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Cloth Successfully Separates Oil From Gulf Water

Chinobi writes "Di Gao, an assistant professor at the Department of Chemical and Petroleum Engineering at the University of Pittsburgh, has developed a method of separating oil from water within just seconds using a cotton cloth coated in a chemical polymer that makes it both hydrophilic (it bonds with the hydrogen atoms in water) and oleophobic (oil-repelling), making it absolutely perfect for blocking oil and letting water pass through. Gao tested his filter successfully on Gulf Oil water and oil and has an impressive video to demonstrate the results." This is a laboratory demonstration; the technology hasn't been tested at scale.

55 of 327 comments (clear)

  1. Too late probably, but... by alfredos · · Score: 4, Insightful

    ...Unfortunately there will be a next time.

    1. Re:Too late probably, but... by Bakkster · · Score: 2, Insightful

      according to TFS you coat a common cloth with a particular chemical... sounds ready made to me.

      Easily-made is not the same as already made. How many thousands (or millions?) of square feet do you think are needed? How long do you think it would take to make that much by hand? How long do you think it would take to retool a production line to start producing it?

      I can conceivably see this being deployed while we are still dealing with the aftermath, but it is definitely too late for most of the areas that really could have benefitted from this. It will be a token contribution for this spill, nothing significant.

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    2. Re:Too late probably, but... by Sethumme · · Score: 2, Insightful

      That's the real issue. Why were there no robust contingency plans for an oil spill in place before off-shore drilling began? How were oil companies even given permission to drill before they demonstrated reliable containment and recovery plans with the necessary materials/products already stockpiled? The risk of spillage has always been a hot topic with offshore drilling. It's bullshit that solutions to the problem are only being worked on after the fact.

    3. Re:Too late probably, but... by drachenstern · · Score: 2, Interesting

      As someone else mentioned below,

      a) it takes days to make chemicals, especially when a small lab can whip some up for a demo in days...

      b) it takes days to make hundreds of thousands of square yards of cloth

      c) it takes apparently a month for BP to get serious about saving the Gulf with any kind of straight face

      d) yes, there are no existing stockpiles of this cloth, nobody needed it before now, and had rig management listened to the crews on the rig and designers back home and had they followed safety protocol, none of this would have happened, as evidenced by the testimony that has come out so far.

      So, what were you saying? None exists "right now" in quantity? Could we have some tomorrow? Will the oil still be causing a problem tomorrow? Could this save most of Florida from having the same problems as LA? How is it too late to start saving the coast? Because we can't save all of it?

      I think you're too worried about the damage that has been done, and not looking to contain the further damage that will be done. I'm furious about both, but only one can be prevented, the other must be saved. This won't save the damaged coast, it'll prevent more coast from being hit.

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    4. Re:Too late probably, but... by Bemopolis · · Score: 3, Insightful

      How were oil companies even given permission to drill before they demonstrated reliable containment and recovery plans with the necessary materials/products already stockpiled?

      I'm shocked too — especially considering the last administration was literally packed with members of the oil and gas industry! Hmmm, waitasec...

      --
      "I guess the moral of the story is, don't paint your airship with rocket fuel." -- Addison Bain
    5. Re:Too late probably, but... by Anonymous+Struct · · Score: 2, Informative

      How big is the biggest oil spill we should be prepared to contain? Keep in mind that the bigger the thing gets, the more ships and people you need, and it's not the kind of problem that increases linearly in resources required. On top of that, keep in mind that it costs money to be prepared for that great big oil spill every single day, even when it's been thousands and thousands of days since the last oil spill. I'm not really surprised that a line was drawn at a relatively conservative size.

      It's just like when I get in my car every morning and buckle my seat belt. I'm hoping another car doesn't run into me, and if it does, I'm hoping my seat belt is enough of a precaution to keep me alive. I *could* install a roll cage, but I don't. And that's my life I'm gambling, too. Compared to that, this oil spill is small potatoes.

  2. Doing in a lab is one thing by gyrogeerloose · · Score: 3, Insightful

    Doing it on a massive scale in the Gulf of Mexico is something else entirely.

