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Ohio Researchers Advance Heat Reclamation Technologies

Downchuck writes "Researchers at Ohio State University claim to have synthesized a new material capable of delivering electricity directly from heat, at an efficiency far better than existing thermoelectric materials. Scott at ArsTechnica has an interesting take: 'Merge this with the new MIT solar dish and you're in business!'"

37 of 124 comments (clear)

  1. Yeah, frying ants with a parabolic is cool and all by iminplaya · · Score: 5, Interesting

    But I like this better.

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  2. Finally! by Anonymous Coward · · Score: 5, Funny

    Finally, we have a truly renewable source of energy - we can just harness all the hot air coming from our politicians.

  3. Technical point by Bruce+Perens · · Score: 5, Insightful

    It's not possible to make electricity directly from heat. It is possible to make it from a difference in heat between two points.

    1. Re:Technical point by ettlz · · Score: 5, Funny

      Yes, on this site we obey the Laws of Thermodynamics!

    2. Re:Technical point by cnettel · · Score: 4, Informative

      You make electricity directly from heat. You can't make electricity directly from temperature (or stored heat) though.

    3. Re:Technical point by Anonymous Coward · · Score: 5, Informative

      It's not possible to make electricity directly from heat. It is possible to make it from a difference in heat between two points

      heat != temperature

      But you are right that you have to have a cold reservoir to get any work from the system. But heat in thermodynamics is not the same as temperature, and it generally denotes the amount of transfered thermal energy between two systems of differing temperature.

      I'm assuming that the cold reservoir is the cooler temperature air surrounding the device.

    4. Re:Technical point by cool_arrow · · Score: 2, Informative

      Yes that is true and I believe that the most efficient thermoelectric devices are somewhere in the range of about 5% efficiency in practical applications.

    5. Re:Technical point by Bruce+Perens · · Score: 2, Insightful

      Oops, I'm getting whipped for "heat in a thermodynamic sense is not the same thing as temperature". But yes, the point here is that they've invented better thermocouple wire and thus possibly an improvement in thermoelectric generation and maybe the Peltier effect. Doubling the efficiency of those things would not necessarily make them competitive with other processes for heating and cooling.

    6. Re:Technical point by Anonymous Coward · · Score: 4, Funny

      The other campaign may call it pandering, but I think the American people deserve a temporary holiday from the Laws of Thermodynamics.

    7. Re:Technical point by Doc+Ruby · · Score: 4, Informative

      But quadrupling them would. The old max zT these researchers were improving was about 0.87. They've now got it to about 1.5. And are targeting about 3.0 in their current research.

      Freon refrigerators have a zT of about 3.0. Which makes these new materials look directly competitive with them for cooling when they reach that efficiency. Since zT 1 materials are about 10% efficient, zT 3 will be able to reclaim about 30% of waste heat. That would be about 20 points of the ~60% of gasoline energy wasted as heat in car engines. Since car engines are about 20% efficient now, that would mean doubling their fuel efficiency.

      If these materials can be made, deployed, and recycled with close to (or less than) the energy inputs required now to make the car radiators/manifolds/exhaust systems they'd probably mostly replace, the benefits would be revolutionary.

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    8. Re:Technical point by Doc+Ruby · · Score: 4, Interesting

      The Technology Review article about the tech is more specific about the material's heat/electricity conversion efficiency. Evidently the current zT:0.87 material is about 6% efficient; the zT:1.5 material already achieved therefore is about 10% (about 10.3448276%) efficient. A zT:3.0 device is about 21% (about 20.6896552%) efficient.

      10% of the 60% of gasoline's energy content wasted as heat is 6% of the gasoline's energy. If the car got the average 20% fuel efficiency, that extra 6 points would be 30% more than the original 20%. A zT:3.0/21% would be 12.6 points extra, or 63% more than 20% to 32.6%.

      A 30MPG car today would get 39MPG tomorrow with the current version material. It would get 48.9MPG with the forecast zT:3 material.

      What I'm really interested in seeing is how embedding the higher zT materials inside fuelcells boost their efficiency. Because fuelcells aren't heat engines, they're not limited to the Carnot Cycle's 40% max efficiency. They already get 50% efficiency or greater at "native" voltages (like 1.48V), where their max theoretical efficiency is 83%. But still, much of their 17%+ inefficiency is generating heat. So they can be even more efficient with heat reclamation, perhaps in practice actually approaching that 83% efficiency.

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    9. Re:Technical point by Lisandro · · Score: 2, Informative

      RTGs (radioisotope thermoelectric generators) would benefit greatly from this aswell. They tend to have long life spans (in the order of the half-life of the radioactive material used), but radiation decay and thermocouple wear reduce their power output much before that.

    10. Re:Technical point by BrotherBeal · · Score: 3, Funny

      What's hard is converting the "water" into "wine"...

      So what you're saying is that Jesus can create electricity directly from heat? I'm confused...

