Slashdot Mirror


Creating Power From Wasted Heat

Roland Piquepaille writes "Today, about 90 percent of the world's electricity is created through an indirect and inefficient conversion of heat. It is estimated that two thirds of the heat used by thermoelectric converters are wasted and released. But now, researchers from the University of California at Berkeley have found a new way to convert this wasted heat into electricity by trapping organic molecules between metal nanoparticles. So far, this method of creating electricity creation is in its very early stage, but if it can scale up to mass production it may lead to a new and inexpensive source of energy."

38 of 186 comments (clear)

  1. New source of power ? by Anonymous Coward · · Score: 5, Insightful

    How is this "a new source of power" ? it's just improving efficiency by reducing loss.

    1. Re:New source of power ? by Chmcginn · · Score: 3, Insightful

      But the result would be the same as doubling the number of power plants available, once this technology (supposing it works as advertised) is installed - you'd suddenly be able to halve the number of running generators.

      --
      Have you been touched by his noodly appendage?
    2. Re:New source of power ? by Fordiman · · Score: 4, Interesting

      You're exactly right. But the common man doesn't understand 'efficiency gains' as something significant. Perceptually, people don't get how much energy is lost to waste heat.

      I mean, hell. If this works well, it could be used as a component in hybrid vehicles; they only have 25% efficiency on the gasoline engine, and if they're parallel types, the heat generated by the gasoline engine could be used to keep the electrical engine in juice.

      It might even be possible to recapture a bit of energy off the moderate heat generated in the electrical motor.

      Of course, there will be the thermodynamical morons in here, trying to say that this little device is next in the step towards the latest self-powering promise, drawing energy from the zero point or whatever other perpetual motion bollocks is being flouted these days.

      Here's a hint guys: you can't win and you can't break even. You can only take your income (solar energy) and savings (batteries, fuels, and nuclear fuels) and spend it (burning fuel or running electrical equipment). If you can boost your output per unit input, great stuff - but please don't assume it means you've hit a lotto (perpetual motion) that doesn't exist.

      --
      110100 1101000 1101000 1100110 0 1101111 1101000 1100011 1
    3. Re:New source of power ? by 0racle · · Score: 4, Funny

      Dude, this is like the next step to a self powering device. It would run forever.

      --
      "I use a Mac because I'm just better than you are."
    4. Re:New source of power ? by Fordiman · · Score: 2, Insightful

      That's if, and only if, the efficiency gain is 100% over nominal. They don't say it is.

      --
      110100 1101000 1101000 1100110 0 1101111 1101000 1100011 1
    5. Re:New source of power ? by hack++slash · · Score: 2, Informative

      It's a nice idea but the power hungry devices of today are just getting more and more power hungry so doubling the output of a standard power plant will just serve to keep the new power hungry devices running.

      Just look at at this previous SlashDot article: http://hardware.slashdot.org/article.pl?sid=07/02/ 16/196235

      --
      To do something right, you often have to roll up your sleeves and get busy.
    6. Re:New source of power ? by jbengt · · Score: 2, Insightful

      It's not a more efficient thermal cycle or a more efficient dynamo. It is a new source of power - waste heat. OK, waste heat has been used before, usually for direct heating, but not for this kind of electricity production in utility power plants.

    7. Re:New source of power ? by pudro · · Score: 2, Interesting

      Nine times out of ten, the "thermodynamical morons" are the ones shouting down the proponents of the "free" power source. The claims are not about whether perpetual motion is possible (it isn't), but whether or not we can get out more energy than we put in by tapping other power sources (anything from naturally occurring temperature differences to some sort of unknown cosmic energy).

      The people who always bring up the impossibility of perpetual motion lose the argument before it even begins, since they fail to realize that it is not a closed system (and therefore not a claim of perpetual motion). But they yell louder than anyone else, so the general populace goes on believing that the Earth is the center of the solar system.

      --
      Freedom is assumed. Then they try to take it away. The degree to which you resist is the degree to which you are free.
  2. Open that fridge! by cat_jesus · · Score: 4, Funny

    So now instead of yelling at my kids for leaving the fridge door open I'll have to get them to leave it open every now and then in order to keep the electricity bill down.

    I could really dig have a lower electricty bill in the summer rather than a higher one. When can I build a house with this stuff?

    1. Re:Open that fridge! by Wavicle · · Score: 4, Funny

      In this house, we obey the laws of thermodynamics!