    While this might prove useful in future spills, it would seem to me to be very unlikely that it could be brought up to scale fast enough to help with the current problem

    --
    This ain't rocket surgery.
    1. Re:Doing in a lab is one thing by pianoman113 · · Score: 5, Insightful

      9 years ago, a great deal of military technology went from lab to massive scale rather quickly for new bombs to wreak havoc in cave strongholds. Why is BP or some other interested party with deep pockets unable to do the same here?

      We have an existing crisis and a potential solution. Somebody pony up the cash and start producing this. Its a risk, but if effective there is a great deal of profit to be made in the event of another oil spill.

      Calling any entrepreneurs...

      --

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    2. Re:Doing in a lab is one thing by aplusjimages · · Score: 5, Insightful

      Clean up is going to take years, so there's time.

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      Can I bum a sig?
    3. Re:Doing in a lab is one thing by schon · · Score: 3, Insightful

      a great deal of military technology went from lab to massive scale rather quickly for new bombs to wreak havoc in cave strongholds. Why is BP or some other interested party with deep pockets unable to do the same here?

      Because there's no money in cleaning it up, and a lot of expense.

      We have an existing crisis and a potential solution. Somebody pony up the cash and start producing this. Its a risk, but if effective there is a great deal of profit to be made in the event of another oil spill.

      Therein lies the problem. BP estimated the likelihood of the current spill as "so close to zero that it doesn't matter". Ask any oil company what the chances are of another spill, and you'll get "so close to zero that it doesn't matter." So why should they spend all this money on something that will never happen?

      Environmental issues are externalities - and it would be socialism to force companies to deal with externalities. After all, we're all responsible for the Gulf spill, because of our demand for oil. And anyway, if you tried to enact a law, they would just shut down and open up under a different name. Let the invisible market fairy handle this, she will make it all go away!

    4. Re:Doing in a lab is one thing by interkin3tic · · Score: 2, Informative

      Worth pointing out that the safety valve that was supposed to prevent this thing, all the plans to stop the flow at the source, and all the dispersants being used to reduce the effects of the oil... all those had never been properly tested either. I think the safety valve had been tested at half the depth it was being used at? So if we make sure it's not going to do any -harm- then we're at least -improving-, even if we don't test efficiency first before we deploy it.

  3. Great for filtering, but - by Brett+Buck · · Score: 2, Insightful

    I would think what you want for an oil cleanup is a material that is oleophilic but hydrophobic,IOW, just the opposite. Dip it in the water, oil sticks, pull it out, oil stays in, water rolls off. Squeeze the oil out into an appropriate receptacle, repeat.

    1. Re:Great for filtering, but - by Anonymous Coward · · Score: 3, Informative

      How do you clean and reuse your cloth? This guy: just pour the oil off the cloth and repeat. Yours only allows for a small amount to be collected before some kind of complicated rinse has to be done.

    2. Re:Great for filtering, but - by dmatos · · Score: 4, Insightful

      You could potentially use big trawling nets of this stuff to sieve the oil out of the gulf, just like fishermen use trawling nets to sieve fish out of the water. Scoop up a big bucket of oil+water, wait for the water to drain out, then pour the oil into a reservoir on the boat. Repeat.

      --

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    3. Re:Great for filtering, but - by DoofusOfDeath · · Score: 4, Insightful

      I would think what you want for an oil cleanup is a material that is oleophilic but hydrophobic,IOW, just the opposite.

      It's probably the difference between having a mop (your proposal) and a strainer (his creation). Depending on a variety of factors either one might be preferable for cleanup.

    4. Re:Great for filtering, but - by AdmiralXyz · · Score: 3, Insightful

      With this (assuming it works at scale) you can "push" the oil to where you want it to go, meaning that if they deployed large ones on the surface they could gradually "herd" all the oil into one place to be siphoned off... or rather, they could, if BP hadn't injected all those dispersants making it end up god-knows-where.

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    5. Re:Great for filtering, but - by Orange+Crush · · Score: 2, Insightful

      But filtering is probably the behavior you want. Much of the gulf spill is a microns-thick rainbow-colored sheen on the surface of the water, and there's really no way to clean that up or burn it off beyond letting nature take its course. If you can run a bunch of supertankers around the oil slick Roomba style, they could pump large volumes of oil and seawater through filters like these, dump the clean water and hold on to the oil. If the filters work well enough, it might be possible to circle the whole slick and keep it confined away from shore.