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  4. Put that in a power plant? by 4D6963 · · Score: 3, Insightful

    Could it be used to get more power out of a nuclear power plant?

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  5. Re:For those who didn't RTFA: by magus_melchior · · Score: 5, Informative

    And since I can't make hyperlinks correctly on slashdot, I'll try again: thallium.

    Nasty stuff, as its compounds are very easily absorbed through potassium uptake pathways in your body, but behave very, very differently from potassium. I seem to remember a chemist friend telling me that if you deal with thallium, you practically need an entirely separate lab for it.

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    "We are Microsoft. You shall be assimilated. Competition is futile."
  6. Hot technology by gmuslera · · Score: 2, Interesting

    That material reach its peak at 950F (~500C). Not sure if MIT approach will worth combining with this as maybe the area needed could make electricity by other means.

    But there are a lot of areas where heat is produced, and some of this could be used to get extra electricity.

    Maybe the most important point, at what cost? how rare/expensive is that new material? If is very, maybe the main use would be not for our normal lifes, but maybe for i.e. space probes.

    1. Re:Hot technology by sokoban · · Score: 2, Informative

      Maybe the most important point, at what cost? how rare/expensive is that new material? If is very, maybe the main use would be not for our normal lifes, but maybe for i.e. space probes.

      Lead is very cheap, Tellurium is about 20 some odd dollars per pound, but Thallium is damn expensive. In the late 90's Thallium was running about $600 per pound. That said, I'm not sure how much Thallium will be needed for this application.

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    2. Re:Hot technology by im_thatoneguy · · Score: 3, Insightful

      Well we are using Platinum in extremely warm car parts as it is. So placing rare earth metals in our exhaust system isn't a far out idea in the automotive industry. ;)

  7. Geothermal plug in by SubComdTaco · · Score: 3, Interesting

    From the article: "the material is most effective between 450 and 950 Fahrenheit" So simply plug this into a geothermal source, instant energy solution until Earth's core freezes.

  8. Re:So, this is a reverse peltier? by cnettel · · Score: 3, Informative
    Any Peltier element can give you power as well. The point is that even the theoretically optimal difference is totally lousy if your heat difference is somewhere like the one between water freezing and water boiling. You need a colder cold sink, or a much hotter heat source, to get some serious efficiency. RTGs tend to be quite hot in the hot end.

    This allows better RTGs, but they would only be marginally efficient for, say, reclaiming computer case waste heat. This is especially so as you can't put them on the CPU directly, where the differential is great, because they are insulating as well. You will need to put it at the radiating end, over a large surface.

  9. Thallium by MillionthMonkey · · Score: 2, Interesting

    Thallium accumulates in your testicles. I remember hearing stories about labs handling thallium where only women were allowed.

    1. Re:Thallium by moderatorrater · · Score: 2, Funny

      Great, now I'm going to start getting spam about using thallium to enhance my testicles.

    2. Re:Thallium by value_added · · Score: 4, Funny

      Thallium accumulates in your testicles. I remember hearing stories about labs handling thallium where only women were allowed.

      Well, the article does explicitly state that "The material does all the work."

    3. Re:Thallium by Mspangler · · Score: 2, Interesting

      "I remember hearing stories about labs handling thallium where only women were allowed."

      True. While I was at the U of I my chemistry professor was trying to stick thallium atoms to a cyclopentadiene molecules for some odd reason. The students working on it were all girls.

    4. Re:Thallium by MillionthMonkey · · Score: 2, Informative

      my chemistry professor was trying to stick thallium atoms to a cyclopentadiene molecules for some odd reason.

      Usually when they stick goofy metals on organic compounds they intend for the metal to be replaced with some organic moiety. The metal guides the reaction so that the organic replacement attaches to the right carbon atom. Thallium cyclopentadiene is a starting material for prostaglandin synthesis. You add methoxymethyl chloride to it, and the methoxymethyl group replaces the thallium and you get methoxymethylcyclopentadiene plus thallium chloride.

      Benzoxymethylchloride works too if you want to start with benzoxymethylcyclopentadiene.

  10. Detailed Scientific Analysis Here by Doc+Ruby · · Score: 4, Informative

    The article at the Green Car Congress site titled New Approach to Developing Thermoelectric Materials Doubles Efficiency" has a lot more scientific details than that article linked from the summary, especially on the actual formula that determines "zT", which is the thermoelectric conversion efficiency coefficient:

    The dimensionless zT for thermoelectric materials is calculated by the formula zT= T*(S2)/), where S is the thermoelectric power or Seebeck coefficient of the TE material, and are the electrical and thermal conductivities, respectively, and T is the absolute temperature.

    And also detailed nanomaterials engineering analysis of the quantum structure of the quantum chemistry's thermoelectric effects.

