health risk though studies have at least shown it is not dramatic. Photons are emitted by moving charged particles with energy to spare. Thus, gamma radiation often accompanies other nuclear radiation as an aftereffect of another decay mechanism.
  6. First Nitpick Post! by fm6 · · Score: 4, Informative
    Bismuth-209 is not an element. Bismuth is the element -- Bismuth-209 is one of its isotopes. So the headline should read, "Bismuth no longer the heaviest element with a stable isotope". Except that's misleading too -- it sounds like they've found one even heavier. How about... oh, never mind.

    Incidentally, all elements have unstable isotopes. Bismuth's are pretty rare, but they do exist!

    Bismuth obsessive will rejoice in the web site of the Bismuth Producers Association.

    I prefer Tums, myself.

  7. Second Nitpick Post! by slug359 · · Score: 4, Informative

    Bismuth-209 is the most common isotope of bismuth (with its mean atomic mass being 208.98038), so it would be acceptable to say ' Bismuth No Longer the Heaviest Stable Element', according to webelements and The Jefferson Lab.

  8. So at the big crunch... by fm6 · · Score: 2, Funny

    ...Pepto Bismal will be in short supply. And just when people really need it!

  9. Re:And the new winner is? by ConceptJunkie · · Score: 2, Informative

    If you look at the periodic table, the answer is obviously the next smaller element, lead, which is what most of the heavier elements eventually decay to.

    --
    You are in a maze of twisty little passages, all alike.
  10. Francium? Freedomium by infernalC · · Score: 4, Funny

    GAITHERSBURG, MD
    22 May 2003

    Today, the National Institute for Standards and Technology, the civilian agency of the US Government responsible for researching and making available data concerning the physical properties of substances including chemical elements, annouces the discontinued use of francium as the name of the 87th chemical element.

    "It's just not appropriate to continue to refer to an element by the name of a nation whose inaction is tantamount to condoning terrorism," said Dr. Hratch G. Semerjian, director of the Chemical Science and Technology Laboratory. "We decided that it would be better to refer to the 87th element as Freedomium in honor of those who died to secure the liberty of our country.

    Asked if the agency would once again return to calling the 87th element francium, Semerjian said that the element would not return to its former name. "We are prepared to take whatever action is necessary to liberate any element whose nomenclature is derived from a repressive regime."

    -

  11. Re:It's dangerous? KILL IT!!! by clem.dickey · · Score: 2, Funny

    > At one event per 36 hours

    Remember, that's just an average. Your experience may be different. It could decay all at once just after you swallow. You can't be too careful.

  12. "Contained" is right! by Markus+Registrada · · Score: 3, Interesting
    Imagine my surprise at finding that Slashdot got something right: forii wrote that a "bottle of Pepto-Bismol contains one decay event" every 36 hours, and it does! Those alpha particles can't get through the glass.

    Not only that, he never said "it's" when he meant "its".

    My favorite element, by the way, is Osmium. It sublimates dreadfully toxic fumes from a solid state at room temperature, and nobody knows exactly what its specific gravity is, nor whether it or Iridium is the heaviest element.

  13. Re:Third Nitpick Post by bobowla · · Score: 3, Informative

    How about "Bismuth not stable; Lead now heaviest stable element". (Polonium has no stable isotopes).

  14. Re:Third Nitpick Post by fm6 · · Score: 2, Funny

    Ok, not only did you catch me in a dyslexism, you came up with a better headline. For that you will suffer!

  15. Proton decay by reverseengineer · · Score: 4, Interesting
    "Other kinds of decays such as protons from proton-rich nuclei could be studied by the same method but this will have to be proved!"

    This could prove to be the most important use of this technique, as most proposed Grand Unified Theories have interactions that can turn quarks into leptons, so that a proton would be expected to eventually decay into a positron and a meson. Unfortunately, this process has never been observed (well, only somewhat unfortunately, as high proton stability is definitely a Good Thing in most ways), and experiment and theory have thus set a lower bound on the lifetime of a proton of roughly 10^33 years, about 23 orders of magnitude greater than the estimated current age of the universe.

    As you can see, compared to the suggested lifetime of a proton, even Bi-209 seems unstable. The expected extreme rarity of a proton decay event, however, is somewhat balanced by the overwhelming abundance of protons in the universe.The "lifetime" for an individual proton is more like a life expectancy, an average figure- given a suitably large collection of protons, odds are good that at least one would decay in a reasonable timeframe. If you carefully watch 10^33 protons for a year, for example, and reality agrees with theory (big if), then it is likely (certainly not guaranteed though) you will see at least one decay event. Now, 10^33 may sound like a tremendous amount, but remember that each proton has a mass of only 1.67*10^-27 kilograms, so that 10^33 protons would have a mass of about 1,600 metric tons- a lot, but not outrageous.

    The real problem lies in that "carefully watching" part. So many other forms of radiation are much more prevalent, and so might mask the signature of proton decay. Cosmic rays, naturally occuring radioisotopes in places you'd never think to look, solar neutrinos, that sort of thing. Ah, why yes, this is one of those experiments they do in a salt mine and uses a gigantic tank of ultrapure water (your proton source). However, as of yet, no one has found concrete evidence for proton decay from one of these experiments. Go here for a excellent site about a proton decay detector that ran in the 80s, and here for one currently in use.

    Perhaps this process will detect this very rare event, lending profound support to one of the many supersymmetric models out there. Unfortunately, if it does not detect proton decay, it will be much more difficult to say just what the result means, it being difficult to prove a negative and all.