    6. Re:Great for filtering, but - by Khashishi · · Score: 2, Informative

      like, perhaps hair?

    7. Re:Great for filtering, but - by Khashishi · · Score: 2, Interesting

      What does this mean for all the sea life that gets pulled into these trawling nets?

    8. Re:Great for filtering, but - by badboy_tw2002 · · Score: 5, Funny

      Prepped and ready for deep frying?

    9. Re:Great for filtering, but - by wonkavader · · Score: 4, Interesting

      Here's a very unpleasant answer:

      Shrimp, fish, squid, etc -- If they were in the oily water, they were dead anyway. They "breath" by pulling that water through gills or similar arrangements. Such surfaces will be clogged with oil and the animals will die.

      Mammals and birds have a better chance, and it seems like a skimmer like this gets them into the boat and gives rescuers a chance to wash them. They're probably better off in the boat than out of it.

    10. Re:Great for filtering, but - by wonkavader · · Score: 2, Interesting

      Actually, some sort of pumping system with this as part of a centrifuge should work well. The pipe goes into a spinning section of rigid membrane pipe. The oil gets spinning in the pipe. Water spins out, since it passes through the membrane, and oil stays in the pipe. The oil keeps going wherever it's being pumped to. This solves several problems, such as waiting for the water to slowly sink out, the cranes and manual labor involved in lifting and draining, etc.

      That is, if there are pumps that work well with oily water... There must be, right?

    11. Re:Great for filtering, but - by AvitarX · · Score: 2, Informative

      The Dutch (I believe it was) have ships that do something similar (I don't know the specifics actually, but they suck in oil and water, and spit out water).

      They were not used as it is illegal to dump the water back if it is contaminated, and the ships are not perfect.

      Miraculously, I don't appear to be totally full of shit:
      http://www.rnw.nl/english/article/dutch-oil-spill-response-team-standby-us-oil-disaster

      Laws against half-assed cleanup have an un-intended consequence. I wonder if honest reports of the actual amount leaking could have gotten these in quicker.

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    12. Re:Great for filtering, but - by winomonkey · · Score: 4, Informative

      I am speaking as the son of a commercial fisherman who still typically takes some vacation time from the office life to work the black cod fishery here in Alaska, and as a person who has gone through the SERV's training to get my HAZWOPER Tier 1 certification (basically, taught how to do crude recovery on open water and near-shore operations). I have spent time both in the class and on the water drilling emergency response up here.

      One of the things discussed during our breaks was that the survival rate of rescued birds and mammals was somewhere around 10% during the Exxon disaster. That does not include all of the wildlife that was missed ... these were the lucky ones. Not to say that saving 10% of the recovered birds (at a very high individual cost) is a bad thing, mind you.

      Perhaps the best quote of the day on this topic basically boiled down to "pictures of people scrubbing ducks is just good PR."

      The whole process of what you described as "skimming" (which is very different in the recovery lingo - means using a floating pump system to recover oil, not dragging stuff through the water) would likely kill all animals that were captured. Critters would be submerged within a cloth net of oil and gunk. Regular trawling is damaging enough to them ... surface trawling with this would only make it that much worse. That said, it would be a great way to do animal body recovery, getting the toxin-laden animals out of the food system and away from the scavengers that would eat their remains.

    13. Re:Great for filtering, but - by MartinSchou · · Score: 2, Interesting

      Yeah, I was looking at that site when I was pondering the question myself, but as they say themselves - they have no long term survival rates.

      It's not that I don't want to see those creatures being put back in the wild. It's just that if they're going to die from after effects "immediately" after being released (i.e. if they get eaten, die of old age or regular stuff, it doesn't count), it's not only cruel to stress these animals by putting them through the cleaning procedure, it's also a huge waste of resources.

      They themselves say upwards of 300 gallons to clean 1 pelican. The average American uses 8,000 gallons a year. That's a LOT. And how clean is clean? Is it 'no more polluted than the average sea bird in areas unaffected by the spill' or is it 'we can't see any more oil on it', which might just be a cosmetic effect.

