Hydrogen Stored in Safe High Density Pellets
sunbeam60 writes "A group of scientists are going to present their breakthrough in hydrogen storage this Wednesday. In contrast to previous storage mechanisms, this method binds hydrogen to a pellet which is completely safe to handle at room temperature. While bound in this medium no hydrogen loss occurs, enabling hydrogen to be stored cheaply for indefinite periods. When needed, the extraction of hydrogen is relatively simple. The pellets exceed all criteria set by the US Department of Energy for 2015, enabling a car to drive more than 500 km on a 50 L tank (13 MJ/l)"
Ok, so I read the article and it's fairly light. The question I have is how do we get the hydrogen back out?
If you crash into another car, do you get to steal the car's pellet and absorb its power?
There seems to be information in the summary that is not substantiated in the referenced article:
While bound in this medium no hydrogen loss occurs, enabling hydrogen to be stored cheaply for indefinite periods.
The article referenced mentions nothing regarding hydrogen loss (or lack therof).
When needed, the extraction of hydrogen is relatively simple.
Is it? Again, nothing in the article about the extraction process.
So where did the submitter get this extra data? If this data is correct, we'd appreciate a link.
If, however, this detail in the summary is unsubstantiated, we'd appreciate less speculation in the future.
____
~ |rip/\/\aster /\/\onkey
The new pellets could also bring about a renaissance for giant hydrogen-filled airships, or as they will now be known, beanbags.
... they decided to coat these pellets with a mixture of iron oxide and aluminum powder.
COAL!
Sadly not much detail on the extraction process. Good ol' water can store a lot of hydrogen cheaply but getting it out is a PITA. Still, it'd be nice to pull up to a station and just drop a pellet (or bag of pellets) into the car and drive off again. D
Do really dense people warp space more than others?
The main thing to consider is the economics. More to the point, how will the existing oil/energy companies financially benefit from such technology? For if they don't have an interest in this product, it will never come to fruition, regardless of its technical merit.
Cyric Zndovzny at your service.
If I feed this to my dog, will he fart lightning?
I wouldn't eat those if I were you. They could give you gas.
*rimshot*
Tsunami -- You can't bring a good wave down!
""A group of scientists are going to present their breakthrough in hydrogen storage this Wednesday."
/. again, I, for one, will not cry "Dupe".
Seeing as neither the article nor the summary give any specifics, why is a press release being passed along as an article?
Why not wait until they've presented their findings, and then submit an article with more information?
Whoever submitted this article is probably interested enough in the subject to search for a better article come Thursday or Friday -- and if it gets on
"Trolls they were, but filled with the evil will of their master: a fell race..." -- J.R.R. Tolkien on Olog-hai
I got 23 miles to the US gallon.
500 km is about 310 miles.
50 liters is about 13 US gallons.
This is comparable to many US sedans. The question is whether the cost of hydrogen processing will be more or less expensive than the cost of refining oil.
The linked article gives very little information. So, while I'm super stoked by this ( it's a really, really important development ) my questions are:
1) How do they get the hydrogen back out? Do they crush the pellets ( destroying them ), do they heat them, etc.
2) Are the pellets re-usable? Or do you have to get new ones? And if they *aren't* re-usable, can the carrier material be re-cycled into new pellets?
My concerns would be that if the material isn't re-usable/re-cyclable we'd end up with vast landfills full of crushed or otherwise useless carrier material, in which case this is hardly a boon.
On the other hand, if it's recyclable, I can see the oil companies being very happy with this, since you could go to a hydrogen station and dump your used pellets and "refill" with a dump of charged pellets. The station would send the used pellets to a recharging or recycling facility. I say "oil companies" because they've already got quite an infrastucture, and would probably be willing to make the investment into such facilities, since it would maintain their quasi-monopoly on automotive energy distribution.
Still, the appeal of safe hydrogen storage is great.
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If he was really up to that task, he would have posted his reply twice.
Slashdot doesn't need editors that don't take that initiative!
I saw an article earlier that talked about hydrogen pellets but they were using them to recharge laptop batteries. It could be similar technology but this article talks about how it works. http://news.uns.purdue.edu/UNS/html4ever/2005/0508 28.Varma.fuelcells.html
If he was really up to that task, he would have posted his reply twice.
Slashdot doesn't need editors that don't take that initiative!
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It's about 23 mi/gal. Of course I used the conversion factor 20oz=591mL right off my Mountain Dew bottle.
"* that is completely safe at room temperature"
Unless your city is below sea level
Those who can do. Those who can't sue.