    --
    "FDA staff reviewers expressed concern about the number of patients who were left out of the study because they died."
  16. somewhat OT isotope question by frovingslosh · · Score: 3, Interesting

    Since there are likely to be a number of people teading this that have good command of the topic, let me ask a question on isotopes. All through school I was taught that different isotopes of an element have the same chemical property. That information is still found in most articles on the subject. Yet I recently found a reference that Heavy Water was poisonous. Since there is no radiation danger, how can heavy water be poisonous if isotopes are chemically identical? What is going on here? And what are the indications of heavy water poisoning?

    --
    I'm an American. I love this country and the freedoms that we used to have.
    1. Re:somewhat OT isotope question by forii · · Score: 3, Informative

      Deuterium has different hydrogen bonding properties from H-1. This is a problem because a lot of biology (DNA, for instance) relies on hydrogen bonding to hold things together correctly. If you started drinking a lot of D2O, the differently shaped molecules wouldn't fit together correctly and you would begin breaking down at the cellular level. If I recall correctly the effects are a lot like radiation poisoning.

      Another way that D2O differs from regular H2O.

    2. Re:somewhat OT isotope question by Idarubicin · · Score: 2, Informative
      ...If you started drinking a lot of D2O, the differently shaped molecules wouldn't fit together correctly and you would begin breaking down at the cellular level...

      No! Deuterium behaves chemically exactly like hydrogen-1 (protium) in the compounds that it forms. The physical properties are slightly different (heavy water--deuterium oxide--is denser, and has higher freezing and boiling points. Heavy water ice cubes will sink in a glass of regular water.) Problems arise simply because of its added mass. It's chemical kinetics are different--reactions involving deuterium run more slowly than reactions involving protium.

      In the delicately balanced biochemical environment of the body, this slight slowing of reactions by the involvement of a heavier isotope would likely cause unpleasant symptoms. This has never been tested (to my knowledge) in any system larger than a cell culture. In those cases, replacement of roughly half the light water with heavy water prevented the formation of microtubules, blocking cell division.

      Heavy water costs about three hundred U.S. dollars per liter--so poisoning a human being by this technique would be extremely costly. Not only that, the effect would be reversible with consumption of regular water. The effects would be like radiation poisoning or chemo, because rapidly dividing cells (in hair follicles, digestive tract, bone marrow) would be affected first.

      --
      ~Idarubicin
  17. Heavy water toxicity by CERDIP · · Score: 2, Informative

    Heavy water poisoning of animals is caused by the D2O (heavy water) inhibiting cell division (mitosis). Bacteria growth rates are reduced, leading to problems in the GI tract, and bone marrow activity is reduced. So GI infections and enemia are symptoms. You would need to approach about from about a quarter to about a third of your body weight in D2O to achieve toxic levels. It would cost in the vicinity of $10,000 dollars and you would weight several pounds more when you died.

    --
    ---- ---- --- -- --- ------ Keep Cool But Do Not Freeze
  18. they already knew about this by EddWo · · Score: 2, Funny

    looks like the pepto-bismol people already knew about this

    http://www.pepto-bismol.com/faqs.htm#8

    How do I read the expiration Date? Can I use Pepto-Bismol® past the expiration date?
    Expiration date example:
    EXP JL02C0041
    EXP = expires
    JL = indicates the month (July)
    02 = indicates the last digits of the year (2002)
    C0041 = indicates plant and production information

    If your Pepto-Bismol® has expired, please do not use it. The ingredients may not be stable after the expiration date.

    that would be EXP JL20000000000000002003C0041 I suppose, it should be safe to drink for a while yet.

    --
    "Taligent is still pure vapor. Maybe they'll be the last who jumps up on Openstep... "
  19. Re:It's dangerous? KILL IT!!! by Alsee · · Score: 2, Funny

    that's just an average... It could decay all at once just after you swallow

    True, you're far more likely to have the hydrogen atoms in a glass of water spontaneously fuse after you drank it. If the bismuth decayed all at once it would kill you, but if hydrogen fused all at once it would kill everyone in a 50 mile radius. :)

    -

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    - - You can't take something off the Internet! That's like trying to take pee out of a swimming pool.
  20. I thought this was old news! by MillionthMonkey · · Score: 2, Informative

    My dad had a copy of Lange's Handbook of Chemistry that was published back in the sixties. I distinctly remember seeing that it listed the half life of Bi-209 as 2x10^23 years. That was only four orders of magnitude too long.

    In principle there are no stable nuclei heavier than iron 56. If you have a nucleus with atomic number A and atomic weight X, and you add up the binding energy of that nucleus, and compare it to the sum of the binding energies of an alpha particle and of a daughter nucleus with atomic number A-2 and atomic weight X-4, you will find that alpha decay is at least a little energetically favorable for many nuclei heavier than iron.

    If alpha decay is energetically favorable for a nucleus, then that nucleus is not stable. Alpha decay is a barrier tunneling process. If there's a potential energy drop on the other side of the barrier, the barrier will get tunneled through by an enterprising alpha particle eventually. It's just a matter of how long it will take- which is determined by the barrier width and the magnitude of the potential energy difference. The only reason many elements (iodine, gold, mercury, lead, etc.) are considered stable by human beings is that their decays have never been observed- because they are difficult to observe within human time scales. You might have to set up your experiment and wait for years, maybe centuries, before you see a decay. A bottle of mercury might contain two alpha decays per century. Is mercury stable? Not really, but for all practical purposes it is. It's all in the eye of the beholder.

    So it seems someone has caught bismuth in the act. Does this mean lead is now the heaviest stable nucleus? No, absolutely not. Lead has some advantages over bismuth- even numbers of neutrons and protons, etc. Pb-208 will definitely have a longer half life than Bi-209. Determining the half life of Pb 208 is going to be hard. But quantitative differences aside, the only real difference between lead and bismuth is that bismuth got caught!