      And do they really need to clean ALL the animals they find? Why do they clean sea gulls? Sea gulls are plentiful and aren't even close to getting on the endangered list. Seems more humane and a better use of resources to euthanize them. Pelicans are close to being endangered, to there it might make sense to keep them alive.

      I realise that a lot of people feel better if we clean the animals and send them off, but unless we have data on their survival rates afterwards, it's essentially just like security theatre. Just a show being put on to make us feel good.

      Like when we're feeding ducks and other birds at the ponds and lakes. It feels good and gets us closer to nature. Never mind the fact that there's enough food in the pond for the ducks. Or were ... until we started polluting it with all the left over bread, leading to a huge bloom in algae growth and less food for the ducks. But the ducks keep coming back, because we feed them. So we get more and more ducks. Too many in that area, so now they end up raping and often times drowning the female ducks during mating season. But hey - we sure do feel good about feeding the birds, don't we?

      People are idiots.

    14. Re:Great for filtering, but - by brentonboy · · Score: 2, Interesting

      Mammals and birds have a better chance, and it seems like a skimmer like this gets them into the boat and gives rescuers a chance to wash them. They're probably better off in the boat than out of it.

      I'm not entirely sure - for two reasons:

      1) Nets are huge. If you get dragged into one, even one that floats on top, and more and more oil is dumped onto you, I think you're going to die unless you're the last thing to get dragged in
      2) I'm rather curious about the survival rate of birds, mammals, turtles etc., after they have been cleaned. It might look really nice, that you start with an oil covered pelican and end up with a shiny white and clean pelican, but if it dies a week after you set it free, because it's swallowed too much oil, infections or whatever, that doesn't bode well for the creature. Might be more humane to kill it instead of cleaning it off.

      Yeah, once the oil is on the birds, they'll likely die.

  4. But we don't want a fix! by BenEnglishAtHome · · Score: 5, Funny

    If it's fixed, we won't be able to get rich quick turning tarballs into, basically, gold!

    1. Re:But we don't want a fix! by dward90 · · Score: 2, Funny

      Don't joke about the tarball burner. It's totally legit. It's even PATENTED.

      --
      My other sig is clever.
  5. Nothing new here by Tisha_AH · · Score: 2, Informative

    I worked in the oil industry in the 80's and 90's (for Amoco coincidentally) and we had adsorbent spill control diapers and booms that we could run through a ringer to extract the oil. Every facility had a stockpile of these things.

    I took an oil spill control class in Pueblo Co one year and we trained on boom deployment, oil recovery and cleanup. This was one of the tools we had available to us.

    Now maybe the hype is that these new products are made of treated cotton (sounds nice and eco-friendly). Once anything picks up oil it is not so eco-friendly and just becomes another piece of hazardous waste.

    --
    Tisha Hayes
    1. Re:Nothing new here by Tisha_AH · · Score: 4, Informative
      --
      Tisha Hayes
    2. Re:Nothing new here by Bakkster · · Score: 5, Informative

      You have it backwards. Booms and diapers absorb the oil, this cloth does not absorb oil. It does the opposite, allowing water to pass through while the oil pools on top or in front.

      In other words, booms and diapers act like sponges, while this cloth acts like a filter.

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  6. Re:Awesome by Gothmolly · · Score: 2, Insightful

    You're right - because someone came up with an elegant, no-moving-parts, no-training-needed design to clean the seawater, but it doesn't clean up the marshlands, it's useless.

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  7. A net? by brianleb321 · · Score: 2, Insightful

    Is there a reason this wouldn't act like a giant net and trap life forms in what they intend to be pure crude oil?

    Won't somebody think of the childr... I mean, won't somebody think of the dolphins?

    --
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    1. Re:A net? by bugs2squash · · Score: 4, Funny

      Those life forms will be considered crude oil eventually. This just speeds up the classification process.

      --
      Nullius in verba
  8. Hmmm,maybe a wide conveyor belt thing. by GarryFre · · Score: 2, Interesting

    I didn't mention this before because I figured there was a problem with this but it occurred to me if they had a set of wide rollers they could attach rugs or such to a wide belt of some sort that could be attached to the front of a ship and the belt would rotate out into the water, collecting oil and pass through a couple rollers that would squeeze most of the oil out, and that part would pass back into the water to lap up more oil. The oil collected could then be processed and used. I figure I might as well mention it now, though I have doubts it would really work, but who knows. I don't.