      --
      Education is a better safeguard of liberty than a standing army.
      Edward Everett (1794 - 1865)
  3. generation vs consumption by mrcdeckard · · Score: 3, Insightful

    we've seen a lot of "new energy" stories on /. today, and there's been a lot of talk in the media lately, too. but NO ONE is talking about conserving energy. of course, this is an american perspective, and self-constraint is unamerican as it gets.

    who cares if we figure out, say, how to meet 10% of our energy needs with new tech when our consumption rises 10% (or more).

    a lot of "new energy" isn't really energy. as others have pointed out, hydrogen, is really just a way to transport energy.

    it occurred to me recently, that, collectively, humans are like any other organism. we cannot control ourselves from the inside (something to do with goedels theorem maybe), and thus we will overrun the planet until we choke on ourselves -- or run out of energy. so i don't worry about it too much.

    oh. whoops. depressing cold day here in st louis today.

    mr c

    --
    "Physics is like sex. Sure, it may give some practical results, but that's not why we do it." - R. Feynman
    1. Re:generation vs consumption by Doppler00 · · Score: 5, Insightful

      LED light bulbs are overrated. Compact florescent bulbs are much more efficient, but they aren't a sexy as LED's. Here's some ways to conserve, but no one will do this:

      1. No more incandescent bulbs.
      2. Live 10 minutes away from work in a condo/apartment instead of the suburbs in a giant house
      3. Stop leaving your computer on all day

      Actually, #2 is about the only one that really saves the most money. Smaller places cost less to heat/cool, and not driving as much saves a huge amount of energy.

      But, oh environmentalists are more concerned about prohibiting housing developments or zoning that actually makes sense.

    2. Re:generation vs consumption by Beryllium+Sphere(tm) · · Score: 2, Informative

      Compact fluorescents, 50-70 lumens per watt off the shelf.

      White LEDs, 30-45 lumens per watt off the shelf, 131 in the lab. And way more expensive.

      http://www.netl.doe.gov/ssl/faqs.htm
      http://www.cree.com/press/press_detail.asp?i=11508 34953712
      http://members.misty.com/don/lede.html

      Right now the reason to use LEDs is if the environment is harsh (vibrations, impacts, etc.) or if you really, really don't want to change the light often (traffic lights, or that %^#@!! bulb over my stairs). LEDs also scale down better than anything else.

  4. Not by trapping molecules actually... by drerwk · · Score: 4, Informative
    The post is misleading. FTFA

    The researchers coated two gold electrodes with molecules of benzenedithiol, dibezenedithiol or tribenzenedithiol, then heated one side to create a temperature differential. For each degree Celsius of difference, the researchers measured 8.7 microvolts of electricity for benzenedithiol, 12.9 microvolts for dibezenedithiol, and 14.2 microvolts for tribenzenedithiol. The maximum temperature differential tested was 30 degrees Celsius (54 degrees Fahrenheit).
    So the device is a thermocouple. You give is a temperature difference and it generates a small voltage. Notice that the current generated is not mentioned, so we can not even tell how much power is generated. If there is something new here it is that we have an organic Seebeck junction instead of the typical solid state junction. The article mentions your car's radiator as an example of wasted heat - no doubt - but to use that heat you need to provide, and maintain a heat differential across your 'recapture device'. Likely the device will just act as an insulator, and your radiator will no longer function. If not you will find that you need some huge fan to blow even more air past the radiator, and now the amount of energy you recover is less than that needed to drive your fan. I also think that the 30% efficiency mentioned for electricity generation is a bit on the low side. Don't hold your breath.
    1. Re:Not by trapping molecules actually... by TubeSteak · · Score: 2, Interesting

      . The article mentions your car's radiator as an example of wasted heat - no doubt - but to use that heat you need to provide, and maintain a heat differential across your 'recapture device'. Likely the device will just act as an insulator, and your radiator will no longer function. If not you will find that you need some huge fan to blow even more air past the radiator, and now the amount of energy you recover is less than that needed to drive your fan. I also think that the 30% efficiency mentioned for electricity generation is a bit on the low side. Don't hold your breath.
      Why do you have to use the radiator?

      How about sticking this thermocouple directly on the engine block/exhaust pipe/other and just add another radiator somewhere else? You know, like what they do for turbochargers or transmissions.

      It'd be nice if it helped your main radiator, but is doesn't have to. If you don't assume that, then you don't have to worry about a fan or insulation & the rest of your objections vanish.