A bit of background info found doing a quick google:
D TU_04.pdf
http://lww.kt.dtu.dk/pdf_publications/department/
Not much there but adds a bit more ligitimacy to the claims. Its a university annual report from the Technical University of Denmark, see pages 24-26.
Danish website ing.dk (run by the danish union of engineers) says in their article, that the hydrogen is store as ammonia in pellets made of seasalt. The hydrogen is released by way of a catalyst (they dont explain how or which catalyst is needed). But i suppose this means the pellets are highly reuseable. If you can read danish, theres a lot more here: http://ing.dk/article/20050907/MILJO/109090025
The pill consists of ammonia absorbed in ordinary seasalt.
The ammonia is made catalytical by combining atmospheric Hydrogen and Nitrogen.
It can be stored as long as necessary.
Only when the ammonia is passed through a catalyst the Hydrogen is released.
When the pellet is emptied, it just needs a new shot of Ammonia to be ready again.
(I believe that heating is necessary in the catalyst)
Max M - IT's Mad Science
"By comparison the post office runs several propane powered vehicles around the city here. These poor performing vehicles run on a fuel with an energy density of 7.5 kwh/liter"
Great, but how much carbon do they release into the atmosphere?
See, energy density isn't the only consideration.
Ever used so-called "bio diesel" (RME) instead of mineral-oil based diesel? Spotted a difference in consumption and gave a thought where that difference originated from?
Btw, hydrogen production is easy. We have plenty of deserts on this planet with hot sunny days, which are just perfect for all-solar powered hydrogen fabs. Just pump (even used) water there.
The problems were rather storage and transport of H2, which just doesn't like to be kept imprisoned and leaked out of the bottle. If that pellet stuff is working as advertised, that problem is solved.
That 10 liters per 100 km (23.5 MPG) is gasoline talk. US DOE wants to store hydrogen into a 50 liter (13.2 gal) tank and be able to drive 500 km (310.7 mi). What makes that challenging is the low density of hydrogen, only about 89 g/m3 (0.089 oz/ft3). High pressure tanks are either very heavy or very expensive, and chemical storage solutions always include reforming equipment or other processing steps to get hydrogen out.
Therefore, we should look at the energy content of the hydrogen stored into that 50 liter tank. With what Amminex claims, they can reach an energy content of 486 MJ (461 kBTU), versus 2150 MJ (2.0 MBTU) of 50 liters of gasoline. 486 MJ equals to 11.3 liters (3.0 gal) of gasoline equivalent. That makes 2.3 liters per 100 km (104.1 MPG!)
How is that possible? Fuel cells, electrical engines and braking energy harvesting. Fuel cells are electrochemical energy conversion devices that are free from the Carnot engine efficiency limitations, and furthermore, their efficiency increases on partial load. Operating a heat engine on partial load is detrimental to efficiency.
The aim of science is not to open the door to infinite wisdom, but to set a limit to infinite error.
-Bertolt Brecht
enabling a car to drive more than 500 km on a 50 L tank
That would be 311 miles in 13.2 gallons.
Hah! I spit on your so-called metric system.
I've found another (from June) article here (in french). For a long time people have been talking about ammonia as hydrogen storage, as it's quite high in energy density and is a relatively safe liquid. However, there are issues with gas expansion, pressurization and toxic fumes.
Essentially, these pellets are an ammonia storage system that stores ammonia nearly as efficiently (by weight and volume) as liquid ammonia. The above article says that they are relatively cheap to produce (initial costs of 1 euro/kilogram of material, which translates to roughly $12.88 USD for the energy equivalent of a gallon of gasoline). The article clearly states that the process is reversible, thus the base materials must be reusable. It does not state what the cost is of 'recharging' the pellets. The recharge cost would have to be at least 4x cheaper than production in order for it to be competitive with gasoline. The extraction technique is listed as 'desorption', which I imagine just means heating the pellets up and siphoning the extracted gas off. As for temperatures, and desorption rates, nothing is cited.
It doesn't state specifically how the reaction runs, but that ammonia is extracted from the pellets, which is then run through a standard ammonia converter (at temperatures of around 350 degrees celsius) to extract the hydrogen. It says the reaction runs quickly, so it's able to provide the hydrogen quickly enough.
The Amminex website has slightly more information available by clicking on the "ammonia storage" page, because it's the exact same technology as the hydrogen storage (link here)
I prefer the "u" in honour as it seems to be missing these days.
I got 1,100 km on my 55L tank just this weekend. What's the trick?
Diesel. Jetta. And my fuel was 30% cheaper than regular unleaded. And I filled up with 20% Bio-Diesel blend before my trip.