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  9. Bigger? by warchildx · · Score: 4, Interesting
    I wouldn't want to pour the entire gulf of mexico worth of water through that small glass jar. reminds me of those pur water filters, where you pour some water in, and have to wait for it to *seep* through the filter material before you can put more in.

    Maybe something more along the lines of this: http://www.youtube.com/watch?v=-W8_GpMz9nI

    1. Re:Bigger? by MartinSchou · · Score: 2, Funny

      No, the idea he has, is that the entire gulf of Mexico is filtered through a 30 cm^2 cloth, because, obviously, this process does not scale in any way, shape or form.

  10. So, if the floating oil is considered salvage... by gestalt_n_pepper · · Score: 3, Interesting

    Then theoretically, any enterprising shrimp boat captain with this filter and a floating storage tank could sop up the stuff and sell it at spot price to a competitor of BP (Insert evil grin here).

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  11. Good point by Benfea · · Score: 2, Interesting

    As has been noted by many before, coagulants would have been a better idea for cleanup, but dispersants proved to be more important to the task of making the oil slick look smaller in all those satellite photos. What's more important? Cleaning up this stuff, or reducing the PR damage to BP?

    1. Re:Good point by tristanreid · · Score: 2, Informative

      When oil droplets are small enough, they're eaten by naturally-occuring bacteria. That's the main reason for dispersants.

      That's also the reason that naturally-occuring oil seeps don't pose a threat to wildlife, because in a seep the oil comes out slowly and spread out, rather than shooting out in a massive non-stop plume.

      I don't put it past BP to have the ulterior motive you're describing, but there's not enough evidence to convict on this particular charge (so to speak).

      -t.

  12. ShamWow! by jdfox · · Score: 2, Funny

    That is all.

  13. Too fine to work by Bicx · · Score: 2, Insightful

    It seems like this would be fine on a small scale, but pulling a large sheet of this stuff through moving ocean water would probably turn out to be extremely difficult. First, the tensile strength of the fabric would probably not be strong enough to withstand currents or other movement without a lot of bracing. Secondly, exposing it to a large quantity of oil would probably overwhelm the staining ability, causing the fabric to be "clogged," not only hampering the filtering properties but also increasing drag quite a bit.

  14. Re:Well, just you just keep on driving by tsalmark · · Score: 2, Informative

    Deepwater Horizon drilled a hole under 5000 feet of water. The depth of the drill hole through bedrock is 30,000 feet. While the bole hole is a feat, the trouble capping the well is more related to the depth of the water above the well not the depth of the well itself.

  15. Cleaner Water? by Tomahawk · · Score: 2, Interesting

    Was is just me, or does it appear that the water the came out was cleaner than the water be used (before mixing it with the oil)?

    Would this be a valid way of cleaning up other (non-oil) polluted water supplies?
    (repost - wasn't logged in... :( )

  16. Market solution by z4ce · · Score: 3, Interesting

    I wonder why BP doesn't offer a bounty for the leaking oil. $500/bbl. My guess if you did that, you'd see an awful lot of creative ways to retrieve that oil.

  17. Re:Well, just you just keep on driving by Vancorps · · Score: 5, Informative

    Wow... simply wow... Ixtoc 1 would beg to differ. That was in 160 feet of water and it took them 9 months to cap it. I know you wanna blame the liberal environmentalists but that is simply not the reason oil is being moved offshore. You ever wonder why the current rig we are dealing with is licensed in a foreign country? The Marshal Islands is home-base for the revenue which is conveniently not taxed.

    Given that Ixtoc 1 happened 30 years ago and they are using the same exact techniques to deal with it I have zero faith that it would have been resolved by now if this spill were in 500 feet or less of water.

    It's amazing the depths of rationalization going on in BPs favor. They have a history of bad behavior and somehow you come to the conclusion that it's the environmentalists forcing them to take risks? Just four years ago BP was shown to be negligent in many of the same ways. It appears little has changed from what should have been a dramatic wake-up call. Regulations for offshore drilling exist for a reason and it's not to make drilling near shore expensive.