      But in the end, I'm not sure what you'd do with the extra electricity in a car, unless we're talking electric motors.
      --
      [Fuck Beta]
      o0t!
    2. Re:Not by trapping molecules actually... by drerwk · · Score: 5, Informative

      Why do you have to use the radiator?
      I inferred from the article that one might add these devices to the radiator to recapture lost heat, and that it would be done for cars already in use. But your question is quite valid. The actual reason for a radiator in a car engine that has one, is to keep the temperature of the engine low enough so that the moving parts continue to move, that the oil lubricates, and that parts don't actually melt. If one had materials that could take the heat, say piston liners that were excellent insulators and still allowed the piston to move, and all of the excess heat simple exited the cylinder you would not need a radiator. Or if you owned a Beetle, a 2CV, or some other vehicle with an air cooled engine you would not need a radiator.
      But fundamental to thermodynamics is that you can not have a cycle more efficient than the Carnot Cycle http://en.wikipedia.org/wiki/Thermodynamic_cycle. This give a max efficiency = 1-(TEMPlow/TEMPhigh), so you always want that low temp to be as low as possible - for a car engine that would be the ambient air. If you have your device, then the hot side is on the engine, and the low side is in the air. But the device itself will get hot, an you will have to blow a lot of air on the cold side to keep it cold. It you let the whole device rise to the same temperature you get no conversion.
  5. Re:Um by Fordiman · · Score: 2, Insightful

    Well, there's no mention of current per unit (each, mol, dozen, etc) of each organic oreo, so the voltages are essentially meaningless.

    --
    110100 1101000 1101000 1100110 0 1101111 1101000 1100011 1
  6. 2nd Law by some_hoser · · Score: 2, Interesting

    I hope no one here will forget about the 2nd law of thermodynamics...

  7. Um hello. Not new. by pair-a-noyd · · Score: 2, Informative

    http://en.wikipedia.org/wiki/Thermoelectric_Effect

    Invented almost 200 years ago. I have a huge box full of Peltier "chips" sitting in my store room..

  8. Re:What? by anagama · · Score: 3, Interesting

    It's pretty easy to generate electricity from heat. I have a pottery kiln and one method of monitoring temperature is to use a thermocouple hooked up to a "pyrometer". A thermocouple is just two different kinds of metals connected. Somehow, when you apply heat, a voltage develops (I won't pretend to understand how). Now, I'm a cheapskate and because a pyrometer is nothing but voltmeter scaled for temperature, I just use a couple digital multimeters to monitor kiln temps (in the type of firing I do, the measured temperature isn't really relevant -- I'm more concerned with whether the temperature is rising or falling). I typically get 35 - 40 millivolts at my peak temperature (somewhere in excess of 2400 degrees F if I'm doing things right). The cheapo type-K thermocouples I use lose their accuracy as I approach peak temps, but no way am I spending over $200 each for platinum thermocouples.

    Anyway, my point, after reading TFA, it became pretty obvious that this stuff would work like a thermocouple, but you could fit many of them over a large area. It's isn't so much "nano-magic", as it would be a miniaturization of an idea that sees daily application. It sure would be cool if they get it functional.

    --
    What changed under Obama? Nothing Good
  9. Awesome! by nacturation · · Score: 4, Funny

    So this means global warming is a good thing. With all the electricity we'll be able to make, it's no problem to just run enough air conditions to solve the problem.

    --
    Want to improve your Karma? Instead of "Post Anonymously", try the "Post Humously" option.
    1. Re:Awesome! by nacturation · · Score: 3, Funny

      Air conditioners also sometimes make a nice "whooooosh!" sound, similar to the one just heard.

      --
      Want to improve your Karma? Instead of "Post Anonymously", try the "Post Humously" option.
  10. I wouldn't worry about the computers.... by Chmcginn · · Score: 4, Insightful

    Computers still are, and probably always will be, a fairly small fraction of electrical consumption. Yeah, data centers are all the way up to 1%... But 1% is 1%. Not a big component... Hell, I'd be more concerned about this - if we replace fossil fuel cars with electric in the next fifty years, electric power used to recharge vehicles will probably become one of the biggest fractions of the total load.

    --
    Have you been touched by his noodly appendage?
  11. Re:2nd Law? Try the 3rd law by Mr+Pippin · · Score: 2, Informative

    I think the 3rd law is more appropriate here, since they are basically talking about using the waste heat of an earlier process, and converting part of it to usable energy.

    The 2nd law just basically states that any energy conversion process cannot be 100% efficient, AKA "entropy".

    In effect, this is adding a secondary process to the first (or possibly list of processes), of which we already know some amount of energy will escape due the 2nd law.

    This additional process just makes the overall process more efficient, and does not really add to it above the original process's input energy. However, the 3rd law just states you can't achieve 0 entropy in a process with a finite number of steps. Basically, you can never have a process that is 100% energy conversion efficient.

    Probably the more important question is does the increase of enthalopy merit the proposed decrease in entropy? AKA, does the cost of implementing this solution outway the benefit.