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  11. The comments attached to the fine article... by Horar · · Score: 4, Informative

    ... contain a link to a possibly more useful article with some more comprehensible numbers:

    http://www.technologyreview.com/Energy/21125/

    e.g. The device could increase fuel efficiency of vehicles by approximately 10 percent.

  12. Themoelectrics Already Pretty Good by Doc+Ruby · · Score: 5, Interesting

    Even though that article linked from the summary says that typical engines in cars get about 25% of the gasoline's energy content into car motion, it's actually about 20%. That's a lot of wasted energy: about 4:1 waste:use.

    But lots of combined cycle plants (like CCGT gas turbines) reclaim a lot of their waste heat into more power. Taking a maximum mechanical power extraction of 60% of the gas' energy up to 85% by heating steam, which is an additional 25% of the original mechanical power.

    CCGT reclamation tech is probably not practical for vehicles, so this new material is a welcome advance. Especially if the researchers get the zT from its new 1.5 high to its predicted 3.0 or so. But in fact DARPA has funded Trinh Vo at Lawrence Livermore National Labs to grow nanowires that already have a zT at 3.

    More of that kind of material research is very welcome, because at zT 3, these materials can replace freon refrigerators with the same electrical efficiency. Since freon refrigerators require lots of energy to build, and then to recycle, replacing them with a simple material that can scale to any size (including very small, as in microelectronics), means a vast sector of modern industry, including transportation, could switch. If making the material is less energy intensive, and less reliant on a limited critical resource than the freon refrigerators or the CCGT reclamation systems, global energy efficiency could take a giant leap.

    A leap that could be just around the corner, in Ohio.

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    1. Re:Themoelectrics Already Pretty Good by Doc+Ruby · · Score: 3, Informative

      "A thermoelectric material designed to replace a conventional Freon-gas refrigerator must have a ZT of at least 3."

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    2. Re:Themoelectrics Already Pretty Good by Doc+Ruby · · Score: 2, Informative

      But this new material is already projecting a zT:3 as part of their current scope of R&D.

      A Technology Review article explains that in car engines, these zT jumps deliver efficiency from the old 6%, to the new 10%, looking at 21%. So it seems that this material does quite well at that hard job.

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  13. Power Efficiency Rating? by mux2000 · · Score: 2, Insightful

    What's this power efficiency rating? How much is 1.5 in God's honest Watts per Kelvin, or a simple percentage of power in/power out?

  14. I have a cheaper way by redcaboodle · · Score: 2, Funny

    Just attach a generator to the lower jaws to my husband and his mother. The energy they produce by moaning about the heat should cool the whole of Cologne for the summer.

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  15. Pity it sounds pretty poisonous by D4C5CE · · Score: 4, Insightful

    thallium-doped lead telluride

    An achievement made up of toxic elements, the first being rat poison, the last being the rarest there is. Chances are this won't be cheap to make nor to dispose of, and I wonder what hazards it would pose to the environment if released (vehicles do crash or get abandoned from time to time).

  16. Peltier devices work both ways by EmbeddedJanitor · · Score: 2, Informative

    Use power to shift heat or generate power from heat flow.

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  17. Re:For those who didn't RTFA: by mosb1000 · · Score: 2, Interesting

    It's doped with thallium, that means that the thallium is imbedded in the metal alloy. I don't think it's going anywhere.

  18. Re:What is the %Efficiency of a 1.5 zT? by florescent_beige · · Score: 2, Interesting

    z is related to the Seebeck coeff (which tells you how much voltage a given delta-temp gives you in a material), the resistivity and thermal conductivity. It is multiplied by T (the average temp at which the performance is measured) to give a non-dimensional number.

    zT doesn't tell you the efficiency because that would depend on the delta T (next para), but it is roughly proportional to it for given operating conditions. zT = 1 materials have efficiency maybe around 5% under best conditions, for zt = 3 you might be around 20%. Notice that if you know S and delta T you know the voltage: you can do some simple circuit calcs with a matched impedance and get the power it will generate. Compare that to the heat energy you get from the delta T and the thermal conductivity and you can get an efficiency, but instead of that lets just throw out some round numbers.

    Remember efficiency depends on the delta T due to the 2nd law of thermodyamics. The smaller delta T is the lower the max theoretical efficiency is. If the engine exhaust is at lets say 500F the max efficiency any device could get would be 1 - (492 + 72)/(492 + 500) = 43%. So that would be 78kW of your 180kW for a thermodynamically perfect device.

    So if you can get maybe 20% out of thermoelectrics under the best conditions, the low-temp engine exhaust scenario would probably mean you could get at best 10%. So 20kW or so I'd guess. Once you design an actual system it would probably be more like 5 or 10kW.

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  19. But how does it compare to the JTEC? by WindBourne · · Score: 2, Informative

    Johnson Thermoelectric Energy Conversion System? Seriously, this one is being developed to operate at lower temps. I wonder if this new one will work better or not? But it sure would be useful to add one (or both) of these to say power plants to absorb some of the heat and continue generating more electricity.

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