  18. Hmm, seen that somewhere by bomek · · Score: 2, Interesting

    This technology seem to be a ripoff of that canadian invention: http://www.sumobrain.com/patents/wipo/Process-absorption-organic-pollutants/WO1990009414.html

  19. Re:Well, just you just keep on driving by Jawnn · · Score: 2, Interesting

    The easy oil is gone, they're having to drill in 5000 feet of water now, so of course there will be a next time.

    No, the "easy" oil is there in nice, safe, relatively shallow water where leaks/spills etc would be comparatively trivial to deal with, but environmental interests have forced rigs further and further offshore

    [citation needed...]

    This ought to be good...

  20. Re:Awesome by hesiod · · Score: 2, Funny

    I'm craving Primanti Brothers right now.

    Whether or not they know it, everyone does. Always.

  21. Re:Well, just you just keep on driving by pluther · · Score: 3, Insightful

    Yay!!

    I knew somebody would figure out a way of making this the "liberals" fault!

    All hail the mighty Spin!

    --
    If the masses can keep you down, you're not the Ubermensch.
  22. Re:Awesome by Anonymous Coward · · Score: 2, Interesting

    Now how about we figure out a way to clean up the marshes that got fucked with an oil-slicked spiked baseball bat?

    aquadam.net
    I work for them, we're trying everything to get noticed, but it seems like the responses we get (less than 10%) are "Talk to BP". I don't know what kind of deal they've got going, but if they don't do something quick, all the wetlands in that area will be fucked.

    Blah blah, anything I say does not represent my employer blah blah
    but seriously, I love nature and hate what is happening here.

  23. Re:Well, just you just keep on driving by SystemicPlural · · Score: 3, Interesting

    Wrong. They would be drilling in both.

  24. Re:Well, just you just keep on driving by UnknowingFool · · Score: 2, Insightful

    No, the "easy" oil is there in nice, safe, relatively shallow water where leaks/spills etc would be comparatively trivial to deal with, but environmental interests have forced rigs further and further offshore in an attempt to effectively halt/limit offshore oil drilling by making it too expensive & difficult for the oil companies, while being able to claim they're not trying to stop offshore drilling, just being good stewards of the planet.

    And what is the source of your information? From my friends in the oil industry, all the "easy" oil is gone. And by "easy" there are a number of different factors.

    Location is only factor. Extraction difficulty is another. Canada is sitting on the largest oil sands in the world at a possible of 1.7 trillion barrels. The problem is all that oil is suspended in sandy soil. The cost of separating the oil from the sands is very expensive. The other downside is extracting this oil requires destroying the land.

    Another factor are impurities once you get the liquid. Sulfur makes the oil "sour" and combines with water to make sulfuric acid corroding any equipment. Processing sour crude is more expensive than sweet crude. Unfortunately, all the sweet crude is gone. And that's just one impurity.

    One of my friends was working on a well that which had 30% H2S gas in the well. 30 years ago, they would have plugged that well and moved on but right now they have no choice.

    So, rather than having a shallow-water rig where any leak or blowout can be swiftly, safely, and effectively dealt with, we have the current situation. I'm sure the wildlife that has and will die, along with the fishing and tourist industries, appreciates the intentions, just maybe not the outcome so much.

    Please have a source for your outrage otherwise it would appear to be merely ravings.

    --
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  25. Re:Well, just you just keep on driving by Vancorps · · Score: 2, Interesting

    It's people like you that lead to lakes dying or even catching on fire. Just because we need a commodity doesn't mean the provider gets to bend us over a barrel and rape our environment. If oil companies didn't show such blatant disregard for the environment I would actually support drilling for oil in ANWR as I think it would stabilize a lot of political pressure in the middle east.

    I don't agree with the method AC used to reply I understand where that frustration comes from since no one seems to be doing anything to control the oil industry out of fear of reprisal. With corporate entities wielding such level of control something really does need to change like a nationalized drilling of ANWR. I don't really like that idea but it does seem better than giving the contract to BP who has twice shown what can be viewed as criminal negligence in four years or Shell who spills the equivalent of an Exxon Valdez oil spill every year. There aren't a lot of good options but I wouldn't rule out one of the much smaller oil companies that have a better track record.