  12. And yet... by belg4mit · · Score: 2, Interesting

    Cogeneration only wastes about 1/3 of the energy. That's not too far off from
    the Carnot efficiency of 86% for a combustion temperature of 2000 centigrade.
    And even the reamining "waste" heat could be used if better planning happened:
    district steam, drying and other industrial uses.

    --
    Were that I say, pancakes?
  13. The market didn't do a thing to help stop... by zogger · · Score: 3, Insightful

    ...water pollution. Nothing. Zero. It took serious government regulations in a lot of directions at the federal, state and local level and mass civil indignation to do that, because the "market" ALL found it cheaper-better for their "shareholder value and bottom line"- to just dump their toxic waste wherever they felt like it and to transfer health care costs to -anyplace else, downstream usually.

      Ya, maybe if we had waited say a few hundred years it might have "corrected", as the remaining few non mutants rose up finally and bumped off the remaining few mass polluters who were left, but for some reason society decided to step in with some stricter laws before it got that bad.

    I could name numerous other examples but that is an easily seen one.

    Sometimes you just can't wait for the "this quarter's profits" mentality boys to do the right thing. Some things might need to be addressed now, once they are clearly understood to either be a problem now or soon will be, as opposed to waiting around for a long time in an economic and social experiment to see what might happen. And believe it or nuts, there are more important things on this Earth than some corporation's bank balance.

    That is not to say that government can't be hugely overbearing and infested with generic mass stoopidity itself,of course it is,I speak out about government abuses all the time, but "the market" is no better really, neither extreme -leave it all to the market (caveat-emptor brand corporatism would be the extreme there) or all to the government(cult of the personality one leader-one party-mass bureaucracy and no one even wants to work any longer except under the whip"- ism government would be the extreme that other way)- is the end all or be all of "solutions". I think what we have more or less constructed- at least semi-regulated markets and at least an attempt at a semi-regulated society via this government thing-is probably the best humans can do at our (barely out of the medieval level intellectually or psychologically) evolutionary stage.

    Of the two extremes and the middle, the middle is what we mostly have and falls under the lesser of the three big evils choices. It is imperfect, absolutely no doubt there, but the best we can do right now. What we can do is to keep chipping away at the imperfections on a case by case basis.

  14. Re:What? by fabs64 · · Score: 2, Interesting

    Also, from what I read this technology still functions at very low differentials, ie 30 degrees celsius, as opposed to the hundreds that just using two metals requires.

  15. Re:Way to save energy.. by willy_me · · Score: 2, Informative

    They don't have to be efficient. The wasted heat is used in the building so there is effectively no waste. Any electricity generated is just an added bonus.

    Large thermoelectric plants are ~40% efficient. A burner heats water, the steam passes over a turbine (connected to a generator), the steam is then condensed (where all the energy is lost) and pumped back into the water tank so it can be heated again.

    My suggested idea would, most likely, use an internal combustion engine at ~25% efficiency. But even at a lower efficiency it is still more efficient then just burning gas at 0%. (Note that the efficiency ratings are for electricity production.)

    Willy

  16. Re:The point of the robot... by Oligonicella · · Score: 4, Insightful

    "But the common man doesn't understand 'efficiency gains' as something significant."

    Yeah, they insulate their houses to save on energy bills just 'cause.

  17. Good to see by darklordyoda · · Score: 2

    Good to see that some professors can both do research and teach without lacking in one or the other. Professor Majumdar's a nice guy, his heat transfer class was very well taught, really helped get me interested in heat transfer as something to elaborate on for MechE.

  18. Not a big deal by Solitonic · · Score: 4, Informative

    Unfortunately, thermoelectric converters based on the Seebeck effect are not going to help with efficiency by a large amount.

    Firstly, there is a theoretical limit (Carnot Cycle) to the efficiency of any pure heat engine based on the Second Law of Thermodynamics.

    If a quantity of heat Q is taken from a high-temperature reservoir at temperature T2, partially converted into useful work W, and the remainder (Q - W) is deposited into a low-temperature reservoir at temperature T1, then the net increase in entropy is at least

          \delta S = (Q-W)/T1 - Q/T2 >= 0.

    So the efficiency (useful work generated per unit energy input)

          e = W/Q < (T2 - T1)/T2

    The waste heat is ultimately deposited into the environment, so T1 can't be much smaller than say 300K.

    In a steam engine T2 has to be greater than the boiling point of water (at whatever pressure it is operated), but it is limited by what the materials of which it is composed can withstand. Temperatures of order 1000K are typical. That gives a maximum theoretical efficiency of around 70%. The best steam engines barely reach about half that efficiency.

