Artificial Leaf Could Provide Cheap Energy
sciencehabit was one of several readers to tip news of a sunlight-harvesting artificial leaf, writing:
"Nearly all the energy we use on this planet starts out as sunlight that plants use to knit chemical bonds. Now, for the first time, researchers at the Massachusetts Institute of Technology have created a potentially cheap, practical artificial leaf that does much the same thing—providing a vast source of energy that's easy to tap. The new device is a silicon wafer about the shape and size of a playing card coated on either side with two different catalysts. The silicon absorbs sunlight and passes that energy to the catalysts to split water into molecules of hydrogen and oxygen. Hydrogen is a fuel that can be either burned or used in a fuel cell to create electricity, reforming water in either case. This means that in theory, anyone with access to water can use it to create a cheap, clean, and available source of fuel."
At last, true vaporware!
"Have you ever thought about just turning off the TV, sitting down with your politician, and hitting them?"
There's only so much insolation to harvest. If this is cheaper and higher efficiency than existing solar cells, then great. Based on the article, it's only 5.5% efficient, so meh. But even if it were 100% efficient, it's not some magical free energy machine, and never can be. While it's true that "nearly all the energy we use on this planet starts out as sunlight", a lot of that energy arrived at earth several millenia ago. In the long run, we're going to need to either use less energy (preferably by making things more efficient, not making do with fewer things) and/or get some near-unlimited fuel source, like fusion.
Ooo, 5.5%. And it's *potentially* cheap!
Get excited.
Read comments.
Excitement crushed.
San Francisco Photographers
I saw a presentation on exactly this technology a few years ago at a conference, not from an MIT researcher. It's a strange phenomena, but within science MIT is just one of many research institutions doing great work, but to the public it has the most significant and frequent press releases. I mean, this isn't even a leaf, it's a silicon wafer which happens to be green and splitting water using catalysts is very old. The only innovation I'm seeing here is a new catalyst, which is pretty common in these fields. I also like the token quote from Bob Grubbs who won a Nobel prize in catalyst research and thus is interviewed in every catalyst article.
Plus as some one who lives in Georgia I can tell you that is is hot! A solar shade for the state might work well!
According to a similar article in science daily http://www.sciencedaily.com/releases/2011/03/110327191042.htm it is 10x more efficient than (natural) photosynthesis.
I'm amazed that the foundation of life on earth is so inefficient (one tenth of 5.5% is only .55%!). Is this right? If it is then I'm glad our solar devices may not have to cover up too much of our planet to generate the energy we need (but if we ever develop solar powered self-replicating nano-bots, they will totally out-compete the natural biosphere).
Also, if this is true, then isn't this a major reason against using biofuels? I mean in addition to this inefficiency of photosynthesis, you've still got to convert it into some sort of fuel (but I guess the same is true of this artificial leaf; hydrogen is not the most practical of fuels). I guess maybe biofuels are still in the running because they can be "manufactured" very cheaply (farming and fermentation) with thousands of years of technology developed. (Or maybe it is the politics of the farming lobby).
(I'm also amazed that they used water from the Charles river in Boston and that it still worked. I remember a time when an accidental dunking in the none-too-clean river meant a quick trip to the doctor's office for shots!)
According to wikipedia, http://en.wikipedia.org/wiki/Electrolysis_of_water , traditional electrolysis is 50-80% efficient, and solar cells are ~20%.
http://en.wikipedia.org/wiki/Solar_cell_efficiency
Therefore, the efficiency of using the solar panel to power electrolysis would be .2*.5 -> .2*.8 = 10% -> 16%, wouldn't it?
So, unless there's a pretty substantial price benefit to the cell, where's the benefit?
Before we get too excited, apparently most of his research to date has been with cobalt, phosporus, tungstun and rhodium. Not sure where all this stuff comes from, but hopefully it is widespread enough won't turn into another middle east problem.
Also, at 5.5% efficiency, we would probably need quite a bit of this stuff which may cause some environmental issues by itself (mining, industrial polution, etc).
As a side note, many people talk about cutting back on petrol consumption as doing our part to reduce the demand for oil which comes from the problematic middle east, but I rarely hear of folks cutting back on electronics "toy" consumption to reduce the demand for coltan (the ore where much of the tantalum for capacitors comes from) which is causing huge problems for countries like the republic of congo. Haven't heard much about the coltan topic on /. Just be cause it's "electronic" and doesn't use oil doesn't mean it's better when scaled to industrial quantitites.
Not saying this proposed "artificial leaf" technology could definitly cause this kind of natural resource scarcity/extraction problem, but the sad fact is that if this becomes industrialized, it may not be much better than what we have today and most folks aren't even aware of the problems we have today (or even care).
When you start talking about that scale, even solar is no longer free. All that sun, hitting the land or the sea, you don't think that energy is otherwise "wasted" or destroyed? It goes to heat the earth. If you capture it with solar panels or other methods, that energy never gets where it was going.
I don't have any good idea what the impact of that is, but you can't just discount it as "free".
I work for the Department of Redundancy Department.
There is not an energy production problem there is an energy storage problem. Almost all green sources of energy have have down times. In the case of solar energy that is night. If we could store some of the energy produced in the day we would be much further ahead. There is some research and a few test being done but energy storage is not as "sexy" as energy production.
A space elevator changes everything, but until then given the astronomical cost of getting anything into orbit it would be cheaper to just build a much bigger solar array with batteries on earth.
Photosynthesis in sugar cane is 7%-8% efficient and compared to this is practically free (needs water and land, but so does this). The stuff manufactures itself for crying out loud, we don't even have to invent nanomachines to construct it for us.
The whole point of photovoltaic panels is that they convert the sunlight directly into electricity for our applications which need electricity. If instead you're going to convert the sunlight into a hydrogen-based fuel like this device, just plant some vegetation and convert its cellulose into alcohol-based biofuel and burn that instead. It's a helluva lot cheaper. The fuel is liquid at room temperature and 1 atmosphere, so is a helluva lot easier to store, transport, and handle than pure hydrogen. And even though burning alcohol fuels releases carbon, it's still carbon neutral since making it consumes the exact same amount of carbon from CO2.
Unless you're in a weight-sensitive application like the space program, or they can get this thing's efficiency up to about 20%-40%, I don't see what the big deal is. Biofuels are much more practical than hydrogen for most applications.
That's why people buy the idea that the coating was what actually exploded.
Computers are useless. They can only give you answers.
-- Pablo Picasso
For solar power to work and be economically viable, it needs to be in orbit. Period. No solar cell, no matter how efficient is going to be viable under an atmosphere.
You have it exactly backwards. Ground based solar power is economically viable now in many places, and will become more so as solar panel prices decrease, and the cost of non-renewable competition increases.
Space-based solar power, OTOH, is a non-starter because the cost of launching solar panels into orbit is so much that you'd get a much better return on your investment leaving the solar panels on the ground. It doesn't matter how efficient the solar panels can be in orbit if it's impractical to get them there.
A space elevator would change all of that, of course, and it would be all kinds of awesome.... but I wouldn't hold my breath on one being put up any time soon.
I don't care if it's 90,000 hectares. That lake was not my doing.
Yes, but you then have to convert the sugar cane to something else (ethanol for example). So you have to look at how much energy you get out of the ethanol you get after you convert the sugar cane which you created with 7-8% efficiency.
I suspect that if you are converting directly to a usable energy source at around 5% it would be fairly competitive and may require less steps (capture hydrogen, compress and store, versus grow sugar, harvest, then truck somewhere to a chemical plant to covert to alcohol etc etc.)
...in the wilderness for toiletries, the results could be shocking.