    However, modern power plants (which are not pure heat engines) use a Combined Cycle that can do better by first generating electricity from their fuel with a combustion turbine and then using the waste heat from the combustion turbine to make steam to generate additional electricity via a steam turbine. Their efficiency can reach about 60% of the net calorific value of the fuel.

    So you can see that one might be able to shave a few more percentage points off the waste, but it will not at all be the godsend we really need...

    IMHO only nuclear power can fulfill that role today.

    1. Re:Not a big deal by Mafiew · · Score: 2, Insightful

      Thank you for a post that actually talks about some thermodynamic principles. Tapping into "waste" heat does seem like an attractive idea to people who do not have an understanding of thermodynamics. My understanding is that if you try to simply strap on another heat engine like a thermocouple, you're working with a very low temperature differential which means low efficiency.

      One question though. Isn't a gas turbine just another heat engine that that is governmed by the limits of any thermodynamic cycle? So would a "combined cycle" be two heat engines connected to each other? Unfortuantely my understanding of thermo is limited to one undergraduate class.

  19. "Wasted" heat is not available for this device. by jolathe · · Score: 5, Informative

    The "wasted" heat that thermal power plants reject to the surroundings is rejected at a temperature only slightly above ambient. A steam turbine generator has an exhaust steam condenser which operates at a vacuum, where the steam condenses at only a few degrees Fahrenheit above the ambient temperature. There is no significant temperature difference available for the new device to operate with. While thermal power plants do reject over half the fuel energy consumed to the surroundings, it is a myth that this rejected heat can be effectively used. The rejected heat is available at a low temperature, only slightly above ambient, therefore little effective use can be made of it. This is the penalty that the laws of thermodynamics impose on the conversion of heat into work.

    1. Re:"Wasted" heat is not available for this device. by rohar · · Score: 3, Interesting
      The analogy that helped me understand the 2nd Law of Thermodynamics was the hydroelectric dam.

      In a hydroelectric dam, you can convert a portion of the potential energy of water flowing downhill into work. You can only convert the energy when the water is flowing downhill and you cannot convert all of the energy because that would stop the water from flowing. The maximum efficiency is the head difference (high and low water points). Unless the low point of the dam is at sea level, you are not getting all of the potential energy out of the water.

      The 2nd Law of Thermodynamics and Carnot Efficiency have the same major points. You can only convert some of the heat to other work while it is moving from hot to cold and the maximum efficiency is the difference in the high and low temperatures relative to absolute zero.

      As the parent post pointed out, power stations attempt to exhaust condensation heat as close as possible to ambient temperatures and there isn't much "waste" heat to recover. If there was an efficient thermocouple device like the article, its use would be in all the industrial waste heat from sources that are currently too small to justify existing heat recovery systems.

  20. Environmentalists? by wytcld · · Score: 3, Interesting

    What's your sample to say what "oh environmentalists" are concerned with? Consider Portland, OR, where environmentalists put in zoning to pack housing into the center of town and prohibit it from sprawling farther out. (True, the anti-environmentalists lately threw a wrench into that with a misleading statewide referendum.) Or on the other side of the country, environmentalists in Vermont are also encouraging more housing in and close to traditional town centers rather than sprawling across the countryside. What is your sample set of "environmentalists" who prefer that we'd all live in suburbs in giant houses? I'd suggest that whoever you can find fitting that description just flies a flag of convenience - the evil often cloak themselves in the names of the good.

    --
    "with their freedom lost all virtue lose" - Milton
  21. Re:The point of the robot... by amRadioHed · · Score: 2, Insightful

    I think he means there is a difference between understanding it's a waste when the heat you are paying for is going out the window, there is a very direct cost. It's less likely for people to think that the heat coming out of the back of their vacuum cleaner is also wasted energy. Electrical appliances get hot when they run, right? Nothing unusual about that.

    --
    We hope your rules and wisdom choke you / Now we are one in everlasting peace
  22. Re:2nd Law? Try the 3rd law by JohnFluxx · · Score: 2, Informative

    I haven't seen anyone point out the efficency of an carnot engine (car, your fridge, etc) depends on the output end being hot (the temperature difference).

    If you cool the radiator to gain energy using this device, then you'll decrease the efficiency of the primary device.

    e.g. if you connect this to the radiator at the back of your fridge, then your fridge will be less efficient.

    I don't know whether the net gain is positive or negative though.

  23. The real story here... by Stone+Rhino · · Score: 2, Informative

    ...is that our buddy Roland Piquepaille finally posted a story that directly summarizes and links to the information instead of telling us to come to his blog for the real story.

    --


    Remember, there were no nuclear weapons before women were allowed to vote.